CN105331994A - Metal surface cleaning agent and using method - Google Patents

Metal surface cleaning agent and using method Download PDF

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Publication number
CN105331994A
CN105331994A CN201510803562.4A CN201510803562A CN105331994A CN 105331994 A CN105331994 A CN 105331994A CN 201510803562 A CN201510803562 A CN 201510803562A CN 105331994 A CN105331994 A CN 105331994A
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CN
China
Prior art keywords
metal surface
cleaning agent
surface cleaning
scavenging solution
agent according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510803562.4A
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Chinese (zh)
Inventor
谢刚
李宝平
邢晓钟
赵德
张霞
黄淑芳
孙正德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jinchuan Group Co Ltd
Original Assignee
Jinchuan Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jinchuan Group Co Ltd filed Critical Jinchuan Group Co Ltd
Priority to CN201510803562.4A priority Critical patent/CN105331994A/en
Publication of CN105331994A publication Critical patent/CN105331994A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a metal surface cleaning agent and a using method, and relates to a cleaning agent and a using method thereof for aluminum and aluminum alloy, zinc and zinc alloy, steel and chromium alloy surfaces. The metal surface cleaning agent consists of the following components in percentage by mass: 45% of sodium carbonate, 40% of trisodium phosphate, 10% of sodium gluconate and 5% of a nonionic surfactant NP-6. In use, the metal surface cleaning agent is prepared into a cleaning solution for the cleaning of a metal surface. The cleaning agent disclosed by the invention does not contain silicate, is good in cleaning effect, and does not corrode the aluminum and the aluminum alloy surfaces, and therefore, further processing performance such as bonding performance, welding performance, anodic polarization or sealing performance and the like are not affected.

Description

A kind of metal surface cleaning agent and using method
Technical field
A kind of metal surface cleaning agent and using method, relate to a kind of for Al and Alalloy, zinc and zinc alloy, the clean-out system on iron and steel and Chrome metal powder surface and using method.
Background technology
At present, conventional Al and Alalloy, zinc and zinc alloy, the surface cleaning agent on iron and steel and Chrome metal powder surface, mostly containing silicate, because silicate has corrosion to piece surface, toxicity is large, because clean-out system contains the clean-out system (because the cloud point impact of silicate Surfactant is very large) that silicate is difficult to be made into high density, and liquid is difficult to process after cleaning, cause environmental-protecting performance poor, energy consumption and cost high, its surperficial grease can not be removed completely.
Summary of the invention
Object of the present invention is exactly the deficiency existed for above-mentioned prior art, provide a kind of without silicate, fast, nontoxic, the good environmental protection of cleaning speed, can not the metal surface cleaning agent on resistant alloy surface and using method.
The object of the invention is to be achieved through the following technical solutions.
A kind of metal surface cleaning agent, it is characterized in that the mass percent of its clean-out system consists of: soda ash 45%, tertiary sodium phosphate 40%, Sunmorl N 60S 10%, nonionic surface active agent NP-6 is 5%.
A kind of metal surface cleaning agent of the present invention, each Component Use is as follows: 1. soda ash: the grease on cleaning components surface, ensures that solution maintains certain alkalinity ranges in oil removal process.2. tertiary sodium phosphate: washing assistant, the grease on cleaning components surface, has infiltration and emulsifying effect, can increase the wetting ability of water, have certain emulsifying effect.3. Sunmorl N 60S: washing assistant, the grease on cleaning components surface, makes coating thing and workpiece surface mortise.4. nonionic surface active agent NP-6: the tensio-active agent not producing ion in aqueous, has excellent emulsification, washing function, stronger to each quasi-grease cleansing power.
The using method of a kind of metal surface cleaning agent of the present invention, when it is characterized in that using, is mixed with scavenging solution by metal surface cleaning agent, carries out cleaning metal surface.
Cleaning is stirred: machinery or slight pneumatic blending, cell body material: iron and steel, workpiece lifting capacity 0.8 ~ 2dm 2/ L.
The using method of a kind of metal surface cleaning agent of the present invention, when it is characterized in that using, the detergent concentration of the scavenging solution be mixed with: 20 ~ 50g/L, temperature: 50 ~ 80 DEG C, soaking and washing time 1 ~ 15min.
The using method of a kind of metal surface cleaning agent of the present invention, when it is characterized in that using, the detergent concentration of the scavenging solution be mixed with is 50g/L, and temperature is 60 DEG C.
The using method of a kind of metal surface cleaning agent of the present invention, is characterized in that the step preparing scavenging solution preparation is as follows: 1. in rinse bath, add 1/2 volumes of deionized water; 2. add clean-out system to stir until dissolve completely; 3. adding deionized water to prescribed volume is heated to service temperature.
The using method of a kind of metal surface cleaning agent of the present invention, is characterized in that concentration of lotion detection method is as follows: 1. get 5mL sample, adds several methyl orange indicators; 2. terminal is titrated to 0.5N sulfuric acid; 3. detergent concentration (g/L)=18.52 × sulfuric acid volume (mL).
A kind of metal surface cleaning agent of the present invention, is not only applicable to slough Al and Alalloy surface grease, is also applicable to process zinc, and iron and steel and Chrome metal powder surface grease, also can be used for the precision work compound removing piece surface; Clean-out system can not corrode Al and Alalloy surface, therefore can not affect the further processing characteristics of part, such as, cohere, welding, anodic polarization or sealing, this clean-out system is one not silicate clean-out system, and cleaning performance is good, can not corrode Al and Alalloy surface, therefore further processing characteristics can not be affected, such as cohere, welding, anodic polarization or sealing property.
Embodiment
A kind of metal surface cleaning agent, the mass percent of its clean-out system consists of: soda ash 45%, tertiary sodium phosphate 40%, Sunmorl N 60S 10%, and nonionic surface active agent NP-6 is 5%.During use, metal surface cleaning agent is mixed with scavenging solution, carries out cleaning metal surface.Detergent concentration in scavenging solution: 20 ~ 50g/L(optimum value 50g/L), temperature: 50 ~ 80 DEG C (optimum value 60 DEG C), soaking and washing time 1 ~ 15min, stirs: machinery or slight pneumatic blending, cell body material: iron and steel, workpiece lifting capacity 0.8 ~ 2dm 2/ L.
The process for preparation of scavenging solution is as follows: 1. in rinse bath, add 1/2 volumes of deionized water.2. add clean-out system to stir until dissolve completely.3. adding deionized water to prescribed volume is heated to service temperature.
Detergent concentration detection method is as follows: 1. get 5mL sample, adds several methyl orange indicators.2. terminal is titrated to 0.5N sulfuric acid.3. detergent concentration (g/L)=18.52 × sulfuric acid volume (mL)
During use, will allocate the concentration of scavenging solution according to the severity of grease, be generally that clean-out system is mixed with 20 ~ 50g/L scavenging solution to use, and concentration improves can improve cleansing power.
Because clean-out system is a kind of alkaline powder, 5%(mass percent) solution ph is 9.2, during operation, avoids eyes and skin contact, during suggestion operations, wears protective gloves, eye-protection glasses and protective clothing.
Embodiment 1
According to embodiment without silicate aluminum cleaning agent composition, obtain solution 1L, detergent concentration 20g/L, cleaning aluminum alloy surface grease, area is about 0.75dm 2, temperature 50 C, time 8min, slight pneumatic blending, the grease of aluminum alloy surface eliminates.
Embodiment 2
According to embodiment without silicate aluminum cleaning agent composition, obtain solution 1L, detergent concentration 30g/L, cleaning aluminum alloy surface grease, area is about 1dm 2, temperature 60 C, time 4min, slight pneumatic blending, the grease of aluminum alloy surface eliminates.
Embodiment 3
According to embodiment without silicate aluminum cleaning agent composition, obtain solution 1L, detergent concentration 50g/L, cleaning steel surface grease, area is about 2dm 2, temperature 60 C, time 6min, slight pneumatic blending, the grease of steel surface eliminates.

Claims (6)

1. a metal surface cleaning agent, is characterized in that the mass percent of its clean-out system consists of: soda ash 45%, tertiary sodium phosphate 40%, Sunmorl N 60S 10%, and nonionic surface active agent NP-6 is 5%.
2. the using method of a kind of metal surface cleaning agent according to claim 1, when it is characterized in that using, is mixed with scavenging solution by metal surface cleaning agent, carries out cleaning metal surface.
3. the using method of a kind of metal surface cleaning agent according to claim 2, when it is characterized in that using, the detergent concentration of the scavenging solution be mixed with: 20 ~ 50g/L, temperature: 50 ~ 80 DEG C, soaking and washing time 1 ~ 15min.
4. the using method of a kind of metal surface cleaning agent according to claim 2, when it is characterized in that using, the detergent concentration of the scavenging solution be mixed with is 50g/L, and temperature is 60 DEG C.
5. the using method of a kind of metal surface cleaning agent according to claim 2, is characterized in that the step preparing scavenging solution preparation is as follows: 1. in rinse bath, add 1/2 volumes of deionized water; 2. add clean-out system to stir until dissolve completely; 3. adding deionized water to prescribed volume is heated to service temperature.
6. the using method of a kind of metal surface cleaning agent according to claim 2, is characterized in that concentration of lotion detection method is as follows: 1. get 5mL sample, adds several methyl orange indicators; 2. terminal is titrated to 0.5N sulfuric acid; 3. detergent concentration (g/L)=18.52 × sulfuric acid volume (mL).
CN201510803562.4A 2015-11-20 2015-11-20 Metal surface cleaning agent and using method Pending CN105331994A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201510803562.4A CN105331994A (en) 2015-11-20 2015-11-20 Metal surface cleaning agent and using method

Publications (1)

Publication Number Publication Date
CN105331994A true CN105331994A (en) 2016-02-17

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473407A (en) * 2017-08-29 2017-12-15 上海键磁复合新材料有限公司 A kind of indicator colour developing type powdered scale-removing agent of sea water desalinating unit

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102220592A (en) * 2011-05-16 2011-10-19 武汉钢铁(集团)公司 Foamless floating-oil-type alkaline cleaning agent used for pre-treatment of pre-coated steel plate

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102220592A (en) * 2011-05-16 2011-10-19 武汉钢铁(集团)公司 Foamless floating-oil-type alkaline cleaning agent used for pre-treatment of pre-coated steel plate

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
《实用化学清洗技术》: "《实用化学清洗技术》", 31 December 2001 *
喻亚非等: "《锅炉化学清洗》", 31 December 2013, 北京:中国电力出版社 *
胡林林等: "《汽车防锈技术》", 31 December 2004, 北京:化学工业出版社 *
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473407A (en) * 2017-08-29 2017-12-15 上海键磁复合新材料有限公司 A kind of indicator colour developing type powdered scale-removing agent of sea water desalinating unit

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