CN105313516A - Anti-fake hot stamping film with 3D effect and preparation method thereof - Google Patents

Anti-fake hot stamping film with 3D effect and preparation method thereof Download PDF

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Publication number
CN105313516A
CN105313516A CN201510610175.9A CN201510610175A CN105313516A CN 105313516 A CN105313516 A CN 105313516A CN 201510610175 A CN201510610175 A CN 201510610175A CN 105313516 A CN105313516 A CN 105313516A
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layer
false proof
blocking film
effect
film
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CN105313516B (en
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杨兴国
徐晓光
郑成赋
鲁琴
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Wuhan Huagong Image Technology & Development Co ltd
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Wuhan Huagong Image Technology & Development Co Ltd
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Abstract

The invention discloses an anti- fake hot stamping film with a 3D effect and a preparation method thereof. The anti- fake hot stamping film comprises a polyethylene glycol terephthalate (PET) plastic thin film, a mold releasing layer, an imaging layer, a metal reflecting layer and a hot melt glue layer which are overlaid sequentially. The imaging layer is an ultraviolet (UV) mold pressing layer composed of two or more disconnected local positioning patterns. The softening point of the mold releasing layer is 95-120 DEG C. The mold releasing layer is composed of a mold releasing agent and thermoplastic acrylic resin. The preparation method of the anti- fake hot stamping film comprises the steps that the mold releasing layer and the UV mold pressing layer are coated on the PET substrate film, the metal reflecting layer is plated on the PET substrate film, and the hot melt glue layer is coated on the PET substrate film. According to the anti- fake hot stamping film, the problems of poor trimming property of a UV coating and plate sticking of UV mold pressing are solved; the 3D effect is achieved on the anti- fake hot stamping film; the environmental protection requirement of products is met, and anti-fake characteristics and visual impact of anti-fake marks are better improved.

Description

A kind of false proof blocking film with 3D effect and preparation method thereof
Technical field
The invention belongs to field of anti-counterfeit technology, relate to a kind of false proof blocking film, particularly relate to a kind of false proof blocking film with 3D effect and preparation method thereof.
Background technology
At present, holographic anti-counterfeiting hot stamping film is widely used in packaging field, and relative to traditional printing technology, holographic anti-counterfeiting hot stamping film is lucuriant in design and have innervation, and has certain anti-counterfeiting power.But, along with the develop rapidly of packaging industry, and the generally use of holographic false proof series products, the single anti-counterfeiting power with the conventional photographic blocking film of holographic false proof function declines gradually.
Opal film is also Fei Nier lens coating or 3D cold lamination film, is a kind of novel decorative packaging material.Opal film is a kind of optical lens array imaging film, and lucuriant in design, third dimension is strong, transparency is high, there is lens wide-angle effect image and there is certain anti-counterfeiting power, can broaden one's vision, several image reduced can be observed, because of the extremely similar opal of viewing effect, therefore claim opal film.But because the application mode of opal film is composite membrane, namely adhere to applicating medium (as paper) surface by glue, plastic film layers cannot be removed, and does not meet the environmental requirement of increasingly stringent, cannot be applicable to the packaging such as tobacco bale, the cosmetics of super quality.
The general structure of current false proof blocking film is: PET film, release layer, imaging layer, metallic reflector and glue-line; Wherein, anti-counterfeiting information is produced on imaging layer.Imaging layer is generally thermoplastic coating, uses the mode of hot pressing to be transferred on imaging layer by the anti-counterfeiting microstructure on masterplate, thus realizes the batch duplicating of anti-counterfeiting information.Thermoplastic coating layer thickness is only 0.5 ~ 2um, and very difficult complete copy has the dark texture structure masterplate of 3D effect, and stereoeffect is also difficult to show.Therefore, traditional material, process system cannot realize stronger 3D effect on blocking film.
Adopt the mode of UV mold pressing can fast, batch duplicating goes out the better dark grain pattern of 3D effect, but, under current technology, also be there is following difficult point in blocking film in UV coatings applications: (1) is due to the toughness of UV coating, during for blocking film, the trimming of UV coating is very poor; (2) peel value due to general blocking film is very low, during UV mold pressing, the UV coating after solidification and the adhesion of masterplate often relatively large, there is the problem of sticky version, successfully cannot complete UV mould pressing process on mould release membrance.
Summary of the invention
The present invention is intended to the deficiency that will solve above-mentioned background technology, a kind of false proof blocking film with 3D effect is provided, UV mould pressing process is incorporated in the production process of blocking film, and avoid UV coating trimming difference and the problem of version is glued in UV mold pressing, false proof blocking film realizes 3D effect, both meet the feature of environmental protection requirement of product, greatly promote again visual impact sense and the security feature of anti-counterfeiting mark.
In order to achieve the above object, the invention provides a kind of false proof blocking film with 3D effect, comprise: the PET film, release layer, imaging layer, metallic reflector and the hot melt adhesive layer that superpose successively, described imaging layer is the UV embossed plies with 3D effect, and this UV embossed plies is made up of the mutual disjunct local positioning pattern of two or more; The softening point of release layer is 95 ~ 120 DEG C, when temperature is less than 95 DEG C release layer and UV embossed plies adhesion large, when blocking point is greater than 120 DEG C, UV embossed plies and release layer are easily peeled off.
The mass percent of each component of described release layer is:
Mould release 80 ~ 90%
Thermoplastic acrylic resin 10 ~ 20%.
Described mould release to be softening point the be high temperature mould release of 95 ~ 120 DEG C.
Preferred ZL-601LX or ZL-605LX, the Zhong Li company of described mould release produces.ZL-601LX or ZL-605LX when temperature is less than 95 DEG C and UV layer adhesive force better, when contributing to preventing UV mold pressing, UV layer and metal mold pressing version glue version, and the fissility of itself and UV embossed plies very well, is conducive to raising thermoprint when blocking point is greater than 120 DEG C.
The vitrification point Tg of described thermoplastic acrylic resin is 95 ~ 105 DEG C.
The vitrification point Tg of described thermoplastic acrylic resin is 98 DEG C.
The preferred model of described thermoplastic acrylic resin is the acrylic resin of 7131-TK-50, and vitrification point Tg is 98 DEG C, and Eternal company produces.The acrylic resin of 7131-TK-50 when being less than 95 DEG C and UV layer adhesive force good, when contributing to preventing UV mold pressing, UV layer and metal mold pressing version glue version, and when blocking point is greater than 120, the adhesive force of itself and UV embossed plies declines, and is conducive to again improving thermoprint.
The described UV embossed plies thickness with 3D effect is preferably 3 ~ 5um.
Described UV embossed plies is made up of the mutual disjunct local positioning pattern of two or more, this local positioning pattern Outside Dimensions perm with thermoprinting machine compared with little 0.5 ~ 2mm, avoid the problem of the trimming difference of UV layer during thermoprint.
Described local positioning pattern be square, rhombus, circle, oval one or more, area is 1 ~ 25cm 2.
Described release layer thickness is 0.7 ~ 1.1um.
Described PET film thickness is 12 ~ 22um.
The present invention also provides a kind of preparation method with the false proof blocking film of 3D effect, and its step comprises:
1) full version coating release layer on PET film, the mass percent of each component of release layer is:
Softening point is the high temperature mould release 80 ~ 90% of 95 ~ 120 DEG C
Thermoplastic acrylic resin 10 ~ 20%;
2) use UV moulding press, localised application UV coating on release layer, location laminating mold pressing version, UV solidification obtains forming UV embossed plies by the mutual disjunct local positioning pattern of two or more;
3) use vacuum aluminum-plating machine evaporation layer of metal reflecting layer in UV embossed plies, this layer thickness is 300 ~ 400 dusts;
4) on metallic reflector, one deck hot melt adhesive layer is coated with; The obtained false proof blocking film with 3D effect.
Beneficial effect of the present invention is: the false proof blocking film with 3D effect, UV mould pressing process is incorporated in the production process of blocking film, false proof blocking film realizes 3D effect, solve problem UV mould pressing process being applied to sticky version existing for blocking film and trimming difference, both meet the feature of environmental protection high request of product, be conducive to again the security feature and the visual impact sense that promote anti-counterfeiting mark.
Accompanying drawing explanation
Fig. 1 is: the structural representation of false proof blocking film of the present invention;
Fig. 2 is: when local positioning pattern is for circle, the floor map of imaging layer in UV blocking film;
Fig. 3 is: when local positioning pattern is for square, the floor map of imaging layer in UV blocking film;
Fig. 4 is: when local positioning pattern is combination pattern a, the floor map of imaging layer in UV blocking film;
Fig. 5 is: when local positioning pattern is combination pattern b, the floor map of imaging layer in UV blocking film;
Description of reference numerals: in FIG, PET film 1; Release layer 2; Imaging layer 3; Metallic reflector 4, hot melt adhesive layer 5.
Detailed description of the invention
In order to be illustrated more clearly in object of the present invention, functional characteristics and beneficial effect, below in conjunction with the drawings and specific embodiments, technical solutions according to the invention are described in detail, can better understand the present invention to make those skilled in the art and can be implemented, but illustrated embodiment is not as a limitation of the invention.
embodiment 1
As shown in Figure 1, the present embodiment provides a kind of false proof blocking film with 3D effect, comprise the PET film 1, release layer 2, imaging layer 3, metallic reflector 4 and the hot melt adhesive layer 5 that superpose successively from bottom to top, the UV embossed plies with 3D effect that imaging layer 3 is made up of mutual disjunct local positioning pattern.
The thickness of PET film 1 is 12um.
Each constituent mass percentage of release layer 2 is: mould release 80%, thermoplastic acrylic resin 20%; The thickness of release layer 2 is 0.7 ~ 1.1um.
Mould release to be softening point the be high temperature mould release ZL-601LX of 95 ~ 120 DEG C, is produced by Zhong Li company; When blocking point is lower than 95 DEG C, between mould release ZL-601LX and UV layer, adhesive force is good, when effectively preventing the mold pressing of UV layer and metal mold pressing version glue version; And when blocking point is higher than 120 DEG C, the fissility of mould release ZL-601LX and UV embossed plies is good, be conducive to improving thermoprint.
The model of thermoplastic acrylic resin is the acrylic resin of 7131-TK-50, vitrification point Tg is 98 DEG C, produced by Eternal company, when blocking point is lower than 95 DEG C, the acrylic resin of 7131-TK-50 is good with the adhesive force of UV layer, and when contributing to preventing UV mold pressing, UV layer and metal mold pressing version glue version, when blocking point is greater than 120 DEG C, the acrylic resin of 7131-TK-50 and the adhesive force of UV embossed plies low, be conducive to again improve thermoprint.
As shown in Figure 2, the UV embossed plies with 3D effect that imaging layer 3 is made up of mutual disjunct some circular opals, UV embossed plies thickness is 3um, and the radius of described circular opal is 2.5cm, area is 19.6cm 2, corresponding, the radius of perming of thermoprinting machine used is 2.6cm, and during thermoprint, will perm center and circular opal center contraposition, can avoid the problem of UV embossed plies trimming difference.
Prepare the above-mentioned method with the false proof blocking film of 3D effect, comprise the following steps:
1) full version coating release layer 2 on PET film 1, the mass percent of each component of release layer 2: the acrylic resin 20% of ZL-601LX high temperature mould release 80%, 7131-TK-50;
2) use UV moulding press, localised application UV coating on release layer 2, location laminating mold pressing version, UV solidifies the UV embossed plies obtained as shown in Figure 2;
3) use vacuum aluminum-plating machine evaporation layer of metal reflecting layer 4 in UV embossed plies, this layer thickness is 400 dusts;
4) on metallic reflector 4, one deck hot melt adhesive layer 5 is coated with; The obtained false proof blocking film with 3D effect.
embodiment 2
As shown in Figure 1, the present embodiment provides a kind of false proof blocking film with 3D effect, comprise the PET film 1, release layer 2, imaging layer 3, metallic reflector 4 and the hot melt adhesive layer 5 that superpose successively from bottom to top, the UV embossed plies with 3D effect that imaging layer 3 is made up of mutual disjunct local positioning pattern.
The thickness of PET film 1 is 15um.
Each constituent mass percentage of release layer 2 is: mould release 90%, thermoplastic acrylic resin 10%; The thickness of release layer 2 is 0.7 ~ 1.1um.
Mould release to be softening point the be high temperature mould release ZL-605LX of 95 ~ 120 DEG C, is produced by Zhong Li company; When blocking point is lower than 95 DEG C, between mould release ZL-605LX and UV layer, adhesive force is good, when effectively preventing the mold pressing of UV layer and metal mold pressing version glue version; And when blocking point is higher than 120 DEG C, the fissility of mould release ZL-605LX and UV embossed plies is good, be conducive to improving thermoprint.
The model of thermoplastic acrylic resin is the acrylic resin of 7131-TK-50, vitrification point Tg is 98 DEG C, produced by Eternal company, when blocking point is lower than 95 DEG C, the acrylic resin of 7131-TK-50 is good with the adhesive force of UV layer, and when contributing to preventing UV mold pressing, UV layer and metal mold pressing version glue version, when blocking point is greater than 120 DEG C, the acrylic resin of 7131-TK-50 and the adhesive force of UV embossed plies low, be conducive to again improve thermoprint.
As shown in Figure 3, the UV embossed plies with 3D effect that imaging layer 3 is made up of mutual disjunct some square opals, UV embossed plies thickness is 5um, and the length of side of described square opal is 4cm, area is 16cm 2, corresponding, the square of the thermoprinting machine used length of side of perming is 4.2cm, and during thermoprint, will perm center and square opal center contraposition, can avoid the problem of UV embossed plies trimming difference.
Prepare the above-mentioned method with the false proof blocking film of 3D effect, comprise the following steps:
1) full version coating release layer 2 on PET film 1, the mass percent of each component of release layer 2: the acrylic resin 10% of ZL-605LX high temperature mould release 90%, 7131-TK-50;
2) use UV moulding press, localised application UV coating on release layer 2, location laminating mold pressing version, UV solidifies the UV embossed plies obtained as shown in Figure 3;
3) use vacuum aluminum-plating machine evaporation layer of metal reflecting layer 4 in UV embossed plies, this layer thickness is 400 dusts;
4) on metallic reflector 4, one deck hot melt adhesive layer 5 is coated with; The obtained false proof blocking film with 3D effect.
embodiment 3
As shown in Figure 1, the present embodiment provides a kind of false proof blocking film with 3D effect, comprise the PET film 1, release layer 2, imaging layer 3, metallic reflector 4 and the hot melt adhesive layer 5 that superpose successively from bottom to top, the UV embossed plies with 3D effect that imaging layer 3 is made up of mutual disjunct local positioning pattern.
The thickness of PET film 1 is 22um.
Each constituent mass percentage of release layer 2 is: mould release 85%, thermoplastic acrylic resin 15%; The thickness of release layer 2 is 0.7 ~ 1.1um.
Mould release to be softening point the be high temperature mould release ZL-605LX of 95 ~ 120 DEG C, is produced by Zhong Li company; When blocking point is lower than 95 DEG C, between mould release ZL-605LX and UV layer, adhesive force is good, when effectively preventing the mold pressing of UV layer and metal mold pressing version glue version; And when blocking point is higher than 120 DEG C, the fissility of mould release ZL-605LX and UV embossed plies is good, be conducive to improving thermoprint.
The model of thermoplastic acrylic resin is the acrylic resin of NeoCrylB-736, vitrification point Tg is 98 DEG C, produced by Ves Corp. difficult to understand, when blocking point is lower than 95 DEG C, the acrylic resin of NeoCrylB-736 is good with the adhesive force of UV layer, and when contributing to preventing UV mold pressing, UV layer and metal mold pressing version glue version, when blocking point is greater than 120 DEG C, the acrylic resin of NeoCrylB-736 and the adhesive force of UV embossed plies low, be conducive to again improve thermoprint.
As shown in Figure 4, the UV embossed plies with 3D effect that imaging layer 3 is made up of some mutual disjunct square holographic location pattern, UV embossed plies thickness is 5um, have circular opal pattern in this pattern center, square holography location overlap, this square hologram pattern length of side is 5cm, area is 25cm 2, circular opal radius is 1.5cm; Corresponding, the square of the thermoprinting machine used length of side of perming is 5.2cm, allows the center of perming and the contraposition of opal center during thermoprint, the problem of the trimming difference of UV embossed plies when can avoid thermoprint like this.
Prepare the above-mentioned method with the false proof blocking film of 3D effect, comprise the following steps:
1) full version coating release layer 2 on PET film 1, the mass percent of each component of release layer 2: the acrylic resin 15% of ZL-605LX high temperature mould release 85%, NeoCrylB-736;
2) use UV moulding press, localised application UV coating on release layer 2, location laminating mold pressing version, UV solidifies the UV embossed plies obtained as shown in Figure 4;
3) use vacuum aluminum-plating machine evaporation layer of metal reflecting layer 4 in UV embossed plies, this layer thickness is 400 dusts;
4) on metallic reflector 4, one deck hot melt adhesive layer 5 is coated with; The obtained false proof blocking film with 3D effect.
embodiment 4
As shown in Figure 1, the present embodiment provides a kind of false proof blocking film with 3D effect, comprise the PET film 1, release layer 2, imaging layer 3, metallic reflector 4 and the hot melt adhesive layer 5 that superpose successively from bottom to top, the UV embossed plies with 3D effect that imaging layer 3 is made up of mutual disjunct local positioning pattern.
The thickness of PET film 1 is 12um.
Each constituent mass percentage of release layer 2 is: mould release 85%, thermoplastic acrylic resin 15%; The thickness of release layer 2 is 0.7 ~ 1.1um.
Mould release to be softening point the be high temperature mould release ZL-601LX of 95 ~ 120 DEG C, is produced by Zhong Li company; When blocking point is lower than 95 DEG C, between mould release ZL-601LX and UV layer, adhesive force is good, when effectively preventing the mold pressing of UV layer and metal mold pressing version glue version; And when blocking point is higher than 120 DEG C, the fissility of mould release ZL-601LX and UV embossed plies is good, be conducive to improving thermoprint.
The model of thermoplastic acrylic resin is the acrylic resin of NeoCrylB-736, vitrification point Tg is 98 DEG C, produced by Ves Corp. difficult to understand, when blocking point is lower than 95 DEG C, the acrylic resin of NeoCrylB-736 is good with the adhesive force of UV layer, and when contributing to preventing UV mold pressing, UV layer and metal mold pressing version glue version, when blocking point is greater than 120 DEG C, the acrylic resin of NeoCrylB-736 and the adhesive force of UV embossed plies low, be conducive to again improve thermoprint.
As shown in Figure 5, the UV embossed plies with 3D effect that imaging layer 3 is made up of some mutual disjunct circular holographic location pattern, UV embossed plies thickness is 2um, square opal pattern is had in this pattern center, circle holography location overlap, this circular opal radius is 2.5cm, and the square opal length of side is 2cm.Corresponding, the circle of thermoprinting machine used radius of perming is 2.7cm, allows the center of perming and the contraposition of opal center during thermoprint, the problem of the trimming difference of UV embossed plies when can avoid thermoprint like this.
Prepare the above-mentioned method with the false proof blocking film of 3D effect, comprise the following steps:
1) full version coating release layer 2 on PET film 1, the mass percent of each component of release layer 2: the acrylic resin 15% of ZL-601LX high temperature mould release 85%, NeoCrylB-736;
2) use UV moulding press, localised application UV coating on release layer 2, location laminating mold pressing version, UV solidifies the UV embossed plies obtained as shown in Figure 5;
3) use vacuum aluminum-plating machine evaporation layer of metal reflecting layer 4 in UV embossed plies, this layer thickness is 400 dusts;
4) on metallic reflector 4, one deck hot melt adhesive layer 5 is coated with; The obtained false proof blocking film with 3D effect.
Be more than embodiments of the invention, must not be interpreted as the restriction to protection scope of the present invention, those skilled in the art should be appreciated that amendment of the present invention or equivalent replacement, all do not depart from the protection domain of technical solution of the present invention.

Claims (10)

1. one kind has the false proof blocking film of 3D effect, comprise and superposing successively from bottom to top: PET film, release layer, imaging layer, coating and hot melt adhesive layer, is characterized in that: the UV embossed plies with 3D effect that described imaging layer is made up of the mutual disjunct local positioning pattern of two or more; The softening point of release layer is 95 ~ 120 DEG C;
In described release layer, the mass percent of each component is:
Mould release 80 ~ 90%
Thermoplastic acrylic resin 10 ~ 20%.
2. the false proof blocking film with 3D effect according to claim 1, is characterized in that: described mould release to be softening point the be high temperature mould release of 95 ~ 120 DEG C.
3. the false proof blocking film with 3D effect according to claim 1, is characterized in that: the vitrification point Tg of described thermoplastic acrylic resin is 95 ~ 105 DEG C.
4. the false proof blocking film with 3D effect according to claim 3, is characterized in that: the vitrification point Tg of described thermoplastic acrylic resin is 98 DEG C.
5. the false proof blocking film with 3D effect according to claim 1, is characterized in that: the thickness of described UV embossed plies is 3 ~ 5um.
6. the false proof blocking film with 3D effect according to claim 1, is characterized in that: described local positioning pattern Outside Dimensions 0.5 ~ 2mm less of the radius of perming of thermoprinting machine used.
7. the false proof blocking film with 3D effect according to claim 1 or 6, is characterized in that: described local positioning pattern is square, rhombus, circle, oval one, and area is 1 ~ 25cm 2.
8. the false proof blocking film with 3D effect according to claim 1, is characterized in that: the thickness of described PET film is 12 ~ 22um.
9. the false proof blocking film with 3D effect according to claim 1, is characterized in that: the thickness of described release layer is 0.7 ~ 1.1um.
10. the preparation method with the false proof blocking film of 3D effect according to claim 1, its step comprises:
1) full version coating release layer on PET film, the mass percent of each component of release layer is:
Softening point is the high temperature mould release 80 ~ 90% of 95 ~ 120 DEG C
Thermoplastic acrylic resin 10 ~ 20%;
2) use UV moulding press, localised application UV coating on release layer, location laminating mold pressing version, UV solidification obtains by two
The UV embossed plies of individual above mutual disjunct local positioning pattern composition;
3) use vacuum aluminum-plating machine, in UV embossed plies, evaporation a layer thickness is the metallic reflector of 300 ~ 400 dusts;
4) on metallic reflector, one deck hot melt adhesive layer is coated with; The obtained false proof blocking film with 3D effect.
CN201510610175.9A 2015-09-23 2015-09-23 A kind of anti-fake blocking film and preparation method thereof with 3D effect Active CN105313516B (en)

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CN105751676A (en) * 2016-04-29 2016-07-13 珠海市瑞明科技有限公司 Thermal printing thin film with stereo embossment visible with naked eyes and manufacturing method of thermal printing thin film
CN106394042A (en) * 2016-08-31 2017-02-15 绍兴虎彩激光材料科技有限公司 Preparation process of snowflake-effect packaging material
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