CN105350309B - A kind of preparation method with fluorescence radiation function bafta - Google Patents
A kind of preparation method with fluorescence radiation function bafta Download PDFInfo
- Publication number
- CN105350309B CN105350309B CN201510983854.0A CN201510983854A CN105350309B CN 105350309 B CN105350309 B CN 105350309B CN 201510983854 A CN201510983854 A CN 201510983854A CN 105350309 B CN105350309 B CN 105350309B
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- Prior art keywords
- bafta
- preparation
- heated
- fluorescence radiation
- solution
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention provides a kind of preparation method with fluorescence radiation function bafta, this method comprises the following steps：（1）Fluorescent material is added in the methylimidazole of 1 pi-allyl of chlorination 3, stirs, is heated to 90oC；（2）Bafta is put into 22%（w/w）1min, washing, drying are impregnated in sodium hydrate aqueous solution；（3）By the bafta of pretreatment in step（1）Repeatedly padded in the solution of gained, pick-up 100% 120%；（4）Bafta after padding is heated into certain time under microwave irradiation；（5）Bafta is taken out, is put into ethanol solution and solidifies 40min, then washes, dry.This technology of preparing is simple and easy to apply, and the bafta prepared has lasting fluorescence radiation performance, while will not change cotton fiber surface property；Any adhesive is not used in preparation process, it is nontoxic.
Description
Technical field
The present invention relates to a kind of preparation method of function fabric, especially a kind of system with fluorescence radiation function bafta
Preparation Method.
Background technology
The functional fabric that can be lighted under automobile illumination is one of civil area functional textile, this feature
Textile can be widely applied to the fields such as communications and transportation, night work, daily life and amusement clothes.For the luminous of textile
Material is typically organic fluorescent dye, and fluorescence is bright in colour, and dissolubility is good, but without covering power, and light transmittance is up to 90%
More than, and weatherability and heat resistance be not good.Inorganic fluorescent powder fluorescence is bright in colour, with good covering power, heat resistance, resistance to
Solvent borne, light resistance are good, without migrating property, non-toxic, are widely used in LED（Light Emitting Diode）Light source
In LASER Light Source, but need addition adhesive to be just adhered to cotton fiber surface, reduce the feel of bafta and to people
The skin-friendly of body.
The content of the invention
The technical problems to be solved by the invention are that the shortcoming existed for above prior art is proposed a kind of with glimmering
The preparation method of light lighting function bafta, the preparation method is simple and easy to apply, prepares with low cost, and the bafta prepared has
Good luminescence, while having good skin-friendly, washability.
To achieve these goals, the solution taken of the present invention is：It is a kind of with fluorescence radiation function bafta
Preparation method, it is characterised in that comprise the following steps：（1）Fluorescent material is added in chlorination 1- pi-allyl -3- methylimidazoles, filled
Divide and stir, be heated to 90oC；（2）Bafta is put into 22%（w/w）1min, washing, baking are impregnated in sodium hydrate aqueous solution
It is dry；（3）By the bafta of pretreatment in step（1）Repeatedly padded in the solution of gained, pick-up 100%-120%；（4）It will pad
Bafta afterwards heats certain time under microwave irradiation；（5）Bafta is taken out, is put into ethanol solution and solidifies 40min, then
Washing, drying.
By such scheme, fluorescent material particle diameter is 10nm-5 μm in described chlorination 1- pi-allyl -3- methylimidazoles.
The beneficial effects of the present invention are,（1）Natural cotton fiber molecular weight is larger, and generally higher than 160000, and chlorination
1- pi-allyl -3- methylimidazoles are shorter to the time of contact of bafta, therefore can only carry out micro dissolution to cotton fiber surface, without
It can damage inside cotton fiber, not result in the reduction of fiber and fabric；（2）It is partly dissolved in surface of cotton fabric
Cellulose formation cellulose concentrated solution, there is adhesive attraction to magnetic nanoparticle；（3）The cellulose that cotton fiber surface is formed
Concentrated solution solidifies again in ethanol solution, plays a part of bonding fluorescent material, while will not change cotton fiber surface property；
（4）Any adhesive is not used in preparation process, it is nontoxic.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that the skill described in following embodiments
The combination of art feature or technical characteristic be not construed as it is isolated, they can be mutually combined so as to reach preferably
Technique effect.
Embodiment 1
（1）5g fluorescent material is added in 100mL chlorination 1- pi-allyl -3- methylimidazoles, stirs, is heated to
90ºC；
（2）10g baftas are put into the 22% of 100mL（w/w）1min, washing, drying are impregnated in sodium hydrate aqueous solution；
（3）By the bafta of pretreatment in step（1）Two leachings two are rolled in the solution of gained, pick-up 100%；
（4）Bafta after padding is heated into 30min under 200W microwave irradiations；
（5）Bafta is taken out, is put into 100mL ethanol solutions and solidifies 40min, then washes, dry.
Embodiment 2
（1）5g fluorescent material is added in 50mL chlorination 1- pi-allyl -3- methylimidazoles, stirs, is heated to
90ºC；
（2）10g baftas are put into the 22% of 100mL（w/w）1min, washing, drying are impregnated in sodium hydrate aqueous solution；
（3）By the bafta of pretreatment in step（1）Two leachings two are rolled in the solution of gained, pick-up 110%；
（4）Bafta after padding is heated into 30min under 400W microwave irradiations；
（5）Bafta is taken out, is put into 100mL ethanol solutions and solidifies 40min, then washes, dry.
Embodiment 3
（1）7g fluorescent material is added in 100mL chlorination 1- pi-allyl -3- methylimidazoles, stirs, is heated to
90ºC；
（2）10g baftas are put into the 22% of 100mL（w/w）1min, washing, drying are impregnated in sodium hydrate aqueous solution；
（3）By the bafta of pretreatment in step（1）Two leachings two are rolled in the solution of gained, pick-up 120%；
（4）Bafta after padding is heated into 20min under 600W microwave irradiations；
（5）Bafta is taken out, is put into 100mL ethanol solutions and solidifies 40min, then washes, dry.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that
Without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment be it is exemplary, no
The restriction of interest field of the present invention should be used as using the embodiments herein.
Claims (2)
1. a kind of preparation method with fluorescence radiation function bafta, it is characterised in that comprise the following steps：
（1）Fluorescent material is added in chlorination 1- pi-allyl -3- methylimidazoles, stirs, is heated to 90oC；
（2）Bafta is put into 22%（w/w）1min, washing, drying are impregnated in sodium hydrate aqueous solution；
（3）By the bafta of pretreatment in step（1）Repeatedly padded in the solution of gained, pick-up 100%-120%；
（4）Bafta after padding is heated into certain time under microwave irradiation；
（5）Bafta is taken out, is put into ethanol solution and solidifies 40min, then washes, dry.
2. preparation method according to claim 1, it is characterised in that fluorescent material particle diameter is 10nm-5 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510983854.0A CN105350309B (en) | 2015-12-24 | 2015-12-24 | A kind of preparation method with fluorescence radiation function bafta |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510983854.0A CN105350309B (en) | 2015-12-24 | 2015-12-24 | A kind of preparation method with fluorescence radiation function bafta |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105350309A CN105350309A (en) | 2016-02-24 |
| CN105350309B true CN105350309B (en) | 2017-09-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510983854.0A Expired - Fee Related CN105350309B (en) | 2015-12-24 | 2015-12-24 | A kind of preparation method with fluorescence radiation function bafta |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106702719A (en) * | 2016-12-01 | 2017-05-24 | 西南大学 | Long-afterglow blue luminescent Dacron preparation method |
| CN107385903A (en) * | 2017-09-04 | 2017-11-24 | 西南大学 | Conductive silk fabric is prepared with ionic liquid |
| CN107541938A (en) * | 2017-09-04 | 2018-01-05 | 西南大学 | Fluorescence wool fabric is prepared with the dithiothreitol (DTT) aqueous solution |
| CN107558186A (en) * | 2017-09-17 | 2018-01-09 | 赵兵 | Fluorescence cotton fiber based on rare earth up-conversion luminescence nanomaterial |
| CN113338037B (en) * | 2021-07-23 | 2022-11-29 | 浙江理工大学绍兴柯桥研究院有限公司 | Preparation method of two-layer structure noctilucent cotton cloth |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101285213A (en) * | 2008-05-22 | 2008-10-15 | 高小山 | Preparation method of purified cotton fibre |
| CN101985782A (en) * | 2010-10-19 | 2011-03-16 | 山东海龙股份有限公司 | Chlorine-free cellulose fibers and preparation method thereof |
| CN102838761A (en) * | 2012-08-27 | 2012-12-26 | 中国热带农业科学院农产品加工研究所 | Method of preventing cellulose from being degraded in ionic liquid |
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2015
- 2015-12-24 CN CN201510983854.0A patent/CN105350309B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101285213A (en) * | 2008-05-22 | 2008-10-15 | 高小山 | Preparation method of purified cotton fibre |
| CN101985782A (en) * | 2010-10-19 | 2011-03-16 | 山东海龙股份有限公司 | Chlorine-free cellulose fibers and preparation method thereof |
| CN102838761A (en) * | 2012-08-27 | 2012-12-26 | 中国热带农业科学院农产品加工研究所 | Method of preventing cellulose from being degraded in ionic liquid |
Non-Patent Citations (1)
| Title |
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| [BMIM]Cl离子液体处理对苎麻性能的影响;袁久刚等;《染整技术》;20131020;第35卷(第10期);第16-19页 * |
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| CN105350309A (en) | 2016-02-24 |
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