CN105293482A - 一种石墨烯的溶剂热剥离制备方法 - Google Patents
一种石墨烯的溶剂热剥离制备方法 Download PDFInfo
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- CN105293482A CN105293482A CN201510883111.6A CN201510883111A CN105293482A CN 105293482 A CN105293482 A CN 105293482A CN 201510883111 A CN201510883111 A CN 201510883111A CN 105293482 A CN105293482 A CN 105293482A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 82
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 36
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 27
- 239000010439 graphite Substances 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000012043 crude product Substances 0.000 claims abstract description 10
- 239000000047 product Substances 0.000 claims abstract description 9
- 238000009830 intercalation Methods 0.000 claims abstract description 7
- 230000002687 intercalation Effects 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 239000003960 organic solvent Substances 0.000 claims abstract description 3
- 239000000725 suspension Substances 0.000 claims abstract 2
- 239000000138 intercalating agent Substances 0.000 claims description 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 235000019253 formic acid Nutrition 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 3
- 238000003828 vacuum filtration Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
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- 238000001914 filtration Methods 0.000 claims description 2
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- 238000004146 energy storage Methods 0.000 abstract description 2
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- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
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- 150000003384 small molecules Chemical class 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 16
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 230000033116 oxidation-reduction process Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
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- 238000001291 vacuum drying Methods 0.000 description 2
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- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 238000004630 atomic force microscopy Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- 238000009835 boiling Methods 0.000 description 1
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- 239000004020 conductor Substances 0.000 description 1
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- 238000001000 micrograph Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
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- 239000002086 nanomaterial Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
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- 238000004557 single molecule detection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000010891 toxic waste Substances 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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Abstract
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Priority Applications (1)
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CN201510883111.6A CN105293482A (zh) | 2015-12-01 | 2015-12-01 | 一种石墨烯的溶剂热剥离制备方法 |
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CN201510883111.6A Pending CN105293482A (zh) | 2015-12-01 | 2015-12-01 | 一种石墨烯的溶剂热剥离制备方法 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105800603A (zh) * | 2016-04-22 | 2016-07-27 | 华侨大学 | 一种快速制备高质量石墨烯的方法 |
CN105905889A (zh) * | 2016-06-06 | 2016-08-31 | 南通伟德动力电池研究所(普通合伙) | 一种高压水热膨胀法制造石墨烯的方法 |
CN106591871A (zh) * | 2016-12-01 | 2017-04-26 | 燕园众欣纳米科技(北京)有限公司 | 一种电化学原位氧化还原制备石墨烯的方法 |
CN107879325A (zh) * | 2016-09-29 | 2018-04-06 | 河南烯碳合成材料有限公司 | 石墨烯的制造方法 |
CN109081316A (zh) * | 2017-06-13 | 2018-12-25 | 天津大学 | 一种基于溶剂热插层法的硒化锗二维材料的制备方法 |
CN110980723A (zh) * | 2019-12-27 | 2020-04-10 | 洛阳森蓝化工材料科技有限公司 | 一种石墨膨化处理工艺 |
CN111137866A (zh) * | 2020-01-10 | 2020-05-12 | 中国南方电网有限责任公司电网技术研究中心 | 一种高效剥离h-BN制备氮化硼纳米片的方法 |
CN116873912A (zh) * | 2023-05-24 | 2023-10-13 | 国电投重庆能源研究院有限公司 | 一种水溶导电型石墨烯及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103213979A (zh) * | 2013-05-10 | 2013-07-24 | 山西大同大学 | 一种溶剂热法制备石墨烯的方法 |
CN103922331A (zh) * | 2014-04-28 | 2014-07-16 | 南京新月材料科技有限公司 | 一种制备石墨烯粉体的方法 |
CN104085886A (zh) * | 2014-07-28 | 2014-10-08 | 嵇天浩 | 石墨烯及其制备方法 |
CN104843679A (zh) * | 2015-04-03 | 2015-08-19 | 北京理工大学 | 由微晶石墨溶剂热剥离制备微晶石墨烯的方法 |
-
2015
- 2015-12-01 CN CN201510883111.6A patent/CN105293482A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103213979A (zh) * | 2013-05-10 | 2013-07-24 | 山西大同大学 | 一种溶剂热法制备石墨烯的方法 |
CN103922331A (zh) * | 2014-04-28 | 2014-07-16 | 南京新月材料科技有限公司 | 一种制备石墨烯粉体的方法 |
CN104085886A (zh) * | 2014-07-28 | 2014-10-08 | 嵇天浩 | 石墨烯及其制备方法 |
CN104843679A (zh) * | 2015-04-03 | 2015-08-19 | 北京理工大学 | 由微晶石墨溶剂热剥离制备微晶石墨烯的方法 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105800603A (zh) * | 2016-04-22 | 2016-07-27 | 华侨大学 | 一种快速制备高质量石墨烯的方法 |
CN105800603B (zh) * | 2016-04-22 | 2018-01-09 | 华侨大学 | 一种快速制备高质量石墨烯的方法 |
CN105905889A (zh) * | 2016-06-06 | 2016-08-31 | 南通伟德动力电池研究所(普通合伙) | 一种高压水热膨胀法制造石墨烯的方法 |
CN107879325A (zh) * | 2016-09-29 | 2018-04-06 | 河南烯碳合成材料有限公司 | 石墨烯的制造方法 |
CN106591871A (zh) * | 2016-12-01 | 2017-04-26 | 燕园众欣纳米科技(北京)有限公司 | 一种电化学原位氧化还原制备石墨烯的方法 |
CN109081316A (zh) * | 2017-06-13 | 2018-12-25 | 天津大学 | 一种基于溶剂热插层法的硒化锗二维材料的制备方法 |
CN110980723A (zh) * | 2019-12-27 | 2020-04-10 | 洛阳森蓝化工材料科技有限公司 | 一种石墨膨化处理工艺 |
CN110980723B (zh) * | 2019-12-27 | 2022-10-21 | 洛阳森蓝化工材料科技有限公司 | 一种石墨膨化处理工艺 |
CN111137866A (zh) * | 2020-01-10 | 2020-05-12 | 中国南方电网有限责任公司电网技术研究中心 | 一种高效剥离h-BN制备氮化硼纳米片的方法 |
CN116873912A (zh) * | 2023-05-24 | 2023-10-13 | 国电投重庆能源研究院有限公司 | 一种水溶导电型石墨烯及其制备方法 |
CN116873912B (zh) * | 2023-05-24 | 2024-05-07 | 国电投重庆能源研究院有限公司 | 一种水溶导电型石墨烯及其制备方法 |
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C06 | Publication | ||
PB01 | Publication | ||
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TA01 | Transfer of patent application right |
Effective date of registration: 20160901 Address after: 100080, room 15, building 1, 3 Haidian Avenue, Beijing,, Haidian District Applicant after: Yanyuan Zhongxin nano science and Technology (Beijing) Co. Ltd. Address before: The 2 group of 441000 Xiangfan province Hubei city Xiangyang District Zhang Gu Yi Zhen Guan Qiao Cun Applicant before: Zhang Yangwei Applicant before: Sun Bin Applicant before: Tian Youhua |
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Application publication date: 20160203 |