CN105325405B - A kind of highly effective pesticide solvent and preparation method thereof - Google Patents
A kind of highly effective pesticide solvent and preparation method thereof Download PDFInfo
- Publication number
- CN105325405B CN105325405B CN201510840470.3A CN201510840470A CN105325405B CN 105325405 B CN105325405 B CN 105325405B CN 201510840470 A CN201510840470 A CN 201510840470A CN 105325405 B CN105325405 B CN 105325405B
- Authority
- CN
- China
- Prior art keywords
- parts
- soybean oil
- weight
- epoxidized soybean
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002904 solvent Substances 0.000 title claims abstract description 22
- 239000000575 pesticide Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 6
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 26
- 239000003549 soybean oil Substances 0.000 claims abstract description 26
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000001149 (9Z,12Z)-octadeca-9,12-dienoate Substances 0.000 claims abstract description 11
- DVWSXZIHSUZZKJ-UHFFFAOYSA-N 18:3n-3 Natural products CCC=CCC=CCC=CCCCCCCCC(=O)OC DVWSXZIHSUZZKJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims abstract description 11
- DVWSXZIHSUZZKJ-YSTUJMKBSA-N methyl linolenate Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(=O)OC DVWSXZIHSUZZKJ-YSTUJMKBSA-N 0.000 claims abstract description 11
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims abstract description 11
- 229940073769 methyl oleate Drugs 0.000 claims abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 10
- 229920000053 polysorbate 80 Polymers 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 7
- 239000004367 Lipase Substances 0.000 claims description 6
- 102000004882 Lipase Human genes 0.000 claims description 6
- 108090001060 Lipase Proteins 0.000 claims description 6
- 229960002163 hydrogen peroxide Drugs 0.000 claims description 6
- 235000019421 lipase Nutrition 0.000 claims description 6
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 2
- 125000002252 acyl group Chemical group 0.000 claims 1
- 125000005594 diketone group Chemical group 0.000 claims 1
- 238000004321 preservation Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 9
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 125000005439 maleimidyl group Chemical group C1(C=CC(N1*)=O)=O 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 241000222120 Candida <Saccharomycetales> Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005586 Nicosulfuron Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000000479 mixture part Substances 0.000 description 1
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The present invention relates to a kind of highly effective pesticide solvents comprising the component of following parts by weight：2 ~ 5 parts of methyl oleate, 2 ~ 5 parts of methyl linolenate, 6 ~ 8 parts of epoxidized soybean oil, 1 ~ 2 part of chiral pyrrolidine -2,5- diketone, 1 ~ 3 part of surfactant.The invention further relates to the methods for preparing above-mentioned highly effective pesticide solvent.The solvent environment of the present invention is friendly, synergistic effect is good.
Description
Technical field
The present invention relates to pesticide solvent technical fields, and in particular to a kind of highly effective pesticide solvent.
Background technology
Usually, the formulations of pesticide include mainly missible oil, aqueous emulsion, microemulsion and soluble liquid, in production process
A large amount of such as toluene, dimethylbenzene organic solvent will be used.These organic solvents can dissolve pesticide original medicine, after adding water emulsification
It sprays, but it is also only limited to dissolve, not only without generating better effect, brings pollution to environment instead.
Invention content
The object of the present invention is to provide the good highly effective pesticide solvents of a kind of environmental-friendly and synergistic effect.
The present invention adopts the following technical scheme that：
A kind of highly effective pesticide solvent comprising the component of following parts by weight：2 ~ 5 parts of methyl oleate, methyl linolenate 2 ~ 5
Part, 6 ~ 8 parts of epoxidized soybean oil, 1 ~ 2 part of chiral pyrrolidine -2,5- diketone, 1 ~ 3 part of surfactant.
Further, the surfactant is Tween-80.
Further, chiral pyrrolidine -2,5- diketone is maleimide and/or tartrimide.
Preferably, chiral pyrrolidine -2,5- diketone is maleimide and tartrimide, mass ratio 1: 1.
Further, the epoxidized soybean oil is made by enzyme process.
Further, the preparation method of the epoxidized soybean oil is：By soybean oil, lipase according to 100 parts by weight: 4 weights
Part mixing is measured, stirring is warming up to 28 DEG C, keeps the temperature and instills 15 weight of hydrogenperoxide steam generator that mass fraction is 5% into mixture
Part, continue after keeping the temperature and stirring 4 hours, centrifugation, alkali cleaning, washing are finally dried to obtain epoxidized soybean oil.
Preferably, the methyl oleate is 4 parts by weight, methyl linolenate is 4 parts by weight, epoxidized soybean oil is 7 weight
Part, 0.5 parts by weight of maleimide, 0.5 parts by weight of tartrimide, Tween-80 are 2 parts by weight.
A method of the above-mentioned highly effective pesticide solvent of power being prepared, method is as follows：The each component for weighing the parts by weight, in 35
Stirring is to be sufficiently mixed at ~ 50 DEG C, after natural cooling to obtain the final product.
In preparation method, preferably 37 DEG C of mixing temperature.
The beneficial effects of the present invention are：
（1）Using the methyl esters of epoxidized soybean oil and pure natural vegetable oil as main component, avoid directly using pure
The problem of oxidative rancidity, easily occurs for crude vegetal, is not only advantageous to dissolving pesticide, is also prevented from the organic solvents such as benzene to ring
The injury in border and operator.
（2）Surfactant selects nonionic surfactant Tween-80, since Tween-80 is oleate,
It is similar to methyl oleate, methyl linolenate, epoxidized soybean oil to mix, while the table of epoxidized soybean oil and vegetable oil solvent can be reduced
Face tension increases emulsifying effectiveness, solubilization is played to pesticide.
（3）Chiral pyrrolidine -2,5- diketone and natural plants oil component and surfactant are synergistic, are more advantageous to agriculture
The dispersion of medicine in a solvent improves pesticide efficacy.
（4）Each component is stirred mixing under thermal condition, is not only able to improve each component and dissolve each other effect, also help
Improve the emulsifying effectiveness of surfactant.
（5）Epoxidized soybean oil is prepared using enzyme process, and local oxygen content can effectively be improved by instilling hydrogen peroxide, be improved
Reaction rate.The too fast rate of release of oxygen caused by avoiding the instantaneous addition of a large amount of hydrogen peroxide simultaneously, and thus bring
Hydrogen peroxide easily lead to enzyme inactivation and reaction be difficult to control the problems such as.
Specific implementation mode
The following describes the present invention in detail with reference to examples.The scope of the present invention is not limited to embodiment, this field
Technical staff makes any change in the range of claim limits and also belongs to the scope of protection of the invention.
In the following example, used epoxidized soybean oil is prepared using enzyme process, and specific method is：Take soybean oil
100kg, lipase 4kg mixing, stirring are warming up to 28 DEG C, keep the temperature and instill matter into the mixture of above-mentioned soybean oil and lipase
The hydrogenperoxide steam generator 15kg that score is 5% is measured, flow control needs to be stirred continuously, peroxidating in 7.5kg/h during instilling
Hydrogen drips off subsequent continuation of insurance temperature and stirs 2 hours, and finally centrifugation, alkali cleaning, washing, drying, obtain epoxidized soybean oil.The lipase
For Candida 99-125 lipase.
Embodiment 1
Methyl oleate 2kg, methyl linolenate 2kg, epoxidized soybean oil 6kg, maleimide 1.5kg, the Tween-80 is taken to be
1kg.Above-mentioned each component is stirred to be sufficiently mixed, after natural cooling at 35 DEG C to obtain the final product.
Embodiment 2
Take methyl oleate 5kg, methyl linolenate 5kg, epoxidized soybean oil 8kg, tartrimide 2kg, Tween-80 3kg.
Above-mentioned each component is stirred to be sufficiently mixed, after natural cooling at 50 DEG C to obtain the final product.
Embodiment 3
To take methyl oleate be 4kg, methyl linolenate 4kg, epoxidized soybean oil 7kg, maleimide 0.5kg, winestone
Acid imide 0.5kg, Tween-80 2kg.Above-mentioned each component is stirred to be sufficiently mixed, after natural cooling at 37 DEG C to obtain the final product.
Comparative example 1
To take methyl oleate be 4kg, methyl linolenate 4kg, epoxidized soybean oil 7kg.By above-mentioned each component at 37 DEG C
Stirring is to be sufficiently mixed, after natural cooling to obtain the final product.
Comparative example 2
To take methyl oleate be 4kg, methyl linolenate 4kg, epoxidized soybean oil 7kg, Tween-80 2kg.It will be above-mentioned each
Component is stirred to be sufficiently mixed, after natural cooling at 37 DEG C to obtain the final product.
Comparative example 3
To take methyl oleate be 4kg, methyl linolenate 4kg, epoxidized soybean oil 7kg, maleimide 0.5kg, winestone
Acid imide 0.5kg, Tween-80 2kg.By above-mentioned each component in room temperature（20℃）Under be stirred to get.
1 product physical and chemical index of effect example（Table 1）
Table 1
As shown in table 1, each physical and chemical index of 1 ~ 3 products obtained therefrom of embodiment is superior to standard value, and epoxidized soybean oil is utilized
Methyl esters with crude vegetal is as main component, in the control of acid value, is even measured again after 6 months,
The acid value value of embodiment 1 ~ 3 remains unchanged up to standard and color also below 7, and therefore, the product of embodiment 1 ~ 3 passes through combination formula, association
With the phenomenon that playing a role, effectively inhibiting oxidative rancidity.
2 preventive effect of effect example is tested
Reagent agent：4% nicosulfuron OF.
Trial crops：198 corn field of Henan.
Test process：Totally 3 processing, each processing are repeated 4 times, totally 12 cells（Random alignment）30 squares of plot area
Rice, in the corn 3-5 leaf phases, the weeds 2-4 leaf phases carry out cauline leaf process, 80 milliliter/mu of pharmaceutical quantities, 30 kgs/acre of the amount of being watered.
2 effect research of table（It estimates within 15 days, claims fresh weight within 30 days）
As can be seen from Table 2, when making solvent with embodiment 1 ~ 3, drug effect significantly improves, and total preventive effect is not less than 96%.
Effect example 3
Select decis for reagent agent, the quality proportioning of solvent and medicament is 2: 1, and medicament is 0.02950 by dose
Microgram/head.The result shows that embodiment 1 ~ 3 any one as solvent when, Mortality of insect be not less than 58%, and with comparative example 1 ~
3 any one as solvent when, Mortality of insect not more than 35%, in contrast, the solvent of embodiment 1 ~ 3 is for pesticide
Synergistic effect it is apparent.
In short, in conjunction with effect example 2 and effect example 3, makees solvent relative to corn oil or when comparative example 1 ~ 3 makees solvent, implement
The drug effect of pesticide greatly improved in example 1 ~ 3, and synergistic is with obvious effects.
Effect example 4
Solvent described in embodiment 1 ~ 3 is subjected to volatility experiment, is compared with common light aromatic solvent, as a result such as table
Shown in 3.
3 flash-point of table and volatility compare
As shown in Table 3, the more typical light aromatic solvent of the flash-point and volatility of embodiment 1 ~ 3 wants excellent, thus its
It produces, in use, endangering performance small, conducive to pesticide efficacy to human body.
The present invention is described in detail according to the above embodiments.It should be noted that above embodiment is only for act
Example illustrates invention.Under the premise of without departing from spirit and substance of the present invention, those skilled in the art can be designed that this
The a variety of alternatives and improvement project of invention, should be understood within protection scope of the present invention.
Claims (1)
1. a kind of pesticide solvent, which is characterized in that it includes the component of following parts by weight：2 ~ 5 parts of methyl oleate, methyl linolenate
2 ~ 5 parts, 6 ~ 8 parts of epoxidized soybean oil, 1 ~ 2 part of chiral pyrrolidine -2,5- diketone, 1 ~ 3 part of surfactant；
The surfactant is Tween-80；Chiral pyrrolidine -2,5- the diketone is that maleimide and/or winestone acyl are sub-
Amine；
The preparation method of the epoxidized soybean oil is：By soybean oil, lipase according to 100 parts by weight: the mixing of 4 parts by weight, stirring
28 DEG C are warming up to, keeps the temperature and is instilled into mixture 15 parts by weight of hydrogenperoxide steam generator that mass fraction is 5%, continue heat preservation simultaneously
After stirring 4 hours, centrifugation, alkali cleaning, washing are finally dried to obtain epoxidized soybean oil；
The preparation method of the pesticide solvent is as follows：The each component for weighing the parts by weight is stirred at 35 ~ 50 DEG C with fully mixed
It closes, after natural cooling to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510840470.3A CN105325405B (en) | 2015-11-27 | 2015-11-27 | A kind of highly effective pesticide solvent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510840470.3A CN105325405B (en) | 2015-11-27 | 2015-11-27 | A kind of highly effective pesticide solvent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105325405A CN105325405A (en) | 2016-02-17 |
| CN105325405B true CN105325405B (en) | 2018-11-02 |
Family
ID=55276395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510840470.3A Active CN105325405B (en) | 2015-11-27 | 2015-11-27 | A kind of highly effective pesticide solvent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105325405B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1379068A (en) * | 2001-03-29 | 2002-11-13 | 气体产品与化学公司 | Low foaming N-alkyl-tartraimine and N-alkyl melicimine wetting agent |
| CN101755790A (en) * | 2009-11-03 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Dispersible agent containing abamectin |
| CN102007915A (en) * | 2010-11-17 | 2011-04-13 | 南京扬子鸿利源化学品有限责任公司 | Synergistic oil solvent-containing ethyl missible oil herbicide and preparation method and application thereof |
| CN102132698A (en) * | 2010-01-21 | 2011-07-27 | 中化化工科学技术研究总院 | Green solvent for pesticide and application of green solvent |
| CN102239828A (en) * | 2011-07-07 | 2011-11-16 | 湖北蕲农化工有限公司 | Azadirachtin insecticide and preparation method thereof |
| CN104247722A (en) * | 2014-05-30 | 2014-12-31 | 馥稷生物科技发展（上海）有限公司 | Insecticide mate and preparation method thereof |
| CN105076132A (en) * | 2015-06-11 | 2015-11-25 | 中国农业大学 | Oil-based type pesticide synergistic auxiliary and preparation method therefor |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3644564B2 (en) * | 1996-10-18 | 2005-04-27 | ライオン株式会社 | Cleaning composition |
-
2015
- 2015-11-27 CN CN201510840470.3A patent/CN105325405B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1379068A (en) * | 2001-03-29 | 2002-11-13 | 气体产品与化学公司 | Low foaming N-alkyl-tartraimine and N-alkyl melicimine wetting agent |
| CN101755790A (en) * | 2009-11-03 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Dispersible agent containing abamectin |
| CN102132698A (en) * | 2010-01-21 | 2011-07-27 | 中化化工科学技术研究总院 | Green solvent for pesticide and application of green solvent |
| CN102007915A (en) * | 2010-11-17 | 2011-04-13 | 南京扬子鸿利源化学品有限责任公司 | Synergistic oil solvent-containing ethyl missible oil herbicide and preparation method and application thereof |
| CN102239828A (en) * | 2011-07-07 | 2011-11-16 | 湖北蕲农化工有限公司 | Azadirachtin insecticide and preparation method thereof |
| CN104247722A (en) * | 2014-05-30 | 2014-12-31 | 馥稷生物科技发展（上海）有限公司 | Insecticide mate and preparation method thereof |
| CN105076132A (en) * | 2015-06-11 | 2015-11-25 | 中国农业大学 | Oil-based type pesticide synergistic auxiliary and preparation method therefor |
Non-Patent Citations (1)
| Title |
|---|
| 油类助剂在除草剂中应用及开发前景;王成菊 等;《精细化工》;20020831;第19卷;92 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105325405A (en) | 2016-02-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104642312A (en) | Rheum officinale free anthraquinone composition for preventing plant powdery mildew and nano emulsion preparation | |
| CN104430357A (en) | Bactericide composition containing coumoxystrobin with synergistic effect | |
| CN101530096B (en) | Sterilizing composition compounded by metalaxyl and teasaponin and application thereof | |
| CN105325405B (en) | A kind of highly effective pesticide solvent and preparation method thereof | |
| CN106561649A (en) | Micro-capsule suspending agent of pretilachlor and preparation method of micro-capsule suspending agent | |
| CN103461328B (en) | Isopropyl methoxalamine microcapsule suspending agent and its preparation method and application | |
| CN105475272B (en) | A kind of emulsifier composite assistant and preparation method thereof | |
| CN105265446B (en) | A kind of composition pesticide containing alkene oxime amine and tetraconazole | |
| CN105360111B (en) | A kind of environmental protection missible oil and preparation method thereof | |
| CN105994276A (en) | Method for improving fruit setting rate of tomatoes | |
| CN110786323A (en) | Dispersible oil suspending agent with glyphosate as effective component and preparation method thereof | |
| CN104886189A (en) | Plant-sourced pesticide microemulsion and preparation method thereof | |
| CN103518755B (en) | Herbicide for paddy field isoproturon and manufacture method | |
| CN101569317A (en) | Chlorpyrifos microemulsion containing chenopodium ambrosioides oil and preparation method thereof | |
| CN105309423B (en) | A kind of environment-protection pesticide solvent and preparation method thereof | |
| CN101543221A (en) | Sterilizing composite compounded by mancozeb and tea saponin and application thereof | |
| CN107467018A (en) | One grow tobacco anti-germinating combination preparation and suppress tobacco axillary bud growth method | |
| CN103719127B (en) | Herbicidal composition for corn safety | |
| WO2018076667A1 (en) | Herbicidal composition in wheat fields and use thereof | |
| CN106465724A (en) | Aqueous suspension agent containing imidacloprid and lambda-cyhalothrin and preparation method and application | |
| CN109601548A (en) | A kind of prevention and treatment wheat paddock broadleaf weeds and gramineous weed weedicide composition | |
| CN101223889B (en) | Food-intake preventer and preparing method thereof for striped flea beetle | |
| CN105766944A (en) | A herbicide and an application thereof | |
| CN103783074A (en) | Synthetic method of cyhalothrin water emulsion | |
| CN105360116A (en) | Herbicide composition and preparation method therefor |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230919 Address after: No.98 Wuqian Road, Daqin Industrial Park, Dongguang County, Cangzhou City, Hebei Province, 061600 Patentee after: Hebei Deda new materials Limited by Share Ltd. Address before: 061600 Da Dan Zhen Cui Cun, Dongguang County, Cangzhou City, Hebei Province Patentee before: CANGZHOU DAYANG CHEMICAL Co.,Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20240402 Address after: 061600 Daqin Industrial Park, Dongguang County, Cangzhou City, Hebei Province Patentee after: CANGZHOU DAYANG CHEMICAL Co.,Ltd. Country or region after: China Address before: No.98 Wuqian Road, Daqin Industrial Park, Dongguang County, Cangzhou City, Hebei Province, 061600 Patentee before: Hebei Deda new materials Limited by Share Ltd. Country or region before: China |