CN105330893A - 负氧离子粉及利用其制备慢弹回记忆棉和pu合成革的方法 - Google Patents

负氧离子粉及利用其制备慢弹回记忆棉和pu合成革的方法 Download PDF

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CN105330893A
CN105330893A CN201510702856.8A CN201510702856A CN105330893A CN 105330893 A CN105330893 A CN 105330893A CN 201510702856 A CN201510702856 A CN 201510702856A CN 105330893 A CN105330893 A CN 105330893A
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negative oxygen
oxygen ion
ion powder
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徐建先
徐啸
杨艳锋
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Shenzhen Zhiweibin Biotechnology Co Ltd
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Abstract

本发明提供了释放负氧离子和远红外线的负氧离子粉，采用该负氧离子粉制备慢弹回记忆棉和PU合成革的制备方法。所用负氧离子粉中，Al2O3的含量为33％-38％，SiO2的含量为32％-36％，B2O3的含量为9％-13％，MgO的含量为2％-6.5％，Fe2O3的含量为8％-12％，Na2O的含量为0.7％-1.1％，K2O的含量为0.01％-0.08％，CaO的含量为0.5％-1.0％，P2O5的含量为0.1％-0.3％，TiO2的含量为0.1％-0.3％和FeO的含量为0.9％-1.5％。而制备方法在现有的生产线上即可完成，成本低廉。

Description

负氧离子粉及利用其制备慢弹回记忆棉和PU合成革的方法
技术领域
本发明涉及新型材料加工技术领域，具体而言，负氧离子粉及利用其制备慢弹回记忆棉和PU合成革的方法。
背景技术
自从19世纪末德国科学家菲利普·莱昂纳德博士在学术上证明了负离子对人体的功效、20世纪初Aschkinass和Caspan肯定空气负离子的生物学意义以来，人们便开始关注空气负离子的存在和作用，负离子的作用主要分为以下两方面：
(1)环保：捕获了一个电子的氧分子称为负氧离子。科学研究发现，空气中的很多有害气体物质是带正电，如细菌、灰尘、烟雾等，负氧离子可以与这些有害物质相结合，起到杀菌和消除异味等净化空气的作用。世界卫生组织规定清新空气的标准是，空气中负氧离子的浓度大于1500个/cm3。
(2)保健：国内外医学界专家通过临床实践验证负氧离子对人体健康及生态有重大影响。医学研究证明：负氧离子有18％是通过人的呼吸道被吸收、82％通过皮肤被人体吸收。当空气中负氧离子的浓度达到5000-50000个/cm3时,负氧离子进入血管和淋巴运送到全身，起到恢复疲劳、使植物神经系统稳定、增强机体免疫力的功效。
远红外线是太阳光线中众多不可见光线中的一种，其中波长为4-14μm波长的一段被称为生命的光波，具有治疗作用。远红外线治疗作用的基础是温热效应。在红外线照射下，组织温度升高，毛细血管扩张，血流加快，物质代谢增强，组织细胞活力及再生能力提高。远红外线治疗慢性炎症时，可以改善血液循环，增加细胞的吞噬功能，消除肿胀，促进炎症消散。远红外线可降低神经系统的兴奋性，有镇痛、解除横纹肌和平滑肌痉挛以及促进神经功能恢复等作用。在治疗慢性感染性伤口和慢性溃疡时，改善组织营养，消除肉芽水肿，促进肉芽生长，加快伤口愈合。远红外线照射有减少烧伤创面渗出的作用。远红外线还经常用于治疗扭挫伤，促进组织肿张和血肿消散以及减轻术后粘连，促进瘢痕软化，减轻瘢痕挛缩等。
因此，一种可释放负氧离子和远红外线的材料具有广阔的应用前景。目前，还没有很好地具有上述两种功能的材料。
有鉴于此，特提出本发明。
发明内容
本发明的第一目的在于提供负氧离子粉。该负氧离子粉解决了现有材料无法实现通过释放负氧离子和远红外线起到保健功能的问题。并且，本发明提供的负氧离子粉中通过铝、硅、硼、铁、钠、钾等元素的合理配比，使制得的负氧离子粉释放的负氧离子粉含量高和远红外线的辐射强度符合国家标准。
本发明的第二目的在于提供采用该负氧离子粉制备PU的方法。该制备方法在现有PU的生产线上即可完成，无需购买新的生产设备，是一种成本低廉的制备方法。
本发明的第三目的在于提供一种采用上述方法制得的具有保健功能的PU材料。
为了实现本发明的上述目的，特采用以下技术方案：
一种负氧离子粉，以质量百分数计，所述负氧离子粉中：Al2O3的含量为33％-38％，SiO2的含量为32％-36％，B2O3的含量为9％-13％，MgO的含量为2％-6.5％，Fe2O3的含量为8％-12％，Na2O的含量为0.7％-1.1％，K2O的含量为0.01％-0.08％，CaO的含量为0.5％-1.0％，P2O5的含量为0.1％-0.3％，TiO2的含量为0.1％-0.3％和FeO的含量为0.9％-1.5％。
本发明提供一种可释放负氧离子和远红外线的负氧离子粉。在该负氧离子粉中，通过铝、硅、硼、铁、钠、钾等元素的合理配比，使制得的负氧离子粉释放的负氧离子含量高和远红外线的辐射强度符合国家标准，从而具有优异的保健功能。
优选地，以质量百分数计，所述负氧离子粉中：Al2O3的含量为35％-36％，SiO2的含量为34％-35％，B2O3的含量为10％-11％，MgO的含量为4％-5％，Fe2O3的含量为10％-11％，Na2O的含量为0.85％-1.0％，K2O的含量为0.03％-0.05％，CaO的含量为0.7％-0.9％，P2O5的含量为0.15％-0.25％，TiO2的含量为0.2％-0.3％和FeO的含量为1.2％-1.4％。
优选地，所述负氧离子粉的粒度为1000目以上。
进一步优选地，所述负氧离子粉的粒度为1200-1600目。
一种利用本发明提供的负氧离子粉制备慢回弹记忆棉的方法，包括如下步骤：
在发泡溶液中添加质量占发泡溶液3％-6％的负氧离子粉，搅拌均匀后经慢回弹发泡机械发泡出慢弹回记忆棉。
为了实现本发明所提供的负氧离子粉的保健功能，本发明提供了一种利用该负氧离子粉制备慢弹回记忆棉的制备方法。该制备方在现有慢弹回记忆棉的生产线上即可完成，无需购买新的生产设备，是一种成本低廉的制备方法。
而且，采用该方法将负氧离子粉均匀融合至慢弹回记忆棉中，使慢弹回记忆棉能够均匀、持久地释放负氧离子和红外线，具有突出的保健功能。
优选地，以重量份计，所述记忆棉发泡溶液包括：聚醚多元醇40-45份、聚醚330N50-55份、聚醚362810-15份、三乙烯0.6-1.0份、二甲基乙醇胺0.5-0.8份、一氟二氯乙烷25-28份、甲苯二异氰酸酯2-5份、二苯基甲烷二异氰酸酯1-2.5份和水3-10份。
一种利用本发明提供的制备方法制得的慢弹回记忆棉。
本发明提供的慢弹回记忆棉不但保留了自身的性质，还具备了负氧离子粉的性质，可均匀、持久地释放负氧离子和远红外线，两者的功能实现完美地结合，使得本发明提供的慢弹回记忆棉具有保健功能。
将该慢弹回记忆棉经加工可制得具有保健功能的产品，如床垫、靠垫、坐垫、护具等。
一种利用本发明提供的负氧离子粉制备PU合成革的制备方法，包括如下步骤：
以起毛布为底基，在涂料中加入质量占涂料3％-6％的负氧离子粉混匀后，将所述底基用所述涂料浸渍、涂覆，经凝固、磨面，得到PU合成革。
为了实现本发明所提供的负氧离子粉的保健功能，本发明提供了一种利用该负氧离子粉制备PU合成革的制备方法。该制备方法在现有PU合成革的生产线上即可完成，无需购买新的生产设备，是一种成本低廉的制备方法。
而且，采用该方法将负氧离子粉均匀融合至PU合成革中，使PU合成革能够均匀、持久地释放负氧离子和远红外线，具有突出的保健功能。
优选地，以重量份计，所述涂料包括：聚醚95-100份，二乙醇胺1-1.2份，双(二甲胺基乙基)醚0.08-0.12份，硅泡沫稳定剂0.4-1.0份，辛酸亚锡0.15-0.16份、甲苯二异氢酸脂30-40份和水2.4-2.8份。
一种本发明提供的制备方法制得的PU合成革。
本发明提供的PU合成革不但保留了自身的性质，还具备了负氧离子粉的性质，可均匀、持久地释放负氧离子和远红外线，两者的功能实现完美地结合，使得本发明提供的PU合成革具有保健功能。
将该PU合成革经加工可制得具有保健功能的产品，如皮带、皮具、皮衣、鞋垫鞋材、护具、医疗器械等。
与现有技术相比，本发明的有益效果为：
(1)提供了一种可释放负氧离子和远红外线的负氧离子粉。该负氧离子粉解决了现有材料无法实现通过释放负氧离子和远红外线起到保健功能的问题。并且，本发明提供的负氧离子粉中通过铝、硅、硼、铁、钠、钾等元素的合理配比，使制得的负氧离子粉释放的负氧离子粉含量高和红外线的辐射强度符合国家标准。
(2)本发明提供了一种采用该负氧离子粉制备PU的制备方法。该制备方法在现有记忆棉、乳胶、海绵和PU合成革的生产线上即可完成，无需购买新的生产设备，是一种成本低廉的制备方法。
(3)本发明提供了一种采用上述方法制得的具有保健功能的PU材料。该PU材料不但保留了自身的性质，还具备了负氧离子粉的性质，可均匀、持久地释放负氧离子和远红外线，两者的功能实现完美地结合，使得提供的PU材料具有保健功能。
具体实施方式
下面将结合实施例对本发明的实施方案进行详细描述，但是本领域技术人员将会理解，下列实施例仅用于说明本发明，而不应视为限制本发明的范围。实施例中未注明具体条件者，按照常规条件或制造商建议的条件进行。所用试剂或仪器未注明生产厂商者，均为可以通过市售购买获得的常规产品。
实施例1
本实施例提供了一种负氧离子粉，以质量百分数计，所述负氧离子粉中：
Al2O3的含量为38％，SiO2的含量为36％，B2O3的含量为9％，MgO的含量为6.5％，Fe2O3的含量为8％，Na2O的含量为0.7％，K2O的含量为0.01％，CaO的含量为0.5％，P2O5的含量为0.1％，TiO2的含量为0.29％和FeO的含量为0.9％。
实施例2
本实施例提供了一种负氧离子粉，以质量百分数计，所述负氧离子粉中：
Al2O3的含量为33％，SiO2的含量为32％，B2O3的含量为13％，MgO的含量为5.72％，Fe2O3的含量为12％，Na2O的含量为1.1％，K2O的含量为0.08％，CaO的含量为1.0％，P2O5的含量为0.3％，TiO2的含量为0.3％和FeO的含量为1.5％。
实施例3
本实施例提供了一种负氧离子粉，以质量百分数计，所述负氧离子粉中：
Al2O3的含量为36％，SiO2的含量为36％，B2O3的含量为9.87％，MgO的含量为4％，Fe2O3的含量为11％，Na2O的含量为0.85％，K2O的含量为0.03％，CaO的含量为0.7％，P2O5的含量为0.15％，TiO2的含量为0.2％和FeO的含量为1.2％。
实施例4
本实施例提供了一种负氧离子粉，其粒度为1200目，以质量百分数计，所述负氧离子粉中：
Al2O3的含量为35％，SiO2的含量为35％，B2O3的含量为11％，MgO的含量为5％，Fe2O3的含量为10.1％，Na2O的含量为1％，K2O的含量为0.05％，CaO的含量为0.9％，P2O5的含量为0.25％，TiO2的含量为0.3％和FeO的含量为1.4％。
实施例5
本实施例提供了一种负氧离子粉，其粒度为1600目，以质量百分数计，所述负氧离子粉中：
Al2O3的含量为35.5％，SiO2的含量为35％，B2O3的含量为11％，MgO的含量为4.7％，Fe2O3的含量为10.2％，Na2O的含量为0.92％，K2O的含量为0.04％，CaO的含量为0.81％，P2O5的含量为0.22％，TiO2的含量为0.26％和FeO的含量为1.35％。
实施例6
本实施例提供了一种采用实施例1-5中的负氧离子粉制备慢回弹回记忆棉的方法，包括如下步骤：
向由聚醚多元醇40kg、聚醚330N50kg、聚醚362810kg、三乙烯0.6kg、二甲基乙醇胺0.5kg、一氟二氯乙烷25kg、甲苯二异氰酸酯2kg、二苯基甲烷二异氰酸酯1kg、水3kg组成的发泡溶液中添加3％(代表负氧离子粉的质量占发泡溶液质量的百分数)的负氧离子粉，搅拌均匀后经慢回弹发泡机械发泡出慢弹回记忆棉。
实施例7
本实施例提供了一种采用实施例1-5中的负氧离子粉制备慢回弹回记忆棉的方法，包括如下步骤：
向由聚醚多元醇45kg、聚醚330N55kg、聚醚362815kg、三乙烯1.0kg、二甲基乙醇胺0.8kg、一氟二氯乙烷28kg、甲苯二异氰酸酯5kg、二苯基甲烷二异氰酸酯2.5kg、水10kg组成的发泡溶液中添加6％(代表负氧离子粉的质量占发泡溶液质量的百分数)的负氧离子粉，搅拌均匀后经慢回弹发泡机械发泡出慢回弹回记忆棉。
实施例8
本实施例提供了一种采用实施例1-5中的负氧离子粉制备PU合成革的方法，包括如下步骤：
以起毛布为底基，在由聚醚95kg，二乙醇胺1kg，双(二甲胺基乙基)醚0.08kg，硅泡沫稳定剂0.4kg，辛酸亚锡0.15kg、甲苯二异氢酸脂30kg，水2.4kg共同组成的涂料中加入3％(代表负氧离子粉的质量占涂料质量的百分数)的负氧离子粉混匀后，将所述底基用所述涂料浸渍、涂覆，经凝固、磨面，得到PU合成革。
实施例9
本实施例提供了一种采用实施例1-5中的负氧离子粉制备PU合成革的方法，包括如下步骤：
以起毛布为底基，在由聚醚100kg，二乙醇胺1.2kg，双(二甲胺基乙基)醚0.12kg，硅泡沫稳定剂1.0kg，辛酸亚锡0.16kg、甲苯二异氢酸脂40kg，水2.8kg共同组成的涂料中加入6％(代表负氧离子粉的质量占涂料质量的百分数)的负氧离子粉混匀后，将所述底基用所述涂料浸渍、涂覆，经凝固、磨面，得到PU合成革。
分别对本发明制得的PU材料与市售普通产品进行检测，经检测得出，本发制得的PU材料相比于市售的普通产品，能够释放负氧离子和远红外线，红外线的法向全发射率为0.88，红外辐射波长范围为6-14μm、负氧离子的浓度为1370个/cm3。
本发明提供的负氧离子粉中通过铝、硅、硼、铁、钠、钾等元素的合理配比，使制得的负氧离子粉释放的负氧离子粉含量高和远红外线的辐射强度符合国家标准。
除此之外，本发明提供了一种采用该负氧离子粉制备PU的制备方法。该制备方法在现有各种PU制备的生产线上即可完成，无需购买新的生产设备，是一种成本低廉的制备方法。
本发明还提供了一种采用上述方法制得的具有保健功能的PU材料。该PU材料不但保留了自身的性质，还具备了负氧离子粉的性质，可均匀、持久地释放负氧离子和远红外线，两者的功能实现完美地结合，使得提供的PU材料具有保健功能。
除了上述的慢回弹记忆棉、乳胶、海绵和PU合成革外，本发明提供的负氧离子粉还可和与EVA、PVC、PC、PE、宝丽优、尼龙、弹性纤维、涂料油漆等载体结合，制备出可释放负氧离子和红外线的相应产品。例如：与PC载体结合，制备出释放负氧离子和红外线的水杯、茶具、矿泉水瓶、防辐射屏、能量喷壶、化妆水喷壶；与聚氨酯涂料载体结合，制备出手机、电脑等外壳漆，家用电器外壳漆，电子数码产品外围设备外用漆，汽车内饰漆，家具漆；与尼龙载体结合，制备出内衣、外衣、护具用布、医疗器械用布。
尽管已用具体实施例来说明和描述了本发明，然而应意识到，在不背离本发明的精神和范围的情况下可以作出许多其它的更改和修改。因此，这意味着在所附权利要求中包括属于本发明范围内的所有这些变化和修改。

Claims (10)

1.一种负氧离子粉，其特征在于，以质量百分数计，所述负氧离子粉中：Al2O3的含量为33％-38％，SiO2的含量为32％-36％，B2O3的含量为9％-13％，MgO的含量为2％-6.5％，Fe2O3的含量为8％-12％，Na2O的含量为0.7％-1.1％，K2O的含量为0.01％-0.08％，CaO的含量为0.5％-1.0％，P2O5的含量为0.1％-0.3％，TiO2的含量为0.1％-0.3％和FeO的含量为0.9％-1.5％。
2.根据权利要求1所述的负氧离子粉，其特征在于，以质量百分数计，所述负氧离子粉中：Al2O3的含量为35％-36％，SiO2的含量为34％-35％，B2O3的含量为10％-11％，MgO的含量为4％-5％，Fe2O3的含量为10％-11％，Na2O的含量为0.85％-1.0％，K2O的含量为0.03％-0.05％，CaO的含量为0.7％-0.9％，P2O5的含量为0.15％-0.25％，TiO2的含量为0.2％-0.3％和FeO的含量为1.2％-1.4％。
3.根据权利要求1或2所述的负氧离子粉，其特征在于，所述负氧离子粉的粒度为1000目以上。
4.根据权利要求3所述的负氧离子粉，其特征在于，所述负氧离子粉的粒度为1200-1600目。
5.一种利用权利要求1-4任一项所述的负氧离子粉制备PU的方法，其特征在于，包括如下步骤：
在发泡溶液中添加质量占发泡溶液3％-6％的负氧离子粉，搅拌均匀后经慢回弹发泡机械发泡出慢弹回记忆棉。
6.根据权利要求5所述的方法，以记忆棉为例，其特征在于，以重量份计，所述发泡溶液包括：聚醚多元醇40-45份、聚醚330N50-55份、聚醚362810-15份、三乙烯0.6-1.0份、二甲基乙醇胺0.5-0.8份、一氟二氯乙烷25-28份、甲苯二异氰酸酯2-5份、二苯基甲烷二异氰酸酯1-2.5份和水3-10份。
7.一种权利要求5或6所述的方法制得的慢弹回记忆棉。
8.一种利用权利要求1-4任一项所述的负氧离子粉制备PU合成革的方法，其特征在于，包括如下步骤：
以起毛布为底基，在涂料中加入质量占涂料3％-6％的负氧离子粉混匀后，将所述底基用所述涂料浸渍、涂覆，经凝固、磨面，得到PU合成革。
9.根据权利要求8所述的方法，其特征在于，以重量份计，所述涂料包括：聚醚95-100份，二乙醇胺1-1.2份，双(二甲胺基乙基)醚0.08-0.12份，硅泡沫稳定剂0.4-1.0份，辛酸亚锡0.15-0.16份、甲苯二异氢酸脂30-40份和水2.4-2.8份。
10.一种权利要求8或9所述的方法制得的PU合成革。
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106113883A (zh) * 2016-06-23 2016-11-16 成都市森远通讯网络有限公司 纳米负离子pvc板的制备方法及汽车挂件和房屋装饰产品
CN108286683A (zh) * 2018-03-11 2018-07-17 哈尔滨医大眼科医疗科技开发有限公司 一种医院用手术灯
CN110876508A (zh) * 2019-12-10 2020-03-13 耐乐途(广东)皮鞋制造有限公司 一种远红外线保健鞋垫的制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102168367A (zh) * 2011-02-23 2011-08-31 北京健热宝科技开发有限公司 一种具有减肥功能的纺织制品及其制备方法
CN102206367A (zh) * 2011-04-29 2011-10-05 东莞市广海大橡塑科技有限公司 一种负离子浴垫及其制备方法
CN203000119U (zh) * 2012-11-26 2013-06-19 张洁 负离子慢回弹记忆棉垫
CN203222692U (zh) * 2013-05-21 2013-10-02 清远市齐力合成革有限公司 一种负离子保健合成革
CN103849955A (zh) * 2014-02-25 2014-06-11 浙江慧德新材料有限公司 一种具有多种功能元素的新型保健纤维的生产工艺

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102168367A (zh) * 2011-02-23 2011-08-31 北京健热宝科技开发有限公司 一种具有减肥功能的纺织制品及其制备方法
CN102206367A (zh) * 2011-04-29 2011-10-05 东莞市广海大橡塑科技有限公司 一种负离子浴垫及其制备方法
CN203000119U (zh) * 2012-11-26 2013-06-19 张洁 负离子慢回弹记忆棉垫
CN203222692U (zh) * 2013-05-21 2013-10-02 清远市齐力合成革有限公司 一种负离子保健合成革
CN103849955A (zh) * 2014-02-25 2014-06-11 浙江慧德新材料有限公司 一种具有多种功能元素的新型保健纤维的生产工艺

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
K.WEISSERMEL、H.J.ARPE: "《工业有机化学》", 30 November 1998, 化学工业出版社 *
中国技术成果大会编辑部: "《中国技术成果大全》", 31 August 1994, 科学技术文献出版社 *
化学工业部科学技术情报研究所: "《世界精细化工产品技术经济手册》", 31 December 1988, 化学工业部科学技术情报研究所 *
商成杰: "《新型染整助剂手册》", 31 October 2002, 中国纺织出版社 *
孙尔康、张剑荣: "《综合化学实验》", 31 May 2014, 南京大学出版社 *
汪多仁: "负离子纤维的开发与应用进展", 《河北纺织》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106113883A (zh) * 2016-06-23 2016-11-16 成都市森远通讯网络有限公司 纳米负离子pvc板的制备方法及汽车挂件和房屋装饰产品
CN108286683A (zh) * 2018-03-11 2018-07-17 哈尔滨医大眼科医疗科技开发有限公司 一种医院用手术灯
CN110876508A (zh) * 2019-12-10 2020-03-13 耐乐途(广东)皮鞋制造有限公司 一种远红外线保健鞋垫的制备方法

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