CN105350300A - Pretreatment process of polyester/chinlon intertexture - Google Patents

Pretreatment process of polyester/chinlon intertexture Download PDF

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Publication number
CN105350300A
CN105350300A CN201510921277.2A CN201510921277A CN105350300A CN 105350300 A CN105350300 A CN 105350300A CN 201510921277 A CN201510921277 A CN 201510921277A CN 105350300 A CN105350300 A CN 105350300A
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intertexture
open
degreaser
wash
bright
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CN201510921277.2A
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Chinese (zh)
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唐晓琦
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/30—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with oxides of halogens, oxyacids of halogens or their salts, e.g. with perchlorates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/238—Tannins, e.g. gallotannic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention relates to a pretreatment process of a polyester/chinlon intertexture, comprising three procedures of open-width scouring, preshrinking and presetting; the open-width scouring is performed on the intertexture in an open-width scouring machine at a low temperature state, wherein 5g/L of NaOH and 30g/L of an efficient emulsifying dispersion degreaser are contained in a scouring bath. The pretreatment process of the polyester/chinlon intertexture is short in process flow, realizes low temperature scouring, is low in composite cost, and is energy-saving and environment-friendly; meanwhile, the problems of thinness and stiffness after conventional dyeing and finishing processing of the polyester/chinlon intertexture can be solved, and the fullness, fluffiness and down feeling of the polyester/chinlon intertexture are increased and improved.

Description

A kind ofly to wash/the pre-treatment process of bright and beautiful intertexture
Technical field
The present invention relates to a kind of dyeing and finishing pre-treatment process, particularly a kind ofly to wash/the pre-treatment process of bright and beautiful intertexture.
Background technology
According to textile industry Eleventh Five-Year Development Plan outline; to Eleventh Five-Year Plan end; China's textile printing and dyeing industry is energy-saving and cost-reducing, Development of Environmental Protection target call ton fiber power consumption reduced by 10% than 2005; ton fiber water consumption reduced by 20% than 2005, and the quantity of wastewater effluent of unit output value reduced by 22% than 2005.As everyone knows, dyeing is always one of rich and influential family of water consumption and quantity of wastewater effluent.Textile industry blowdown flow rate accounts for 35% of total industrial wastewater, and wherein dyeing waste water accounts for again 80% of national textile wastewater discharge, and average reclamation rate is only 10%.At present, the unit product water consumption of China's printing and dyeing enterprise is generally about 3 times of developed country.
The consumption costs of current printing and dyeing enterprise water, electricity, vapour, account for about 40% of the total cost of dyeing cloth.The energy resource consumption of printing and dyeing production water, electricity, vapour is mainly used in pre-treatment.In general, pre-treatment water account for produce total water 55% ~ 60%, with vapour account for produce total vapour 30%, electricity consumption account for production total electricity consumption 35%.Pre-treatment energy resource consumption accounts for more than 50% of all over products, first of row dyeing, stamp and arrangement.Shortening pre-treatment process-cycle, pre-treatment energy-conserving and environment-protective processing, is the direction of 21 century Dyeing & Finishing Industry sustainable development.
And tradition uses alkali destarch and refining pre-treatment process, usually cause fabric weight to reduce and increase the burden of finishing process, particularly pre-treatment process generally all adopts alkali-alkali-oxygen or alkali-oxygen technique or destarch enzyme-refining enzymatic process, and refining enzyme is mostly for pure cotton fabric, its operation is long, power consumption is large, and efficiency is low.
Summary of the invention
The object of the invention is to overcome traditional pre-treatment process and consume high, inefficient shortcoming, provide a kind of to wash the/pre-treatment process of bright and beautiful intertexture, technological process is short, realizes low temperature concise, and integrated cost is low, energy-conserving and environment-protective; Can solve simultaneously wash/bright and beautiful intertexture routine dyeing and finishing process after occur thin, stiff, increase that it is plentiful, fluffy, the feel of wool.
To achieve these goals, the present invention adopts following technical scheme: a kind ofly to wash/the pre-treatment process of bright and beautiful intertexture, comprise open-width scouring, preshrunk and pre-setting three process, under low-temperature condition, in open-width scouring machine, open-width scouring is carried out to fabric, wherein concise bath comprises the efficient emulsion dispersion degreaser of NaOH and 30g/L of 5g/L, described efficient emulsion dispersion degreaser, with parts by weight, composed of the following components:
N butyl oleate sodium sulfonate 20-30
Alkyl polyoxyethylene derivative 15-18
Polyox-yethylene-polyoxypropylene block copolymer 12-16
Sodium chlorite 3-7
Polyacrylamide 2-8
Fatty alcohol sulfate single ethanol ammonium salt 0.5-3
Tannic acid 4-8
Di-n-octyl sebacate 10-20
Ethoxylated dodecyl alcohol phosphate 2-5
Ethanol 30-50
Deionized water is about 80-100;
Described ethoxylated dodecyl alcohol phosphate generates ethoxylated dodecyl alcohol by fatty alcohol and reacting ethylene oxide, then with phosphorus pentoxide esterification, neutralize and get final product; Described open-width scouring machine forms primarily of cloth-feeding-delivering device, tension-adjusting gear, amplitude-expanding device, flat wash trough, heater, cold water spray device and squezzing drying unit; Described low-temperature condition refers to the normal temperature condition without the need to heating dressing liquid.
Further, described efficient emulsion dispersion degreaser also comprises with the Macrogol 600 of parts by weight 15-20 part.
Further, described efficient emulsion dispersion degreaser in use dressing liquid pH value remain on 8-9 the best.
Further, the described open-width scouring processing time is 6-10h.
Beneficial effect of the present invention is: the present invention is at long vehicle pretreatment procedure through a large amount of engineer testing, Optimization Technology point, and realize low temperature concise, integrated cost is low, energy-conserving and environment-protective; Fiber can be made fully to expand, add the thickness of fabric, velvet, destarch rate, capillary effect, whiteness, reduce pre-treatment cost simultaneously, this technique is that one of field of printing and dyeing is innovated greatly simultaneously.
Detailed description of the invention
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment one:
A kind ofly to wash/the pre-treatment process of bright and beautiful intertexture, comprise open-width scouring, preshrunk and pre-setting three process, under low-temperature condition, in open-width scouring machine, open-width scouring is carried out to fabric, wherein concise bath comprises the efficient emulsion dispersion degreaser of NaOH and 30g/L of 5g/L, described efficient emulsion dispersion degreaser, with parts by weight, composed of the following components:
N butyl oleate sodium sulfonate 30
Alkyl polyoxyethylene derivative 18
Polyox-yethylene-polyoxypropylene block copolymer 16
Sodium chlorite 7
Polyacrylamide 8
Fatty alcohol sulfate single ethanol ammonium salt 0.3
Tannic acid 8
Di-n-octyl sebacate 20
Ethoxylated dodecyl alcohol phosphate 5
Ethanol 50
Deionized water 100;
Described ethoxylated dodecyl alcohol phosphate generates ethoxylated dodecyl alcohol by fatty alcohol and reacting ethylene oxide, then with phosphorus pentoxide esterification, neutralize and get final product; Described open-width scouring machine forms primarily of cloth-feeding-delivering device, tension-adjusting gear, amplitude-expanding device, flat wash trough, heater, cold water spray device and squezzing drying unit; Described low-temperature condition refers to the normal temperature condition without the need to heating dressing liquid.Described efficient emulsion dispersion degreaser also comprises with the Macrogol 600 of parts by weight 20 parts.Described efficient emulsion dispersion degreaser in use dressing liquid pH value remains on 8-9 the best.The described open-width scouring processing time is 6h.
Embodiment two:
A kind ofly to wash/the pre-treatment process of bright and beautiful intertexture, comprise open-width scouring, preshrunk and pre-setting three process, under low-temperature condition, in open-width scouring machine, open-width scouring is carried out to fabric, wherein concise bath comprises the efficient emulsion dispersion degreaser of NaOH and 30g/L of 5g/L, described efficient emulsion dispersion degreaser, with parts by weight, composed of the following components:
N butyl oleate sodium sulfonate 20
Alkyl polyoxyethylene derivative 15
Polyox-yethylene-polyoxypropylene block copolymer 12
Sodium chlorite 3
Polyacrylamide 2
Fatty alcohol sulfate single ethanol ammonium salt 0.5
Tannic acid 4
Di-n-octyl sebacate 10
Ethoxylated dodecyl alcohol phosphate 2
Ethanol 30
Deionized water 80.
Described ethoxylated dodecyl alcohol phosphate generates ethoxylated dodecyl alcohol by fatty alcohol and reacting ethylene oxide, then with phosphorus pentoxide esterification, neutralize and get final product; Described open-width scouring machine forms primarily of cloth-feeding-delivering device, tension-adjusting gear, amplitude-expanding device, flat wash trough, heater, cold water spray device and squezzing drying unit; Described low-temperature condition refers to the normal temperature condition without the need to heating dressing liquid.Described efficient emulsion dispersion degreaser also comprises with the Macrogol 600 of parts by weight 15 parts.Described efficient emulsion dispersion degreaser in use dressing liquid pH value remains on 8-9 the best.The described open-width scouring processing time is 10h.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.

Claims (4)

1. wash/the pre-treatment process of bright and beautiful intertexture for one kind, comprise open-width scouring, preshrunk and pre-setting three process, it is characterized in that: under low-temperature condition, in open-width scouring machine, open-width scouring is carried out to fabric, wherein concise bath comprises the efficient emulsion dispersion degreaser of NaOH and 30g/L of 5g/L, described efficient emulsion dispersion degreaser, with parts by weight, composed of the following components:
N butyl oleate sodium sulfonate 20-30
Alkyl polyoxyethylene derivative 15-18
Polyox-yethylene-polyoxypropylene block copolymer 12-16
Sodium chlorite 3-7
Polyacrylamide 2-8
Fatty alcohol sulfate single ethanol ammonium salt 0.5-3
Tannic acid 4-8
Di-n-octyl sebacate 10-20
Ethoxylated dodecyl alcohol phosphate 2-5
Ethanol 30-50
Deionized water is about 80-100;
Described ethoxylated dodecyl alcohol phosphate generates ethoxylated dodecyl alcohol by fatty alcohol and reacting ethylene oxide, then with phosphorus pentoxide esterification, neutralize and get final product; Described open-width scouring machine forms primarily of cloth-feeding-delivering device, tension-adjusting gear, amplitude-expanding device, flat wash trough, heater, cold water spray device and squezzing drying unit; Described low-temperature condition refers to the normal temperature condition without the need to heating dressing liquid.
2. according to claim 1ly a kind ofly to wash/the pre-treatment process of bright and beautiful intertexture, it is characterized in that, described efficient emulsion dispersion degreaser also comprises with the Macrogol 600 of parts by weight 15-20 part.
3. a kind of according to claim 1 and 2 wash/pre-treatment process of bright and beautiful intertexture, and it is characterized in that, described efficient emulsion dispersion degreaser in use dressing liquid pH value remains on 8-9 the best.
4. a kind of according to claim 1 and 2 wash/pre-treatment process of bright and beautiful intertexture, and it is characterized in that, the described open-width scouring processing time is 6-10h.
CN201510921277.2A 2015-12-14 2015-12-14 Pretreatment process of polyester/chinlon intertexture Pending CN105350300A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101058781A (en) * 2007-05-24 2007-10-24 朱思聪 Low-temperature energy-saving emulsifier for industrial washing clothes
CN102978863A (en) * 2012-12-05 2013-03-20 吴江市高发纺织有限公司 Pretreatment process of thin stretch fabrics
CN103821006A (en) * 2014-02-18 2014-05-28 吴江市桃源海润印染有限公司 Elastic polyester-cotton fabric dyeing and finishing pretreatment method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101058781A (en) * 2007-05-24 2007-10-24 朱思聪 Low-temperature energy-saving emulsifier for industrial washing clothes
CN102978863A (en) * 2012-12-05 2013-03-20 吴江市高发纺织有限公司 Pretreatment process of thin stretch fabrics
CN103821006A (en) * 2014-02-18 2014-05-28 吴江市桃源海润印染有限公司 Elastic polyester-cotton fabric dyeing and finishing pretreatment method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
陈溥等: "《纺织染整助剂手册》", 31 August 1995, 中国轻工业出版社 *
韩长日等: "《精细有机化工产品生产技术手册（下卷）》", 30 June 2010, 中国石化出版社 *

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Application publication date: 20160224