CN103975966A - Titanium oxynitride/iron chloride composite powdery blue-green algae processing agent and preparation method - Google Patents
Titanium oxynitride/iron chloride composite powdery blue-green algae processing agent and preparation method Download PDFInfo
- Publication number
- CN103975966A CN103975966A CN201410166769.0A CN201410166769A CN103975966A CN 103975966 A CN103975966 A CN 103975966A CN 201410166769 A CN201410166769 A CN 201410166769A CN 103975966 A CN103975966 A CN 103975966A
- Authority
- CN
- China
- Prior art keywords
- parts
- iron chloride
- green algae
- blue
- minute
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a titanium oxynitride/iron chloride composite powdery blue-green algae processing agent, which is characterized by comprising the following raw materials by weight: 30-35 parts of polymeric iron oxide, 17-19 parts of maleate, 20-25 parts of iron chloride, 19-21 parts of titanium oxynitride, 18-22 parts of calcium chloride, 17-24 parts of sodium alginate, 20-24 parts of powdered steatile, 19-21 parts of diatom, 1-3 parts of cyrtomium rhizome, 2-4 parts of rhizoma smilacis glabrae, 2-5 parts of Chinese pulsatilla root and 3-6 parts of scutellaria baicalensis. The titanium oxynitride/iron chloride composite powdery blue-green algae processing agent has the advantages of high efficiency and low cost, and is suitable for various scales application. The powdery blue-green algae processing agent has the advantages of multi-function and high efficiency, the powder is convenient for storage, package and transport of the product, thereby the comprehensive cost of the product is reduced.
Description
Technical field
The present invention relates to water-treatment technology field, be specifically related to a kind of titanium oxynitrides/iron chloride composite powder blue-green algae inorganic agent and preparation method thereof.
Background technology
In recent years, along with the continuous increase of China's size of population and developing rapidly of industrial and agricultural production, water requirement rapidly increases, and water pollutes more and more serious simultaneously.It is that world today's pollution is the most serious that water pollutes, one of pollution of harmfulness maximum, China's quantity of wastewater effluent is large, cause the pollutant in the rivers and lakes water bodys such as Taihu Lake to grow with each passing day, pollution speed has surpassed the detergent power of lake body self, some of them are phosphorous, a large amount of discharges of nitrogen-containing compound, accelerated rivers and lakes eutrophication process, cause the particularly abnormal breeding growth of blue-green algae of algae, and at the water surface, to form one deck blue-green and have the offscum of stench taste be wawter bloom, discharge stench, water quality is degenerated.Large-scale blue algae bloom, is called as " green tide ", exhausts water oxygen gas and cause the death of fish when serious.More seriously, in blue-green algae, some kind (as Microcystis aeruginosa) also can produce Microcystin (microcystins is called for short MCs), in about 50% green tide, contains a large amount of MCs.MCs, except directly fish, people and animals being produced murder by poisoning, is also the major incentive of liver cancer.
It is a complicated system engineering that blue-green algae is administered engineering.The main method of taking at present still outside a large amount of manpower and materials of environmental input draw the mode that dirt removal clearly, resettlement contaminating enterprises etc. are transferred the pollution, not contaminated solution root; Aspect interior environmental improvement, the method and the inorganic agent that although domestic, have in succession occurred bioanalysis (comprising microbial method, animal law, plant method), all kinds of improvement blue-green algaes of chemical method, but be still difficult to so far obtain extensively, effectively application, main cause is that existing improvement technology is single, process is complicated, functional not high.
Summary of the invention
Object of the present invention is just to provide a kind of titanium oxynitrides/iron chloride composite powder blue-green algae inorganic agent and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of titanium oxynitrides/iron chloride composite powder blue-green algae inorganic agent, it is characterized in that, by the raw material of following weight portion, made: polymerization oxidation iron 30-35, maleic acid 17-19, iron chloride 20-25, titanium oxynitrides 19-21, calcium chloride 18-22, sodium alginate 17-24, talcum powder 20-24, diatom 19-21, rhizome of cyrtomium 1-3, smilax 2-4, Chinese pulsatilla 2-5, root of large-flowered skullcap 3-6.
The preparation method of described a kind of titanium oxynitrides/iron chloride composite powder blue-green algae inorganic agent, is characterized in that comprising the following steps:
(1) diatom, rhizome of cyrtomium, smilax, the Chinese pulsatilla, the root of large-flowered skullcap decocted together in water 2-3 hour and filter, getting its filtrate and flood together with talcum powder 30 minutes, drying;
(2) filter residue of step (1) is sent in retort, calcination processing 3-4 hour at 545-650 ℃, takes out and dries, and is ground into powder;
(3) by iron chloride and calcium chloride mixing 30-40 minute, add titanium oxynitrides mixing 45-50 minute, then add sodium alginate mixing 50-60 minute;
(4) step (1), (2), (3) reaction mass and other residual componentss are mixed to 120-150 minute.
The present invention has following beneficial effect: the characteristic that the present invention utilizes titanium oxynitrides to produce active substance under visible ray suppresses the growth of blue-green algae, and efficiency is high, cost is low, the application of applicable various scales; The present invention is compound by Powdered reagent, brings high efficiency energy, and is Powderedly convenient to product storage, packing and transportation, thereby has reduced the integrated cost of product.
Embodiment
Described a kind of titanium oxynitrides/iron chloride composite powder blue-green algae inorganic agent, it is characterized in that, by the raw material of following weight portion, made: polymerization oxidation iron 32, maleic acid 18, iron chloride 20, titanium oxynitrides 19, calcium chloride 18, sodium alginate 17, talcum powder 24, diatom 21, rhizome of cyrtomium 1, smilax 2, the Chinese pulsatilla 5, the root of large-flowered skullcap 3.
Preparation method comprises the following steps:
(1) diatom, rhizome of cyrtomium, smilax, the Chinese pulsatilla, the root of large-flowered skullcap decocted together in water 2-3 hour and filter, getting its filtrate and flood together with talcum powder 30 minutes, drying;
(2) filter residue of step (1) is sent in retort, calcination processing 3-4 hour at 545-650 ℃, takes out and dries, and is ground into powder;
(3) by iron chloride and calcium chloride mixing 30-40 minute, add titanium oxynitrides mixing 45-50 minute, then add sodium alginate mixing 50-60 minute;
(4) step (1), (2), (3) reaction mass and other residual componentss are mixed to 120-150 minute.
Use blue-green algae inorganic agent of the present invention as shown in the table to wastewater suspended substance clean-up effect:
Table 1 composite powder blue-green algae inorganic agent wastewater suspended substance clean-up effect
Claims (2)
1. titanium oxynitrides/iron chloride composite powder blue-green algae inorganic agent, it is characterized in that, by the raw material of following weight portion, made: polymerization oxidation iron 30-35, maleic acid 17-19, iron chloride 20-25, titanium oxynitrides 19-21, calcium chloride 18-22, sodium alginate 17-24, talcum powder 20-24, diatom 19-21, rhizome of cyrtomium 1-3, smilax 2-4, Chinese pulsatilla 2-5, root of large-flowered skullcap 3-6.
2. the preparation method of a kind of titanium oxynitrides/iron chloride composite powder blue-green algae inorganic agent according to claim 1, is characterized in that comprising the following steps:
(1) diatom, rhizome of cyrtomium, smilax, the Chinese pulsatilla, the root of large-flowered skullcap decocted together in water 2-3 hour and filter, getting its filtrate and flood together with talcum powder 30 minutes, drying;
(2) filter residue of step (1) is sent in retort, calcination processing 3-4 hour at 545-650 ℃, takes out and dries, and is ground into powder;
(3) by iron chloride and calcium chloride mixing 30-40 minute, add titanium oxynitrides mixing 45-50 minute, then add sodium alginate mixing 50-60 minute;
(4) step (1), (2), (3) reaction mass and other residual componentss are mixed to 120-150 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410166769.0A CN103975966A (en) | 2014-04-23 | 2014-04-23 | Titanium oxynitride/iron chloride composite powdery blue-green algae processing agent and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410166769.0A CN103975966A (en) | 2014-04-23 | 2014-04-23 | Titanium oxynitride/iron chloride composite powdery blue-green algae processing agent and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103975966A true CN103975966A (en) | 2014-08-13 |
Family
ID=51268340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410166769.0A Pending CN103975966A (en) | 2014-04-23 | 2014-04-23 | Titanium oxynitride/iron chloride composite powdery blue-green algae processing agent and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103975966A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105104452A (en) * | 2015-07-22 | 2015-12-02 | 合肥一诺生物科技有限公司 | High-efficiency cyanobacteria treating agent, and preparation method thereof |
| CN109042762A (en) * | 2018-07-27 | 2018-12-21 | 无锡市智者水生态环境工程有限公司 | A kind of Chinese herbal and crude drugs preparations being able to suppress cyanobacterial bloom and preparation method thereof and application method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475230A (en) * | 2009-01-20 | 2009-07-08 | 合肥蓝鑫新材料有限责任公司 | Blue algae inhibitor, preparation and use method thereof |
| CN102408145A (en) * | 2011-10-21 | 2012-04-11 | 浙江大学舟山海洋研究中心 | Composite flocculant and use thereof |
| CN102786121A (en) * | 2011-05-17 | 2012-11-21 | 江苏南天絮凝剂有限公司 | Composite flocculant for urban sewage treatment, and use method thereof |
-
2014
- 2014-04-23 CN CN201410166769.0A patent/CN103975966A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475230A (en) * | 2009-01-20 | 2009-07-08 | 合肥蓝鑫新材料有限责任公司 | Blue algae inhibitor, preparation and use method thereof |
| CN102786121A (en) * | 2011-05-17 | 2012-11-21 | 江苏南天絮凝剂有限公司 | Composite flocculant for urban sewage treatment, and use method thereof |
| CN102408145A (en) * | 2011-10-21 | 2012-04-11 | 浙江大学舟山海洋研究中心 | Composite flocculant and use thereof |
Non-Patent Citations (4)
| Title |
|---|
| 宋东辉，徐晶，宋子昀等: "《生态环境水利工程应用技术》", 31 May 2013, article "《蓝藻处理技术》" * |
| 张瑞娜，曾彤，赵由才: "《饮用水安全与人民生活 保护生命之源》", 30 June 2012, article "《饮用水安全与人民生活 保护生命之源》" * |
| 张饮江，李岩，张曼曼，等: "《富营养化水体原位控藻技术研究进展》", 《科技导报》, vol. 31, no. 10, 31 December 2013 (2013-12-31), pages 67 - 73 * |
| 穆祥燕，黄慧，张发杰: "《蓝藻水华防治技术研究综述》", 《环境工程》, vol. 31, no. 1, 31 December 2013 (2013-12-31), pages 83 - 85 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105104452A (en) * | 2015-07-22 | 2015-12-02 | 合肥一诺生物科技有限公司 | High-efficiency cyanobacteria treating agent, and preparation method thereof |
| CN109042762A (en) * | 2018-07-27 | 2018-12-21 | 无锡市智者水生态环境工程有限公司 | A kind of Chinese herbal and crude drugs preparations being able to suppress cyanobacterial bloom and preparation method thereof and application method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104326635A (en) | High-efficiency modifying agent of substrate of aquiculture pond and preparation method of modifying agent | |
| CN104250179A (en) | Grape organic fertilizer with high nutrition and low cost and preparation method thereof | |
| CN103947694B (en) | A kind of blue algae inhibitor composition and preparation method thereof | |
| CN103214281A (en) | Method for performing chemical innocent treatment on erythromycin waste residues and using erythromycin waste residues for producing organic fertilizer | |
| CN104177149A (en) | Organic fertilizer for increasing soil fertility and preparation method thereof | |
| CN103936101B (en) | Moringa oleifera and bauxite cyanobacteria combined treating agent and preparation method thereof | |
| CN103936087B (en) | Mixed blue-green algae treating agent | |
| CN103936119B (en) | Polysilicate ferric aluminum chloride/fluorescent brightener composite cyanobacteria treatment agent and manufacturing method thereof | |
| CN103947691B (en) | A kind of hydrogen peroxide/polymeric aluminum sulfate silicate compound cyanophyte inorganic agent and preparation method thereof | |
| CN105693302A (en) | Method for producing natural organic fertilizer from reconstituted tobacco wastewater sludge | |
| CN103936126B (en) | Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof | |
| CN103975966A (en) | Titanium oxynitride/iron chloride composite powdery blue-green algae processing agent and preparation method | |
| CN104030398B (en) | A kind of modified water rice straw blue algae treatment agent and preparation method thereof | |
| CN103936122B (en) | A kind of deodorizing powdery blue algae treatment agent and preparation method thereof | |
| CN103936125B (en) | Rare-earth blue algae treating agent and preparation method thereof | |
| CN103936120B (en) | A kind of inorganic/organic floculant Composite powdery blue algae treatment agent and preparation method thereof | |
| CN103723887A (en) | Treatment method for wastewater produced by circuit board production | |
| CN103936123B (en) | Oxidation-reduction powdery blue algae treating agent and production method thereof | |
| CN101921003B (en) | 2-(acetoxyl) benzoic acid compounding agent, preparation method and application thereof to killing algae | |
| CN105016437A (en) | Blue algae processing agent with water purification function and preparation method thereof | |
| CN105104452A (en) | High-efficiency cyanobacteria treating agent, and preparation method thereof | |
| CN103936124B (en) | Composite powdered cyanobacteria treatment agent and fabrication method thereof | |
| CN104193543A (en) | Organic fertilizer applicable to crop with high calcium content and preparation method thereof | |
| CN107746224A (en) | A kind of configuration of solid dephosphorization matrix and its processing method | |
| CN103964537B (en) | Aluminium chlorohydroxide/lignose composited blood-green algae treating agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140813 |
|
| RJ01 | Rejection of invention patent application after publication |