CN105274543B - A kind of alkaline Wax removal water - Google Patents
A kind of alkaline Wax removal water Download PDFInfo
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- CN105274543B CN105274543B CN201510629821.6A CN201510629821A CN105274543B CN 105274543 B CN105274543 B CN 105274543B CN 201510629821 A CN201510629821 A CN 201510629821A CN 105274543 B CN105274543 B CN 105274543B
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Abstract
The invention discloses a kind of alkaline Wax removal water, by weight, including：The parts by weight of basic component 1 10；The parts by weight of alkanolamide class surfactant 10 75；The derivative modified parts by weight of three-dimensional grapheme 2.5 10 of acetylenic glycols；The parts by weight of complexones 2 10；The parts by weight of anion surfactant 1 10；The parts by weight of solvent 1 20；The parts by weight of water 10 50.
Description
Technical field
The present invention relates to Wax removal water field, more particularly to a kind of alkaline Wax removal water.
Technical background
Metal works, clock and watch, handicraft, ornaments are after mechanical polishing, and its surface can remain a large amount of wax polishing powder adhesions
Thing, these burs are main to be made up of paraffin, aliphatic acid, rosin soap, metal oxide and some inoganic solids polishing little particle,
Need to fall the dirty thoroughly cleaning of these waxes before dispatching from the factory or being further processed.Existing frequently-used method is to use ultrasonic wave, electricity
Solution is cleaned manually, however, electrolysis or ultrasonic wave Wax removal water be not general, hydrochloric acid, sulfuric acid or the grass contained in it
Acid, in addition adjuvant used, corrosion inhibiter is mismatched, will cause paraffin removal aqueous corrosion be electrolysed or ultrasonic equipment cell body, cleaning speed it is slow,
The harmful effects such as cleaning is not thorough, generation excessive erosion phenomenon, the finish of destruction workpiece surface.
The content of the invention
In view of the shortcomings of the prior art, one aspect of the present invention provide one kind do not corrode electrolysis or ultrasonic equipment cell body, it is clear
The alkaline Wax removal water for thoroughly having excellent remove function especially for metal oxide and inoganic solids polishing little particle is washed, is pressed
Parts by weight meter, including：
Basic component 1-10 parts by weight；Alkanolamide class surfactant 10-75 parts by weight；Acetylenic glycols derivative changes
Property three-dimensional grapheme 2.5-10 parts by weight；Complexones 2-10 parts by weight；Anion surfactant 1-10 parts by weight；
Solvent 1-20 parts by weight；Water 10-50 parts by weight.
It is used as a kind of preferred technical scheme of the present invention, in the derivative modified three-dimensional grapheme of acetylenic glycols, alkynes two
The structural formula of 01 derivatives is：
Wherein, R1、R2It is independently selected from C1-C10 alkyl, n1、n2Stand alone as 0-40 integer.
It is used as a kind of preferred technical scheme of the present invention, in the structural formula of the acetylenic glycols derivative, n1、n2Stand alone as
10-35 integer.
It is used as a kind of preferred technical scheme of the present invention, in the derivative modified three-dimensional grapheme of acetylenic glycols, alkynes two
The mass fraction of 01 derivatives is between 0.1%-15%.
It is used as a kind of preferred technical scheme of the present invention, in the derivative modified three-dimensional grapheme of acetylenic glycols, alkynes two
The mass fraction of 01 derivatives is between 1%-10%.
It is three-dimensional in the derivative modified three-dimensional grapheme of acetylenic glycols as a kind of preferred technical scheme of the present invention
The specific surface area of graphene is 300-2000 m2/ g, porosity is 50%-99.5%.
It is three-dimensional in the derivative modified three-dimensional grapheme of acetylenic glycols as a kind of preferred technical scheme of the present invention
The specific surface area of graphene is 400-1000 m2/ g, porosity is 60%-80%.
As a kind of preferred technical scheme of the present invention, the structural formula of described alkanolamide class surfactant is：
Wherein, R is the alkyl that carbon chain lengths are C6-C20, n1For 0-10 integer, n3For 1 or 2,（AO）n2For polyoxy second
The block copolymer of alkene, polyoxypropylene or polyoxyethylene and polyoxypropylene, n2For 0-20 integer.
As a kind of preferred technical scheme of the present invention, the pH scopes of the Wax removal water are 8-10.
Another aspect provides the preparation method of the alkaline Wax removal water, preparation process is as follows：
Add water in reactive tank, add alkanolamide class surfactant, complexones, the anion table of metered amount
Face activating agent, solvent, are stirred 20-30 minutes；
The derivative modified three-dimensional grapheme of acetylenic glycols is added, is stirred 20-30 minutes；
Basic component is added, regulation pH value of solution is 8-10.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to described further below.
Embodiment
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of art of the present invention
The identical implication that art personnel are generally understood that.When there is contradiction, the definition in this specification is defined.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements
Thing, step, method, product or device are not necessarily limited to those key elements, but can include not expressly listed other key elements or
Such a composition, step, method, product or the intrinsic key element of device.
Conjunction " Consists of " excludes any key element do not pointed out, step or component.If be used in claim, this
Phrase will make claim be closed, it is not included the material in addition to materials of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following in the clause that phrase " Consists of " appears in claim main body after theme,
It is only limited to the key element described in the clause；Other key elements are not excluded outside as the overall claim.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit
During the Range Representation that choosing value is limited, this, which is appreciated that, specifically discloses by any range limit or preferred value and any scope
All scopes that any pairing of lower limit or preferred value is formed, regardless of whether whether the scope separately discloses.For example, when open
During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1-2 ", " 1-2 and 4-5 ",
" 1-3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope be intended to include its end value with
All integers and fraction within the range.
In addition, the indefinite article " one kind " and " one " before key element of the present invention or component are to key element or the quantitative requirement of component
(i.e. occurrence number) unrestriction.Therefore " one " or " one kind " should be read as including one or at least one, and odd number
The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
One aspect of the present invention provides a kind of alkaline Wax removal water, by weight, including：
Basic component 1-10 parts by weight；Alkanolamide class surfactant 10-75 parts by weight；Acetylenic glycols derivative changes
Property three-dimensional grapheme 2.5-10 parts by weight；Complexones 2-10 parts by weight；Anion surfactant 1-10 parts by weight；
Solvent 1-20 parts by weight；Water 10-50 parts by weight.
Basic component
Basic component described herein is that the pH value of its aqueous solution is more than 7 material, for example, can include hydroxide
Lithium, sodium hydroxide, potassium hydroxide, rubidium hydroxide, cesium hydroxide, beryllium hydroxide, magnesium hydroxide, calcium hydroxide, strontium hydroxide, hydrogen
Barium monoxide, hydroxide radium, iron hydroxide, ferrous hydroxide, Kocide SD, aluminium hydroxide, silver hydroxide, zinc hydroxide, hydrogen-oxygen
Change mercury, chromium hydroxide, nickel hydroxide, sodium carbonate, potassium carbonate, ammoniacal liquor, monomethyl ammonium hydroxide, dimethyl hydrogen amine-oxides, front three
Base ammonium hydroxide, TMAH, tetraethyl ammonium hydroxide, positive TPAOH, different TPAOH, just
TBAH, different TBAH, tertiary TBAH, four pentyl ammonium hydroxide, four hexyl hydroxides
One or more in ammonium choline and triethanolamine, it is preferable that the basic component be potassium hydroxide, sodium hydroxide, potassium carbonate,
One or more in ammoniacal liquor, TMAH, choline, triethanolamine.The addition of the alkali is 1-10 parts by weight, excellent
Selection of land, the addition of the alkali is 3-7 parts by weight.
Alkanolamide class surfactant
Alkanolamide class surfactant is nonionic surface active agent, and alkanolamide class surface of the present invention is lived
Property agent be molecular structure in contain such as formula（1）The material of the structure：
Wherein, R is the alkyl that carbon chain lengths are C6-C20, n1For 0-10 integer, n3For 1 or 2,（AO）n2For polyoxy second
The block copolymer of alkene, polyoxypropylene or polyoxyethylene and polyoxypropylene, n2For 0-20 integer.
In one embodiment, described alkanolamide can enumerate such as N, N- bis-（2- ethoxys）Coconut oleoyl amine,
N, N- bis-（2- ethoxys）Hexane alkylolamides, N, N- bis-（2- ethoxys）Heptane alkylolamides, N, N- bis-（2- ethoxys）Octane alcohol
Acid amides, N, N- bis-（2- ethoxys）Nonane alkylolamides, N, N- bis-（2- ethoxys）Decane alkylolamides, N, N- bis-（2- ethoxys）Ten
One alkanolamide, lauric acid diethyl amide, N, N- bis-（2- ethoxys）Tridecanol acid amides, N, N- bis-（2- ethoxys）14
Alkanolamide, N, N- bis-（2- ethoxys）Pentadecanol acid amides, N, N- bis-（2- ethoxys）Palmitamide, N, N- bis-（2- hydroxyl second
Base）Heptadecanol acid amides, N, N- bis-（2- ethoxys）Octadecanol acid amides, N, N- bis-（2- ethoxys）Nonadecanol acid amides, N,
N- bis-（2- ethoxys）Eicosanol acid amides, polyoxyethylene caproamide, polyoxyethylene heptamide, polyoxyethylene caprylamide, polyoxy
Ethene pelargonamide, polyoxyethylene decyl amide, polyoxyethylene undecanoic amide, polyoxyethylene lauramide, polyoxyethylene tridecanoyl amine,
Polyoxyethylene myristamide, polyoxyethylene pentadecanoyl amine, polyoxyethylene palmitamide, polyoxyethylene heptadecanoyl amine, polyoxyethylene
Stearamide, the acid amides of polyoxyethylene 19, the acid amides of polyoxyethylene 20, polyoxypropylene caproamide, polyoxypropylene heptamide, polyoxy
It is propylene caprylamide, polyoxypropylene pelargonamide, polyoxypropylene decyl amide, polyoxypropylene undecanoic amide, polyoxypropylene lauramide, poly-
Oxypropylene tridecanoyl amine, polyoxypropylene myristamide, polyoxypropylene pentadecanoyl amine, polyoxypropylene palmitamide, polyoxypropylene ten
One or more in seven acid amides, polyoxypropylene stearamide, the acid amides of polyoxypropylene 19, the acid amides of polyoxypropylene 20, preferably
Ground, the alkanolamide class surfactant for N, N- bis-（2- ethoxys）Coconut oleoyl amine, N, N- bis-（2- ethoxys）Palm
Acid amides, N, N- bis-（2- ethoxys）Octadecanol acid amides, polyoxyethylene lauramide, polyoxyethylene palmitamide, polyoxyethylene
One or more in myristamide, polyoxypropylene lauramide, polyoxypropylene myristamide, polyoxypropylene palmitamide.With
Parts by weight meter, the consumption of the alkanolamide class surfactant is 10-75 parts by weight, it is preferable that the alkanolamide class table
The consumption of face activating agent is 45-60 parts by weight.
The derivative modified three-dimensional grapheme of acetylenic glycols
The derivative modified three-dimensional grapheme of acetylenic glycols described herein is at least one acetylenic glycols derivatives graft in three
The material formed on dimension graphene.
Acetylenic glycols derivative
The structural formula of the acetylenic glycols derivative is：
Wherein, R1、R2It is independently selected from C1-C10 alkyl, n1、n2Stand alone as 0-40 integer, it is preferable that n1、n2Stand alone as
10-35 integer.
Herein described acetylenic glycols derivative be selected from 2,4,7,9- tetramethyl -5- decine -4,7- glycol, 4,7- dimethyl -
5- decine -4,7- glycol, 2,5,8,11- tetramethyl -6- dodecynes -5,8- glycol, 2,3,5,8,10,11- hexamethyl -6- 12
Alkynes -5,8- glycol, 3,6- dimethyl -4- octynes -3,6- glycol, 2,5- dimethyl -3- hexins -2,5- glycol, 3,6- dimethyl -
4- n-heptylacetylenes -3,6- glycol, 5,8- dimethyl -6- undecynes -5,8- glycol, 2,5,8,10- tetramethyl -6- undecynes -5,8- bis-
Alcohol, alkynes -6, the 9- glycol of 6,9- dimethyl -7- 14, alkynes -6, the 9- glycol of 2,6,9,13- tetramethyl -7- 14,2,3,6,9,12,
Alkynes -6, the 9- glycol of 13- hexamethyls -7- 14,7,10- dimethyl -8- hexadecines -7,10- glycol, 2,7,10,15- tetramethyls -
8- hexadecines -7,10- glycol, 2,3,7,10,14,15- hexamethyl -8- hexadecine -7,10- glycol, Isosorbide-5-Nitrae butynediols ethyoxyl
Polyethers, 2,4,7,9- tetramethyl -5- decine -4,7- diol ethoxylates polyethers, 4,7- dimethyl -5- decine -4,7- glycol ethoxies
Base polyethers, 2,5,8,11- tetramethyl -6- dodecyne -5,8- diol ethoxylates polyethers, 2,3,5,8,10,11- hexamethyl -6- ten
Diine -5,8- diol ethoxylate polyethers, 3,6- dimethyl -4- octyne -3,6- diol ethoxylates polyethers, 3,6- dimethyl -4- nonyls
Alkynes -3,6- diol ethoxylate polyethers, 2,5- dimethyl -3- hexin -2,5- diol ethoxylates polyethers, 5,8- dimethyl -6- 11
Alkynes -5,8- diol ethoxylate polyethers, 2,5,8,10- tetramethyl -6- undecyne -5,8- diol ethoxylates polyethers, 6,9- dimethyl -
Alkynes -6, the 9- diol ethoxylate polyethers of 7- 14, alkynes -6, the 9- diol ethoxylate polyethers of 2,6,9,13- tetramethyl -7- 14,2,3,
Alkynes -6, the 9- diol ethoxylate polyethers of 6,9,12,13- hexamethyl -7- 14,7,10- dimethyl -8- hexadecine -7,10- glycol second
Epoxide polyethers, 2,7,10,15- tetramethyl -8- hexadecine -7,10- diol ethoxylates polyethers, 2,3,7,10,14,15- hexamethyls -
One or more in 8- hexadecine -7,10- diol ethoxylate polyethers, it is preferable that the acetylenic glycols derivative is 2,4,7,9-
Tetramethyl -5- decine -4,7- glycol, 4,7- dimethyl -5- decine -4,7- glycol, 2,5,8,11- tetramethyl -6- dodecyne -5,
8- glycol, 2,3,5,8,10,11- hexamethyl -6- dodecynes -5,8- glycol, 2,4,7,9- tetramethyl -5- decine -4,7- glycol
Ethyoxyl polyethers, 4,7- dimethyl -5- decine -4,7- diol ethoxylates polyethers, 2,5,8,11- tetramethyl -6- dodecynes -5,8-
One kind or several in diol ethoxylate polyethers, 2,3,5,8,10,11- hexamethyl -6- dodecyne -5,8- diol ethoxylate polyethers
Kind.
Three-dimensional grapheme
The three-dimensional grapheme is the graphene oxide three-dimensional porous shape structure through being self-assembly of at high temperature.
The graphene oxide has no particular limits, and can be commercially available, and oneself can also synthesize, used herein
Graphene oxide is obtained with Hummers methods oneself synthesis, and synthesis step is as follows：The sodium nitrate for weighing 5g graphite powders and 1-5g is put
Enter in beaker, added under conditions of ice bath after the 70-120 ml concentrated sulfuric acid, stirring 0.5-3h, add 5-15 g potassium permanganate,
Controlling reaction temperature is less than 10 DEG C, stirring 1-3 h；30-40 DEG C is warming up to, 0.5-2h is kept, is slowly added to 200-300 ml and goes
Ionized water, keeps mixeding liquid temperature in 98 DEG C or so 0.5h, sequentially adds 40-80 ml deionized waters and 10-30 ml 30
After vol% hydrogen peroxide, 10-30 min, after the hydrochloric acid stirring for adding the vol% of 20-60 ml 10, it will be reacted with centrifugal washing
Thing is washed till neutrality, produces the graphene oxide.
The preparation method of the three-dimensional grapheme is：Graphene oxide is configured to water of the concentration in 0.01-15 mg/ml
Solution, ultrasonic disperse 0.1-2 h, takes 10-500 ml to be added in hydrothermal reaction kettle, and 1-32 h are handled under the conditions of 50-200 DEG C,
It is freeze-dried or not freeze-dried, produce the not aqueous or aqueous three-dimensional grapheme.Three are synthesized in graphene oxide
In the self assembling process for tieing up graphene, reaction condition is controlled, is made in the three-dimensional grapheme of synthesis at least containing an oxygen-containing function
Group, specific surface area is 300-2000 m2/ g, porosity is 50%-99.5%, it is preferable that in the three-dimensional grapheme of the synthesis,
The content of oxygen element is 0.01 at%-10 at%, and specific surface area is 400-1000 m2/ g, porosity is 60%-80%, more preferably,
In the three-dimensional grapheme, the content of oxygen element is 0.1at%-3at%, and specific surface area is 450-800 m2/ g, porosity is
65%-78%。
The preparation method of the derivative modified three-dimensional grapheme of acetylenic glycols is：By foregoing prepare not aqueous or contain
The three-dimensional grapheme grinding of water or the little particle that 50-500 mesh is dispersed into the presence of shearing force, a certain amount of acetylenic glycols are spread out
Biology is added in reactor, and the mass ratio for controlling water-free three-dimensional grapheme and acetylenic glycols derivative is 1-30：1, in solvent
Under conditions of catalyst, in 50-300 DEG C of conditioned response 1-32 hours, after reaction terminates, solvent and low boiling point is evaporated off
Composition, produce the derivative modified three-dimensional grapheme of the acetylenic glycols.In above-mentioned reactions steps, reaction temperature is preferably 70-
250 DEG C, the reaction time is preferably 5-20 hours.The catalyst is chloroplatinic acid, nickel, platinum, cobalt, gold, platinum, ruthenic chloride, dichloride
Iridium, rhodium chloride, rhodium trichloride hydrate, palladium chloride, nickel nitrate, nickel sulfate, nickel chloride, palladium, the positive platinum of chlorination, tri-chlorination
One or more in platinum, platinous chloride, gold chloride, aurous chloride, chlorauride, acetic acid gold, the special platinum catalyst in Lars, consumption
For the 0.0001%-0.1% of not aqueous three-dimensional grapheme weight, it is preferable that the consumption of the catalyst is not aqueous three-dimensional graphite
The 0.001%-0.01% of alkene weight.After reaction, in modified three-dimensional grapheme, the mass fraction of control acetylenic glycols derivative exists
Between 0.1%-15%, it is preferable that the mass fraction of control acetylenic glycols derivative is between 1%-10%.The acetylenic glycols derivative changes
Property three-dimensional grapheme addition be 2.5-10 parts by weight, it is preferable that the derivative modified three-dimensional grapheme of acetylenic glycols plus
Enter amount for 5-7 parts by weight.
Due to there is Van der Waals force and Π-Π active forces and heap forms three-dimensional grapheme between graphene oxide,
Π-Π tracks in three-dimensional grapheme can overlap with the d tracks in metal and form good complexing, therefore, three-dimensional
Graphene can be removed metal oxide from substrate surface by complexing.And the bigger serface in three-dimensional grapheme and
Vesicular texture can largely adsorb inoganic solids polishing little particle, and then effectively remove it from substrate surface.However, by
Oxygen-containing functional group part in the graphene oxide in self assembling process comes off from surface, causes the three-dimensional graphite prepared
The hydrophily of alkene is poor, therefore, and the application increases the hydrophily of three-dimensional grapheme with the derivative modified three-dimensional grapheme of acetylenic glycols,
Preferably reach that removal metal oxide and inoganic solids polish short grained effect, form beneficial effects of the present invention.
Complexones
Complexones of the present invention refers to the polycarboxylic acid complexing agent containing amino, can specifically include natrium adetate
Calcium, diethylene triamine pentacetic acid (DTPA), chelating carboxylic acids, Hedta, 2,2- double [two（Carboxymethyl）Amine] diethyl ether,
1,2- diaminourea cyclohexane tetraacethyl, hydroxyethyl diamine triacetic acid trisodium salt, hydroxyethyl diamine tetraacethyl trisodium salt, ethylenediamine tetraacetic
One or more in acetic acid disodium, tetrasodium ethylenediamine tetraacetate.The consumption of the complexones is 1-20 parts by weight, preferably
Ground, the consumption of the complexones is 2-10 parts by weight.
Anion surfactant
Herein described anion surfactant has no particular limits, and can include with 6-22 carbon atom
It is saturation or unrighted acid or its salt, the salt of fatty alcohol race sulfuric ester with 6-22 carbon atom, former with 6-22 carbon
Salt, the alkene of sulphation, sulfated oil, the sulfuric acid of fatty acid ester of the aliphatic alcohol of son and the sulfuric ester of ethylene oxide adduct
Salt, the alkene of sulphation, sulfonate, carbonate, salt of phosphate etc..Specially neopelex, cetyl
Benzene sulfonic acid sodium salt, Tetradecylbenzene naphthenic acid sodium, lauryl sodium sulfate, sodium tetradecyl sulfate, sodium hexadecyl sulfate, fatty alcohol
APEO, alkylpolyoxyethylene sodium sulphate, myristyl polyethenoxy ether sodium sulfate, cetyl polyoxyethylene
Ether sodium sulfate, Steareth sodium sulphate, oleoyl N-methyltaurine sodium, one kind in sodium methylene bis-naphthalene sulfonate or
It is several.
Solvent
Solvent used herein is 1- butoxy -2- propyl alcohol, ethanol, dipropylene glycol methyl ether, butyl glycol ether, diethylene glycol
Ether, glycerine ether, isopropanol, diethyl ether, dipropyl ether, ethyl-butyl ether, diisopropyl ether, butyl oxide, diamyl ether, diisoamyl
Ether, two hexyl ethers, tetrahydrofuran, oxirane, expoxy propane, epoxychloropropane, dichlorodiethyl ether, dimethoxymethane, diethyl
Mixture more than one or both of epoxide methane, ethylene glycol, glycerine, it is preferable that the solvent is 1- butoxy -2-
One or more in propyl alcohol, diethylene glycol ether, ethanol, ethyl-butyl ether.The consumption of the solvent is 1-20 parts by weight.
Other
In addition, the alkaline Wax removal water of the present invention can also use corrosion inhibiter, anion surfactant, bactericide, froth breaking
Agent, bleeding agent, except additives such as carbon surfactants.These additives can select those commonly used in the art.
Another aspect provides the preparation method of the alkaline Wax removal water, preparation process is as follows：
Add water in reactive tank, add alkanolamide class surfactant, complexones, the anion table of metered amount
Face activating agent, solvent, are stirred 20-30 minutes；
The derivative modified three-dimensional grapheme of acetylenic glycols is added, is stirred 20-30 minutes；
Basic component is added, regulation pH value of solution is 8-10.
Present invention also offers the method for cleaning base material with the alkaline Wax removal water, including：The alkaline Wax removal water is dilute
Release to the 1%-5% of original content, it is 60-80 DEG C to control cleaning temperature, be put into the base material for needing to clean, ultrasonic cleaning, electrolytic cleaned
Or Manual-cleaning 2-10 minutes, rinsing or do not rinse, produce cleaning rear substrate.
In order that technical problems, technical solutions and advantageous effects to be solved by the present invention are more clearly understood, below in conjunction with
Embodiment, the present invention will be described in further detail.It should be appreciated that following examples are served only for doing furtherly the present invention
Bright, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field is according to the content of the invention described above
Some the nonessential modifications and adjustment made, still fall within protection scope of the present invention.
In addition, if without other explanations, all raw materials are all commercially available, and the number is parts by weight.
Raw material：
A1：Potassium hydroxide
B1：N, N- bis-（2- ethoxys）Coconut oleoyl amine
B2：N, N- bis-（2- ethoxys）Palmitamide
C1：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 800 m2/ g, porosity is 75%, and acetylenic glycols derivative is 2,5,8,11- in the derivative modified three-dimensional grapheme of acetylenic glycols
Tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is the 0.1at% of the derivative modified three-dimensional grapheme of acetylenic glycols, second
The number of repeat unit of alkene ether is 10-35）
C2：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 800 m2/ g, porosity is 75%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,8,
11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is 15 at% of the derivative modified three-dimensional grapheme of acetylenic glycols,
The number of repeat unit of vinyl ethers is 10-35）
C3：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 800 m2/ g, porosity is 75%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,8,
11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is 1 at% of the derivative modified three-dimensional grapheme of acetylenic glycols,
The number of repeat unit of vinyl ethers is 10-35）
C4：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 800 m2/ g, porosity is 75%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,8,
11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is 10 at% of the derivative modified three-dimensional grapheme of acetylenic glycols,
The number of repeat unit of vinyl ethers is 10-35）
C5：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 800 m2/ g, porosity is 75%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,8,
11- tetramethyl -6- dodecyne -5,8- glycol, content is 5 at% of the derivative modified three-dimensional grapheme of acetylenic glycols）
C6：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 800 m2/ g, porosity is 75%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,8,
11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is 5 at% of the derivative modified three-dimensional grapheme of acetylenic glycols,
The number of repeat unit of vinyl ethers is 35-40）
C7：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 800 m2/ g, porosity is 75%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,8,
11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is 5 at% of the derivative modified three-dimensional grapheme of acetylenic glycols,
The number of repeat unit of vinyl ethers is 10-35）
C8：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 300 m2/ g, porosity is 50%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,8,
11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is 5 at% of the derivative modified three-dimensional grapheme of acetylenic glycols,
The number of repeat unit of vinyl ethers is 10-35）
C9：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 2000 m2/ g, porosity is 99.5%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,
5,8,11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is the 5 of the derivative modified three-dimensional grapheme of acetylenic glycols
At%, the number of repeat unit of vinyl ethers is 10-35）
C10：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 400 m2/ g, porosity is 60%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,8,
11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is 5 at% of the derivative modified three-dimensional grapheme of acetylenic glycols,
The number of repeat unit of vinyl ethers is 10-35）
C11：The derivative modified three-dimensional grapheme of acetylenic glycols（Synthesize according to the method, wherein, the ratio surface of three-dimensional grapheme
Product is 1000 m2/ g, porosity is 85%, and the acetylenic glycols derivative for the derivative modified three-dimensional grapheme of acetylenic glycols is 2,5,
8,11- tetramethyl -6- dodecyne -5,8- glycol vinyl ethers, content is the 5 of the derivative modified three-dimensional grapheme of acetylenic glycols
At%, the number of repeat unit of vinyl ethers is 10-35）
D1：Hydroxyethyl diamine triacetic acid trisodium salt
E1：1- butoxy -2- propyl alcohol
F1 ：Lauryl sodium sulfate
G1：Soft water
Embodiment 1-14 and comparative example 1-3：
Alkaline Wax removal water is prepared according to the formula in table 1, preparation method is as follows：
（1）Add water in reactive tank, add the alkanolamide class surfactant of metered amount, complexones, it is cloudy from
Sub- surfactant, solvent, are stirred 20-30 minutes；
（2）The derivative modified three-dimensional grapheme of acetylenic glycols is added, is stirred 20-30 minutes；
（3）Basic component is added, it is 9.5 to make pH value of solution.
Embodiment 15 and the preparation method of embodiment 16 as above, but add water make the pH value of reaction system be respectively 8 Hes
10。
Table 1 prepares the raw material and consumption of alkaline Wax removal water（Parts by weight）
Method of testing：
The method of testing of the application refers to professional standard ZBY43003-1986《General water-base metal detergent test method》
It is measured.
Paraffin removal aptitude tests：The Q235 steel test pieces of propolizing are placed in the Wax removal water for being diluted to 3%, ultrasonic wave cleans 3 points
Clock, rinsing, drying is weighed.
The calculation formula of paraffin removal efficiency is：
In formula, X- paraffin removal efficiency, %；
W0The quality of bloom, g before-non-waxdip；
W1The quality of bloom, g after-waxdip；
W2The quality of bloom, g after-cleaning.
Determination of corrosion：Sample steel disc is dried and weighed, in the Wax removal water for being then immersed in 80 DEG C, after 2 hours, examination is taken out
Piece, is rinsed, acetone is dehydrated, drying with distilled water, weighed.Variable quality is calculated as etching extent, is represented with mg.Etching extent=clear
The quality after quality-cleaning before washing.
Rust-preventing characteristic is tested：Sample steel disc is put into except 30 seconds take out in wax liquor, is put into 40 DEG C of baking ovens, is dried 15 minutes,
Then sample steel disc is put into the damp and hot device that temperature is 35 DEG C, relative humidity is 90%, placed 24 hours, take out sample steel disc
Check outward appearance.
Result evaluation：
0 grade：Surface is rustless, no significant change；
1 grade：Surface is rustless, light discolouration or loss of gloss；
2 grades：Surface is gently become rusty, or uneven discoloration；
3 grades：Surface large area corrosion；
According to the requirement of standard, to No. 45 steel, outward appearance is set to 0 grade.
Foaming properties test, is tested with Roche foam meter.
Thimble test：Wax removal water is put into closed vessel, kept for 6 hours at 60 DEG C, is recovered after room temperature, observation
Cosmetic variation.
Result evaluation：
◎ ：Without layering, without muddiness；
○ ：Without layering, slight haze；
△：Slight layering, substantially muddiness；
× ：Obvious layering, substantially muddiness.
Cold performance test：
In the refrigerator that sample steel disc is put into subzero 5 degree, kept for 24 hours, taken out, after clear-cutting forestland room temperature, observe outward appearance
Change.
Result evaluation：
◎ ：Without layering, without muddiness；
○ ：Without layering, slight haze；
△：Slight layering, substantially muddiness；
× ：Obvious layering, substantially muddiness.
Above-mentioned test result is shown in Table 2
The performance test of the alkaline Wax removal water prepared under the different conditions of mixture ratios of table 2
Data above can be seen that compared with without using the Wax removal water of the derivative modified three-dimensional grapheme of acetylenic glycols, this Shen
The alkaline Wax removal water that please be prepared has more preferable paraffin removal ability and less foam, thus provides beneficial effects of the present invention.
Foregoing example is merely illustrative, some features of the feature for explaining the disclosure.Appended claim
The scope as wide as possible for requiring to be contemplated that is intended to, and embodiments as presented herein is only according to all possible embodiment
Combination selection embodiment explanation.Therefore, the purpose of applicant is appended claim not by the explanation present invention
Feature example selectional restriction.And the progress in science and technology by formed language performance it is inaccurate due to and not
The possible equivalent or son being presently considered are replaced, and these changes should also be interpreted by appended in the conceived case
Claim is covered.
Claims (2)
1. a kind of alkaline Wax removal water, it is characterised in that by weight, including：
Basic component 1-10 parts by weight；Alkanolamide class surfactant 10-75 parts by weight；The derivative modified three-dimensional stone of acetylenic glycols
Black alkene 2.5-10 parts by weight；Complexones 2-10 parts by weight；Anion surfactant 1-10 parts by weight；Solvent 1-20 weight
Part；Water 10-50 parts by weight；
In the derivative modified three-dimensional grapheme of acetylenic glycols, the structural formula of acetylenic glycols derivative is：
Wherein, R1、R2It is independently selected from C1-C10 alkyl, n1、n2Stand alone as 10-35 integer；
In the derivative modified three-dimensional grapheme of acetylenic glycols, the mass fraction of acetylenic glycols derivative is between 1%-10%；
In the derivative modified three-dimensional grapheme of acetylenic glycols, the specific surface area of three-dimensional grapheme is 400-1000m2/ g, porosity
For 50%-99.5%；
The preparation process of the derivative modified three-dimensional grapheme of acetylenic glycols, at least comprises the following steps：
The preparation method of the three-dimensional grapheme is：Graphene oxide is configured to the aqueous solution of the concentration in 0.01-15mg/ml,
Ultrasonic disperse 0.1-2h, takes 10-500ml to be added in hydrothermal reaction kettle, and 1-32h is handled under the conditions of 50-200 DEG C, chilled dry
It is dry or not freeze-dried, produce the not aqueous or aqueous three-dimensional grapheme；
The preparation method of the derivative modified three-dimensional grapheme of acetylenic glycols is：By the not aqueous or aqueous three-dimensional grapheme
Grinding or the little particle that 50-500 mesh is dispersed into the presence of shearing force, reactor is added by a certain amount of acetylenic glycols derivative
Interior, the mass ratio for controlling water-free three-dimensional grapheme and acetylenic glycols derivative is 1-30：1, in the condition of solvent and catalyst
Under, in 50-300 DEG C of conditioned response 1-32 hours, after reaction terminates, solvent and the composition of low boiling point is evaporated off, produces described
The derivative modified three-dimensional grapheme of acetylenic glycols；
The structural formula of described alkanolamide class surfactant is：
Wherein, R is the alkyl that carbon chain lengths are C6-C20, n1For 0-10 integer, n3For 1 or 2, (AO) n2For polyoxyethylene, gather
The block copolymer of oxypropylene or polyoxyethylene and polyoxypropylene, n2For 0-20 integer；
The pH scopes of the Wax removal water are 8-10.
2. a kind of preparation method of alkaline Wax removal water as claimed in claim 1, it is characterised in that preparation process is as follows：
Add water in reactive tank, add the alkanolamide class surfactant, complexones, anion surface active of metering
Agent, solvent, are stirred 20-30 minutes；
The derivative modified three-dimensional grapheme of acetylenic glycols is added, is stirred 20-30 minutes；
Basic component is added, regulation pH value of solution is 8-10.
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| CN107475734A (en) * | 2017-08-22 | 2017-12-15 | 南通科星化工有限公司 | A kind of cleaning agent for being used to remove grease stain on metallic surface |
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| CN1693439A (en) * | 2004-04-30 | 2005-11-09 | 三洋化成工业株式会社 | Alkali cleaner |
| CN102212836A (en) * | 2010-12-18 | 2011-10-12 | 江苏德美科技有限公司 | Wax removing water for cleaning wax scale on surface of polished workpiece and preparation method thereof |
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| CN102877082A (en) * | 2012-09-18 | 2013-01-16 | 广东红日星实业有限公司 | Wax solvent for cleaning magnesium alloy or aluminum alloy workpiece |
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| CN1693439A (en) * | 2004-04-30 | 2005-11-09 | 三洋化成工业株式会社 | Alkali cleaner |
| CN102443500A (en) * | 2010-09-30 | 2012-05-09 | 奇美实业股份有限公司 | Detergent remover component and washing method |
| CN102212836A (en) * | 2010-12-18 | 2011-10-12 | 江苏德美科技有限公司 | Wax removing water for cleaning wax scale on surface of polished workpiece and preparation method thereof |
| CN102877082A (en) * | 2012-09-18 | 2013-01-16 | 广东红日星实业有限公司 | Wax solvent for cleaning magnesium alloy or aluminum alloy workpiece |
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