CN105301683A - Sticking type retroreflective film and preparation method thereof - Google Patents

Sticking type retroreflective film and preparation method thereof Download PDF

Info

Publication number
CN105301683A
CN105301683A CN201510908555.0A CN201510908555A CN105301683A CN 105301683 A CN105301683 A CN 105301683A CN 201510908555 A CN201510908555 A CN 201510908555A CN 105301683 A CN105301683 A CN 105301683A
Authority
CN
China
Prior art keywords
layer
film
sticky note
sticking
retroreflective
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510908555.0A
Other languages
Chinese (zh)
Inventor
冯守中
李洁
高巍
王军
夏玉明
冒卫星
白杲
朱小康
屈双双
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd
Original Assignee
ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd filed Critical ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd
Priority to CN201510908555.0A priority Critical patent/CN105301683A/en
Publication of CN105301683A publication Critical patent/CN105301683A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/12Reflex reflectors
    • G02B5/122Reflex reflectors cube corner, trihedral or triple reflector type
    • G02B5/124Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/416Reflective

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to a sticking type retroreflective film, successively comprising four layers from top to bottom: a protection layer, a retroreflective layer, a sticking layer and a substrate layer, wherein the substrate layer is composed of a base material, an adhesive and an isolating film. A preparation method comprises: first, uniformly spraying the sticking layer on the surface of the substrate layer to form a stable structure; secondly, before complete solidification of the sticking layer, uniformly spraying the retroreflective film on the surface of the sticking layer; and finally, covering the transparent sticking layer on the surface of the retroreflective film to form the sticking type retroreflective film. The sticking type retroreflective film is prepared by employing four layer composite technology, and is simple and convenient to use; through a retroreflective microstructure, the sticking type retroreflective film possesses excellent retroreflective effects; an outer layer is covered by the protection layer, thereby prolonging the service life; meanwhile, preparation processes are simple, and raw materials are easy to obtain, thereby facilitating processing line production.

Description

A kind of sticky note formula Counter-reflection membrane and preparation method thereof
Technical field
The present invention belongs to optical technical field, is specifically related to a kind of sticky note formula Counter-reflection membrane and preparation method thereof.
Background technology
Counter-reflection membrane is widely used in traffic safety facilities, personal security, and billboard etc. are multi-field.Wherein have broad application prospects in means of transportation, as the warning notice on vehicle, the warning notice in road and instruction, the many aspects such as navigation marker, provide powerful guarantee for people go on a journey safely.Along with the maturation of reflectance coating technology, the effect with warning and eye-catching effect also obtains in other association areas to be widelyd popularize, can strengthen visual effect as added reflectance coating in billboard, in the direction board of factory, add reflectance coating can Methodisticly manage.
But the use of current reflex reflection product is add in coating by reflecting material mostly, in the position needing to use through the construction technology such as brushing on its surface to reach reflective effect, this more loaded down with trivial details construction technology has limited its application at more commercialization or industrial circle.
Summary of the invention
The object of the invention is to: a kind of sticky note formula Counter-reflection membrane and preparation method thereof is provided, to improve the deficiencies in the prior art, namely will meets the effect with reflex reflection light, again without the need to loaded down with trivial details construction technology.
To achieve these goals, the present invention adopts following technical scheme:
A kind of sticky note formula Counter-reflection membrane, be made up of four-layer structure, four-layer structure is followed successively by protective seam, retroreflective layer, sticking layer, substrate layer from top to bottom, and described substrate layer is made up of base material, adhesive, barrier film three part.
Preferably, described protective seam is layer of transparent material, is polyethylene film, polypropylene screen, polystyrene film, polychloroethylene film, and polyester film, one or more in polyamide membrane are composited.
Preferably, described retroreflective layer is made up of some reflex reflection microstructures.
Preferably, described sticking layer is formed by the adhesive even spread of high score subclass, for one or more in epoxy resin, unsaturated polyester (UP), phenolics, polyacrylic resin, Corvic, urethane resin, silica gel combine.
Preferably, the base material of described substrate layer is made up of one or more in paper, cloth, plastics, sheet metal.
Preferably, the adhesive of described substrate layer is made up of one or both in elastomeric-type pressure sensitive adhesive or resin pressure sensitive adhesive.
Preferably, the barrier film of described substrate layer is polyethylene film, polypropylene screen, and one or more in polystyrene film, polyester film or release liners, silicone oil paper, barrier paper are composited.
Preferably, the preparation method of described sticky note formula Counter-reflection membrane, concrete steps are as follows: first, at substrate layer surface uniform spray sticking layer, form rock-steady structure; Next, in its surface uniform spreading retroreflective layer before sticking layer does not solidify completely; Finally, sticky note formula Counter-reflection membrane is formed at the surface coverage layer of transparent protective seam of retroreflective layer.
Beneficial effect of the present invention is: the present invention adopts four layers of complex technique preparation directly can glue the Counter-reflection membrane of note formula; easy to use; by adding reflex reflection microstructure; product has excellent reflex reflection effect; and be coated with protective seam at skin, can increase the service life, preparation technology is simple simultaneously; starting material are simple and easy to get, are easy to pipeline system and produce.
Accompanying drawing explanation
Fig. 1 is the structural representation of sticky note formula Counter-reflection membrane of the present invention;
Fig. 2 is the structural representation of substrate layer of the present invention
In Reference numeral: the barrier film of the base material of 1-protective seam, 2-retroreflective layer, 3-sticking layer, 4-substrate layer, 5-substrate layer, the adhesive of 6-substrate layer, 7-substrate layer.
Embodiment
The technological means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with concrete diagram, setting forth explanation further.
As shown in Figure 1 and Figure 2,
A kind of sticky note formula Counter-reflection membrane, be made up of four-layer structure, four-layer structure is followed successively by protective seam 1, retroreflective layer 2, sticking layer 3, substrate layer 4 from top to bottom, and described substrate layer 4 is made up of base material 5, adhesive 6, barrier film 7 three part.
Preferably, described protective seam 1 is layer of transparent material, is polyethylene film, polypropylene screen, polystyrene film, polychloroethylene film, and polyester film, one or more in polyamide membrane are composited.
Preferably, described retroreflective layer 2 is made up of some reflex reflection microstructures.
Preferably, described sticking layer 3 is formed by the adhesive even spread of high score subclass, for one or more in epoxy resin, unsaturated polyester (UP), phenolics, polyacrylic resin, Corvic, urethane resin, silica gel combine.
Preferably, the base material 5 of described substrate layer is made up of one or more in paper, cloth, plastics, sheet metal.
Preferably, the adhesive 6 of described substrate layer is made up of one or both in elastomeric-type pressure sensitive adhesive or resin pressure sensitive adhesive.
Preferably, the barrier film 7 of described substrate layer is polyethylene film, polypropylene screen, and one or more in polystyrene film, polyester film or release liners, silicone oil paper, barrier paper are composited.
Preferably, the preparation method of described sticky note formula Counter-reflection membrane, concrete steps are as follows: first, at substrate layer 4 surface uniform spray sticking layer 3, form rock-steady structure; Next, in its surface uniform spreading retroreflective layer 2 before sticking layer 3 does not solidify completely; Finally, sticky note formula Counter-reflection membrane is formed at the surface coverage layer of transparent protective seam 1 of retroreflective layer 2.
The present invention is the sticky note formula Counter-reflection membrane adopting Simple process to prepare, and manufacture craft is simple, is easy to use in many aspects.The external sheath matcoveredn 1 of retroreflective layer, can extend the serviceable life of product, have a good application prospect simultaneously.

Claims (8)

1. a sticky note formula Counter-reflection membrane, it is characterized in that, be made up of four-layer structure, four-layer structure is followed successively by protective seam, retroreflective layer, sticking layer, substrate layer from top to bottom, and described substrate layer is made up of base material, adhesive, barrier film three part.
2. sticky note formula Counter-reflection membrane according to claim 1, it is characterized in that, described protective seam is layer of transparent material, is polyethylene film, polypropylene screen, polystyrene film, polychloroethylene film, and polyester film, one or more in polyamide membrane are composited.
3. sticky note formula Counter-reflection membrane according to claim 1, it is characterized in that, the retroreflective structure that described retroreflective layer is made up of at random reflex reflection glass microballoon forms.
4. sticky note formula Counter-reflection membrane according to claim 1, it is characterized in that, described sticking layer is formed by the adhesive even spread of high score subclass, for one or more in epoxy resin, unsaturated polyester (UP), phenolics, polyacrylic resin, Corvic, urethane resin, silica gel combine.
5. sticky note formula Counter-reflection membrane according to claim 1, it is characterized in that, the base material of described substrate layer is made up of one or more in paper, cloth, plastics, sheet metal.
6. sticky note formula Counter-reflection membrane according to claim 1, it is characterized in that, the adhesive of described substrate layer is made up of one or both in elastomeric-type pressure sensitive adhesive or resin pressure sensitive adhesive.
7. sticky note formula Counter-reflection membrane according to claim 1, is characterized in that, the barrier film of described substrate layer is polyethylene film, polypropylene screen, and one or more in polystyrene film, polyester film or release liners, silicone oil paper, barrier paper are composited.
8. the preparation method of the sticky note formula Counter-reflection membrane according to claim 1-7 any one, it is characterized in that, concrete steps are as follows: first, at substrate layer surface uniform spray sticking layer, form rock-steady structure; Next, in its surface uniform spreading retroreflective layer before sticking layer does not solidify completely; Finally, sticky note formula Counter-reflection membrane is formed at the surface coverage layer of transparent protective seam of retroreflective layer.
CN201510908555.0A 2015-12-08 2015-12-08 Sticking type retroreflective film and preparation method thereof Pending CN105301683A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510908555.0A CN105301683A (en) 2015-12-08 2015-12-08 Sticking type retroreflective film and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510908555.0A CN105301683A (en) 2015-12-08 2015-12-08 Sticking type retroreflective film and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105301683A true CN105301683A (en) 2016-02-03

Family

ID=55199155

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510908555.0A Pending CN105301683A (en) 2015-12-08 2015-12-08 Sticking type retroreflective film and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105301683A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105926875A (en) * 2016-06-27 2016-09-07 田芳 Indoor wide seamless glass bead composite decorative material and preparation technology thereof
CN109501411A (en) * 2018-11-05 2019-03-22 佛山市顺德区晶晶装饰材料有限公司 A kind of energy-saving explosion-proof mirror and energy-saving explosion-proof mirror production method
CN110128960A (en) * 2019-05-24 2019-08-16 东莞市铭伟电子科技有限公司 A kind of multipurpose quick and convenient patch

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2118085U (en) * 1992-03-10 1992-10-07 中国科学院安徽光学精密机械研究所 Engineering grade rear direction reflecting film
US5310436A (en) * 1991-04-19 1994-05-10 Stimsonite Corporation Preprinted retroreflective highway sign and method for making the sign
CN1187838A (en) * 1995-06-16 1998-07-15 美国3M公司 Retroreflective articles for life saving devices at sea
EP2296020A1 (en) * 2004-04-01 2011-03-16 3M Innovative Properties Co. Retroreflective sheeting with controlled cap-Y
CN102721989A (en) * 2012-06-21 2012-10-10 绵阳龙华薄膜有限公司 Retro reflecting film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5310436A (en) * 1991-04-19 1994-05-10 Stimsonite Corporation Preprinted retroreflective highway sign and method for making the sign
CN2118085U (en) * 1992-03-10 1992-10-07 中国科学院安徽光学精密机械研究所 Engineering grade rear direction reflecting film
CN1187838A (en) * 1995-06-16 1998-07-15 美国3M公司 Retroreflective articles for life saving devices at sea
EP2296020A1 (en) * 2004-04-01 2011-03-16 3M Innovative Properties Co. Retroreflective sheeting with controlled cap-Y
CN102721989A (en) * 2012-06-21 2012-10-10 绵阳龙华薄膜有限公司 Retro reflecting film

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105926875A (en) * 2016-06-27 2016-09-07 田芳 Indoor wide seamless glass bead composite decorative material and preparation technology thereof
CN109501411A (en) * 2018-11-05 2019-03-22 佛山市顺德区晶晶装饰材料有限公司 A kind of energy-saving explosion-proof mirror and energy-saving explosion-proof mirror production method
CN110128960A (en) * 2019-05-24 2019-08-16 东莞市铭伟电子科技有限公司 A kind of multipurpose quick and convenient patch

Similar Documents

Publication Publication Date Title
RU2014108957A (en) OPTIONAL TRANSFER OPTICAL SYSTEM WITH LOWER THICKNESS
CN105301683A (en) Sticking type retroreflective film and preparation method thereof
WO2002013978A3 (en) Process for forming a reflective surface
CN110045447B (en) Spray-painting reflective film and preparation process thereof
US10276005B2 (en) Shrink wrapped advertising for fire hydrants and fixtures
US8402653B2 (en) Solar energy converter assembly incorporating display system and method of fabricating the same
CN103192554A (en) Microprism reflective membrane and manufacturing method thereof
CN103105637A (en) Manufacturing method of high-strength type reflection film
CN102223771A (en) Electronic device shell and manufacturing method of same
CN206057619U (en) A kind of Microprism reflective membrane
CN102392424A (en) Reflective tube used for road traffic and preparation method thereof
CN104062698A (en) Production method for high-intensity reflective films
CN206725798U (en) Microprism reflecting film
CN201629100U (en) Reflecting paster
CN103048713B (en) Manufacture method for colored reflective product
CN104570179A (en) Aluminium-coated microprism product with large angle
CN105242338A (en) Reflective luminous filament and preparation method thereof
CN213448164U (en) Self-luminous and reflective preformed marking line
CN104150098A (en) Plate structure with three-dimensional effect and manufacturing method thereof
CN204575881U (en) A kind of microprism goods of aluminizing with wide-angle
US3187068A (en) Method of making reflex reflective sheeting
CN102096132A (en) Reflecting object and manufacturing method thereof
CN203096637U (en) Pole collision avoidance mark
PL1744862T3 (en) Method and apparatus for manufacture of a product from composite material
CN204676448U (en) A kind of alarm column

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 239500 ten Tan modern industrial park, Quanjiao County, Anhui, Chuzhou

Applicant after: ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY CO., LTD.

Address before: 239000 Anhui province Chuzhou City Jiuhua Road West, north of Tongling Road

Applicant before: ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY CO., LTD.

COR Change of bibliographic data
RJ01 Rejection of invention patent application after publication

Application publication date: 20160203

RJ01 Rejection of invention patent application after publication