CN105272715A - Phosphogypsum soil conditioner - Google Patents
Phosphogypsum soil conditioner Download PDFInfo
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- CN105272715A CN105272715A CN201510055304.2A CN201510055304A CN105272715A CN 105272715 A CN105272715 A CN 105272715A CN 201510055304 A CN201510055304 A CN 201510055304A CN 105272715 A CN105272715 A CN 105272715A
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- phosphogypsum
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Abstract
The invention discloses a phosphogypsum soil conditioner. The phosphogypsum soil conditioner is composed of the following raw materials, by weight, 720-760 parts of phosphogypsum, 50-60 parts of amino acid chelates, 100-120 parts of plant ash, 50-60 parts of amino acids, 45-50 parts of ferrous sulphate, 3-5 parts of boric acid and 0.6-1 part of functional biological bacteria. The soil conditioner is advantageous in that present waste phosphogypsum resources are changed into valuables from waste, necessary medium elements are provided for growth of crops, the soil salinization problems are solved effectively, the soil ph value is adjusted and balanced effectively, nutrition ingredients are rich, matching is reasonable, and soil ingredients can be balanced, improved and conditioned effectively.
Description
Technical field
The present invention relates to the technical field of amendment, more particularly relate to the technical field of soil conditioner.
Background technology
One of major high concentration composite fertilizer kind that Lin Anshi China greatly develops, often produces one ton of ammonium phosphate product and about produces 2.5 tons of phosphogypsum slags.Wet-Process Phosphoric Acid in The World annual production is more than 3,000 ten thousand tons, and the phosphogypsum of generation is more than 1.5 hundred million tons, and the growing amount of phosphogypsum is much larger than the calcium sulfate aggregate consumption in the world, and as the product of sulphur dioxide of phosphor chemical industry, resource is very abundant.Phosphogypsum has now become one of ammonium phosphate enterprises and has born greatly, this waste residue of method process that quite a few enterprise takes landfill and stores up, but this treatment process also can only be makeshift.The continuous increase of phosphogypsum not only takies a large amount of soil, and causes larger pressure to environment, how this waste resource of digestion process, is ammonium phosphate enterprises problem in the urgent need to address.But on the other hand, the soil salinization is also a global problem, be also solve a difficult problem maximum in land deterioration in the world simultaneously.Add up according to current research, the various types of saline soil total amount of China is 14.87 hundred million mu, wherein potential saline soil 1,734 ten thousand hectares, Secondary salinization soil accounts for 1/6th of the saline soil total area, mainly be distributed in northeast, North China, Northwest inland area and North of Yangtze River coastal area, the direct economic loss caused because of the soil salinization is every year up to several hundred million unit.Again salinization soil is developed if think, just must carry out effective and reasonable conditioning to it, although the various soil conditioner kinds on existing market are more, but various amendment composition collocation is scientific and reasonable not, for soil, particularly for the medium trace element needed for crop, nutrition is abundant not, can not nurse one's health soil well and reach needed for plant growth.
Summary of the invention
Object of the present invention is exactly provide a kind of nutritious to solve above-mentioned deficiency, composition collocation is scientific and reasonable, the existing phosphogypsum resource gone out of use can also be turned waste into wealth, element sulphur in phosphogypsum and calcium constituent are fully absorbed by farm crop, the medium trace element that growth is necessary is provided to farm crop, alleviate the degree of salinity of soil, the phosphogypsum soil conditioner of active balance and improvement can be carried out soil composition.
The technical solution that the present invention adopts to solve the problems of the technologies described above is as follows:
Phosphogypsum soil conditioner, it is made up of the raw material of following weight, phosphogypsum 720-760, amino-acid chelate 50-60, plant ash 100-120, amino acid 50-60, ferrous sulfate 45-50, boric acid 3-5 and functional biological bacterium 0.6-1, described phosphogypsum adopts the phosphogypsum of calcic 22-24% and sulfur-bearing 18-20%; Described amino-acid chelate is by containing amino acid 30%, forming containing zinc 4-6% with containing the material of manganese 4-6%, its concrete chelating process is: first amino acid, zinc sulfate and manganous sulfate to be placed in vaporizers that temperature is 110-115 degree chelating 2 hours under normal pressure, then the temperature in vaporizer is reduced to 78-82 when spending, internal pressure controls at-0.6MPa, then chelating terminates for 2 hours; Described functional biological bacterium is formed by the material mixing of following weight: bacillus amyloliquefaciens 0.5-0.7, subtilis 0.05-0.1, Bacillus licheniformis 0.03-0.1, colloid bacillus cereus 0.02-0.1; Its production process is: first by above-mentioned weight by plant ash together with amino acid, amino-acid chelate Homogeneous phase mixing, make amino acid, amino-acid chelate is adsorbed on plant ash, again by the ferrous sulfate of above-mentioned weight and boric acid, functional biological bacterium and this be adsorbed with the plant ash Homogeneous phase mixing of amino acid, amino-acid chelate after stack 2-3 days, then even with phosphogypsum compound again, namely can be finished product finally by crushing packing.
It is made up of the raw material of following optimum weight part proportioning, phosphogypsum 755, amino-acid chelate 56, plant ash 110, amino acid 58, ferrous sulfate 48, boric acid 4 and functional biological bacterium 0.8.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is: 1, the existing phosphogypsum resource gone out of use turned waste into wealth, in phosphogypsum, S, Ca element obtains effective utilization, significantly reduce due to phosphogypsum landfill and store up the pressure that environment is caused; 2, under the effect of other compositions such as amino acid, the element sulphur in phosphogypsum and calcium constituent are fully absorbed by farm crop, provide necessary moderate-element to crop growth; 3, the metal ion in soil replaced by the calcium ion by being rich in phosphogypsum, efficiently solves a soil salinization difficult problem; 4, effectively regulate and balance the potential of hydrogen of soil; 5, in soil, supplement medium trace element, solve in soil the problem lacking medium trace element, reach the object of balanced soil nutritive element; 6, because amino acid can directly be absorbed by farm crop, amino-acid chelate after amino acid and zinc, manganese, iron plasma chelating can directly be absorbed by farm crop too, reduce trace element by soil fixing, improve the utilization ratio of the trace elements such as zinc, manganese and iron, thus reach the object improving agricultural output and improve quality of agricultural product; 7, nutrition is enriched, and collocation rationally, can carry out active balance, improvement and conditioning to soil composition.
Accompanying drawing explanation
Fig. 1 is survey report homepage of the present invention;
Fig. 2 is survey report of the present invention time page;
Fig. 3 is survey report last page of the present invention;
Embodiment
Embodiment 1: phosphogypsum soil conditioner, it is made up of the raw material of following weight proportion, phosphogypsum 720 kilograms, amino-acid chelate 60 kilograms, plant ash double centner, 60 kilograms, amino acid, 45 kilograms, ferrous sulfate, boric acid 5 kilograms and functional biological bacterium 0.6 kilogram, described phosphogypsum adopts the phosphogypsum of calcic 22% and sulfur-bearing 20%, described amino-acid chelate is by containing amino acid 30%, form containing zinc 6% with containing the material of manganese 4%, its concrete chelating process is: first by amino acid, zinc sulfate and manganous sulfate be placed in temperature be in the vaporizer of 110 degree under normal pressure chelating 2 hours, when then the temperature in vaporizer being reduced to 82 degree, internal pressure controls at-0.6MPa, chelating terminates for 2 hours again, the amino acid using how much quantity is specifically needed in this chelating process, zinc sulfate and manganous sulfate, at this without the need to describing in detail, those skilled in the art can obtain concrete quantity by conventionally calculation and reasoning, only need final amino-acid chelate containing amino acid 30%, containing zinc 6% with containing manganese 4%, described functional biological bacterium is formed by the material mixing of following weight proportion: bacillus amyloliquefaciens 0.5 kilogram, subtilis 0.05 kilogram, Bacillus licheniformis 0.03 kilogram, colloid bacillus cereus 0.02 kilogram.Production process is: first by above-mentioned weight proportion by plant ash together with amino acid, amino-acid chelate Homogeneous phase mixing, make amino acid, amino-acid chelate is adsorbed on plant ash, again by the ferrous sulfate of above-mentioned weight proportion and boric acid, functional biological bacterium and this be adsorbed with the plant ash Homogeneous phase mixing of amino acid, amino-acid chelate after stack 2-3 days, then even with phosphogypsum compound again, namely can be finished product finally by crushing packing.
Embodiment 2: phosphogypsum soil conditioner, it is made up of the raw material of following weight proportion, phosphogypsum 760 kilograms, amino-acid chelate 50 kilograms, plant ash 120 kilograms, 50 kilograms, amino acid, 50 kilograms, ferrous sulfate, boric acid 3 kilograms and functional biological bacterium 1 kilogram, described phosphogypsum adopts the phosphogypsum of calcic 24% and sulfur-bearing 18%, described amino-acid chelate is by containing amino acid 30%, form containing zinc 4% with containing the material of manganese 6%, its concrete chelating process is: first by amino acid, zinc sulfate and manganous sulfate be placed in temperature be in the vaporizer of 115 degree under normal pressure chelating 2 hours, when then the temperature in vaporizer being reduced to 78 degree, internal pressure controls at-0.6MPa, chelating terminates for 2 hours again, the amino acid using how much quantity is specifically needed in this chelating process, zinc sulfate and manganous sulfate, at this without the need to describing in detail, those skilled in the art can obtain concrete quantity by conventionally calculation and reasoning, only need final amino-acid chelate containing amino acid 30%, containing zinc 4% with containing manganese 6%, described functional biological bacterium is formed by the material mixing of following weight proportion: bacillus amyloliquefaciens 0.7 kilogram, subtilis 0.1 kilogram, Bacillus licheniformis 0.1 kilogram, colloid bacillus cereus 0.1 kilogram.Its production process is as follows: first by above-mentioned weight proportion by plant ash together with amino acid, amino-acid chelate Homogeneous phase mixing, make amino acid, amino-acid chelate is adsorbed on plant ash, again by the ferrous sulfate of above-mentioned weight and boric acid, functional biological bacterium and this be adsorbed with the plant ash Homogeneous phase mixing of amino acid, amino-acid chelate after stack 2-3 days, then even with phosphogypsum compound again, namely can be finished product finally by crushing packing.
Embodiment 3: phosphogypsum soil conditioner, it is made up of the raw material of following weight proportion, phosphogypsum 755 kilograms, amino-acid chelate 56 kilograms, plant ash 110 kilograms, 58 kilograms, amino acid, 48 kilograms, ferrous sulfate, boric acid 4 kilograms and functional biological bacterium 0.8 kilogram, described phosphogypsum adopts the phosphogypsum of calcic 23% and sulfur-bearing 19%, described amino-acid chelate is by containing amino acid 30%, form containing zinc 5% with containing the material of manganese 5%, its concrete chelating process is: first by amino acid, zinc sulfate and manganous sulfate be placed in temperature be in the vaporizer of 110 degree under normal pressure chelating 2 hours, when then the temperature in vaporizer being reduced to 80 degree, internal pressure controls at-0.6MPa, chelating terminates for 2 hours again, the amino acid using how much quantity is specifically needed in this chelating process, zinc sulfate and manganous sulfate, at this without the need to describing in detail, those skilled in the art can obtain concrete quantity by conventionally calculation and reasoning, only need final amino-acid chelate containing amino acid 30%, containing zinc 5% with containing manganese 5%, described functional biological bacterium is formed by the material mixing of following weight proportion: bacillus amyloliquefaciens 0.6 kilogram, subtilis 0.05 kilogram, Bacillus licheniformis 0.08 kilogram, colloid bacillus cereus 0.07 kilogram.Its production process is: first by above-mentioned weight proportion by plant ash together with amino acid, amino-acid chelate Homogeneous phase mixing, make amino acid, amino-acid chelate is adsorbed on plant ash, again by the ferrous sulfate of above-mentioned weight proportion and boric acid, functional biological bacterium and this be adsorbed with the plant ash Homogeneous phase mixing of amino acid, amino-acid chelate after stack 2-3 days, then even with phosphogypsum compound again, namely can be finished product finally by crushing packing.
The applicant has carried out the inspection of product composition and content to it to this product special commission holder Hubei authoritative inspection organization, spy encloses survey report.
Claims (2)
1. phosphogypsum soil conditioner, it is characterized in that: it is made up of the raw material of following weight, phosphogypsum 720-760, amino-acid chelate 50-60, plant ash 100-120, amino acid 50-60, ferrous sulfate 45-50, boric acid 3-5 and functional biological bacterium 0.6-1, described phosphogypsum adopts the phosphogypsum of calcic 22-24% and sulfur-bearing 18-20%; Described amino-acid chelate is by containing amino acid 30%, forming containing zinc 4-6% with containing the material of manganese 4-6%, its concrete chelating process is: first amino acid, zinc sulfate and manganous sulfate to be placed in vaporizers that temperature is 110-115 degree chelating 2 hours under normal pressure, then the temperature in vaporizer is reduced to 78-82 when spending, internal pressure controls at-0.6MPa, then chelating terminates for 2 hours; Described functional biological bacterium is formed by the material mixing of following weight: bacillus amyloliquefaciens 0.5-0.7, subtilis 0.05-0.1, Bacillus licheniformis 0.03-0.1, colloid bacillus cereus 0.02-0.1; Its production process is: first by above-mentioned weight by plant ash together with amino acid, amino-acid chelate Homogeneous phase mixing, make amino acid, amino-acid chelate is adsorbed on plant ash, again by the ferrous sulfate of above-mentioned weight and boric acid, functional biological bacterium and this be adsorbed with the plant ash Homogeneous phase mixing of amino acid, amino-acid chelate after stack 2-3 days, then even with phosphogypsum compound again, namely can be finished product finally by crushing packing.
2. phosphogypsum soil conditioner according to claim 1, it is characterized in that: it is made up of the raw material of following optimum weight part proportioning, phosphogypsum 755, amino-acid chelate 56, plant ash 110, amino acid 58, ferrous sulfate 48, boric acid 4 and functional biological bacterium 0.8.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510055304.2A CN105272715A (en) | 2015-02-03 | 2015-02-03 | Phosphogypsum soil conditioner |
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| CN201510055304.2A CN105272715A (en) | 2015-02-03 | 2015-02-03 | Phosphogypsum soil conditioner |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105950172A (en) * | 2016-06-17 | 2016-09-21 | 战锡林 | Organophosphorus pesticide contaminated soil remediation agent |
| CN105967872A (en) * | 2016-05-13 | 2016-09-28 | 淄博夸克医药技术有限公司 | Biomass organic fertilizer |
| CN106365892A (en) * | 2016-08-26 | 2017-02-01 | 青岛根源生物技术集团有限公司 | Soil conditioner for improving and remediating soil and application thereof |
| CN109354556A (en) * | 2018-12-05 | 2019-02-19 | 兴安盟博川农业科技有限公司 | A kind of composite conditioner and the preparation method and application thereof for improveing alkaline land soil |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102219616A (en) * | 2011-04-26 | 2011-10-19 | 深圳市文科园艺实业有限公司 | Natural conditioner functioning in soil conditioning and fertilizing |
| CN103420739A (en) * | 2012-05-26 | 2013-12-04 | 罗学贵 | Method for producing sandy soil modifier by house refuse and sludge-based phosphogypsum fermentation |
| CN103626601A (en) * | 2013-10-23 | 2014-03-12 | 丁群 | Fertilizer containing Chinese herbal medicines and preparation method thereof |
| CN103772032A (en) * | 2014-01-11 | 2014-05-07 | 魏坤峰 | Tree rooting fertilizer and preparation method thereof |
| CN104045487A (en) * | 2014-05-28 | 2014-09-17 | 马鞍山市心洲葡萄专业合作社 | Environmental-protection composite coated fertilizer containing phosphogypsum and preparation method thereof |
-
2015
- 2015-02-03 CN CN201510055304.2A patent/CN105272715A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219616A (en) * | 2011-04-26 | 2011-10-19 | 深圳市文科园艺实业有限公司 | Natural conditioner functioning in soil conditioning and fertilizing |
| CN103420739A (en) * | 2012-05-26 | 2013-12-04 | 罗学贵 | Method for producing sandy soil modifier by house refuse and sludge-based phosphogypsum fermentation |
| CN103626601A (en) * | 2013-10-23 | 2014-03-12 | 丁群 | Fertilizer containing Chinese herbal medicines and preparation method thereof |
| CN103772032A (en) * | 2014-01-11 | 2014-05-07 | 魏坤峰 | Tree rooting fertilizer and preparation method thereof |
| CN104045487A (en) * | 2014-05-28 | 2014-09-17 | 马鞍山市心洲葡萄专业合作社 | Environmental-protection composite coated fertilizer containing phosphogypsum and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967872A (en) * | 2016-05-13 | 2016-09-28 | 淄博夸克医药技术有限公司 | Biomass organic fertilizer |
| CN105950172A (en) * | 2016-06-17 | 2016-09-21 | 战锡林 | Organophosphorus pesticide contaminated soil remediation agent |
| CN106365892A (en) * | 2016-08-26 | 2017-02-01 | 青岛根源生物技术集团有限公司 | Soil conditioner for improving and remediating soil and application thereof |
| CN109354556A (en) * | 2018-12-05 | 2019-02-19 | 兴安盟博川农业科技有限公司 | A kind of composite conditioner and the preparation method and application thereof for improveing alkaline land soil |
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Application publication date: 20160127 |