CN105360874A - Deoxidizer for food fresh keeping - Google Patents
Deoxidizer for food fresh keeping Download PDFInfo
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- CN105360874A CN105360874A CN201410416365.2A CN201410416365A CN105360874A CN 105360874 A CN105360874 A CN 105360874A CN 201410416365 A CN201410416365 A CN 201410416365A CN 105360874 A CN105360874 A CN 105360874A
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- metal halide
- iron powder
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- deoxidizer
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Abstract
The invention discloses a deoxidizer for food fresh keeping. The deoxidizer comprises, by weight, 10 parts of iron, 2.5-3 parts of active carbon, 2.1-4.5 parts of metal halide, 1.5-1.9 parts of a swelling agent, 0.2-0.5 parts of pumice, and 0.5-1.2 parts of water. The deoxidizer has the following advantages: the active carbon and the metal halide are used to catalyze, so the deoxidization effect of reduction iron powder is substantially improved; the swelling agent and the pumice are added, so the catalysis effect of the metal halide is still kept in high-temperature wet environment, thereby the full oxidation reaction of the iron powder is guaranteed, and the timeliness and the deoxidization amount of the deoxidizer are integrally improved; and material selected in the invention are cheap and general products, so the cost is low.
Description
Technical field
The invention belongs to food storage anti-corrosive fresh-keeping oxygen scavenger technical field, relate to a kind of food fresh-keeping oxygen scavenger.
Background technology
Oxygen scavenger, has another name called deoxidier.Be widely used in biochemical industry, the industry manufacture field such as pharmaceuticals, food, smelting.In food storage, the breeding of oxygen meeting cooperating microorganisms germ, and cause oil food to rot, or because making food fade with food material surface oxidation reaction, so the free oxygen removed in air is the important method of preserving food.Be generally used for food storage, the oxygen scavenger of Keep the quality and freshness is the inorganic oxygen scavenger of iron system, its principles of chemistry are just give birth to oxidation reaction by iron and oxygen to generate Fe
2o
3thus oxygen depleted.But, conventional iron powder deoxidier because of its iron be need to complete under the effect of water, so need high moisturizing environment, and reaction rate is slow, in order to solve Similar Problems, common iron system oxidant is based on iron powder, auxiliary interpolation metal halide such as calcium chloride etc.But problem new is thus that calcium chloride adds can cause deliquescence too much, forms secondary pollution.Chinese patent (publication number: CN103653185A) discloses a kind of food moisture-proof deoxidier, and a kind of preferred ingredient is wherein: iron powder 100 parts, 10 parts, calcium chloride, active carbon 10 parts and auxiliary material 30 parts; Described auxiliary material is attapulgite and montmorillonite, and mass ratio is 6:4.The program has made improvement for the use problem of calcium chloride, by adding the Composition Control of concavo-convex stone rod, keeps the negative balance to high humidity environment.But the program still have employed the not low sodium chloride of ratio, and deliquescence phenomenon still exists, another problem of the program is that concavo-convex stone rod is the chemical material that a kind of price is partially expensive, and its market price is about 400 yuan/kilogram.Cause the inevitable cost intensive of this product, be unfavorable for marketing.
Summary of the invention
For the defect existed in above technology, the present invention, by rational selection and proportioning, provides one can keep the efficient moisture-proof simultaneously of oxidation of iron powder effect, but food fresh-keeping oxygen scavenger with low cost.
For solving the problems of the technologies described above, food fresh-keeping oxygen scavenger of the present invention consists of the following composition, and counts by weight, iron: 10 parts, active carbon: 2.5 ~ 3 parts, metal halide: 2.1 ~ 4.5 parts, swelling agent: 1.5 ~ 1.9 parts, pumice: 0.2 ~ 0.5 part, water: 0.5 ~ 1.2 part.
Wherein, described food fresh-keeping oxygen scavenger, is characterized in that described iron powder is reduced iron powder.
Described food fresh-keeping oxygen scavenger, is characterized in that described active carbon is cocoanut active charcoal.
Described food fresh-keeping oxygen scavenger, is characterized in that described metal halide is sodium bromide.
Described food fresh-keeping oxygen scavenger, is characterized in that described swelling agent is calcium bentonite.
As a further improvement on the present invention, described food fresh-keeping oxygen scavenger, counts by weight, has following one-tenth to be grouped into---iron: 10 parts, active carbon: 2.6 parts, metal halide: 2.5 parts, swelling agent: 1.68 parts, pumice: 0.21 part, water: 0.67 part.
Advantage of the present invention has: by the component of rational proportion active carbon, and the composition of rational proportion metal halide, catalysis iron powder oxidation reaction, the deaerating effect of reduced iron powder is significantly improved, meanwhile, swelling agent is added, pumice, make the catalytic effect that still can keep metal halide under high temperature, wet environment, ensure that the fully oxidized reaction of iron powder with this.Integral lifting oxygen scavenger ageing and except oxygen amount.And selected materials all belongs to known general chemical material, with low cost.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated, and note that the present embodiment supplements of the present invention, is not limitation of the present invention.
Embodiment 1
First get iron powder by weight: 100g (10 parts), then the amount according to iron powder is benchmark, get active carbon: 25g (2.5 parts), metal halide (sodium bromide): 22g (2.2 parts), swelling agent (calcium bentonite): 17.8g (1.78 parts), pumice: 2.5g (0.25 part), water: 9.7g (0.97 part).
Then iron powder, active carbon, metal halide (sodium bromide), swelling agent (calcium bentonite), pumice are poured in container in the lump, stir together, fully mix.Then add water, rapid stirring, after treating that moisture soaks into, can preservation be packed.
Embodiment 2
First get iron powder by weight: 100g (10 parts), then the amount according to iron powder is benchmark, get active carbon: 26g (2.6 parts), metal halide (sodium bromide): 25g (2.5 parts), swelling agent (calcium bentonite): 16.8g (1.68 parts), pumice: 2.1g (0.21 part), water: 6.7g (0.67 part).
Then iron powder, active carbon, metal halide (sodium bromide), swelling agent (calcium bentonite), pumice are poured in container in the lump, stir together, fully mix.Then add water, rapid stirring, after treating that moisture soaks into, can preservation be packed.
Embodiment 3
First get iron powder by weight: 100g (10 parts), then the amount according to iron powder is benchmark, get active carbon: 30g (3 parts), metal halide (sodium bromide): 25g (2.5 parts), swelling agent (calcium bentonite): 17.9g (1.79 parts), pumice: 2.0g (0.2 part), water: 7g (0.7 part).
Then iron powder, active carbon, metal halide (sodium bromide), swelling agent (calcium bentonite), pumice are poured in container in the lump, stir together, fully mix.Then add water, rapid stirring, after treating that moisture soaks into, can preservation be packed.
Embodiment 4
First get iron powder by weight: 100g (10 parts), then the amount according to iron powder is benchmark, get active carbon: 30g (3 parts), metal halide (sodium bromide): 22g (2.2 parts), swelling agent (calcium bentonite): 19g (1.9 parts), pumice: 3.5g (0.35 part), water: 10g (1 part).
Then iron powder, active carbon, metal halide (sodium bromide), swelling agent (calcium bentonite), pumice are poured in container in the lump, stir together, fully mix.Then add water, rapid stirring, after treating that moisture soaks into, can preservation be packed.
Claims (6)
1. a food fresh-keeping oxygen scavenger, is characterized in that, constituent is with weight parts: iron: 10 parts, active carbon: 2.5 ~ 3 parts, metal halide: 2.1 ~ 4.5 parts, swelling agent: 1.5 ~ 1.9 parts, pumice: 0.2 ~ 0.5 part, water: 0.5 ~ 1.2 part.
2. food fresh-keeping oxygen scavenger according to claim 1, is characterized in that: constituent is with weight parts: iron: 10 parts, active carbon: 2.6 parts, metal halide: 2.5 parts, swelling agent: 1.68 parts, pumice: 0.21 part, water: 0.67 part.
3. food fresh-keeping oxygen scavenger according to claim 1, is characterized in that described iron powder is reduced iron powder.
4. food fresh-keeping oxygen scavenger according to claim 1, is characterized in that described active carbon is cocoanut active charcoal.
5. food fresh-keeping oxygen scavenger according to claim 1, is characterized in that described metal halide is sodium bromide.
6. food fresh-keeping oxygen scavenger according to claim 1, is characterized in that described swelling agent is calcium bentonite.
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CN201410416365.2A CN105360874A (en) | 2014-08-21 | 2014-08-21 | Deoxidizer for food fresh keeping |
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CN201410416365.2A CN105360874A (en) | 2014-08-21 | 2014-08-21 | Deoxidizer for food fresh keeping |
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CN201410416365.2A Pending CN105360874A (en) | 2014-08-21 | 2014-08-21 | Deoxidizer for food fresh keeping |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105733993A (en) * | 2016-04-05 | 2016-07-06 | 湖北工业大学 | Method for utilizing Fe-C primary battery for deoxidization to culture clostridium butyricum |
Citations (6)
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US6133361A (en) * | 1996-02-03 | 2000-10-17 | Mitsubishi Gas Chemical Company, Inc. | Oxygen-absorbing composition, oxygen-absorbing resin composition, packing material, multi-layered packing, oxygen absorber packet, packing method and preservation method |
CN101252984A (en) * | 2005-10-21 | 2008-08-27 | 三菱瓦斯化学株式会社 | Solid oxygen scavenger composition and process for producing the same |
JP2011057265A (en) * | 2009-09-11 | 2011-03-24 | Mitsubishi Gas Chemical Co Inc | Oxygen scavenger package, continuous packages, continuous packages with cover film, hermetic container containing fresh meat, and method of preserving the fresh meat |
CN102958601A (en) * | 2011-06-09 | 2013-03-06 | 三菱瓦斯化学株式会社 | Deoxidant composition, and deoxidizing packaging material and method for deoxidizing using same |
CN103653185A (en) * | 2013-11-13 | 2014-03-26 | 广西弘耀祥科技有限公司 | Moisture-proof deoxidizing agent for foodstuff |
CN103767041A (en) * | 2014-01-03 | 2014-05-07 | 广东广益科技实业有限公司 | Deoxidization preservative suitable for low-humidity environment and preparation method thereof |
-
2014
- 2014-08-21 CN CN201410416365.2A patent/CN105360874A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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US6133361A (en) * | 1996-02-03 | 2000-10-17 | Mitsubishi Gas Chemical Company, Inc. | Oxygen-absorbing composition, oxygen-absorbing resin composition, packing material, multi-layered packing, oxygen absorber packet, packing method and preservation method |
CN101252984A (en) * | 2005-10-21 | 2008-08-27 | 三菱瓦斯化学株式会社 | Solid oxygen scavenger composition and process for producing the same |
JP2011057265A (en) * | 2009-09-11 | 2011-03-24 | Mitsubishi Gas Chemical Co Inc | Oxygen scavenger package, continuous packages, continuous packages with cover film, hermetic container containing fresh meat, and method of preserving the fresh meat |
CN102958601A (en) * | 2011-06-09 | 2013-03-06 | 三菱瓦斯化学株式会社 | Deoxidant composition, and deoxidizing packaging material and method for deoxidizing using same |
CN103653185A (en) * | 2013-11-13 | 2014-03-26 | 广西弘耀祥科技有限公司 | Moisture-proof deoxidizing agent for foodstuff |
CN103767041A (en) * | 2014-01-03 | 2014-05-07 | 广东广益科技实业有限公司 | Deoxidization preservative suitable for low-humidity environment and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105733993A (en) * | 2016-04-05 | 2016-07-06 | 湖北工业大学 | Method for utilizing Fe-C primary battery for deoxidization to culture clostridium butyricum |
CN105733993B (en) * | 2016-04-05 | 2019-04-05 | 湖北工业大学 | A method of utilizing Fe-C primary battery deoxygenation culture clostridium butyricum |
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