CN105272681A - Matrix capable of enhancing formaldehyde plant purification rate in air and preparation method thereof - Google Patents

Matrix capable of enhancing formaldehyde plant purification rate in air and preparation method thereof Download PDF

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Publication number
CN105272681A
CN105272681A CN201510848428.6A CN201510848428A CN105272681A CN 105272681 A CN105272681 A CN 105272681A CN 201510848428 A CN201510848428 A CN 201510848428A CN 105272681 A CN105272681 A CN 105272681A
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China
Prior art keywords
formaldehyde
matrix
concentration
solution
air
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CN201510848428.6A
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Chinese (zh)
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赵媛媛
刘凯艳
苏玉红
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Xinjiang University
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Xinjiang University
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Abstract

The invention discloses a matrix capable of enhancing a formaldehyde plant purification rate in air and a preparation method thereof. The matrix consists of the following substances: a formaldehyde bacterium liquid, 4g/L sludge, 2g/L humus, and 1/2 concentration of Hoogland nutrient solution, wherein the ratio of the bacterium liquid to the nutrient solution is 4:1. The preparation method comprises the following steps: (1) collecting a proper amount of garden soil, adding a formaldehyde solution of a certain concentration, sealing for two days, draining the liquid, continuing the operation until a high-concentration formaldehyde solution is obtained, and collecting the bacterium liquid at the last time; (2) culturing the bacteria obtained in the step (1) by using the formaldehyde solutions of different concentrations, wherein the 50mg/L formaldehyde culture bacterium liquid has the highest degradation rate; and (3) taking a certain amount of bacterium liquid, adding sludge, humus and nutrient solution, culturing by using a 50g/L formaldehyde solution per day for three days, thereby obtaining the matrix. According to verification in a glass fiber reinforced plastic simulation device, the efficiency of plants added with the matrix for degrading formaldehyde in air is enhanced by 20-80 percent compared with that of plants without the matrix, namely the matrix has an effect of obviously enhancing the formaldehyde plant purification rate in air.

Description

A kind ofly strengthen matrix of formaldehyde in air plant purification speed and preparation method thereof
Technical field
The present invention relates to a kind of matrix that can strengthen formaldehyde in air plant purification efficiency, particularly relate to the preparation method of this matrix.
Background technology
The formaldehyde pollution that interior decoration brings is subject to extensive concern, is to perplex the healthy Tough questions of resident.Wide material sources, the hazardness of formaldehyde are large, the time length is long, and become China's ubiquity and one of comparatively serious indoor pollutant, its carinogenicity has obtained the confirmation of internal authority mechanism.The approach of present control Formaldehyde Pollution of Indoor Air mainly contains physical method, chemical process, biological method.Because physical method and the undesirable and limitation of chemical process effect are comparatively large, the formaldehyde therefore utilizing green plants absorption chamber interior decoration to produce becomes the focus studied now.Formaldehyde in plant purification air is paid close attention to widely as a kind of safe, effective, easy green technology, but research at present mainly concentrates on screening has the plant face of detergent power and the research of mechanism thereof, less to the matrix aspect research of fortification of plants PARA FORMALDEHYDE PRILLS(91,95) purification efficiency.Especially in plant growth medium and medium, the influence research of microorganism to plant purification efficiency is unintelligible, thus set up a kind of strengthen formaldehyde in air plant purification speed matrix and preparation method particularly important.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of matrix of strengthening formaldehyde in air plant purification speed with low cost and preparation method simple to operate.
The technical solution used in the present invention is as follows:
(1) gather garden soil 500g, pick up out deadwood and rotten leaf, and load in brown bottle;
(2) add the formaldehyde solution of 50mg/L when starting, do not have soil, after sealing two days, strain liquid, add the formaldehyde solution of 100mg/L again, by that analogy to the formaldehyde solution of 250mg/L, collect the solution strained for the last time, the bacterium liquid after filtration loads in clean brown bottle;
(3) cultivate bacterium liquid with the formaldehyde solution of 4 kinds of concentration (50mg/L, 100mg/L, 200mg/L, 250mg/L), result shows that the bacterium liquid degradation rate cultivated with the formaldehyde of 50mg/L is the fastest;
(4) get bacterium liquid 400mL, the concentration adding active sludge and soil ulmin is respectively 4g/L, 2g/L, nutritive medium 100mL, and with every day, the formaldehyde solution of 50mg/L cultivates three days, obtained matrix;
(5) with closing transparent glass cylinder, glass jar top freely can be opened and is provided with the test sample hole of diameter 1cm.Concentration known is added and volume can the formaldehyde solution of cover glass cylinder bottom completely in said apparatus, simulate Formaldehyde Pollution of Indoor Air environment, matrix is quantitatively joined in the vial of outsourcing aluminium-foil paper, and plant is moved into rapidly, and seal bottleneck and collar space with sponge and aluminium-foil paper, then vertically put into simulator, tightly seal with wide adhesive tape, do one group simultaneously and do not add contrasting of matrix, the concentration of formaldehyde solution in glass jar is measured after certain treatment time, calculate degradation rate, show that the efficiency that the ratio adding matrix does not add the plant degradation formaldehyde of matrix exceeds 20% ~ 80%,
The condition of cultivating in described step (2), (3), (4) and (5) is temperature 25 ~ 30 DEG C, and pH is 5 ~ 6;
The present invention compared with prior art has the following advantages:
1, the starting material used in the present invention are easy to get inexpensive, and prepared matrix can to purify air the efficiency of middle formaldehyde by fortification of plants, and the formaldehyde efficiency of the 50mg/L that degraded in 4 hours that matrix can be independent is 80% ~ 95%.By the checking in simulator, add matrix and strengthen 20% ~ 80% with the efficiency of the plant degradation formaldehyde not adding matrix, efficiently solve the shortcomings such as degradation efficiency in conventional art is low, consuming time;
2, the present invention adopts methyl ethyl diketone determination of color concentration of formaldehyde, efficiently solves the complicated operation of technology, the shortcomings such as required expensive equipment;
3, the matrix made of the present invention is conveniently preserved, cost is low, preparation method is simple.
Embodiment
embodiment 1matrix is to the strengthening of the purification efficiency of the formaldehyde in bracketplant degraded air
(1) prepare the vial of 6 50mL, outsourcing aluminium-foil paper, wherein 3 add 40mL nutritive medium respectively, and other 3 add matrix 40mL respectively, prepare the bracketplant that 6 strain sizes are identical, put into wherein by its root, with sponge and aluminium-foil paper by bottle sealing;
(2) the glass reinforced plastic glass jar (90cm × 50cm × 50cm) that preparation two is identical, the 1000mL50mg/L formaldehyde solution prepared is added in glass jar, rapidly the vial that seedling is housed vertically is put into glass jar, note making leaf not adherent, do not contact use liquid, cover the lid of glass jar, and tightly seal with wide adhesive tape, prevent gas leakage, survey the change of formaldehyde in a molten steel every several hours;
(3) as stated above, measure the concentration absorbing formaldehyde in molten steel after 0h, 7h, 24h respectively, calculate degradation rate, compare the efficiency of the plant degradation formaldehyde adding matrix and do not add matrix, the degradation rate adding matrix when 7h strengthens 20%, the degradation rate adding matrix during 24h strengthens 75.31%, and result shows strengthening effect when the 24h highly significant of matrix to the purification efficiency of the formaldehyde in bracketplant degraded air.
embodiment 2matrix is to the strengthening of the purification efficiency of the formaldehyde in epipremnum aureum degraded air
Similar to Example 1, it is identical that its difference is that step (1) and plant in (2) change size into, the epipremnum aureum that growing way is identical, measure the concentration of formaldehyde in molten steel after 0h, 4h, 8h, 24h respectively, result calculates degradation rate, strengthen 25.8% when adding degradation rate enhancing 20.1%, the 8h of matrix during 4h, strengthen 37.31% when 24h.Result shows that the strengthening effect of matrix to the purification efficiency of the formaldehyde in epipremnum aureum degraded air is remarkable.
embodiment 3matrix is to the strengthening of the purification efficiency of the formaldehyde in tiger fur orchid degraded air
Similar to Example 1, it is identical that its difference is that step and (1) and plant in (2) change size into, growing way identical tiger fur blue, measure the concentration of formaldehyde in molten steel after 0h, 4h, 8h, 24h respectively, result calculates degradation rate, strengthen 34.34% when adding degradation rate enhancing 80%, the 8h of matrix during 4h, strengthen 23.39% when 24h.Result shows that the purification efficiency of matrix to the formaldehyde in epipremnum aureum degraded air is remarkable at the strengthening effect of 4h.

Claims (4)

1. strengthen matrix of formaldehyde in air plant purification speed and preparation method thereof for one kind, it is characterized in that matrix is made up of following material: Formaldehyde degradation bacterium, active sludge 4g/L, soil ulmin 2g/L, the Huo Gelande nutritive medium of 1/2 concentration, the ratio of bacterium liquid and nutritive medium is 4:1.
2. strengthen matrix and the preparation method of formaldehyde in air plant purification speed, it is characterized in that matrix composition step is as follows:
(1) gather garden soil 500g, pick up out deadwood and rotten leaf, and load in brown bottle;
(2) add the formaldehyde solution of 50mg/L when starting, do not have soil, after sealing two days, strain liquid; Add the formaldehyde solution of 100mg/L again, by that analogy to the formaldehyde solution of 250mg/L, collect the solution strained for the last time, the bacterium liquid after filtration loads in clean brown bottle;
(3) cultivate Formaldehyde degradation bacterium with the formaldehyde solution of 4 kinds of concentration (50mg/L, 100mg/L, 200mg/L, 250mg/L), result shows that the bacterium liquid degradation of formaldehyde speed of cultivating with the formaldehyde of 50mg/L is the fastest, and namely the speed of growth of Formaldehyde degradation bacterium is the fastest;
(4) get bacterium liquid 400mL, the concentration adding active sludge and soil ulmin is respectively 4g/L, 2g/L, nutritive medium 100mL, and with every day, the formaldehyde solution of 50mg/L cultivates three days;
(5) with closing transparent glass cylinder, glass jar top can freely be opened, concentration known is added and volume can the formaldehyde solution of cover glass cylinder bottom completely in said apparatus, simulate Formaldehyde Pollution of Indoor Air environment, matrix is quantitatively joined in the vial of outsourcing aluminium-foil paper, and plant is moved into rapidly, and seal bottleneck and collar space with sponge and aluminium-foil paper, then vertically put into simulator, tightly seal with wide adhesive tape; Do one group simultaneously and do not add contrasting of matrix, survey a secondary data every certain hour, calculate Degradation Formaldehyde rate; Removal effect calculation formula:
y=(Ca-Cb)/Ca×100%
Y-clearance in formula
Ca-initial concentration of formaldehyde
Concentration of formaldehyde after Cb-2h.
3. a kind of matrix moiety strengthening formaldehyde in air plant purification speed as claimed in claim 1, is characterized in that Formaldehyde degradation bacterium is the bacterium that oneself is cultivated.
4. a kind of matrix and preparation method strengthening formaldehyde in air plant purification speed as claimed in claim 2, it is characterized in that the condition that described step (2), (3), (4) and (5) are used in cultivation Formaldehyde degradation bacterium is temperature 25 ~ 30 DEG C, pH is 5 ~ 6.
CN201510848428.6A 2015-11-30 2015-11-30 Matrix capable of enhancing formaldehyde plant purification rate in air and preparation method thereof Pending CN105272681A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107617424A (en) * 2017-10-09 2018-01-23 常州凯途纺织品有限公司 A kind of preparation method of material for air purification
CN110117638A (en) * 2019-05-21 2019-08-13 新疆大学 A kind of method of formaldehyde dehydrogenase activity size in evaluation leaves of plants
CN111974204A (en) * 2020-08-28 2020-11-24 郭威 Soil beneficial to adsorption and decomposition of harmful substances and preparation method and application thereof
CN112169578A (en) * 2020-08-28 2021-01-05 北京首诚田园科技发展有限公司 Method for efficiently degrading indoor formaldehyde

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5433923A (en) * 1992-02-07 1995-07-18 Wolverton; Billy C. Indoor humidifier and air purifier
CN102233237A (en) * 2010-04-30 2011-11-09 肖春玲 Method for purifying air through plant-microbe combination
CN104946527A (en) * 2015-06-26 2015-09-30 青岛理工大学 Culturing device for formaldehyde degradation bacteria
CN104987215A (en) * 2015-07-10 2015-10-21 河南鑫饰板业有限公司 Preparation method of lignin soilless culture substrate with formaldehyde removing function

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5433923A (en) * 1992-02-07 1995-07-18 Wolverton; Billy C. Indoor humidifier and air purifier
CN102233237A (en) * 2010-04-30 2011-11-09 肖春玲 Method for purifying air through plant-microbe combination
CN104946527A (en) * 2015-06-26 2015-09-30 青岛理工大学 Culturing device for formaldehyde degradation bacteria
CN104987215A (en) * 2015-07-10 2015-10-21 河南鑫饰板业有限公司 Preparation method of lignin soilless culture substrate with formaldehyde removing function

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张淑娟等: ""利用植物净化室内甲醛污染的研究进展"", 《生态环境学报》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107617424A (en) * 2017-10-09 2018-01-23 常州凯途纺织品有限公司 A kind of preparation method of material for air purification
CN110117638A (en) * 2019-05-21 2019-08-13 新疆大学 A kind of method of formaldehyde dehydrogenase activity size in evaluation leaves of plants
CN111974204A (en) * 2020-08-28 2020-11-24 郭威 Soil beneficial to adsorption and decomposition of harmful substances and preparation method and application thereof
CN112169578A (en) * 2020-08-28 2021-01-05 北京首诚田园科技发展有限公司 Method for efficiently degrading indoor formaldehyde

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Application publication date: 20160127