CN105299993B - A kind of method of industrialized production Ozone Ice - Google Patents
A kind of method of industrialized production Ozone Ice Download PDFInfo
- Publication number
- CN105299993B CN105299993B CN201510716740.XA CN201510716740A CN105299993B CN 105299993 B CN105299993 B CN 105299993B CN 201510716740 A CN201510716740 A CN 201510716740A CN 105299993 B CN105299993 B CN 105299993B
- Authority
- CN
- China
- Prior art keywords
- ozone
- water
- ice
- concentration
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25C—PRODUCING, WORKING OR HANDLING ICE
- F25C1/00—Producing ice
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Production, Working, Storing, Or Distribution Of Ice (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
A kind of method that the invention discloses industrialized production Ozone Ice, it comprises the following steps: (1) prepares water at low temperature；(2) Ozone Water is prepared: the water at low temperature of step (1) gained and the ozone that produced by ozone generating-device being pressurizeed in pressure vessel is mixed into Ozone Water；Ozone concentration on-line monitoring sensor is used the ozone concentration in described Ozone Water to be monitored, so that the ozone concentration in described Ozone Water is maintained in the ozone concentration setting value of ozone concentration on-line monitoring sensor；(3) tentatively freezing: described Ozone Water is carried out in the freezing equipment of temperature≤10 DEG C just one-step forming；(4) freeze settled: the primary Ozone Ice of step (3) gained is delivered in another freezing equipment, carry out the most freeze settled at a temperature of ＜ 0 DEG C.The method using the present invention, can realize large-scale batch production, and can manufacture the Ozone Ice with different ozone concentration according to the concrete needs produced.
Description
Technical field
The present invention relates to ozone application field, a kind of method particularly relating to industrialized production Ozone Ice.
Background technology
Ozone (O) is a kind of strong oxidizer, and its oxidation-reduction potential in water is 2.07 eV, and oxidability is higher than chlorine
(1.36eV) with chlorine dioxide (1.5eV), it is only second to fluorine (2.5eV).Ozone can destroy the cell wall of decomposing bacteria such that it is able to
Diffuse in bacterial cell soon, and decompose and destroy the macromolecule polyalcohols such as DNA, RNA, protein, lipid and polysaccharide, broken
The normal metabolism of bad antibacterial and breeding, reach bactericidal effect.Ozone all keeps relatively stable molecule to tie under different pH value
Structure, can be reduced into oxygen after sterilization voluntarily, not produce any disinfection byproduct (DBP).On the other hand, traditional hypochlorous acid class sterilization
Agent is unstable under sour environment, and can produce the disinfection byproduct (DBP) such as chloramines class, haloform class, chlorine, after needing further
Continuous process.Additionally, the sterilizing ability of ozone and efficiency are all much stronger than traditional hypochlorous acid class disinfectant.In addition to sterilization,
Ozone also can eliminate rapidly and thoroughly in air and various abnormal flavour in water, all has higher exploitation value in field widely
Value.
The effect of ozone sterilization is closely related with its concentration, and for different sterilisation purposes, ozone threshold concentration
The suitableeest ozone concentration also differs.Ozone threshold concentration refers to the least concentration when ozone has certain sterilizing ability；?
Suitable ozone concentration refers to ozone concentration when comprehensive bactericidal effect is preferably.Although it is said that in general, sterilization speed when ozone concentration is the highest
Rate is the highest, but too high ozone concentration not necessarily brings optimal comprehensive bactericidal effect.Such as: although working as ozone concentration
During for 10ppm, the antibacterial of Meat Surface 99% can be destroyed in 10 seconds, and sterilization speed is when ozone concentration is 5ppm
Three times；But the meat processed through 10ppm ozone loses the taste of meat originally, and quality declines to a great extent, and uses 5ppm ozone
Such problem is not then had during sterilization.
Ozone less stable at normal temperatures and pressures, is decomposed into oxygen the most voluntarily, it is difficult to preserve.Research finds that ozone exists
In the frozen water of 0 DEG C more stable, the most stable in ice cube, the half-life was up to 2000 years.Manufacture of the prior art is smelly
The method of oxygen ice is generally: utilize ozone generators that oxygen is changed into ozone, followed by gas and water mixer, ozone is molten
Yu Shuizhong, the most again through frozen section system, is made into ice cube ozoniferous.But, this technique is more simple, not
There is the optimization carrying out parameter for industrial specific requirement, it is difficult to be applied in mass production.Additionally, this technique is also
The ozone concentration in ice cube can not be controlled, it is impossible to meet the needs of different sterilisation purpose.This makes Ozone Ice only at narrower neck
Territory obtains fragmentary application.
Summary of the invention
A kind of method that it is an object of the invention to provide industrialized production Ozone Ice, can realize extensive batch metaplasia
Produce, and the Ozone Ice with different ozone concentration can be manufactured according to the concrete needs produced.
In order to reach foregoing invention purpose, the present invention by the following technical solutions:
A kind of method of industrialized production Ozone Ice, it is characterised in that comprise the following steps:
(1) water at low temperature is prepared: by water for cooling to 3 ~ 5 DEG C；
(2) Ozone Water is prepared: the water at low temperature of step (1) gained and the ozone produced by ozone generating-device are held at pressure
In device, pressurization is mixed into Ozone Water；Use ozone concentration on-line monitoring sensor that the ozone concentration in described Ozone Water is carried out
Monitoring, so that the ozone concentration in described Ozone Water is maintained at the ozone concentration setting value of ozone concentration on-line monitoring sensor
On；
It is (3) tentatively freezing: described Ozone Water is carried out in the freezing equipment of temperature≤-10 DEG C just one-step forming so that it is
Surface quickly forms ozone ice film, is frozen into primary Ozone Ice；The volume of described ozone ice film account for Ozone Water cumulative volume 2 ~
30%；
(4) freeze settled: the primary Ozone Ice of step (3) gained is delivered in another freezing equipment, in the temperature of ＜ 0 DEG C
Carry out the most freeze settled under degree, form finished product Ozone Ice.
At ambient temperature and pressure, ozone dissolubility in water is relatively low.Therefore, before ozone is mixed with water, need pre-
First water is lowered the temperature, and mix under pressure.The ozone generating-device that step (2) is used can be selected for market
Upper common ozonator, it can convert the oxygen to ozone.In a preferred embodiment, in step (2)
Ozone concentration on-line monitoring sensor can adjust produced by adjusting driving electric current and the driving frequency of ozonator
Ozone amount.Therefore, as long as the parameter of ozone concentration on-line monitoring sensor is set, just can be according to concrete production need
Want, obtain the Ozone Water of different ozone concentration, thus obtain the Ozone Ice of different ozone concentration.The ozone concentration of Ozone Water with make
Ozone concentration in the Ozone Ice condensed into by this Ozone Water is proportional, and concrete ratio therebetween is concrete according to used
The difference of the factors such as the ozone concentration in equipment and Ozone Water and different, can be by carrying out pre-reality before carrying out large-scale production
Test, this ratio is measured.In an embodiment of the present invention, the ozone concentration in Ozone Water is made with using this Ozone Water
The ratio of the ozone concentration of Ozone Ice is 8 ~ 15 1.
In the embodiment that the present invention recommends, the pressure vessel pressure applied in step (1) 0.1～
In the range of 0.45Mpa；The ozone concentration setting value of the ozone concentration on-line monitoring sensor in step (2) is at 0.1 ~ 150ppm
In the range of.
The present invention uses molding procedure at least twice, Ozone Water is freezed as Ozone Ice, and prior art simply just will
Ozone Water is once lowered the temperature and is shaped to Ozone Ice.In the production of industrial mass, once cooling molding needs large-scale freezing
Equipment could realize.The production site that large-scale freezing equipment needs is relatively big, power consumption is high, production cost is high, and there also have environment to be unfavorable
Impact.The method of the present invention preferably carries out just one-step forming and freeze settled, in satisfied production in enormous quantities in different equipment
On the premise of amount, cost of investment and the land area of Ozone Ice production line, environmental protection simultaneously can be substantially reduced.
The first one-step forming described in step (3) of the present invention has chilling rate feature faster, preferably by low temperature stream
Waterline equipment: after Ozone Water is placed in container, first one-step forming on low temperature streamline conveyer belt.In addition it is also possible to use general
Logical refrigerator-freezer carries out freezing.Once Ozone Water reaches the requirement of just one-step forming, just primary Ozone Ice can be transferred to fixating shape step
Freezing equipment in shape, and the freezing equipment used by forming step just can vacant out, to carry out the one-tenth of next batch
Type, turnover is flexibly.
Freeze settled in step of the present invention (4) is once, it is possible to for more than once, according to whether need in actual production
Ozone Ice is further processed and adjusts: if having the further demoulding or packaging and other steps, then need at these
Again shape after step.The temperature of sizing can carry out concrete configuration according to required throughput rate.It is it desired to
Obtain finished product in relatively short period of time, then can reduce setting temperature.The freezing equipment that step (4) is used is preferably refrigerator-freezer.
Preferably, the water used in step (1) is the water reaching drinking water standard.The stability of Ozone Water is by institute in water
Impure impact is bigger.If containing Organic substance in water, ozone soluble in water will be consumed；If water has some metal ion
Existing, ozone is decomposed into the most rapidly oxygen.It is therefore preferred that the water used to be carried out the pretreatment such as filtration so that it is reach
Water quality as required by the GB5749-2006 " drinking water sanitary standard " that country promulgates.
Preferably, in step (1), use temperature online monitoring sensor that the temperature of described water is monitored, and
The water described in feedback signal control according to described temperature online monitoring sensor and the mixing of ozone.By mixing with ozone
The temperature of the water at low temperature closed is accurately controlled, and the ozone concentration of Ozone Water can be made to keep stable.A preferred enforcement
In scheme, the water in step (1) is lowered the temperature in refrigerating plant, and direct and step (2) the gas-liquid mixed of this refrigerating plant fills
Put connected.When the water of refrigerating plant reaches the default temperature of temperature online monitoring sensor, the water inlet of Liqiud-gas mixing device
Valve is opened, and water at low temperature is entered in Liqiud-gas mixing device by refrigerating plant, and mixes with ozone；When the water temperature in refrigerating plant is high
In or less than sensor preset temperature time, inlet valve close.
Preferably, in step (3), first Ozone Water can be inputted in the mould that size and dimension is different, then carry out preliminary
Freezing.
When the method using the present invention carries out the production in enormous quantities of Ozone Ice, the daily output of every production line can reach 40 tons
Above, annual production reaches more than 1.44 ten thousand tons.When the Ozone Ice weight produced is between 1 ~ 50000g, can be by changing
Ice bank mould implementation specification is changed, and conversion efficiency is 2h/ time.When monolithic Ozone Ice weight is more than 50000g, can be by changing
Refrigerating plant implementation specification is changed, and conversion efficiency is 8h/ time.
Technical scheme has the advantage that
1. the concentration of ozone ozone in water for different application targets, can be adjusted, thus produce different ozone concentration
Ozone Ice；
2. the ozone concentration in pair Ozone Water and temperature monitor in real time, it is to avoid same batch ozone in prior art
The unbalanced drawback of ozone concentration contained by ice；
3. optimizing existing production procedure and technique so that it is can be applicable to industrial mass production, production efficiency is high；
4. use the method for reducing temperature twice that Ozone Water is freezed, improve the motility of production, reduce and produce into
Basis and energy consumption.
Detailed description of the invention
The present invention will be described to be exemplified below specific embodiment.It is pointed out that embodiment is served only for the present invention
It is described further, does not represent protection scope of the present invention, nonessential amendment that other people make according to the present invention and adjustment,
Still fall within protection scope of the present invention.
In following embodiment, the running water filter used is preferably sky water treatment facilities (Ganzhou) limited public affairs
The charcoal filter that department is produced；It is raw that the tap water cooling device used is preferably Guangzhou Ao Xue refrigerating equipment corporation, Ltd
The multifunctional table-type calorstat that model is HWX-195 produced；The PSA industrial oxygenerating device used is preferably Guangzhou wound ring ozone
The PSA industrial oxygenerating machine that electric equipment company limited is produced；The ozonator used is preferably Guangzhou wound ring ozone electricity
The minitype vertical type ozonator (CH-WZQ) that device equipment company limited is produced；The Liqiud-gas mixing device used is preferably wide
The CH-QY-B2 Ozone Water pressurization blender that state wound ring ozone electric equipment company limited is produced；The ozone concentration used exists
Line monitoring sensor is preferably the ATI Q45H/64 dissolved ozone analyser purchased from Zibo ADEL observation and control technology company limited；
The freezing equipment that preliminary forming step is used is preferably the CH-SD-that Guangzhou wound ring ozone electric equipment company limited is produced
The model that B1 pipeline system Quick freezing device or Fu Da freezing equipment company limited of Shenzhen produce be BKDB-100L-135 or
The low temperature refrigerator of BKDW-318L-65；The freezing equipment that freeze settled step is used preferably Shenzhen's richness reaches freezing equipment to be had
The low temperature refrigerator that model is BKDB-100L-135 or BKDW-318L-65 that limit company produces；The temperature online monitoring used
Sensor is preferably the radio temperature sensor that Tai Shite Science and Technology Co., Ltd. of Shenzhen produces.Enumerate except above-mentioned it
Outward, those skilled in the art select according to routine, it is also possible to select other to have the said goods enumerated with the present invention and have phase
Like the product of performance, the purpose of the present invention all can be realized.
Embodiment 1
(1) use running water filter to filter tap water, and in cooling device, be cooled to 3 DEG C；
(2) use PSA industrial oxygenerating device to prepare the oxygen that purity is 89 ~ 90%, then be passed into ozonator；
(3) water at low temperature of step (1) gained is inputted Liqiud-gas mixing device with the speed of 2t/h；By step (2) gained
Ozone inputs this Liqiud-gas mixing device with the speed of 20g/h, and is sufficiently mixed as ozone under the pressure of 0.3MPa with water at low temperature
Water.Use the ozone concentration in ozone concentration this Ozone Water of on-line monitoring Sensor monitoring, and feedback signal be to ozonator,
Thus the driving electric current and driving frequency to this ozonator is adjusted, to adjust gaseous mixture produced by ozonator
The concentration of ozone in body, makes the ozone concentration in Ozone Water be maintained between 8ppm ~ 9ppm；
(4) described Ozone Water is carried out at a temperature of-35 DEG C just one-step forming.The surface of Ozone Ice is formed in 30s
Ozone ice film, is frozen into primary Ozone Ice；The volume of described ozone ice film accounts for the 5% of Ozone Water cumulative volume；
(5) by the primary Ozone Ice of step (3) gained by conveyer belt, it is conveyed in freezing equipment, and in the temperature of-12 DEG C
Carry out the most freeze settled under degree, after 8 hours, form finished product Ozone Ice.Ozone concentration in this Ozone Ice be 0.6ppm ~
0.7ppm。
Embodiment 2
(1) use running water filter to filter tap water, and in cooling device, be cooled to 5 DEG C；
(2) use PSA industrial oxygenerating device to prepare the oxygen that purity is 89 ~ 90%, then be passed into ozonator；
(3) water at low temperature of step (1) gained is inputted Liqiud-gas mixing device with the speed of 2t/h；By step (2) gained
Ozone inputs this Liqiud-gas mixing device with the speed of 20g/h, and is sufficiently mixed as ozone under the pressure of 0.2MPa with water at low temperature
Water.Use the ozone concentration in ozone concentration this Ozone Water of on-line monitoring Sensor monitoring, and feedback signal be to ozonator,
Thus the driving electric current and driving frequency to this ozonator is adjusted, to adjust gaseous mixture produced by ozonator
The concentration of ozone in body, makes the ozone concentration in Ozone Water be maintained between 12ppm ~ 13ppm；
(4) described Ozone Water is carried out at a temperature of-30 DEG C just one-step forming.The surface of Ozone Ice is formed in 30s
Ozone ice film, is frozen into primary Ozone Ice；The volume of described ozone ice film accounts for the 2% of Ozone Water cumulative volume；
(5) by the primary Ozone Ice of step (3) gained by conveyer belt, it is conveyed in freezing equipment, and in the temperature of-20 DEG C
Carry out the most freeze settled under degree, after 6 hours, form finished product Ozone Ice.Ozone concentration in this Ozone Ice is 0.9ppm ~ 1ppm.
Embodiment 3
(1) in cooling device, tap water is cooled to 3 DEG C；Use the temperature online monitoring sensor temperature to described water
Degree is monitored, and controls whether to input the water at low temperature of gained according to the feedback signal of described temperature online monitoring sensor
Liqiud-gas mixing device；
(2) use PSA industrial oxygenerating device to prepare the oxygen that purity is 89 ~ 90%, then be passed into ozonator；
(3) water at low temperature of 4 DEG C of step (1) gained is inputted Liqiud-gas mixing device with the speed of 2t/h；By step (2) institute
Ozone input this Liqiud-gas mixing device with the speed of 20g/h, and with water at low temperature be sufficiently mixed under the pressure of 0.1MPa into
Ozone Water.Use the ozone concentration in ozone concentration this Ozone Water of on-line monitoring Sensor monitoring, and feedback signal is sent out to ozone
Raw device, thus the driving electric current and driving frequency to this ozonator is adjusted, to adjust produced by ozonator
The concentration of ozone in mixed gas, makes the ozone concentration in Ozone Water be maintained between 0.1ppm ~ 1ppm；
(4) Ozone Water of gained is inputted in square mould, and at a temperature of-60 DEG C, carry out just one-step forming.Ozone
The surface of ice forms ozone ice film in 120s, is frozen into primary Ozone Ice；It is total that the volume of described ozone ice film accounts for Ozone Water
The 30% of volume；
(5) by the primary Ozone Ice of step (3) gained by conveyer belt, it is conveyed in freezing equipment, at a temperature of-5 DEG C
Freezing 5 hours, after tentatively shaping, carry out the demoulding；Then, then freezing 10 hours at-10 DEG C, obtain square Ozone Ice.Should
Ozone concentration in Ozone Ice is 0.05 ~ 0.2ppm.
Embodiment 4
(1) use running water filter to filter tap water, and in cooling device, be cooled to 3 DEG C；
(2) use PSA industrial oxygenerating device to prepare the oxygen that purity is 89 ~ 90%, then be passed into ozonator；
(3) water at low temperature of step (1) gained is inputted Liqiud-gas mixing device with the speed of 2t/h；By step (2) gained
Ozone inputs this Liqiud-gas mixing device with the speed of 40g/h, and is sufficiently mixed as ozone under the pressure of 0.45MPa with water at low temperature
Water.Use the ozone concentration in ozone concentration this Ozone Water of on-line monitoring Sensor monitoring, and feedback signal be to ozonator,
Thus the driving electric current and driving frequency to this ozonator is adjusted, to adjust gaseous mixture produced by ozonator
The concentration of ozone in body, makes the ozone concentration in Ozone Water be maintained between 149ppm ~ 150ppm；
(4) Ozone Water of gained is inputted in cuboid mould, and at a temperature of-10 DEG C, carry out just one-step forming.Ozone
The surface of ice forms ozone ice film in 120s, is frozen into primary Ozone Ice；It is total that the volume of described ozone ice film accounts for Ozone Water
The 3% of volume；
(5) by the primary Ozone Ice of step (3) gained by conveyer belt, it is conveyed in freezing equipment, freezing 2 at-20 DEG C
Hour, carry out the demoulding after preliminary sizing；Then freezing 1 hour at-25 DEG C, packs；Finally, at-30 DEG C, freezing 5 is little
Cuboid Ozone Ice is formed time after.Ozone concentration in this Ozone Ice is 13ppm ~ 14ppm.
Embodiment 5
(1) use running water filter to filter tap water, and in cooling device, be cooled to 4 DEG C；
(2) use PSA industrial oxygenerating device to prepare the oxygen that purity is 89 ~ 90%, then be passed into ozonator；
(3) water at low temperature of step (1) gained is inputted Liqiud-gas mixing device with the speed of 2t/h；By step (2) gained
Ozone inputs this Liqiud-gas mixing device with the speed of 30g/h, and is sufficiently mixed as ozone under the pressure of 0.35MPa with water at low temperature
Water.Use the ozone concentration in ozone concentration this Ozone Water of on-line monitoring Sensor monitoring, and feedback signal be to ozonator,
Thus the driving electric current and driving frequency to this ozonator is adjusted, to adjust gaseous mixture produced by ozonator
The concentration of ozone in body, makes the ozone concentration in Ozone Water be maintained between 99ppm ~ 100ppm；
(4) described Ozone Water is carried out at a temperature of-40 DEG C just one-step forming.The surface of Ozone Ice is formed in 120s
Ozone ice film, is frozen into primary Ozone Ice；The volume of described ozone ice film accounts for the 23% of Ozone Water cumulative volume；
(5) by the primary Ozone Ice of step (3) gained by conveyer belt, it is conveyed in freezing equipment, the temperature of-120 DEG C
Under carry out the most freeze settled, after 0.5 hour formed finished product Ozone Ice.Ozone concentration in this Ozone Ice is 7ppm ~ 8ppm.
Claims (9)
1. the method for an industrialized production Ozone Ice, it is characterised in that comprise the following steps:
(1) water at low temperature is prepared: by water for cooling to 3～5 DEG C；
(2) Ozone Water is prepared: by the water at low temperature of step (1) gained and the ozone that produced by ozone generating-device in pressure vessel
Pressurization is mixed into Ozone Water；Use ozone concentration on-line monitoring sensor that the ozone concentration in described Ozone Water is supervised
Control, so that the ozone concentration in described Ozone Water is maintained at the ozone concentration setting value of ozone concentration on-line monitoring sensor,
Described ozone concentration setting value is in the range of 0.1～150ppm；
(3) tentatively freezing: described Ozone Water to be carried out in the freezing equipment of temperature≤-10 DEG C just one-step forming so that it is surface
Quickly form ozone ice film, be frozen into primary Ozone Ice；The volume of described ozone ice film account for Ozone Water cumulative volume 2～
30%；
(4) freeze settled: the primary Ozone Ice of step (3) gained is delivered in another freezing equipment, at a temperature of ＜ 0 DEG C
Carry out the most freeze settled, form finished product Ozone Ice.
The method of industrialized production Ozone Ice the most according to claim 1, it is characterised in that: the pressure in step (1) holds
Device pressure applied is in the range of 0.1～0.45Mpa.
The method of industrialized production Ozone Ice the most according to claim 1 and 2, it is characterised in that: step (3) is used
Freezing equipment is low temperature pipelining equipment.
The method of industrialized production Ozone Ice the most according to claim 1 and 2, it is characterised in that: step (3) is used
Freezing equipment is refrigerator-freezer.
The method of industrialized production Ozone Ice the most according to claim 3, it is characterised in that: it is cold that step (4) is used
Freeze equipment and be preferably refrigerator-freezer.
The method of industrialized production Ozone Ice the most according to claim 5, it is characterised in that: used in step (1)
Water is the water reaching drinking water standard.
The method of industrialized production Ozone Ice the most according to claim 6, it is characterised in that: in step (1), use temperature
The temperature of described water is monitored by degree on-line monitoring sensor, and according to the feedback of described temperature online monitoring sensor
Water described in signal control and the mixing of ozone.
The method of industrialized production Ozone Ice the most according to claim 7, it is characterised in that: in step (3), can first by
In the mould that Ozone Water input size and dimension is different, then carry out preliminary freezing.
The method of industrialized production Ozone Ice the most according to claim 8, it is characterised in that: the one-tenth described in step (4)
The ozone concentration of product Ozone Ice is 0.6～14ppm.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510716740.XA CN105299993B (en) | 2015-10-30 | 2015-10-30 | A kind of method of industrialized production Ozone Ice |
| PCT/CN2016/090605 WO2017071313A1 (en) | 2015-10-30 | 2016-07-20 | Method for industrial production of ozone ice |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510716740.XA CN105299993B (en) | 2015-10-30 | 2015-10-30 | A kind of method of industrialized production Ozone Ice |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105299993A CN105299993A (en) | 2016-02-03 |
| CN105299993B true CN105299993B (en) | 2016-07-27 |
Family
ID=55197549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510716740.XA Active CN105299993B (en) | 2015-10-30 | 2015-10-30 | A kind of method of industrialized production Ozone Ice |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN105299993B (en) |
| WO (1) | WO2017071313A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105299993B (en) * | 2015-10-30 | 2016-07-27 | 张旭 | A kind of method of industrialized production Ozone Ice |
| CN110172587B (en) * | 2019-05-09 | 2020-08-11 | 北京科技大学 | Preparation method and application of ozone ice long-acting oxygen sustained release agent |
| JP2023519785A (en) * | 2020-04-03 | 2023-05-15 | ヴェンミル インダストリーズ インコーポレイテッド | ice machine cleaning equipment |
| WO2022246990A1 (en) * | 2021-05-26 | 2022-12-01 | 雷伯敏 | Salt-ozone ice medicine for injection and production thereof |
| CN113251714B (en) * | 2021-05-26 | 2022-10-28 | 中国海洋大学 | Preparation method of high-concentration ozone ice |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10267476A (en) * | 1997-03-26 | 1998-10-09 | Kobe Steel Ltd | Method for manufacturing ice containing ozone |
| KR20020029708A (en) * | 2000-10-13 | 2002-04-19 | 변점수 | Ozone ice and Maunfacturing method thereof |
| CN1920449A (en) * | 2005-08-26 | 2007-02-28 | 周桂梅 | Low bacterium ice cake containing ozone and process for preparing the same |
| JP2007170714A (en) * | 2005-12-20 | 2007-07-05 | Noboru Sakano | Method of making useful gas-containing ice |
| KR20110122918A (en) * | 2010-05-06 | 2011-11-14 | 조기원 | Sterilized ice made of high concentration ozone water and its manufacturing method |
| CN105299993B (en) * | 2015-10-30 | 2016-07-27 | 张旭 | A kind of method of industrialized production Ozone Ice |
-
2015
- 2015-10-30 CN CN201510716740.XA patent/CN105299993B/en active Active
-
2016
- 2016-07-20 WO PCT/CN2016/090605 patent/WO2017071313A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| CN105299993A (en) | 2016-02-03 |
| WO2017071313A1 (en) | 2017-05-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105299993B (en) | A kind of method of industrialized production Ozone Ice | |
| CN108576226A (en) | It is a kind of can the inflation mousse fermented dairy product and preparation method thereof that preserves of cryogenic freezing | |
| CN103694105A (en) | Method for purifying sorbic acid | |
| CN107549315A (en) | A kind of formula and preparation method for freezing cheese's milk lid thickener | |
| CN104886702A (en) | A clarified and concentrated fruit juice preparation method | |
| CN105289342A (en) | High-concentration ozone water preparation device, high-concentration ozone water preparation method and application of high-concentration ozone water preparation device | |
| CN106307501A (en) | Preparation method of full-watermelon enzyme | |
| CN105167060A (en) | Raspberry fruit juice beverage and preparation method thereof | |
| CN204933277U (en) | A kind of high-concentration ozone water preparing device | |
| EP0651727B1 (en) | Manufacture of gas hydrates | |
| CN108276205A (en) | A kind of special Water soluble fertilizer improving Peach fruits quality | |
| CN113251714B (en) | Preparation method of high-concentration ozone ice | |
| CN110897004A (en) | Milk freezing concentration pasteurization method | |
| CN103125605A (en) | Fruit juice acidic milk tea beverage and production method thereof | |
| CN101283827B (en) | Tomato fruit vinegar beverage and production method thereof | |
| CN106631496A (en) | Selenium-enriched foliar fertilizer | |
| JP7266268B2 (en) | Method for producing bulk gas-containing ice | |
| CN101744186B (en) | Bean curd and preparation method thereof | |
| CN110037208A (en) | A kind of processing method of Kiwi berry original flavor pulp | |
| CN102071151A (en) | Method for breaking yeast cell walls | |
| CN107751906B (en) | A kind of production technology of fruit frost and the equipment used | |
| CN1121820C (en) | Honeyed ice beverage jelly with sandwich and its preparing process | |
| CN100415901C (en) | Liquid crystal sugar production method | |
| CN102907492A (en) | Method and system of using carbonated water for preserving raw milk | |
| CN106631176B (en) | Preparation and application of slow-release plant physiological acid salt-polypeptide sulfate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170510 Address after: 510663 210A, compound courtyard, 18 West Mu Xi Street, Tianhe District, Guangdong, Guangzhou, China Patentee after: GUANGZHOU CHUANGHUAN OZONE ELECTRICAL EQUIPMENT CO., LTD. Address before: 108, room 510663, compound 18, West Street, Tianhe District, Guangdong, Guangzhou Patentee before: Zhang Xu |