CN105289853A - Normal-temperature short-process collecting agent for hematite reverse flotation - Google Patents
Normal-temperature short-process collecting agent for hematite reverse flotation Download PDFInfo
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- CN105289853A CN105289853A CN201510745361.3A CN201510745361A CN105289853A CN 105289853 A CN105289853 A CN 105289853A CN 201510745361 A CN201510745361 A CN 201510745361A CN 105289853 A CN105289853 A CN 105289853A
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- reverse flotation
- collecting agent
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Abstract
A normal-temperature short-process collecting agent for hematite reverse flotation comprises, by mass, 0-60% of sodium lignin sulfonate, 35%-90% of acid oil and 5%-20% of polyoxyethylene-polyoxypropylene block polyether. The structural formula of the polyoxyethylene-polyoxypropylene block polyether is shown in the specification, wherein a ranges from 15 to 19, b ranges from 8 to 12, and c ranges from 8 to 12. Through the collecting agent under the condition of the normal temperature ranging from 22 DEG C to 25 DEG C, the concentrate grade of feed mixed magnetic concentrate with the grade being 47.9% can be made to reach 67%-69% through one time of roughing, one time of concentration and one time of scavenging, and the concentrate iron yield reaches 88%-91.5%; the concentrate grade is high, the concentrate recovery rate is high, and the purposes of simplifying the process, increasing the yield and reducing the cost are realized.
Description
Technical field
The invention belongs to technical field of beneficiation, particularly a kind of hematite reverse flotation normal temperature short route collecting agent.
Background technology
In oxide ore ore dressing field such as bloodstone, reducing flotation temperature, increasing the efficiency of separation, shorten flow process, simplify the operation is the key issue of iron ore flotation technology, significant to the comprehensive benefit improving Mineral Processing Enterprises.
In order to improve the beneficiating efficiency of bloodstone, need development of new floating agent.The research of current this area is very active; related invention is reported in succession; such as; Chinese Patent Application No.: 2014102560544 disclose a kind of hematite low temperature flotation agent and preparation method; the mixing of hydroxy fatty acid, alpha-sulfonated fatty acid and unrighted acid is added foaming agent; make through saponification, hydroxy fatty acid price used is high, roughly selects 800g/t consumption large.Chinese Patent Application No.: 2015100906877 disclose and are by mass percentage: ambient-temperature collector prepared by a-ethylenediamine yl carboxylic acid 86 ~ 96%, a-bromo carboxylic acid 2 ~ 7% and ethylenediamine 2 ~ 7%, bromination price is high, and process is complicated, and yield 74.43% is lower.The Chinese patent application of application number 2014101096425 discloses containing C
16h
31cOCH (COONa)
2collecting agent, wherein, C
16h
31-be at C
7 ~ 8between have the straight-chain alkenyl of unsaturated double-bond.Also containing one or more in castor oil acid, vegetable oil acid, animal oleic acid or oleic acid, 200g is to ore deposit 2% collecting agent 12mL, and consumption is too high, and a thick essence three is swept traditional handicraft and seemed complicated.In order to improve bloodstone beneficiating efficiency and simple flow, reduce costs, need the more effective collecting agent that further exploitation is new to be used for hematite reverse flotation technique.
Summary of the invention
The object of the invention is for the deficiencies in the prior art, a kind of hematite reverse flotation normal temperature short route collecting agent is provided, at reduction flotation temperature, reduce consumption and save energy and reduce the cost simultaneously; Shorten flotation process, simplify the operation.
The chemical constituent of hematite reverse flotation normal temperature short route collecting agent of the present invention is by mass percentage: sodium lignin sulfonate 0 ~ 60%; Acidification oil 35 ~ 90%; Polyoxyethylene polyoxypropylene block polyether 5 ~ 20%; The structural formula of described polyoxyethylene polyoxypropylene block polyether is:
Wherein a=15 ~ 19, b=8 ~ 12, c=8 ~ 12.
Acid number 110 ~ the 150KOHmg/g of above-mentioned acidification oil, saponification number 160 ~ 200KOHmg/g; Iodine number 90 ~ 120I
2g/100g.
The using method of hematite reverse flotation normal temperature short route collecting agent of the present invention is:
What 1, adopt is the mixed magnetic concentrate of bloodstone to ore deposit, will add water make ore pulp to ore deposit;
2, ore pulp is carried out reverse flotation at 22 ~ 25 DEG C to roughly select, when reverse flotation is roughly selected, the consumption of adjusting agent NaOH adds 700 ~ 800g by per ton to ore deposit, the consumption of inhibitor starch adds 700 ~ 800g by per ton to ore deposit, the consumption of activator calcium oxide adds 550 ~ 570g by per ton to ore deposit, and the consumption of hematite reverse flotation normal temperature short route collecting agent adds 400 ~ 410g by per ton to ore deposit; Reverse flotation roughly selects rear acquisition rougher concentration and rougher tailings;
3, rougher concentration is carried out reverse flotation at 22 ~ 25 DEG C selected, when reverse flotation is selected, the consumption of adjusting agent NaOH adds 90 ~ 110g by per ton to ore deposit, and the consumption of hematite reverse flotation normal temperature short route collecting agent adds 150 ~ 160g by per ton to ore deposit; Obtain
concentrateand cleaner tailings.
In said method, cleaner tailings turns back to reverse flotation and roughly selects step, together carries out reverse flotation roughly select with ore pulp.
In said method, rougher tailings is scanned at 22 ~ 25 DEG C, and when scanning, the consumption of NaOH adds 300 ~ 400g by per ton to ore deposit, obtains scavenger concentrate and scans mine tailing; Scavenger concentrate turns back to reverse flotation and roughly selects step, together carries out reverse flotation roughly select with ore pulp; Scan, roughly select and selected common formation closed circuit reverse flotation flowsheet.
The concentrate yield of above-mentioned closed circuit reverse flotation flowsheet 61 ~ 64%, the Iron grade of concentrate 67.0 ~ 69%,
In concentrate, the rate of recovery of iron is 88 ~ 91.5%.
In said method, reverse flotation is roughly selected, it is selected to select and the time that is that scan at 2.5 ~ 5min.
Collecting agent of the present invention can obtain the effect of traditional collecting agent at high temperature (38 ~ 45 DEG C) reverse flotation at normal temperature, generally apply with traditional mineral processing plant an one thick essence three is swept compared with flow process, technological process of the present invention is shortened, concentrate grade is high, the concentrate rate of recovery is high, achieves the object that technique simplifies, improves yield, reduces costs; With acidification oil, sodium lignin sulfonate for primary raw material, can ensure under the prerequisite of collecting ability and reverse flotation effect cheap, good economic benefit and strong competitiveness can be produced; Adopt ethylene oxide propylene oxide block polyether can dispersible aliphatic acid water soluble salt and lignin sulfonic acid water soluble salt at normal temperatures, reduce so that eliminate micella, in the solution dispersed, form stable associated matter enter foam with the silica after activating with calcium oxide, finality is formed through once purging selection, anionic collector obtained like this have raw material sources extensively, produce simple and convenient, cost is lower, nonpoisonous and tasteless pollution-free, can the feature such as normal temperature use, be the more satisfactory collecting agent of normal temperature flotation bloodstone.
Accompanying drawing explanation
Fig. 1 is the hematite reverse flotation schematic flow sheet of the embodiment of the present invention 3.
Detailed description of the invention
Sodium lignin sulfonate in the embodiment of the present invention is commercial products.
Acidification oil in the embodiment of the present invention is commercial products, brown viscous liquid.
Polyoxyethylene polyoxypropylene block polyether in the embodiment of the present invention is commercial products.
NaOH in the embodiment of the present invention, starch and calcium oxide are commercial products.
Roughly selecting with in concentration step by joining after the saponification of iron ore reverse flotation normal temperature short route collecting agent in the embodiment of the present invention, measuring with giving the ratio in ore deposit in unsaponified iron ore reverse flotation normal temperature short route collecting agent during metering; Saponification process in hematite reverse flotation normal temperature short route collecting agent, adds NaOH 90 ~ 100 DEG C of insulations 0.5 ~ 1 hour, and the consumption of NaOH is 15 ~ 25% of hematite reverse flotation normal temperature short route collecting agent gross mass.
Hematite reverse flotation normal temperature short route collecting agent in the embodiment of the present invention sodium lignin sulfonate, acidification oil and polyoxyethylene polyoxypropylene block polyether is mixed to be prepared from.
In the embodiment of the present invention, the mass concentration of ore pulp is 30 ~ 35%.
Embodiment 1
The chemical constituent of hematite reverse flotation normal temperature short route collecting agent is by mass percentage: sodium lignin sulfonate 5.0%; Acidification oil 90%; Polyoxyethylene polyoxypropylene block polyether 5%; The structural formula of described polyoxyethylene polyoxypropylene block polyether is:
Wherein a=15, b=8, c=12;
The acid number 150KOHmg/g of acidification oil, saponification number 200KOHmg/g; Iodine number 120I
2g/100g;
Use flow process as shown in Figure 1:
It is to ore deposit that mixed magnetic essence is got at scene by Anshan flotation mill being 47.91% by Iron grade, add water and make ore pulp, control temperature is at 22 DEG C, when reverse flotation is roughly selected, the consumption of adjusting agent NaOH adds 700g by per ton to ore deposit, the consumption of inhibitor starch adds 700g by per ton to ore deposit, the consumption of activator calcium oxide adds 560g by per ton to ore deposit, and the consumption of hematite reverse flotation normal temperature short route collecting agent adds 400g by per ton to ore deposit; Carry out reverse flotation to roughly select, time 3min.Reverse flotation roughly selects rear acquisition rougher concentration and rougher tailings;
Rougher concentration is carried out choosing essence at 22 DEG C, and the consumption of adjusting agent NaOH adds 100g by per ton to ore deposit, and the consumption of hematite reverse flotation normal temperature short route collecting agent adds 160g by per ton to ore deposit, and it is selected to carry out reverse flotation, time 2.5min; Obtain concentrate and cleaner tailings; Cleaner tailings turns back to reverse flotation and roughly selects step, together carries out reverse flotation roughly select with ore pulp;
Rougher tailings still controls at 22 DEG C, and the consumption of NaOH adds 400g to ore deposit scan by per ton, time 3min; Obtain scavenger concentrate and scan mine tailing; Scavenger concentrate turns back to reverse flotation and roughly selects step, together carries out reverse flotation roughly select with ore pulp.Scan, roughly select and selected common formation closed circuit reverse flotation flowsheet; The concentrate yield of closed circuit reverse flotation flowsheet is 63.9%, and the Iron grade of total concentrate is 67.50%, and in concentrate, the rate of recovery of iron is 90.03%.
Embodiment 2
The chemical constituent of hematite reverse flotation normal temperature short route collecting agent is by mass percentage: acidification oil 80%; Polyoxyethylene polyoxypropylene block polyether 20%; A=17, b=12, c=8 in polyoxyethylene polyoxypropylene block polyether structural formula;
The acid number 110KOHmg/g of acidification oil, saponification number 160KOHmg/g; Iodine number 90I
2g/100g;
Method is with embodiment 1, and difference is:
(1) the mixed magnetic concentrate of grade 47.91 is added water make ore pulp, control slurry temperature at 24 DEG C, the consumption of NaOH adds 750g by per ton to ore deposit, the consumption of starch adds 800g by per ton to ore deposit, the consumption of calcium oxide adds 570g by per ton to ore deposit, the consumption of hematite reverse flotation normal temperature short route collecting agent adds 400g by per ton to ore deposit, roughly selects the reverse flotation time at 3.5min;
(2) selected control is carried out at 24 DEG C, and the consumption of adjusting agent NaOH adds 95g by per ton to ore deposit, and the consumption of hematite reverse flotation normal temperature short route collecting agent adds 150g by per ton to ore deposit, the selected time 2.5min of reverse flotation;
(3) rougher tailings is scanned at 24 DEG C, and the consumption of NaOH adds 350g by per ton to ore deposit, and the time of scanning is at 4.5min.Concentrate yield is 61.2%, and the Iron grade of concentrate is 68.95%, and the rate of recovery of iron is 88.08%.
Embodiment 3
The chemical constituent of hematite reverse flotation normal temperature short route collecting agent is by mass percentage: sodium lignin sulfonate 18%; Acidification oil 75%; Polyoxyethylene polyoxypropylene block polyether 7%; A=18, b=10, c=11 in polyoxyethylene polyoxypropylene block polyether structural formula;
The acid number 130KOHmg/g of acidification oil, saponification number 180KOHmg/g; Iodine number 100I
2g/100g;
Method is with embodiment 1, and difference is:
(1) by ore pulp control temperature at 25 DEG C, the consumption of NaOH adds 750g by per ton to ore deposit, the consumption of starch adds 750g by per ton to ore deposit, the consumption of calcium oxide adds 565g by per ton to ore deposit, the consumption of hematite reverse flotation normal temperature short route collecting agent adds 405g by per ton to ore deposit, carry out reverse flotation to roughly select, the time is at 4min;
(2) under 25 DEG C of conditions, the consumption of adjusting agent NaOH adds 100g by per ton to ore deposit, and the consumption of hematite reverse flotation normal temperature short route collecting agent adds 160g by per ton to ore deposit, the selected time 3min of reverse flotation;
(3) rougher tailings controls at 25 DEG C, and the consumption of NaOH adds 350g by per ton to ore deposit, scans, the time at 3min; Concentrate yield is 63.90%, and the Iron grade of total concentrate is 68.34%, and the rate of recovery of iron is 91.15%.
Embodiment 4
The chemical constituent of hematite reverse flotation normal temperature short route collecting agent is by mass percentage: sodium lignin sulfonate 30%; Acidification oil 60%; Polyoxyethylene polyoxypropylene block polyether 10%; A=19, b=10, c=10 in polyoxyethylene polyoxypropylene block polyether structural formula;
The acid number 120KOHmg/g of acidification oil, saponification number 180KOHmg/g; Iodine number 95I
2g/100g;
Method is with embodiment 1, and difference is:
(1) slurry temperature is controlled at 25 DEG C, the consumption of NaOH adds 760g by per ton to ore deposit, the consumption of starch adds 710g by per ton to ore deposit, the consumption of calcium oxide adds 580g by per ton to ore deposit, the consumption of hematite reverse flotation normal temperature short route collecting agent adds 410g by per ton to ore deposit, selects the thick time at 3.0min;
(2) under 25 DEG C of conditions, the consumption of adjusting agent NaOH adds 95g by per ton to ore deposit, and the consumption of hematite reverse flotation normal temperature short route collecting agent adds 150g by per ton to ore deposit, and it is selected to carry out reverse flotation, time 2.5min;
(3) rougher tailings is under 25 DEG C of conditions, and the consumption of NaOH adds 320g by per ton to ore deposit, and scan, the time is at 4min; Concentrate yield 63.5%; The Iron grade of total concentrate is 68.01%, and the rate of recovery of iron is 90.14%.
Embodiment 5
The chemical constituent of hematite reverse flotation normal temperature short route collecting agent is by mass percentage: sodium lignin sulfonate 60%; Acidification oil 35%; Polyoxyethylene polyoxypropylene block polyether 5%; A=16, b=9, c=11 in polyoxyethylene polyoxypropylene block polyether structural formula;
The acid number 140KOHmg/g of acidification oil, saponification number 170KOHmg/g; Iodine number 100I
2g/100g;
Method is with embodiment 1, and difference is:
(1) slurry temperature is at 23 DEG C, the consumption of NaOH adds 800g by per ton to ore deposit, the consumption of starch adds 740g by per ton to ore deposit, the consumption of calcium oxide adds 560g by per ton to ore deposit, the consumption of hematite reverse flotation normal temperature short route collecting agent adds 400g by per ton to ore deposit, carry out reverse flotation to roughly select, the time is at 4.5min;
(2) selected temperature controls at 23 DEG C, and the consumption of adjusting agent NaOH adds 90g by per ton to ore deposit, and the consumption of hematite reverse flotation normal temperature short route collecting agent adds 160g by per ton to ore deposit, the selected time 3.5min of reverse flotation;
(3) rougher tailings carries out at 23 DEG C, and the consumption of NaOH adds 300g by per ton to ore deposit, and the time is at 3.5min; Concentrate yield 64.0%, the Iron grade of concentrate in the rate of recovery of 67.02% iron 89.77%.
Above by detailed description of the invention to invention has been detailed description, but these explanations do not form any restriction to protection scope of the present invention; When not departing from the present invention's spirit and protection domain, those skilled in the art can carry out multiple improvement, equivalencing or modification to the present invention and embodiment thereof, but these all should fall within the scope of protection of the present invention.
Claims (2)
1. a hematite reverse flotation normal temperature short route collecting agent, is characterized in that chemical constituent is by mass percentage: sodium lignin sulfonate 0 ~ 60%; Acidification oil 35 ~ 90%; Polyoxyethylene polyoxypropylene block polyether 5 ~ 20%; The structural formula of described polyoxyethylene polyoxypropylene block polyether is:
Wherein a=15 ~ 19, b=8 ~ 12, c=8 ~ 12.
2. a kind of hematite reverse flotation normal temperature short route collecting agent according to claim 1, is characterized in that the acid number 110 ~ 150KOHmg/g of described acidification oil, saponification number 160 ~ 200KOHmg/g; Iodine number 90 ~ 120I
2g/100g.
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| CN201510745361.3A CN105289853A (en) | 2015-11-05 | 2015-11-05 | Normal-temperature short-process collecting agent for hematite reverse flotation |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115837317A (en) * | 2023-01-03 | 2023-03-24 | 天津天宝翔科技有限公司 | Oxidized ore room-temperature flotation collector and application thereof |
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| CN102076419A (en) * | 2008-07-02 | 2011-05-25 | 佐治亚-太平洋化工品有限公司 | Collectors |
| CN102240605A (en) * | 2010-05-12 | 2011-11-16 | 北京君致清科技有限公司 | Preparation method, application and using process of floating agent prepared from drainage oil |
| CN103447158A (en) * | 2013-09-05 | 2013-12-18 | 鞍钢集团矿业公司 | Anionic collector for normal temperature flotation of hematite and preparation method thereof |
| CN103801462A (en) * | 2012-11-08 | 2014-05-21 | 肖国光 | Iron mine oxidized ore flotation green collector and production process thereof |
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2015
- 2015-11-05 CN CN201510745361.3A patent/CN105289853A/en active Pending
Patent Citations (5)
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| CN102076419A (en) * | 2008-07-02 | 2011-05-25 | 佐治亚-太平洋化工品有限公司 | Collectors |
| CN102240605A (en) * | 2010-05-12 | 2011-11-16 | 北京君致清科技有限公司 | Preparation method, application and using process of floating agent prepared from drainage oil |
| CN101912822A (en) * | 2010-08-23 | 2010-12-15 | 长沙矿冶研究院 | Negative/positive ion collector for iron ore flotation and preparation method thereof |
| CN103801462A (en) * | 2012-11-08 | 2014-05-21 | 肖国光 | Iron mine oxidized ore flotation green collector and production process thereof |
| CN103447158A (en) * | 2013-09-05 | 2013-12-18 | 鞍钢集团矿业公司 | Anionic collector for normal temperature flotation of hematite and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115837317A (en) * | 2023-01-03 | 2023-03-24 | 天津天宝翔科技有限公司 | Oxidized ore room-temperature flotation collector and application thereof |
| CN115837317B (en) * | 2023-01-03 | 2023-04-28 | 天津天宝翔科技有限公司 | Oxidized ore room temperature flotation collector and application thereof |
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| CB02 | Change of applicant information |
Address after: 114001 Anshan District, Liaoning, No. 219 Road, No. 39, Tiedong Applicant after: Anshan Iron and Steel Group Mining Co., Ltd. Address before: 114001 Anshan District, Liaoning, No. 219 Road, No. 39, Tiedong Applicant before: Anshan Iron & Steel Group Mining Co., Ltd. |
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Application publication date: 20160203 |
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