CN105276838A - Refraction-based solar light homogenizing pipe type reactor or drier - Google Patents

Refraction-based solar light homogenizing pipe type reactor or drier Download PDF

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Publication number
CN105276838A
CN105276838A CN201510697002.5A CN201510697002A CN105276838A CN 105276838 A CN105276838 A CN 105276838A CN 201510697002 A CN201510697002 A CN 201510697002A CN 105276838 A CN105276838 A CN 105276838A
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light
drier
cylindrical transparent
transparent hollow
solar energy
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CN201510697002.5A
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CN105276838B (en
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范亮亮
赵亮
赵宏
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Xian Jiaotong University
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Xian Jiaotong University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • Y02E10/44Heat exchange systems

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Abstract

A refraction-based solar light homogenizing pipe type reactor or drier is formed by connecting a plurality of cylindrical transparent hollow light refractive media with a certain refractive index and a certain thickness in a tangent manner. The outer surface of the cylindrical transparent hollow light refractive medium on the outmost layer, the inner surface of the cylindrical transparent hollow light refractive medium on the innermost layer and the position between every two adjacent cylindrical transparent hollow light refractive media are coated with antireflection films so as to reduce light reflection losses. The interior of the antireflection film on the inner surface of the cylindrical transparent hollow light refractive medium on the innermost layer serves as an inner wall, and an inner reacting or drying cavity is formed in the inner wall. The relative refractive indexes of the cylindrical transparent hollow light refractive media are sequentially increased from outside to inside. When light spreads in all hollow transparent cylinders different in refractive index, the light deflects constantly due to the refraction action, the circumferential light receiving angle is increased remarkably, and distribution of the light in the circumferential direction of the reactor or drier is more even.

Description

A kind of equal light pipe type reactor of solar energy based on refraction or drier
Technical field
The present invention relates to a kind of solar energy tubular reactor or drier, be specifically related to a kind of based on refraction principle, there is the more uniform solar energy tubular reactor of larger circumferential light receiver angle, circumferential photic-energy transfer or drier.
Background technology
Along with the increase of energy demand in world wide, conventional fossil fuel reduces gradually, and problem of environmental pollution becomes and becomes increasingly conspicuous, and utilizes regenerative resource to become the important means solving current energy source demand and environmental pollution.Solar energy have have a very wide distribution, the advantage such as reserves are large, cleanliness without any pollution, be a kind of typical regenerative resource.Greatly develop solar energy the sustainable development realizing human society is had great significance.
Solar energy photocatalytic hydrogen manufacturing utilizes solar energy, realizes Conversion of Energy, solves a kind of effective form of energy crisis.For compound parabolic photocatalysis hydrogen production reactor (CPC), solar irradiation is mapped on tubular catalytic reactor, under the effect at sunshine of the reactant liquor of catalytic reactor internal flow, catalytic reaction occurs, produce hydrogen, realize the conversion of solar energy to Hydrogen Energy.The catalytic reaction of distribution of solar energy on catalytic reactor on inside reactor has important impact.At present, catalytic reactor is made by the transparent material such as very thin glass usually, and larger energy loss is caused because of light reflection in surface.In addition, also having light circumference receiving angle, limited (sensitive surface is only just to light portion, circumference acceptance angle≤180 °), the shortcoming of distribution of light concentration of local, backlight side is owing to being subject to illumination, efficient photocatalysis hydrogen production reaction cannot be carried out, reduce the solar energy utilization ratio in photocatalysis hydrogen production process.
Solar dryer is the another kind of effective means utilizing solar energy.Specifically, in solar dryer, solar energy impinges is to material surface, import heat into internal batch, make moisture diffusion contained in material to material surface, and then be diffused in air, the moisture simultaneously in air is constantly taken away, thus contained humidity in material is gradually reduced, finally become drying regime.Solar dryer can make full use of solar radiant energy, effectively improves baking temperature, shortens drying time, improves the credit rating of product.Solar dryer mainly comprises greenhouse type solar dryer, heat-collector type solar drier, green house-heat-collector type solar drier, concentrating solar drier and monoblock type solar dryer.For greenhouse type solar dryer, sunlight is radiated at the one side of material to be dried through glass cover-plate, material can be made to be subject to the rapid draing of illumination side, and backlight side is owing to cannot be subject to illumination, rate of drying is relatively slow, material concentration of local is heated, and the quality to product after drying, profile are caused adverse effect.In addition, solar irradiation is mapped to dryer surface and can causes larger energy loss because of reflex.
In sum, current solar energy reactor or drier Problems existing mainly comprise:
1), when solar irradiation is mapped to reactor or dryer surface, light reflection effect is comparatively strong, causes larger energy loss;
2) receiving angle is limited (is generally just to light portion for reactor or drier light circumference, circumference acceptance angle≤180 °), Energy distribution concentration of local, uneven, the synchronous evenly occasion that distribution of light uniformity is had higher requirements such as dry of solar energy photocatalytic hydrogen manufacturing, material cannot be applied to.
Summary of the invention
In order to overcome above-mentioned prior art Problems existing, the object of this invention is to provide a kind of equal light pipe type reactor of solar energy based on refraction or drier, solar energy can be utilized to realize efficient, uniform light-catalyzed reaction or dry materials, can be used for the solar energy optical-thermal applications such as photocatalysis hydrogen production, solar energy drying, solar energy sewage disposal.There is the advantages such as structure is simple, the circumferential acceptance angle of light is large, the circumferential distribution of light is comparatively even, have a good application prospect.
For achieving the above object, the technical solution adopted in the present invention is:
A kind of equal light pipe type reactor of solar energy based on refraction or drier, by multiplely having certain refractive index, certain thickness cylindrical transparent hollow anaclasis medium mutually suits and forms, anti-reflection film is covered with, in order to reduce light reflection loss between the cylindrical transparent hollow anaclasis internal dielectric surfaces of outermost cylindrical transparent hollow anaclasis media inside surface, innermost layer and adjacent cylindrical transparent hollow anaclasis medium; The anti-reflection film inside of the cylindrical transparent hollow anaclasis internal dielectric surfaces of innermost layer is inner wall, is internal-response or dry cavity in inner wall; Ecto-entad, the relative index of refraction of cylindrical transparent hollow anaclasis medium and air increases successively.
The material of described anti-reflection film is magnesium fluoride, titanium oxide, vulcanized lead or lead selenide.
Describedly multiplely have certain refractive index, certain thickness cylindrical transparent hollow anaclasis medium is two, described solar energy equal light pipe type reactor or drier are followed successively by outer anti-reflection film 1, ground floor cylindrical transparent hollow anaclasis medium 2, intermediate layer anti-reflection film 3, second layer cylindrical transparent hollow anaclasis medium 4, internal layer anti-reflection film 5, inner wall 6 and internal-response or dry cavity 7 from outside to inside; The thickness of each layer anti-reflection film determines according to the anti-reflection light of target and its thickness is minimum, ignores the impact of its thickness on light transmition.
The material of described ground floor cylindrical transparent hollow anaclasis medium 2 is simple glass, and its refractive index is 1.5, and external diameter is 4cm, and internal diameter is 2.66cm, and thickness is 0.67cm; The material of described second layer cylindrical transparent hollow anaclasis medium 4 is extradense flint, and its refractive index is 1.89, and external diameter is 2.66cm, and internal diameter is 2.12cm, and thickness is 0.27cm; The material of described inner wall 6 is simple glass, and its refractive index is 1.5, and external diameter is 2.12cm, and internal diameter is 1.92cm, and thickness is 0.1cm.
The length of the equal light pipe type reactor of described solar energy or drier is 2m.
Compare with traditional solar energy pipe reaction or drier, advantage of the present invention is as follows:
1) all anti-reflection film is designed with between solar energy of the present invention equal light pipe type reactor or drier surfaces externally and internally, each layer anaclasis medium, can effectively reduce the energy loss caused due to light reflection effect, the photo-thermal efficiency of the equal light pipe type reactor of solar energy or drier is obtained improve, be convenient to the rapid draing that the reaction of efficient photocatalysis hydrogen production and material occur.
2) application of each layer different refractivity light transmission medium, constantly there is refraction when light is propagated in refractive medium and deflect, a part of light is finally made to enter the incoming position of the equal light pipe type reactor of solar energy or drier internal cavity from just becoming backlight side to light side, thus considerably increase the light receiver angle (being increased to circumference 351.4 ° by circumference 180 °) of the equal light pipe type reactor of solar energy or drier circumference, light is made to distribute more even at solar energy equal light pipe type reactor or drier circumference, photocatalysis hydrogen production can be used to, the occasion that the synchronous evenly drying of material etc. has higher requirements to distribution of light uniformity.
3) the certain thickness anaclasis medium of each layer has accumulation of heat effect, effectively can heat the reactant liquor or air flowing through cavity, forms convection current, thus provides favourable temperature and flox condition for light-catalyzed reaction or dry materials.
Accompanying drawing explanation
Fig. 1 is that light is at solar energy tubular reactor of the present invention or drier internal communication route schematic diagram.
Fig. 2 uses the distribution of light location drawing on the inner wall of the present invention of software calculating acquisition.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
As shown in Figure 1, the present embodiment, based on the equal light pipe type reactor of solar energy reflected or drier, is made up of outer anti-reflection film 1, ground floor cylindrical transparent hollow anaclasis medium 2, intermediate layer anti-reflection film 3, second layer cylindrical transparent hollow anaclasis medium 4, internal layer anti-reflection film 5, inner wall 6 and internal-response or dry cavity 7 from outside to inside.The thickness of each layer anti-reflection film determines according to the anti-reflection light of target and its thickness is minimum, ignores the impact of its thickness on light transmition.
As the preferred embodiment of the present invention, the material of described ground floor cylindrical transparent hollow anaclasis medium 2 is simple glass, and its refractive index is 1.5, and external diameter is 4cm, and internal diameter is 2.66cm, and thickness is 0.67cm, circular ring structure; The material of described second layer cylindrical transparent hollow anaclasis medium 4 is extradense flint, and its refractive index is 1.89, and external diameter is 2.66cm, and internal diameter is 2.12cm, and thickness is 0.27cm, circular ring structure; The material of described inner wall 6 is simple glass, and its refractive index is 1.5, and external diameter is 2.12cm, and internal diameter is 1.92cm, and thickness is 0.1cm.The diameter of internal-response or dry cavity 7 is 1.92cm, for as light-catalyzed reaction and dry materials space.
As the preferred embodiment of the present invention, the length of the equal light pipe type reactor of described solar energy or drier is 2m.And redesign adjustment can be carried out according to the actual requirements.
The present embodiment based on the solar energy equal light pipe type reactor of refraction or the operation principle of drier is: when light is irradiated to outer anti-reflection film 1, hyporeflexia, transmitted light strengthens, light reflects after entering ground floor cylindrical transparent hollow anaclasis medium 2, light path deflects, when being irradiated to intermediate layer anti-reflection film 3, reflection ray weakens, most light enters second layer cylindrical transparent hollow anaclasis medium 4, light deflects again, eventually pass through internal layer anti-reflection film 5 and inner wall 6, enter internal-response or dry cavity 7, realize light-catalyzed reaction and dry materials.The energy loss that anti-reflection film effectively can reduce light reflection and cause, improves the photo-thermal efficiency of the equal light pipe type reactor of solar energy or drier; The two-layer application with different refractivity anaclasis medium, light is constantly deflected in refractive medium, the light receiver angle (being increased to circumference 351.4 ° by circumference 180 °) of the equal light pipe type reactor of solar energy or drier circumference can be enlarged markedly, make light distribute more even at solar energy equal light pipe type reactor or drier circumference; Two-layer certain thickness anaclasis medium has accumulation of heat effect, effectively can heat the reactant liquor or air flowing through cavity, forms convection current, for solar energy photocatalytic reaction or dry materials provide favourable temperature and flox condition.
React for solar energy photocatalysis hydrogen production, internal-response cavity one end is connected with feed tube, the internal-response cavity other end is connected with drain pipe/gas-collecting pipe, light-catalyzed reaction liquid containing catalyst enters the equal light pipe type reactor of solar energy by internal-response cavity one end, and is full of the equal light pipe type reactor of whole solar energy.Solar irradiation is mapped to outer anti-reflection film 1, hyporeflexia, transmitted light strengthens, light reflects after entering ground floor cylindrical transparent hollow anaclasis medium 2, light path deflects, when being irradiated to intermediate layer anti-reflection film 3, reflection ray weakens, transmitted light enters second layer cylindrical transparent hollow anaclasis medium 4, light deflects again, through internal layer anti-reflection film 5 and inner wall 6, enter internal-response cavity, final a part of light enter internal-response cavity incoming position will because of refraction action from just to light side become reactor backlight side (light circumference receiving angle by circumference 180 ° be increased to circumference 351.4 °), sunshine distributes comparatively uniformly in the circumference of the equal light pipe type reactor of solar energy, reactant liquor is under the effect of the incident sunshine of circumference, there is light-catalyzed reaction.Now, the reactant liquor being originally positioned at backlight side also will be subject to the radiation of light and light-catalyzed reaction occur, thus improve the efficiency of light-catalyzed reaction.Anaclasis medium has certain heat storage capacity, and by the reactant liquor in heating reaction cavity, form convection current, the disturbance of accelerated reaction liquid, avoids catalyst sedimentation, improves the efficiency of photocatalysis hydrogen production reaction further.Equal for multiple solar energy of the present invention light pipe type reactor is combined, the reaction of large-scale photocatalysis hydrogen production can be realized.After photocatalysis hydrogen production has reacted, export waste liquid by solar energy equal light pipe type reactor one end, or constantly carry out circular response to obtain hydrogen, the present invention can be used for the occasion such as photocatalysis hydrogen production or solar energy sewage disposal.
For dry materials, material to be dried is inputted inner dry cavity by solar energy equal light pipe type drier one end, and the solar energy equal light pipe type drier other end communicates with air, is convenient to form cross-ventilation, accelerates dry materials process.Solar irradiation is mapped to outer anti-reflection film 1, hyporeflexia, transmitted light strengthens, light reflects after entering ground floor cylindrical transparent hollow anaclasis medium 2, light path deflects, when being irradiated to intermediate layer anti-reflection film 3, reflection ray weakens, transmitted light enters second layer cylindrical transparent hollow anaclasis medium 4, light deflects again, through internal layer anti-reflection film 5 and inner wall 6, enter inner dry cavity, final a part of light enter inner dry cavity incoming position will because of refraction action from just to light side become solar energy equal light pipe type drier backlight side (light circumference receiving angle by circumference 180 ° be increased to circumference 351.4 °), material absorbs solar energy comparatively equably by the circumference of the equal light pipe type drier of solar energy, contained moisture diffusion is to material surface, and then be diffused in air, refractive medium has certain heat storage capacity simultaneously, by the air in heat drying cavity, and then formation cross-ventilation, constantly take away moisture, contained humidity in material is reduced gradually, finally become drying regime.Reach after drying regime can be exported by solar energy equal light pipe type drier one end until a batch materials, in the dry cavity in inside, input next group material to be dried, thus carry out cyclic drying.Light makes the present invention greatly can improve the solar thermal utilization efficiency of solar energy in the more uniform distribution of solar energy equal light pipe type drier circumference; Material circumference absorbs solar energy comparatively equably, has great significance for raising product drying quality.Equal for multiple solar energy of the present invention light pipe type drier is combined, quick, large-scale dry materials can be realized.
Checking the incoming position of a part of light just can be become the equal light pipe type reactor of solar energy or drier backlight side to light side from solar energy equal light pipe type reactor or drier for the present invention is based on refraction principle, thus increase the light receiver angle of the equal light pipe type reactor of solar energy or drier circumference significantly, light is made to distribute more even at solar energy equal light pipe type reactor or drier circumference, software is used to calculate the communication process of light on conventional tube reactor or drier and the equal light pipe type reactor of solar energy of the present invention or drier, distribution of light position on the inner wall 6 of final acquisition, as shown in Figure 2: the light receiver angle of conventional tube reactor or drier circumference is 180 °, the light receiver angle of inner wall 6 circumference of the present invention is 351.4 °, the equal light pipe type reactor of solar energy of the present invention or drier circumference nearly all have light, therefore the light distribution of light on the inner wall 6 of the present invention is more even, thus demonstrate the light receiver angle that the present invention has effectively the increase equal light pipe type reactor of solar energy or drier circumference, light is acted on more uniformly at the equal light pipe type reactor of solar energy or the distribution of drier circumference.

Claims (5)

1. the equal light pipe type reactor of solar energy based on refraction or drier, it is characterized in that: by multiplely having certain refractive index, certain thickness cylindrical transparent hollow anaclasis medium mutually suits and forms, anti-reflection film is covered with, in order to reduce light reflection loss between the cylindrical transparent hollow anaclasis internal dielectric surfaces of outermost cylindrical transparent hollow anaclasis media inside surface, innermost layer and adjacent cylindrical transparent hollow anaclasis medium; The anti-reflection film inside of the cylindrical transparent hollow anaclasis internal dielectric surfaces of innermost layer is inner wall, is internal-response or dry cavity in inner wall; Ecto-entad, the relative index of refraction of cylindrical transparent hollow anaclasis medium and air increases successively.
2. a kind of equal light pipe type reactor of solar energy based on refraction according to claim 1 or drier, is characterized in that: the material of described anti-reflection film is magnesium fluoride, titanium oxide, vulcanized lead or lead selenide.
3. a kind of equal light pipe type reactor of solar energy based on refraction according to claim 1 or drier, it is characterized in that: described multiplely have certain refractive index, certain thickness cylindrical transparent hollow anaclasis medium is two, described solar energy equal light pipe type reactor or drier are followed successively by outer anti-reflection film (1) from outside to inside, ground floor cylindrical transparent hollow anaclasis medium (2), intermediate layer anti-reflection film (3), second layer cylindrical transparent hollow anaclasis medium (4), internal layer anti-reflection film (5), inner wall (6) and internal-response or dry cavity (7), the thickness of each layer anti-reflection film determines according to the anti-reflection light of target and its thickness is minimum, ignores the impact of its thickness on light transmition.
4. a kind of equal light pipe type reactor of solar energy based on refraction according to claim 3 or drier, it is characterized in that: the material of described ground floor cylindrical transparent hollow anaclasis medium (2) is simple glass, its refractive index is 1.5, external diameter is 4cm, internal diameter is 2.66cm, and thickness is 0.67cm; The material of described second layer cylindrical transparent hollow anaclasis medium (4) is extradense flint, and its refractive index is 1.89, and external diameter is 2.66cm, and internal diameter is 2.12cm, and thickness is 0.27cm; The material of described inner wall (6) is simple glass, and its refractive index is 1.5, and external diameter is 2.12cm, and internal diameter is 1.92cm, and thickness is 0.1cm.
5. a kind of equal light pipe type reactor of solar energy based on refraction according to claim 3 or drier, is characterized in that: the length of the equal light pipe type reactor of described solar energy or drier is 2m.
CN201510697002.5A 2015-10-22 2015-10-22 A kind of equal light pipe type reactor of solar energy based on refraction or drier Active CN105276838B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1398305A (en) * 2000-12-12 2003-02-19 柯尼卡株式会社 Method for forming thin film, article having thin film, optical film, dielectric coated electrode, and plasma discharge processor
WO2009042184A2 (en) * 2007-09-26 2009-04-02 Solyndra, Inc. Photovoltaic modules having a filling material
CN201336310Y (en) * 2009-01-26 2009-10-28 河南华美新材料科技有限公司 Single matte surface solar cell glass
CN102563933A (en) * 2010-12-15 2012-07-11 太仓南极风能源设备有限公司 Anti-reflection glass heat collecting tube
CN202562083U (en) * 2012-04-10 2012-11-28 林嘉宏 Solar mirror having characteristic of high reflection or high transmission
CN102872785A (en) * 2012-10-20 2013-01-16 南京工业大学 Straight-through solar heat collection high-temperature reactor
CN203920357U (en) * 2014-04-29 2014-11-05 江苏鼎云信息科技有限公司 A kind of Vehicular solar skylight
CN104576793A (en) * 2013-10-27 2015-04-29 西安中科麦特电子技术设备有限公司 Double-side coated photovoltaic glass

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1398305A (en) * 2000-12-12 2003-02-19 柯尼卡株式会社 Method for forming thin film, article having thin film, optical film, dielectric coated electrode, and plasma discharge processor
WO2009042184A2 (en) * 2007-09-26 2009-04-02 Solyndra, Inc. Photovoltaic modules having a filling material
CN201336310Y (en) * 2009-01-26 2009-10-28 河南华美新材料科技有限公司 Single matte surface solar cell glass
CN102563933A (en) * 2010-12-15 2012-07-11 太仓南极风能源设备有限公司 Anti-reflection glass heat collecting tube
CN202562083U (en) * 2012-04-10 2012-11-28 林嘉宏 Solar mirror having characteristic of high reflection or high transmission
CN102872785A (en) * 2012-10-20 2013-01-16 南京工业大学 Straight-through solar heat collection high-temperature reactor
CN104576793A (en) * 2013-10-27 2015-04-29 西安中科麦特电子技术设备有限公司 Double-side coated photovoltaic glass
CN203920357U (en) * 2014-04-29 2014-11-05 江苏鼎云信息科技有限公司 A kind of Vehicular solar skylight

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