CN105327785A - Flotation technology of PPM level low-iron high-purity quartz sand - Google Patents
Flotation technology of PPM level low-iron high-purity quartz sand Download PDFInfo
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- CN105327785A CN105327785A CN201510779912.8A CN201510779912A CN105327785A CN 105327785 A CN105327785 A CN 105327785A CN 201510779912 A CN201510779912 A CN 201510779912A CN 105327785 A CN105327785 A CN 105327785A
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- flotation
- quartz sand
- ore
- ppm level
- sand
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000005188 flotation Methods 0.000 title claims abstract description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000006004 Quartz sand Substances 0.000 title claims abstract description 19
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 14
- 238000005516 engineering process Methods 0.000 title abstract description 6
- 239000004576 sand Substances 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 4
- 238000007667 floating Methods 0.000 claims description 20
- 239000011521 glass Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 239000002283 diesel fuel Substances 0.000 claims description 5
- 239000003208 petroleum Substances 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000003814 drug Substances 0.000 claims description 2
- 238000007885 magnetic separation Methods 0.000 claims description 2
- 238000005065 mining Methods 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000002002 slurry Substances 0.000 abstract description 3
- 208000005156 Dehydration Diseases 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 11
- 239000011707 mineral Substances 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 239000003921 oil Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 238000009291 froth flotation Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 229910002703 Al K Inorganic materials 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000013083 solar photovoltaic technology Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/025—Froth-flotation processes adapted for the flotation of fines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/007—Modifying reagents for adjusting pH or conductivity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to a flotation technology of PPM level low-iron high-purity quartz sand. The flotation technology is characterized in that the quartz sand raw material is mixed and stirred through three slurry mixing barrels, a specially blended flotation reagent is added, the ore pulp is fed into a flotation machine for flotation, and fine sand and tailings are subjected to desliming and dehydration treatment, so as to obtain a low-iron high-purity fine quartz sand product and a remaining tailing product. The quartz sand flotation method is easy to achieve and simple in operation, and the flotation of quartz sand can be quickly and effectively achieved by virtue of the flotation technology and the flotation reagent provided by the invention, so that the output rate of high quality quartz sand is improved, and the production cost of high quality quartz sand is greatly reduced.
Description
Technical field
The present invention relates to low iron-stone sand purification field, particularly relate to a kind of low iron-stone sand and glass sand floatation process and with the use of floating agent.
Technical background
Solar-photovoltaic technology is the technology converting solar energy into electric power, and the glass substrate of solar photovoltaic generation system needs to use ultra-clear glasses, and ultra-clear glasses substantially increases photoelectric transformation efficiency with the high transmission rate of its uniqueness (91.5%).Photovoltaic glass requires high to impurity content, light transmittance, microdefect etc. because of the environment for use of himself finished product, and the quality requirement of the low iron glass sand (accounting for 60-70%) of its main material PPM level is extremely strict, the chemical analysis that General Requirements reaches: SiO
2(99.5%), Fe
2o
3(80PPM).In order to high efficiency, low cost produces the low iron glass sand of satisfactory PPM level, need existing production technology upgrading, the floating wash agent of improvement.
The low iron glass sand of PPM level, can be used for equally producing high-grade ware glass, quartz ampoule and polysilicon etc., has a extensive future.
Summary of the invention
The object of this invention is to provide the low iron-stone sand of a kind of PPM level and glass sand floatation process, the quality of quartz sand can be increased substantially, the growing quality requirements problem in market cannot be met with the production solving current China quartz sand.
In order to achieve the above object, the technical solution adopted in the present invention is:
A kind of PPM level low iron glass sand floatation process, comprises the following steps:
(1), the quartz sand raw material of tcrude ore mechanical crushing after desliming, classification, magnetic separation of mining gained is sent in the first mixing cirtern, stir, regulate ore pulp PH to 6.0-7.5;
(2), by the ore pulp that step (1) is handled well send into the second mixing cirtern, in mixing cirtern, add floating agent, stir and make its abundant hybrid reaction;
(3) ore pulp, by step (2) handled well sends into the 3rd mixing cirtern, in the 3rd mixing cirtern, add terpenic oil, stirs and in fact mixes, then sent in flotation device by ore pulp and carry out flotation;
(4), by the essence sand floatingly selected send into washed ore pond, squeeze in upper strata desliming bucket through Pulp pump, slough floating agent, then flow into lower floor's desliming bucket, add clear water, washed ore is rinsed well, squeeze in washed ore storehouse;
Between the composition of described floating agent and each composition by weight ratio:
Mixed amine 25-30%
Petroleum sodium sulfonate 5-7%
Aliphatic acid 25-30%
Diesel oil 30-35%.
The reagent regulating PH in step (1) is 5%H
2sO
4or NaOH solution.
In described step (2), quartz sand raw material flotation medicament addition per ton is 2kg.
In described step (3), raw material terpenic oil addition per ton is 0.102kg.Use the floating agent of this concentration and terpenic oil obviously can promote the effect of flotation.
A kind of floating agent, between its composition and each composition by weight ratio:
Mixed amine 25-30%
Petroleum sodium sulfonate 5-7%
Aliphatic acid 25-30%
Diesel oil 30-35%.
The theoretical foundation of various floatation process is substantially identical, and namely ore particle is because of the hydrophobic property of its own face or hydrophobic (close gas or oil) characteristic of obtaining after floating agent effect, can assemble at liquid-gas or water-oily interface.Most widely used is at present froth flotation method.Ore makes various mineral disaggregation become monomer particle through broken with grinding, and makes granular size meet floatation process requirement.Add various floating agent to the ore pulp after ore grinding and stir mediation, making and mineral grain effect, to expand the intergranular floatability difference of different minerals.The ore pulp mixed up sends into flotation cell, stirs inflation.Ore particle in ore pulp and bubble contact, collision, the ore particle that floatability is good optionally adheres to bubble and is carried to rise becomes the mineralized froth layer of airwater mist cooling composition, overflows through mechanical scraping or from mineral slurry level, then dewaters, is dried to concentrate product.The mineral grain such as floaty gangue, does not discharge as product from failing bottom flotation cell with ore pulp.Another by useless mineral grain emersion, valuable mineral particle is stayed in ore pulp, is called reverse flotation, as emersion quartz etc. from iron ore.
Usual foam flotation is suitable for the ore particle sorting 0.5mm to 5 μm, and concrete grain limit is depending on mineral.Special method for floating need be adopted when selected granularity is less than 5 μm.If flocculation-flotation makes the valuable mineral of particulate flocculate into larger particles with flocculant, float again after deviating from the thin mud of gangue and remove coarse grain gangue.Carrier flotation makes carrier with the ore particle that granularity is suitable for flotation, makes fine mineral particle adhere to carrier surface and sorting of thereupon floating.Also useful oils makes the reunion of thin ore particle carry out oil aggregation flotation and the emulsion floatation of flotation; And utilize high-temperature chemical reaction to make Gold in Ores belong to the segregation flotation etc. of Mineral Transformation for flotation again after metal.During with metal ion in froth flotation recycle-water solution, first chemically precipitate or spent ion exchange resin adsorbs, and then flotation sediment or resin particle.The material of process in molecule, ion and colloid size, adopts offscum to be separated.Be characterized in the hydrophobicity utilizing some material, slowly stir and inflate on a small quantity, make into offscum and be gathered on the water surface and scrape.As reclaimed grease, protein, paper pulp and chemical products etc. from water.Ion flotation be can occur to precipitate with ion or complexing surfactant effect under, make reaction product enter offscum, complete sorting.
The quartz sand flotation method that the present invention relates to is easy to realize, simple to operate, the flotation of quartz sand fast and effeciently can be realized by method for floating of the present invention and floating agent, and then improve the output capacity of high-quality quartz sand, and greatly reduce the production cost of high-quality quartz sand, also reduce the labour intensity of operating personnel.
Accompanying drawing explanation
Fig. 1 is production technological process of the present invention.
Detailed description of the invention
A kind of PPM level low iron glass sand floatation process, sends into pretreated quartz sand raw material in first mixing cirtern through rubber conveyer, according to the detection to pH value, adds appropriate 5%H to the first mixing cirtern
2sO
4or NaOH solution, regulate slurry pH in the first mixing cirtern to 6.0 ~ 7.5, if the natural ph of raw material is in 6.0 ~ 7.5 scopes, then do not need to add H
2sO
4or NaOH solution regulates.Ore pulp is input in the second mixing cirtern after stirring again, and adds floating agent, stirs, fully react to the second mixing cirtern, Fe in ore pulp
2o
3, mica, the impurity such as feldspar activity will change.Ore pulp inputs in the 3rd mixing cirtern again, adds terpenic oil stir to the 3rd mixing cirtern, and after fully stirring evenly, ore pulp flows in flotation device and carries out flotation.The washed ore floatingly selected flows into washed ore pond, squeezes in upper strata desliming bucket, slough floating agent through Pulp pump, then flows into lower floor's desliming bucket, adds clear water, rinsed well by washed ore, squeeze in washed ore storehouse.The waste water produced in production, flows in preset pond after natural sedimentation, capable of circulationly re-uses.
Between the composition of described floating agent and each composition by weight ratio:
Mixed amine 25-30%
Petroleum sodium sulfonate 5-7%
Aliphatic acid 25-30%
Diesel oil 30-35%.
Data Comparison (content PPM) before and after the flotation of a glass sand sample
| Element | Li | B | Na | Mg | Al | K | Fe | Other element | Impurity summation | Productive rate |
| Before flotation | 7.10 | 9.53 | 30.25 | 32.20 | 707.37 | 153.44 | 79.17 | 10.05 | 1029.11 | |
| After flotation | 5.05 | 6.72 | 11.4 | 21.48 | 265.84 | 28.64 | 18.23 | 1.71 | 360.59 | 98% |
Claims (5)
1. a PPM level low iron glass sand floatation process, is characterized in that, comprise the following steps:
(1), the quartz sand raw material of tcrude ore mechanical crushing after desliming, classification, magnetic separation of mining gained is sent in the first mixing cirtern, stir, regulate ore pulp PH to 6.0-7.5;
(2), by the ore pulp that step (1) is handled well send into the second mixing cirtern, in mixing cirtern, add floating agent, stir and make its abundant hybrid reaction;
(3) ore pulp, by step (2) handled well sends into the 3rd mixing cirtern, in the 3rd mixing cirtern, add terpenic oil, stirs and in fact mixes, then sent in flotation device by ore pulp and carry out flotation;
(4), by the essence sand floatingly selected send into washed ore pond, squeeze in upper strata desliming bucket through Pulp pump, slough floating agent, then flow into lower floor's desliming bucket, add clear water, washed ore is rinsed well, squeeze in washed ore storehouse;
Between the composition of the floating agent in described flow chart and each composition by weight ratio:
Mixed amine 25-30%
Petroleum sodium sulfonate 5-7%
Aliphatic acid 25-30%
Diesel oil 30-35%.
2. a kind of PPM level according to claim 1 low iron glass sand floatation process, is characterized in that, the reagent regulating PH in step (1) is 5%H
2sO
4or NaOH solution.
3. a kind of PPM level according to claim 1 low iron glass sand floatation process, is characterized in that, in described step (2), quartz sand raw material flotation medicament addition per ton is 2kg.
4. a kind of PPM level according to claim 1 low iron glass sand floatation process, is characterized in that, in described step (3), raw material terpenic oil addition per ton is 0.102kg.
5. a floating agent, is characterized in that: between its composition and each composition by weight ratio:
Mixed amine 25-30%
Petroleum sodium sulfonate 5-7%
Aliphatic acid 25-30%
Diesel oil 30-35%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510779912.8A CN105327785A (en) | 2015-11-16 | 2015-11-16 | Flotation technology of PPM level low-iron high-purity quartz sand |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510779912.8A CN105327785A (en) | 2015-11-16 | 2015-11-16 | Flotation technology of PPM level low-iron high-purity quartz sand |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105327785A true CN105327785A (en) | 2016-02-17 |
Family
ID=55278664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510779912.8A Pending CN105327785A (en) | 2015-11-16 | 2015-11-16 | Flotation technology of PPM level low-iron high-purity quartz sand |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105327785A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106076650A (en) * | 2016-06-14 | 2016-11-09 | 蚌埠玻璃工业设计研究院 | A kind of quartz mineral purifying and flotation agent |
| CN106269273A (en) * | 2016-08-08 | 2017-01-04 | 合肥万泉非金属矿科技有限公司 | A kind of PPM level low ferrum glass sand floating agent |
| CN106861890A (en) * | 2017-01-18 | 2017-06-20 | 长春黄金研究院 | A kind of cassiterite process mineralogy ore-dressing technique |
| CN108607679A (en) * | 2018-04-28 | 2018-10-02 | 四川南联环资科技股份有限公司 | A kind of quartz sand preparation process of high-efficiency environment friendly |
| CN111013813A (en) * | 2019-12-27 | 2020-04-17 | 中建材蚌埠玻璃工业设计研究院有限公司 | Method for preparing 10ppm low-iron quartz sand by non-pickling process |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61157374A (en) * | 1984-12-28 | 1986-07-17 | Takehisa Miki | High degree purification of silica sand |
| CN1586728A (en) * | 2004-09-16 | 2005-03-02 | 中国凯盛国际工程有限公司 | Flotation process for quartz tail sand and its special floatation collecting agent |
| CN101507947A (en) * | 2009-04-02 | 2009-08-19 | 广宝来特种石英（凤阳）科技有限公司 | Quartz sand flotation method |
| CN101628258A (en) * | 2009-08-18 | 2010-01-20 | 广宝来特种石英（凤阳）科技有限公司 | Floatation process of quartz sand |
| CN102189037A (en) * | 2011-03-08 | 2011-09-21 | 仪征风日石英科技有限公司 | Impurity removal process for quartz sand |
| CN103964444A (en) * | 2014-05-05 | 2014-08-06 | 临沂晟泉矿业有限公司 | Method for producing high-purity quartz sand |
| CN104340981A (en) * | 2013-08-09 | 2015-02-11 | 新沂市中大石英科技有限公司 | Preparation method for high-purity quartz sand |
-
2015
- 2015-11-16 CN CN201510779912.8A patent/CN105327785A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61157374A (en) * | 1984-12-28 | 1986-07-17 | Takehisa Miki | High degree purification of silica sand |
| CN1586728A (en) * | 2004-09-16 | 2005-03-02 | 中国凯盛国际工程有限公司 | Flotation process for quartz tail sand and its special floatation collecting agent |
| CN101507947A (en) * | 2009-04-02 | 2009-08-19 | 广宝来特种石英（凤阳）科技有限公司 | Quartz sand flotation method |
| CN101628258A (en) * | 2009-08-18 | 2010-01-20 | 广宝来特种石英（凤阳）科技有限公司 | Floatation process of quartz sand |
| CN102189037A (en) * | 2011-03-08 | 2011-09-21 | 仪征风日石英科技有限公司 | Impurity removal process for quartz sand |
| CN104340981A (en) * | 2013-08-09 | 2015-02-11 | 新沂市中大石英科技有限公司 | Preparation method for high-purity quartz sand |
| CN103964444A (en) * | 2014-05-05 | 2014-08-06 | 临沂晟泉矿业有限公司 | Method for producing high-purity quartz sand |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106076650A (en) * | 2016-06-14 | 2016-11-09 | 蚌埠玻璃工业设计研究院 | A kind of quartz mineral purifying and flotation agent |
| CN106076650B (en) * | 2016-06-14 | 2018-07-10 | 蚌埠玻璃工业设计研究院 | A kind of quartz mineral purifying and flotation agent |
| CN106269273A (en) * | 2016-08-08 | 2017-01-04 | 合肥万泉非金属矿科技有限公司 | A kind of PPM level low ferrum glass sand floating agent |
| CN106861890A (en) * | 2017-01-18 | 2017-06-20 | 长春黄金研究院 | A kind of cassiterite process mineralogy ore-dressing technique |
| CN106861890B (en) * | 2017-01-18 | 2019-05-21 | 长春黄金研究院 | A kind of cassiterite process mineralogy ore-dressing technique |
| CN108607679A (en) * | 2018-04-28 | 2018-10-02 | 四川南联环资科技股份有限公司 | A kind of quartz sand preparation process of high-efficiency environment friendly |
| CN111013813A (en) * | 2019-12-27 | 2020-04-17 | 中建材蚌埠玻璃工业设计研究院有限公司 | Method for preparing 10ppm low-iron quartz sand by non-pickling process |
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Application publication date: 20160217 |