CN105309466A - Insect disinfestation and sterilization ternary compound composition and seed coating agent thereof - Google Patents
Insect disinfestation and sterilization ternary compound composition and seed coating agent thereof Download PDFInfo
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- CN105309466A CN105309466A CN201410362316.5A CN201410362316A CN105309466A CN 105309466 A CN105309466 A CN 105309466A CN 201410362316 A CN201410362316 A CN 201410362316A CN 105309466 A CN105309466 A CN 105309466A
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- insecticidal
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- bactericidal composition
- difenoconazole
- diacloden
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Abstract
The present invention discloses an insect disinfestation and sterilization composition containing thiamethoxam, fipronil and difenoconazole, wherein a mass ratio of the three active components such as thiamethoxam, fipronil and difenoconazole is 5-80:1-20:1-15. According to the present invention, the insect disinfestation and sterilization composition can be prepared into the seed coating agent, and can further be used for prevention and control of plant diseases and insect pests of corn, wheat or peanuts.
Description
Technical field
The invention belongs to technical field of plant protection, relate generally to a kind of pesticide-germicide ternary recompounded composite and seed coat agent thereof.
Background technology
Maize head smut, rough dwarf disease (small brown rice planthopper causes), grub, wireworm, aphid, small brown rice planthopper, take-all, banded sclerotial blight, loose kernel smut, aphid, grub, wireworm, Roots of Peanut maize ear rot, grub are damage by disease and insect important in agricultural production, often cause be short of seedling disconnected ridge and a large amount of dead seedling, very large on crop yield impact, time serious, underproduction 30%-50% even has no harvest.
For preventing and treating above-mentioned crop disease and insect, carrying out seed treatment is a kind of method preferably, and wherein seed coat agent is a kind of selection well.Seed coat agent is a kind of for crop seed dressing, the material with film forming characteristics, usually be processed into by active ingredient (insecticide, bactericide etc.), film forming agent, dispersant, warning colouration, antifreezing agent and other auxiliary agents, there is efficacy of a drug lasting period length, growth promoting effects, improvement quality, improve the advantage such as percentage of seedgermination, be a kind of diseases prevention, control worm, seed processing technology that sterilization, growth promoting effects combine together.
Therefore exploitation is needed a kind ofly to have high-efficiency low-toxicity, the environmentally friendly and double composite seed coat agent controlled of damage by disease and insect.
Summary of the invention
The object of the present invention is to provide a kind of high-efficiency low-toxicity, the double insecticidal and bactericidal composition controlled of environmentally friendly, sick worm.
For reaching goal of the invention the technical solution used in the present invention be:
A kind of insecticidal and bactericidal composition, containing three kinds of active components, the first active component is Diacloden, second active ingredient is ethiprole, the third active component is Difenoconazole, and the quality proportioning between described three kinds of active components is: Diacloden 5 ~ 80, ethiprole 1 ~ 20, Difenoconazole 1 ~ 15.
In insecticidal and bactericidal composition of the present invention, above-mentioned Diacloden (Thiamethoxam) is a kind of second generation nicotinoids high-efficient low toxicity insecticide of brand new, and have stomach toxicity to insect, tag and systemic activity, speed of action is fast, the lasting period is long.Both can be used for cauline leaf process, seed treatment, also can be used for soil treatment.Rapidly by interior suction after its dispenser, and be transmitted to each position of plant, soil insect can be prevented and treated as grub, wireworm, cutworm, ground insect can be prevented and treated again as aphid, plant hopper, thrips, leafhopper, aleyrodid etc.
Above-mentioned ethiprole (Fipronil) is Phenylpyrazole insecticides, insecticidal spectrum is wide, based on stomach poison function, have concurrently and tag and certain systemic action, very high insecticidal activity is had, to crop without poisoning to important pests such as aphid, leafhopper, plant hopper, lepidopterous larvae, fly class and coleopteras.This medicament imposes on soil can effective chrysomelid, the soil insect such as wireworm and cutworm of control of grubs, root.
Above-mentioned Difenoconazole (Difenoconazole) belongs to triazole bactericidal agent, it is the triazole bactericidal agent of the higher broad-spectrum high efficacy of safety, the biosynthesis of main suppression germ cell ergosterol, to ascus subphylum, Basidiomycotina and comprise Alternaria, Ascochyta, the mould genus of tail spore, colletotrichum, ball seat Pseudomonas, Phoma, Ramularia, Septoria, raw meat Venturia is interior imperfect fungus, Erysiphaceae, Uredinales and some Seedborne pathogen have lasting protection and therapeutic activity, and simultaneously to cercospora leaf spot of sugar beet, wheat glume blotch, leaf blight, rust, apple scab, powdery mildew, grape powdery mildew, target, leaf spot of peanut and net blotch etc. all have good result for the treatment of.
As preferred mode, the quality proportioning in above-mentioned insecticidal and bactericidal composition between three kinds of active components is preferably: Diacloden 10 ~ 50, ethiprole 5 ~ 15, Difenoconazole 1 ~ 10.As further preferred mode, the quality proportioning in above-mentioned insecticidal and bactericidal composition between three kinds of active components is preferably: Diacloden 10 ~ 15, ethiprole 5 ~ 15, Difenoconazole 1 ~ 10.
Insecticidal and bactericidal composition of the present invention can be formulated into pesticide-germicide seed coat agent, in described pesticide-germicide seed coat agent containing by weight 5 ~ 90% insecticidal and bactericidal composition, all the other are agriculturally acceptable carrier and auxiliary agent.As preferred mode, in described pesticide-germicide seed coat agent, contain the insecticidal and bactericidal composition of by weight 10 ~ 70%.Pesticide-germicide seed coat agent of the present invention can be prepared into seed treatment suspending agent (FS), seed treatment wettable powder (WS) or seed treatment microcapsule suspending agent (CF) according to the method that this area is general.
Carrier of the present invention can be solid or liquid, and any carrier being generally used for preparing insecticidal bactericide all can use.
Suitable solid carrier comprises: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin such as, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is such as: calcium carbonate, dolomite.Sulfates as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.Plant is such as: citrus pulp, corncob cellulose, rice husk powder, rice husk, large soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride such as, sodium chloride.
Liquid-carrier comprises water and organic solvent.Suitable organic solvent comprises aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, such as vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, such as petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol such as, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether such as, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidon such as; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be used alone, also can be used in combination, can also mix together with water.
Auxiliary element of the present invention can comprise surfactant, defoamer, thickener, film forming agent, warning colouration, antifreezing agent, preservative, cyst material as required, can also comprise other auxiliary agents that the industry is conventional as required.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; The polycondensation product of the fatty acid containing at least 12 carbon atoms in molecule or fatty amine and oxirane and/expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In the molecule at least containing the sulfuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkali salt, be preferably sodium salt, as the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate and neopelex; The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonylphenol ether of nonionic emulsifier, fatty alcohol-polyoxyethylene ether, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether, styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic emulsifier mainly comprises calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, thermally coupled distillation columns amine salt, castor oil polyoxyethylene ether phosphate amine salt.
When pesticide-germicide seed coat agent of the present invention is formulated into seed treatment suspending agent, each composition proportion is: Diacloden 5.0 ~ 50.0%, ethiprole 3.0 ~ 15.0%, Difenoconazole 3.0 ~ 10.0%, dispersant 3.0 ~ 5.0%, wetting agent 1.0 ~ 3.0%, film forming agent 3.0%, antifreezing agent 4.0 ~ 6.0%, preservative 0.02 ~ 0.05%, defoamer 0.2 ~ 0.5%, thickener 0.2 ~ 0.5%, pH adjusting agent 0.3 ~ 0.5%, warning colouration 2.0 ~ 4.0%, its surplus are water.As preferred mode, described dispersant comprises: polycarboxylate, acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid and to the one in hydroxyphenyl lignin sulfonic acid sodium salt, more than two or three combination; Described wetting agent comprises: the one in alkylphenol polyoxyethylene, alkylnaphthalene sulfonate and aliphatic alcohol sulfate, two or three; Described film forming agent comprises polyvinyl alcohol (being called for short PVA), all polyvinyl acetate, sodium carboxymethylcellulose; Described antifreezing agent is urea, ethylene glycol or propane diols; Described preservative is BIT (being called for short BIT); Described defoamer is organically-modified silica alkane defoamer; Described thickener is aluminium-magnesium silicate or xanthans; Described warning colouration is basic rhodamine, acid scarlet or oil-soluble azarin; Described pH adjusting agent is citric acid, glacial acetic acid or lauric acid.
Micro-capsule wall material of the present invention is preferably polymethyl methacrylate, polystyrene or SMA alternate copolymer.
Insecticidal and bactericidal composition provided by the invention and pesticide-germicide seed coat agent can be used in control of maize, wheat or peanut damage by disease and insect, are particularly suitable for preventing and treating smut, full rot, banded sclerotial blight, root rot, rough dwarf disease, grub, wireworm, small brown rice planthopper or aphid.
Insecticidal and bactericidal composition provided by the invention has following advantage compared to existing technology:
(1) three kind of active component composite in certain ratio range performance obviously can expand pesticide-germicide spectrum effect, reach that disease worm is doublely controlled, the soil insect double effect controlled of insect on the ground, and there is the feature that the good and lasting effect of interior absorption grows control;
(2) reduce times for spraying, reduce drug cost, increasing both production and income;
(3) seed coat agent product film forming speed is fast, expulsion rate is low, has good coating effect, easy to use, quick, and to corn, wheat, peanut seed safety, environmentally friendly.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that all alternatives, improvement project and the equivalents that present invention encompasses and may comprise in Claims scope.
The following example Raw composition represents by active ingredient mass percent.
One, formulation Example
Embodiment 123% Diacloden ethiprole Difenoconazole seed treatment suspending agent (FS)
Diacloden 15.0%, ethiprole 5.0%, Difenoconazole 3.0%, polyvinyl alcohol (PVA) 1.8%, all polyvinyl acetate 0.2%, aliphatic alcohol sulfate 2.0%, polyoxyethylene polyoxypropylene block copolymer 4.0%, ethylene glycol 5.0%, 1,2-benzisothiazole-3-ketone (BIT) 0.03%, organically-modified silica alkane defoamer 0.3%, xanthans 0.2%, acid scarlet 1.5%, its surplus is water.
Components in certain proportion each in above-mentioned formula is pre-mixed, then adds in sand mill and grind, after high shear mixing, add film forming agent and obtained 23% Diacloden ethiprole Difenoconazole seed treatment suspending agent (FS) of warning colouration allotment.
Embodiment 270% Diacloden ethiprole Difenoconazole seed treatment wettable powder (WS)
Diacloden 45.0%, ethiprole 15.0%, Difenoconazole 10.0%, sodium carboxymethylcellulose 3.0%, sodium lignin sulfonate 2.0%, lauryl sodium sulfate 4.0%, oil-soluble azarin 2.0%, white carbon 10%, its surplus are kaolin.
Components in certain proportion each in above-mentioned formula is carried out premixed, then adds airslide disintegrating mill and carry out gas powder, obtain 70% Diacloden ethiprole Difenoconazole seed treatment wettable powder (WS).
Embodiment 330% Diacloden ethiprole Difenoconazole seed treatment microcapsule suspending agent (CF)
Diacloden 20.0%, ethiprole 5.0%, Difenoconazole 5.0%, hydroxyethylcellulose 2.0%, agriculture breast 600#1.5%, aliphatic alcohol sulfate 1.8%, polyoxyethylene polyoxypropylene block copolymer 3.0%, ethylene glycol 5.0%, 1,2-benzisothiazole-3-ketone (BIT) 0.03%, organically-modified silica alkane defoamer 0.3%, xanthans 0.15%, acid scarlet 1.5%, its surplus is water.
Composition each in above-mentioned formula is prepared into the micro-capsule containing active component, adds dispersant, wetting agent, film forming agent, warning colouration, antifreezing agent, preservative etc. while stirring and namely obtain 30% Diacloden ethiprole Difenoconazole seed treatment microcapsule suspending agent (CF).Two, field control effectiveness test embodiment
Wheat, corn, peanut seed and above-mentioned obtained pesticide-germicide seed coat agent are carried out even dressing with suitable pesticide-seeds ratio.The plot that test selects soil fertility etc. better, in recent years to have to a certain degree damage by disease and insect to cause harm.Scientific arrangement experimental plot, according to the rationally sowing of sowing custom, with non-capsuled seed for blank.Community adopts the group arrangement of random district, repeats 4 times.Field control effectiveness test and result investigation is carried out by " pesticide field efficacy medicine test criterion " related request.The composite seed coat agent dressing of Diacloden ethiprole Difenoconazole to wheat, corn, peanut damage by disease and insect field test results in table 1 ~ 3.
Result display in table, pesticide-germicide seed coat agent of the present invention, has good control efficiency to wheat, corn, peanut damage by disease and insect, control efficiency is all better than single dose, and whole vegetative period safety is showed to wheat, corn, peanut, occur without symptom of chemical damage, production-increasing function is obvious.
Table 1 Diacloden ethiprole Difenoconazole (being called for short thiophene fluorobenzene) seed coat agent is to wheat field test results
Table 2 Diacloden ethiprole Difenoconazole (being called for short thiophene fluorobenzene) seed coat agent is to corn field test results
Table 3 Diacloden ethiprole Difenoconazole (being called for short thiophene fluorobenzene) seed coat agent is to peanut field test results
Claims (10)
1. an insecticidal and bactericidal composition, it is characterized in that described insecticidal and bactericidal composition contains three kinds of active components, the first active component is Diacloden, second active ingredient is ethiprole, the third active component is Difenoconazole, and the quality proportioning between described three kinds of active components is: Diacloden 5 ~ 80, ethiprole 1 ~ 20, Difenoconazole 1 ~ 15.
2., according to insecticidal and bactericidal composition according to claim 1, it is characterized in that the quality proportioning between described three kinds of active components is: Diacloden 10 ~ 50, ethiprole 5 ~ 15, Difenoconazole 1 ~ 10.
3., according to insecticidal and bactericidal composition according to claim 2, it is characterized in that the quality proportioning between described three kinds of active components is: Diacloden 10 ~ 15, ethiprole 5 ~ 15, Difenoconazole 1 ~ 10.
4. according to the application of insecticidal and bactericidal composition according to claim 1, it is characterized in that described insecticidal and bactericidal composition is formulated into pesticide-germicide seed coat agent, in described pesticide-germicide seed coat agent containing by weight 5 ~ 90% insecticidal and bactericidal composition, all the other are agriculturally acceptable carrier and auxiliary agent.
5., according to the application of insecticidal and bactericidal composition according to claim 4, it is characterized in that the insecticidal and bactericidal composition containing by weight 10 ~ 70% in described pesticide-germicide seed coat agent.
6., according to the application of insecticidal and bactericidal composition according to claim 3, it is characterized in that described pesticide-germicide seed coat agent is formulated into seed treatment suspending agent, seed treatment wettable powder or seed treatment microcapsule suspending agent.
7., according to the application of insecticidal and bactericidal composition according to claim 6, it is characterized in that in described seed treatment suspending agent, each composition proportion is: Diacloden 5.0 ~ 50.0%, ethiprole 3.0 ~ 15.0%, Difenoconazole 3.0 ~ 10.0%, dispersant 3.0 ~ 5.0%, wetting agent 1.0 ~ 3.0%, film forming agent 3.0%, antifreezing agent 4.0 ~ 6.0%, preservative 0.02 ~ 0.05%, defoamer 0.2 ~ 0.5%, thickener 0.2 ~ 0.5%, pH adjusting agent 0.3 ~ 0.5%, warning colouration 2.0 ~ 4.0%, its surplus are water.
8., according to the application of insecticidal and bactericidal composition according to claim 7, it is characterized in that described dispersant is selected from polycarboxylate, acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid and combines the one in hydroxyphenyl lignin sulfonic acid sodium salt, more than two or three; Described wetting agent is selected from the one, two or three in alkylphenol polyoxyethylene, alkylnaphthalene sulfonate and aliphatic alcohol sulfate; Described film forming agent is polyvinyl alcohol, all polyvinyl acetate, sodium carboxymethylcellulose; Described antifreezing agent urea, ethylene glycol or propane diols; Described preservative is BIT; Described defoamer is organically-modified silica alkane defoamer; Described thickener is aluminium-magnesium silicate or xanthans; Described pH adjusting agent is citric acid, glacial acetic acid or lauric acid; Described warning colouration is basic rhodamine, acid scarlet or oil-soluble azarin.
9., according to the application of insecticidal and bactericidal composition according to claim 1, it is characterized in that described pesticide-germicide seed coat agent is used to control of maize, wheat or peanut damage by disease and insect.
10., according to the application of insecticidal and bactericidal composition according to claim 9, it is characterized in that described pesticide-germicide seed coat agent is used to prevent and treat smut, full rot, banded sclerotial blight, root rot, rough dwarf disease, grub, wireworm, small brown rice planthopper or aphid.
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| CN201410362316.5A CN105309466A (en) | 2014-07-28 | 2014-07-28 | Insect disinfestation and sterilization ternary compound composition and seed coating agent thereof |
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| CN201410362316.5A CN105309466A (en) | 2014-07-28 | 2014-07-28 | Insect disinfestation and sterilization ternary compound composition and seed coating agent thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090124499A1 (en) * | 2005-06-30 | 2009-05-14 | Syngenta Crop Protection, Inc. | Enhanced formulations |
| CN102308838A (en) * | 2011-09-28 | 2012-01-11 | 联保作物科技有限公司 | Flowable concentrate for seed coating for insecticidal purpose and disease prevention |
| CN102334489A (en) * | 2011-10-31 | 2012-02-01 | 联保作物科技有限公司 | Insect-killing and disease-preventing suspension seed coating formulation |
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2014
- 2014-07-28 CN CN201410362316.5A patent/CN105309466A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090124499A1 (en) * | 2005-06-30 | 2009-05-14 | Syngenta Crop Protection, Inc. | Enhanced formulations |
| CN102308838A (en) * | 2011-09-28 | 2012-01-11 | 联保作物科技有限公司 | Flowable concentrate for seed coating for insecticidal purpose and disease prevention |
| CN102334489A (en) * | 2011-10-31 | 2012-02-01 | 联保作物科技有限公司 | Insect-killing and disease-preventing suspension seed coating formulation |
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Application publication date: 20160210 |