CN1052851C - Composite rare-earth fresh cut flower preserving agent - Google Patents

Composite rare-earth fresh cut flower preserving agent Download PDF

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Publication number
CN1052851C
CN1052851C CN96103247A CN96103247A CN1052851C CN 1052851 C CN1052851 C CN 1052851C CN 96103247 A CN96103247 A CN 96103247A CN 96103247 A CN96103247 A CN 96103247A CN 1052851 C CN1052851 C CN 1052851C
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rare earth
preserving agent
earth
flowers
fresh cut
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CN1138943A (en
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徐新宇
张玉梅
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Abstract

The present invention relates to a compound rare earth freshness preserving agent for fresh cut flowers, which is scientifically prepared from a rare earth compound, etc. in the three preparation forms of powder (or granule and tablet), paste and thick liquid and has the characteristics of high possibility of dissolving in water, no color, transparence and no stink. The pH valve of the freshness preserving agent is from 5 to 6.5. The freshness preserving agent of the present invention has the advantages of no denaturation during long-term storage, no damage to flowers, people and livestock, no environmental pollution, simple and convenient preparation process and low cost. The freshness preserving agent is not in need of replacement in usage periods but in need of appropriate replenishment, and is suitable for various herbaceous flowers and shrubby flowers to cause the flowering rate of flower buds to be averagely improved above 95%; compared with general freshness preserving agents, after the freshness preserving agent is used, the flowering phase of cutting flowers arranged in vases is averagely prolonged by 1 to 3 days with the advantages of petal increment, vivid flower color and full fragrance.

Description

Composite rare-earth fresh cut flower preserving agent
The present invention is a kind of composite rare-earth fresh cut flower preserving agent (code name for " 3HR "), is used for the fresh cut-flowers of draft and the multiple flowers of shrub class, improves the open rate of fresh cut-flowers bud, prolongs bottle and insert the life-span and improve the fresh cut-flowers proterties of blooming, and makes it keep bright-coloured for a long time.Belong to the antistaling agent for cut-flower class.
The fresh cut-flowers branch is in case after shearing the disengaging parent, a series of physiological disorders different with parent can occur.Produce a large amount of polyphenyl class materials and cause a large amount of breedings of microorganism as the fresh cut-flowers otch, hinder the normal transport of moisture and nutriment; Occur " physiology transition " that respiration raises rapidly after fresh cut-flowers exsomatizes, cause a large amount of formation and the release of endogenous ethylene, accelerated to cut flower withering; After exsomatizing, fresh cut-flowers broken off the supply of moisture, nutrient and hormone substance and very fast forfeiture freshness etc. from parent.For overcoming, a large amount of research work have all been done both at home and abroad such as above-mentioned obstacle.Be many wherein to select the protectiveness chemical agent to make tailored version antistaling agent aspect.As " RVB ", " DVB ", " LVB " and Ha Erwei solution, U.S.'s solution, Israel's solution and the Zi Aisilin solution of abroad using etc. for the producer and sale fresh cut-flowers person; (Wu Jingxu: " popular flowers " such as the Ottawa solution of using for the consumer, Cornell solution, gentle this solution of agate, plant acid solution, alum class solution and " white is prolonged the life spirit ", " livingly ", " Fu Laixiu ", " wheat suckle Dare ", " Ao Yaxisi ", " Hua Zhijing ", " Li Bide " and " Xi Aolai " solution, 1987,16); Beijing research institute of scientific-technical information: " world's cutflower preservation new technology is newly filled a prescription ", 1988; Medium during bear: " flowers and trees bonsai ", 1990, (3); " cutflower preservation " thematic digest both at home and abroad).Domestic except that quoting external antistaling agent commonly used, also made number of research projects, as cut rose flower antistaling agent (Gao Yong etc. " gardening journal ", 1990,17 (1); The king is clear etc.: " gardening journal ", 1992,19 (4); Gao Yong: " Scientia Agricultura Sinica ", 1990,23 (6)), tree peony, peony cut-flower antistaling agent (just medium " the Henan agricultural science " 1986 of poplar, (7); " gardening journal " 1987,14 (1)) and wax plum cutflower preservation (Yang Kangmin etc. " gardens ", 1991, (1)) Xu Xudan etc.:.Both at home and abroad the common feature of the antistaling agent of development is: all with the sulphate or the citrate of oxine; Silver salt and compound, complex compound thereof are to divide main the composition, are aided with formations such as carbohydrate, aluminum contained compound, hormone and preservative.Though fresh-keeping effect is in various degree arranged, remains in following problem and defective.(1) oxine and its esters all have tangible stench and certain toxicity, and this gives production and uses antistaling agent to make troubles; (2) silver salt and compound, complex compound thereof are met light or can be produced the silver sulfide black precipitate after seasoning a period of time, especially sedimentary generation is fast especially under summer or the hot conditions, cause fresh-keeping effect to weaken rapidly or instability, and contain silver material and cost an arm and a leg, consumption is limited, brings difficulty for production and use; (3) oxine salt and silver salt antiseptic effect in antistaling agent is unsatisfactory, and over-borrowing helps bactericide again.But bactericide also has harmful effect to the dosage of killing or restrain microbial reproduction to fresh cut-flowers itself, and some is easily offset the preservation of antistaling agent; Have obvious facilitation when (4) application of somatotropin in antistaling agent is suitable, but consumption control is strict, otherwise easily causes negative interaction, and price is more expensive, easily loses activity under the water-soluble state.
The objective of the invention is for fear of above-mentioned weak point, developed a kind of " composite rare-earth fresh cut flower preserving agent ".Used rare earth and derivative thereof (hereinafter to be referred as RE composite) have tangible preservation to multiple fresh cut-flowers.Rationally the preparation fresh-keeping effect is even more ideal with aluminium salt, salicylic acid and carbohydrate etc.And the rare earth price only is 1%~2% of silver salt and an oxine compounds price; Proved that now rare earth belongs to basic innocuous substance, the aceptable daily intake (ADI) of oral administration is 0.1~1.0mgkg -1Body weight (in rare earth oxide).This value is taken in the amount of rare earth from daily food considerably beyond people.In composite rare-earth fresh cut flower preserving agent of the present invention, the consumption of rare earth is (100~300ppmRE seldom 2O 3), using rare earth is safe (Xu Xinyu, Zhang Yumei: " agrology progress ", 1990,18 (6) in antistaling agent; " agricultural environment and development ", 1995,12 (3); Guo Baisheng etc.: " rare earth in the agricultural ", Chinese agriculture science and technology publishing house, 1990).Though rare earth China be widely used in agricultural herd with aquaculture in, but do not see as yet so far about with rare earth as the report of fresh cut-flower antistaling agent principal component (Chinese rare earth association, Chinese rare-earth journal, national rare earth application center: " and national rare earth agricultural herd and aquaculture in application study paper " summary " collection, 1993).
The object of the present invention is achieved like this:
Composite rare-earth fresh cut flower preserving agent of the present invention composed as follows (in contained weight in the 1 premium on currency solution, g):
The citric acid rare earth is (with RE 2O 3Meter) 0.10~0.50
Potassium alum 0.02~0.50
Salicylic acid 0.20~0.07
Cobalt chloride 0.05~0.10
Sodium dichloro cyanurate 0.0~0.010
Granulated sugar 10~40
pH 4.5~6.5
Purpose of the present invention can also further realize by the following method:
The best composition of composite rare-earth fresh cut flower preserving agent for (in contained weight in the 1 premium on currency solution, g):
The citric acid rare earth is (with RE 2O 3Meter) 0.20
Potassium alum 0.30
Salicylic acid 0.03
Cobalt chloride 0.07
Sodium dichloro cyanurate 0.007
Granulated sugar 20
pH 5~6.5
Citric acid rare earth in the composite rare-earth fresh cut flower preserving agent component of the present invention can be used the double salt (RE of ascorbic acid rare earth or ethylenediamine tetra-acetic acid rare earth or rare earth sulfate 2(SO 4) 3(NH 4) SO 4RE 2(SO 4) 3K 2SO 4) replace.Also can use nitric acid rare earth, rare earth chloride, sulfuric acid rare earth, humic acid rare earth and amino-acid rare earth etc.Each RE composite can be used separately, also can compound use more than a kind.But used rare earth type and compound proportioning must guarantee that the content in this antistaling agent is 0.10~0.50g/ premium on currency solution during compound use.Rare earth has the propagation of inhibition microorganism and the generation of endogenous ethylene in antistaling agent; Stimulate the reproductive physiology activity of fresh cut-flowers tissue; Promote increasing of endogenous growth hormone such as IAA, GA and Cytokinins etc.; Strengthen the control ability that plant cell membrane exosmoses to electrolyte and delay the aging of fresh cut-flowers, and strengthen absorbing moisture, sugar, phosphorus potassium nutrition material.Thereby the bottle that has significantly prolonged fresh cut-flowers is inserted life-span and the open rate of bud.
The present invention forms potassium alum used in the branch and can use aluminum sulfate, aluminum nitrate, ammonia-alum and aluminium polychloride to replace.Having the mediation conduit keeps water balance, keeps pattern gorgeous and prolong effect such as cutting flower life.
It is a kind of well " the short flower factor " that the present invention forms salicylic acid in the branch, can make plant guard cell closure, reduces moisture transpiration and delay that fresh cut-flowers is withered withers.Certain antisepsis is also arranged.This is formed and divides available acetylsalicylic acid replacement.
The present invention forms cobalt chloride in the branch to have ethene suppressing and discharges, keeps the petal turgescence, keeps effect such as pattern.Available cobalt nitrate replaces.
The present invention forms the granulated sugar that uses in the branch energy substance as the fresh cut-flowers live body, stores in order to augment in the cut-flower body sugar, plays the enhancing assimilation, suppresses effects such as the generation of metabolism nuisance and restriction transpiration rate.Available continuous sugar, glucose replace (granulated sugar refers to that beet sugar, continuous sugar refer to cane suger).
Sodium dichloro cyanurate is that the present invention forms auxiliary element in the branch, in order to kill or to suppress microbial reproduction, also can.
Composite rare-earth fresh cut flower preserving agent of the present invention is simple for use, and the product that whenever are bundled into can use after with 1 intensification water or cold water dissolved dilution.Bottle need not changed fresh-keeping liquid during inserting, and the liquid measure of only in good time replenishing consume gets final product.Fresh cut-flowers before bottle is inserted soaks with the warm water of 0.25 ‰~0.5 ‰ liquor potassic permanganate or 37 °~40 ° that to cut 15 minutes its effects of stem better.
Obtain the tangible flowers of fresh-keeping effect with the present invention and can list freesia, Chinese rose, rose, lily, bull China pink, carnation, sword lily, chrysanthemum, frost flower, Chinese herbaceous peony, Hipeastrum vittalum (L Her.) Herb.-Amaryllisvittata Ait, blackberry lily etc.Also can effectively be used for pot marigold, straw flower, flameray gerbera, tulip, flowering plum etc.And the various kinds to above-mentioned flowers all can be effective.Can make the open rate of bud on average be increased to more than 95%; The slotting life-span of bottle on average prolongs 3~10 days than antistaling agent commonly used; And petal and corolla diameter increase, and pattern is gorgeous, aromatic flavour.
Composite rare-earth fresh cut flower preserving agent of the present invention is solid, powdery (or grain slice), paste and three kinds of formulations of dope shape.The water white transparency shape that is soluble in water, odorless can seasoning consistency for a long time, to flowers and person poultry harmless, uses free from environmental pollution for a long time.Be applicable to the fresh cut-flowers that family, restaurant, hotel, meeting room, office etc. place, also be applicable to the fresh cut-flowers producer and seller.
The manufacturing process flow of composite rare-earth fresh cut flower preserving agent of the present invention is as follows:
Each component proportioning is in accordance with regulations measured respectively, is pulverized, and is delivered in mixing (or knead, the stir) equipment through transfer equipment and puddles, again through dispensing apparatus (1) or (2), (3) packing.As the need granulation, can be with mixed powder through extruding granulation equipment granulation or sheet, packing then.
Figure C9610324700081
Embodiment:
Illustrate below, but the present invention is not limited to following example.
Embodiment 1: paste type composite rare-earth fresh cut flower preserving agent preparation (to produce 1 ton of butt finished product consumption).
Take by weighing commercially available citric acid rare earth (RE 2O 3~20%) 48kg, potassium alum (KAl (SO 4) 212H 2O 〉=90%) 14.6kg, salicylic acid (C 7H 6O 3〉=99%) 1.4kg, cobalt chloride (Co 〉=24%) 3.4kg, sodium dichloro cyanurate (containing effective Cl 〉=60%) 0.4kg, granulated sugar 961.3kg.Pulverize respectively, add running water 110kg while kneading.Wait to knead to puddle and made full and uniform back packing in 3~5 minutes.But 50,000 bags of packing per ton.According in January, 1996 raw material buy valency and adjust, about 15607.28 yuan of the factory cost of product per ton, about 18000 yuan/ton of income from sales, 2341.1 yuan of the taxes of making a profit per ton, economic benefit obviously is better than commercially available similar products at home and abroad.As under the basic identical condition of packing specification, every bag of unit price of product of the present invention is 0.4~0.5 yuan, only is 1/10~1/2 of commercial like product price.
Embodiment 2: the composite rare-earth fresh cut flower preserving agent using method.
Get the container that powder product one bag of the present invention places cleaning, the cold water that adds 1kg makes abundant dissolving stand-by.The liquor potassic permanganate of the rose of buying back and each a branch of usefulness 0.05% of freesia soaked cut stem, insert the bottle that has injected above-mentioned stand-by liquid then to the long 2/3 place preliminary treatment of stem 15 minutes.During inserting, bottle often adds the fresh-keeping liquid of loss.The result shows, uses the present invention and pretreated rose, and the open rate of bud is 100%, and bottle is inserted 14 days life-spans, and indivedual flowers reach 15 days; The inflorescence bottle that the open rate of freesia bud is 97%, 7~10 flower buds is inserted 13 days life-spans, and 10 above inflorescence bottles of flower bud were inserted the life-span more than 17 days.And rosebud long 2.5~2.7cm, cut-flower stem length 〉=20cm's, the opening of the equal energy 100% of freesia bud length 〉=0.7cm, cut-flower stem length 〉=10cm.
Embodiment 3: the composite rare-earth fresh cut flower preserving agent result of use.
The fresh cut-flowers kind is freesia, white Chinese rose, orange Chinese rose, pink colour Chinese rose, red Chinese rose, purple rugose rose (Rosa rugosa var, royal lily, sword lily, frost flower, Beijing little morning of chrysanthemum, carnation, bull China pink, Chinese herbaceous peony and blackberry lily etc.Preprocess method is with embodiment 2.Do contrast (being called for short CK) with cold water.Be the effect of contrast rare earth, other establishes with composite rare-earth fresh cut flower preserving agent (being called for short 3HR) composition and divides identical (being called for short 3H) that does not only add rare earth to handle.Room temperature was 25 °~28 ° when bottle was inserted, relative moisture 60~70%, the about 1000Lux of illumination.During inserting, bottle in time adds the liquid measure of loss.The result shows, composite rare-earth fresh cut flower preserving agent fresh-keeping effect of the present invention and cold water contrast, and the open rate of bud on average improves 31%, and the slotting life-span of bottle on average prolongs 5.7 days, and the corolla diameter on average increases 1.6cm.With etc. composition divide the 3H ratio do not contain rare earth, the open rate of average bud improves 5%, bottle is inserted a life-span and is on average prolonged 2 days, the corolla average diameter increases 0.1cm.
The slotting life-span of the average bottle of the average open rate of bud (%) (my god) average corolla diameter (cm) cut-flower kind
CK 3H 3HR CK 3H 3HR CK 3H 3HR 85 94 97 7.5 12.9 13.3 3.2 4.9 4.1 50 100 100 4.0 5.5 6.5 6.8 8.0 8.4 67 100 100 4.0 6.0 7.0 8.4 10.2 10.4 33 100 100 6.5 10.0 11.0 5.5 7.0 7.5 75 100 100 6.3 11.0 12.7 5.0 6.7 7.3 64 100 100 5.2 12.0 15.2 6.8 8.8 7.9 63 100 100 7.0 9.0 11.3 10.0 11.2 12.4 83 83 92 9.0 12.0 14.5 5.7 6.8 7.4 87 92 93 7.0 10.5 12.5 3.2 3.4 3.573 76 97 16.8 21.5 26.0 4.6 5.1 5.8 100 100 100 9.0 13.0 16.0 4.6 5.0 4.9 28 93 95 7.8 16.8 18.8 3.3 5.8 5.8 50 100 100 3.0 6.0 6.0 3.4 16.0 15.0 80 95 96 4.0 6.0 9.0 9.7 10.2 11.2 66 92 97 8.4 12.2 14.2 5.2 6.7 6.8
Embodiment 4: composite rare-earth fresh cut flower preserving agent and the antistaling agent contrast that contains oxine.
Adopt fresh cut-flowers such as purple rugose rose (Rosa rugosa var, white Chinese rose, orange Chinese rose and royal lily, in order to compare with oxine citrate (being called for short 8QH) and oxine borate (being called for short 8QB).Compare with clear water, with the fresh-keeping effect of checking 3HR.Contrast condition temp. and humidity and preliminary treatment are equal to embodiment 3.The result shows that the composite rare-earth fresh cut flower preserving agent fresh-keeping effect obviously is better than the citrate and the boratory antistaling agent of oxine.Insert life-span prolongation 2.6 days or 3.3 days with the ratio 8QH of 3HR of the present invention and the bottle of 8QB, the open rate of bud improves 6% and 14% respectively, and the corolla average diameter increases 2.0cm and 1.5cm respectively.
The average uncork of bud insert the life-span (my god) the average flowers kind of corolla handles
Put the white Chinese rose CK 50 5.0 4.5 7.1 of rate (%) (maximum) (mean value) diameter (cm)
3HR 100 8.0 6.5 8.9
8QH 100 6.0 5.0 6.2
8QB 100 6.0 5.0 6.1 orange Chinese rose CK 67 5.0 4.5 8.4
3HR 100 9.0 7.0 10.3
8QH 100 7.0 6.0 9.3
8QB 100 7.0 4.5 9.0 purple rugose rose (Rosa rugosa var CK 43 7.0 5.0 6.8
3HR 100 15.0 12.5 7.9
8QH 100 8.0 6.8 6.7
8QB 43 8.0 5.7 7.5 royal lily CK 57 8.0 7.0 10.0
3HR 100 16.0 11.3 12.4
8QH 75 11.0 9.0 9.2
8QB 100 10.0 8.7 11.3 embodiment 5: composite rare-earth fresh cut flower preserving agent and the contrast of argentiferous antistaling agent.
With 3HR of the present invention and argentiferous antistaling agent 5H (0.1mol/AgNO 30.2ml.L -1), 4H (20g sucrose L -1+ 0.1mol/AgNO 30.2ml.L -1) and 4HR (4H+300ppmRE 2O 3) its fresh-keeping effect of comparison.With material is red freesia.Other condition is with embodiment 3.The result shows, adopt the freesia of 3HR antistaling agent of the present invention, the on average open rate of bud is 100%, the slotting life-span of bottle can extend to 17 days, average 15.8 days, corolla average diameter 4.7cm obviously is better than clear water contrast and 5H, 4H argentiferous antistaling agent (bottle is inserted 10 days left and right sides flowers and substantially all withered, and liquid for immersing in bottle becomes turbid).The 4H of argentiferous is added rare earth (300ppmRE 2O 3) be that flowering is normal behind the 4HR, liquid for immersing in bottle does not have muddy phenomenon, but bottle is inserted the life-span than 3HR shortening of the present invention 2~3 days, and product cost obviously increases.
The average uncork of bud insert the life-span (my god) the corolla average treatment
Put rate (%) (maximum) (mean value) diameter (cm) CK 85 9.0 7.5 3.2 3HR 100 17.0 15.8 4.7 4H 96 13.0 12.5 5.0 4HR 100 15.0 13.5 4.0 5H 89 15.0 12.5 4.3
Embodiment 6: composite rare-earth fresh cut flower preserving agent and the contrast of commercially available Chrysal antistaling agent.
With red Chinese rose, Beijing little morning of chrysanthemum and frost flower is the fresh cut-flowers material, contrasts its fresh-keeping effect with 3HR of the present invention and commercially available Chrysal (abbreviating U.S.A as) antistaling agent.Other condition is with embodiment 3.The result shows, obviously is better than commercially available Chrysal antistaling agent (U.S.A) with red Chinese rose, Beijing little morning of the chrysanthemum and the frost flower fresh cut-flowers fresh-keeping effect of 3HR antistaling agent of the present invention.Three kinds of fresh cut-flowers are 97% with the on average open rate of the bud of 3HR of the present invention, than the average raising 16% with the U.S.A antistaling agent; Bottle is inserted the life-span than the average prolongation of using the U.S.A antistaling agent 2.9 days; The corolla average diameter is also than the average increase 0.4cm with the U.S.A antistaling agent.
The average uncork of bud insert the life-span (my god) the average cut-flower kind of corolla handles
Put the red Chinese rose CK 60 8.0 6.3 5.0 of rate (%) (maximum) (mean value) diameter (cm)
3HR 100 15.0 13.0 7.3
U.S.A 67 10.0 8.0 6.8 Beijing little morning of chrysanthemum CK 73 22.0 16.8 4.6
3HR 97 30.0 26.0 5.8
U.S.A 88 25.0 24.8 5.4 frost flower CK 87 8.0 7.0 3.2
3HR 93 13.0 12.5 3.5
U.S.A 87 10.0 10.0 3.1

Claims (2)

1. composite rare-earth fresh cut flower preserving agent is characterized in that: composed as follows in the composite rare-earth fresh cut flower preserving agent of contained weight in grams in the premium on currency solution:
The citric acid rare earth is with RE 2O 3Meter 0.10-0.50
Potassium alum 0.20-0.50
Salicylic acid 0.02-0.07
Cobalt chloride 0.05-0.10
Sodium dichloro cyanurate 0.00-0.010
Granulated sugar 10-40
pH 4.5-6.5
Citric acid rare earth in the component of the present invention can be used ascorbic acid rare earth or ethylenediamine tetra-acetic acid rare earth or rare earth sulfate double salt [RE 2(SO 4) 3. (NH 4) 2SO 4RE 2(SO 4) 3.K 2SO 4] replace, also can use nitric acid rare earth, rare earth chloride, sulfuric acid rare earth, humic acid rare earth and amino-acid rare earth etc.;
The potassium alum that uses in the component can use aluminum sulfate, aluminum nitrate or aluminium polychloride to replace;
Salicylic acid in the component can replace with acetylsalicylic acid;
Cobalt chloride in the component can replace with cobalt nitrate.
2. according to the described a kind of composite rare-earth fresh cut flower preserving agent of claim 1, it is characterized in that: best composed as follows in the composite rare-earth fresh cut flower preserving agent of contained weight in grams in the premium on currency solution:
The citric acid rare earth is with RE 2O 3Meter 0.20
Potassium alum 0.30
Salicylic acid 0.03
Cobalt chloride 0.07
Sodium dichloro cyanurate 0.007
Granulated sugar 20
pH 5-6.5
CN96103247A 1996-03-13 1996-03-13 Composite rare-earth fresh cut flower preserving agent Expired - Fee Related CN1052851C (en)

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Publication number Priority date Publication date Assignee Title
CN1324969C (en) * 2004-07-28 2007-07-11 中国农业大学 Fruit freshness preserving suspension emulsion and its preparing method
CN102106343A (en) * 2010-11-29 2011-06-29 天津滨海国际花卉科技园区股份有限公司 Gladiolus cut flower preservative and preparation and using methods thereof
CN112352779B (en) * 2020-10-27 2022-06-24 北京林业大学 Vase solution for plum blossom cut flowers and method for improving ornamental value of plum blossom cut flowers
CN113367125A (en) * 2021-05-18 2021-09-10 中农实创(北京)环境工程技术有限公司 Fresh-keeping nutrient solution for fresh cut flowers of roses

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03130201A (en) * 1989-07-28 1991-06-04 Mitsubishi Kasei Corp Macrobiotic agent for cut flower
JPH0570270A (en) * 1991-09-06 1993-03-23 Seiwa Kasei Kk Fertilizer for growing cultured plant and growing method
JPH0859402A (en) * 1994-08-26 1996-03-05 Masatoshi Nakano Plant nutrient agent and method of activating cut flowers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03130201A (en) * 1989-07-28 1991-06-04 Mitsubishi Kasei Corp Macrobiotic agent for cut flower
JPH0570270A (en) * 1991-09-06 1993-03-23 Seiwa Kasei Kk Fertilizer for growing cultured plant and growing method
JPH0859402A (en) * 1994-08-26 1996-03-05 Masatoshi Nakano Plant nutrient agent and method of activating cut flowers

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* Cited by examiner, † Cited by third party
Title
园艺学报第16卷第2期 1989.5.1 高勇,吴绍锦《切花保鲜剂研究综合》 *

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