CN105265467A - Agricultural insecticidal composition comprising thiamethoxam and ZJ4042, and insecticide thereof - Google Patents
Agricultural insecticidal composition comprising thiamethoxam and ZJ4042, and insecticide thereof Download PDFInfo
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- CN105265467A CN105265467A CN201410291078.3A CN201410291078A CN105265467A CN 105265467 A CN105265467 A CN 105265467A CN 201410291078 A CN201410291078 A CN 201410291078A CN 105265467 A CN105265467 A CN 105265467A
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- diacloden
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Abstract
The invention discloses an agricultural insecticidal composition comprising thiamethoxam and ZJ4042, and an insecticide thereof. The composition comprises two active components. The first active component is thiamethoxam. The second active component is 3-chloro-N1-(2-methyl-4-heptafluoroisopropylphenyl)-N2-(1-methyl-1-cyanoethyl)polyphthalamide. The weight ratio of the first active component to the second active component is 1-50:30-1. The insecticidal composition provided by the invention is suitable to be used for controlling sucking mouthpart pests and lepidopteran pests, especially sucking mouthpart pests such as aphids, leafhoppers, planthoppers and whiteflies and lepidopteran pests such as prodenia litura, beet armyworms, diamondback moths, cotton bollworms, leaf rollers and rice stem borers. The insecticidal composition is better than single doses in the aspects of fast-acting property and persistence. With the insecticidal composition, pesticide dose and application cost are reduced. The insecticidal composition is beneficial for environment protection and agricultural pest comprehensive treatment.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of by Diacloden and the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2the high-efficiency low-toxicity agricultural pesticide composition that-(1-methyl isophthalic acid-cyano ethyl) phthalic amide is composite and insecticide thereof.
Background technology
Lepidoptera class pest, sucking pest are one of global Important Agricultural insects, and 3R (resistance, then wildness, the residual) problem of chemistry of pesticide control is a global problem.Due to Long-Time Service single variety agricultural chemicals, the increase of Pesticide use amount and not scientifical use agricultural chemicals, the development of drug resistance speed goes of insect is fast, simultaneously, high dose uses organic phosphates, carbamates and the organochlorine insecticides agricultural chemicals high to mammalian toxicity, causes that residue of pesticide exceed standard, the series of problems such as environmental pollution and the increase of peasant's drug cost.Therefore, the pesticide of efficient, the low toxicity of research and development, environmental protection has positive effect to agricultural sustainable development.
Diacloden is a kind of anabasine insecticide of efficient, low toxicity, wide spectrum, its mechanism of action is Selective depression insect CNS nicotinic acetylcholine esterase acceptor mainly, and then block the normal conduction of insect CNS, cause insect to be poisoned to death.Diacloden not only have tag, stomach toxicity and systemic activity, and there is better safety, wider insecticidal spectrum and the feature such as speed of action is fast, the lasting period is long, be replace that those are high to mammalian toxicity, there have to be residual and the better kind of the organic phosphates of environmental problem, carbamates and organochlorine insecticides.To coleoptera, diptera, Lepidoptera, especially homoptera pest has high activity, effectively can prevent and treat the insect of the insects such as various aphid, leafhopper, plant hopper, aleyrodid, chafer larva, colorado potato beetle, nematode, ground beetle, leaf miner and knot polytype chemical pesticide generation resistance.
The chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide (hereinafter referred to as " ZJ4042 "), shown in structural formula following (I):
The insecticidal activity of this compound and the fipronil bisamide of recent development substantially suitable.Fipronil bisamide; English common name (flubendiamide) is researched and developed by Nihon Nihyaku Co., Ltd; chemical name is the iodo-N ' of 3--(2-mesyl-1; 1-dimethyl ethyl-N-{4-[1; 2; the fluoro-1-of 2,2-tetra-(trifluoromethyl) ethyl]-o-tolyl } phthalic amide, molecular formula is: C
23h
22f
7n
2o
4s, belong to Novel ortho benzenedicarboxamide insecticides, activate calcium release channel in blue Buddhist nun's alkali recipient cell, cause the runaway release of storing calcium ion, it is the compounds acting on blue Buddhist nun's alkali (Ryanodine) acceptor of insect cell few in number at present, produce without cross resistance with existing insecticide, be suitable for very much the control that existing insecticide produces the lepidoptera pest of resistance.
In agricultural production, lepidoptera pest and pierce-suck type often occur simultaneously, and when Diacloden and ZJ4042 are used alone, insecticidal spectrum is narrower.The pesticide species mixture of the Diacloden mechanism of action different from ZJ4042, not only effectively can expand insecticidal spectrum, and experiment shows synergistic effect in addition, can dosage be reduced, reduce costs, delay the generation of pest resistance to insecticide, extending the service life of medicament, is the important means of integrated pest management.
The mixture control sucking pest of Diacloden and ZJ4042 and Lepidoptera class pest there is no report and application at present.
Summary of the invention
The object of the present invention is to provide a kind of efficient, wide spectrum, low toxicity, effectively can prevent and treat agricultural pesticide composition and the insecticide thereof of sucking pest and Lepidoptera class pest.
For reaching goal of the invention the technical solution used in the present invention be:
For a Pesticidal combination for pest, containing two kinds of active components, the first active component is Diacloden active component is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the weight ratio that the first active component described and the second activity become is 1 ~ 50: 30 ~ 1.
The first active component above-mentioned and the weight ratio that becomes of the second activity are preferably 1 ~ 20: 20 ~ 1, and more preferably 1 ~ 10: 10 ~ 1, be particularly preferably 1 ~ 5: 5 ~ 1.
Present invention also offers a kind of insecticide for pest, by weight containing 5% ~ 90% above-mentioned Pesticidal combination, all the other are agriculturally acceptable carrier and auxiliary agent.
As preferred mode, containing 20% ~ 80% in described insecticide.
Above-mentioned Pesticidal combination, is particularly preferably the Pesticidal combination containing 40% ~ 80% in insecticide.
Carrier of the present invention can be solid or liquid, and any carrier being generally used for preparing insecticides all can use.
Suitable solid carrier comprises: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin such as, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is such as: calcium carbonate, dolomite.Sulfates as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.Plant is such as: citrus pulp, corncob cellulose, rice husk powder, rice husk, large soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride such as, sodium chloride.
Liquid-carrier comprises water and organic solvent.When active ingredient be aqueous emulsion or suspension emulsion time, organic solvent plays solubilising and antifreeze effect.Suitable organic solvent comprises aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, such as vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, such as petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol such as, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether such as, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidon such as; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, own nitrile; Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be used alone, also can be used in combination, can also mix together with water.
Auxiliary agent of the present invention can comprise one or more in surfactant, defoamer, thickener, suspending agent and antifreezing agent as required, can also comprise other auxiliary agents that the industry is conventional as required.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.
Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; The polycondensation product of the fatty acid containing at least 12 carbon atoms in molecule or fatty amine and oxirane and/expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In the molecule at least containing the sulfuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkali salt, be preferably sodium salt, as the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate and neopelex; The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonylphenol ether of nonionic emulsifier, fatty alcohol-polyoxyethylene ether, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether, styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic emulsifier mainly comprises calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, thermally coupled distillation columns amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention comprises: acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid, to one or more in hydroxyphenyl lignin sulfonic acid sodium salt.
Wetting agent of the present invention comprises: fatty alcohol-polyoxyethylene ether, naphthalene sulfonate, lauryl sodium sulfate, one or more combinations in alkyl phenol resin polyoxyethylene ether sulfate.
Thickener of the present invention comprises xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, gum Arabic, gelatin, one or more in polyvinyl alcohol.Defoamer of the present invention is preferably: bubble enemy, silicone, C8 ~ 10 fatty alcohol, C10 ~ 20 saturated fat acids and acid amides etc.
Insecticide of the present invention can be mixed with suspending agent, missible oil, wetting powder, water-dispersible granules according to the method that this area is general.
Pesticidal combination provided by the invention and insecticide are suitable for control sucking pest and Lepidoptera class pest.
Pesticidal combination of the present invention and insecticide have following advantage compared to existing technology:
(1) in composition, two kinds of active components are composite shows excellent synergistic effect in certain ratio range, after mixing the insecticidal effect of composition comparatively its single dose be significantly improved, and have the advantages that the good and lasting effect of quick-acting grows;
(2) reduce using dosage, reduce peasant's drug cost;
(3) two kinds of active components are utilized to carry out reasonably mixture to the different mode of action of insect, the different mechanism of action, both the Pesticide use life-span had been extended, delay the generation of pest resistance to insecticide, expand insecticidal spectrum again, can be used for control sucking pest if aphid, leafhopper, plant hopper, aleyrodid and Lepidoptera class pest are as prodenia litura, beet armyworm, diamond-back moth, cotton bollworm, rice leaf roller, striped rice borer.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that all alternatives, improvement project and the equivalents that present invention encompasses and may comprise in Claims scope.
In following embodiment, material prescription is selected can suit measures to local conditions, on result without substantial impact.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
The present inventor has carried out Toxicity Determination test to Diacloden and ZJ4042 mixture.
Test evaluates SOP (insecticide volume) with reference to pesticide indoor bioassay test rule (agricultural industry criteria Y/T1154.7-2006) and initiative pesticide bioactivity, adopts dip method.
Synergy adopts following method to calculate:
The content (%) of toxicity index × B in using with of content (the %)+B of toxicity index × A in using with of theoretical mixed toxicity index (TTI)=A
If co-toxicity coefficient is greater than 120, show there is synergistic effect; If be less than 80, be indicated as antagonism; If be greater than 80 to be less than 120, be indicated as summation action.
Embodiment 1:ZJ4042 and Diacloden mixture
Table 1ZJ4042 and Diacloden are to the effect of rice leaf roller Cnaphalocrocismedinalis synergy
Table 2ZJ4042 and Diacloden are to the effect of brown planthopper Nilaparvatalugens synergy
As can be seen from result of the test table 1, table 2, Diacloden and the composite agricultural pesticide composition of ZJ4042, in the scope of 1 ~ 50: 30 ~ 1 (by weight), co-toxicity coefficient is all greater than 120, all shows as synergistic effect to rice leaf roller and brown planthopper.Diacloden and ZJ4042 mixture have reasonability and feasibility.
Embodiment 220% Diacloden ZJ4042 wetting powder
By Diacloden 5%, ZJ404215%, lauryl sodium sulfate 3%, alkyl naphthalene formaldehyde condensate sulfonates 4%, lignin 8%, surplus is kaolin.Above-mentioned formula is mixed in proportion shearing, the obtained 20% Diacloden ZJ4042 wetting powder of air-flow crushing.
This embodiment 2 is applied to control rice leaf roller Cnaphalocrocismedinalis.20% Diacloden ZJ4042 wetting powder is watered even spraying by 27 grams/ha in rice leaf roller low instar larvae occurrence in peak period, and after medicine, the preventive effect of 7 days, 14 days is respectively 93.2%, 94.9%.Contrast single dose 25% Diacloden wetting powder (formulation rate is 50 grams/ha), 20%ZJ4042 suspending agent (formulation rate is 30 grams/ha), same method dispenser pressed by contrast medicament 34% thiophene worm indoxacarb suspending agent 60 grams/ha, after medicine, the preventive effect of 7 days is respectively 53.8%, 82.9%, 87.3%, and after medicine, the preventive effect of 14 days is 63.5%, 86.7%, 89.5%.After Diacloden and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 340% Diacloden ZJ4042 suspending agent
By Diacloden 30%, ZJ40410%, emulsifier 1601# (styrylphenol polyoxyethylene poly-oxygen propylene aether) 10%, dispersant SOPA-27043%, bentonite 2%, xanthans 0.1%, silicone defoaming agent 0.4%, glycerine 5%, surplus is deionized water.Above-mentioned formula is pulverized in proportion in advance, then adds in sand mill and grind, the obtained 40% Diacloden ZJ4042 suspending agent of allotment after high shear mixing.
This embodiment 3 is applied to control striped rice borer Chilosuppressalis (Walker).40% Diacloden ZJ4042 suspending agent is watered even spraying by 38 grams/ha in striped rice borer low instar larvae occurrence in peak period, and after medicine, the preventive effect of 7 days, 14 days is respectively 93.4%, 94.4%.Contrast single dose 25% Diacloden wetting powder (formulation rate is 50 grams/ha), 20%ZJ4042 suspending agent (formulation rate is 30 grams/ha), same method dispenser pressed by contrast medicament 34% thiophene worm indoxacarb suspending agent 60 grams/ha, after medicine, the preventive effect of 7 days is respectively 63.8%, 82.9%, 87.3%, after medicine, the preventive effect of 14 days is 70.5%, 86.7%, 89.5%.After Diacloden and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
That more than enumerates is only specific embodiments of the invention, obviously, the invention is not restricted to above embodiment.All distortion that those of ordinary skill in the art can directly derive from content disclosed by the invention or associate, all should belong to protection scope of the present invention.
Claims (10)
1. contain an agricultural pesticide composition of Diacloden and ZJ4042, it is characterized in that: containing two kinds of active components, the first active component is Diacloden, and second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the weight ratio of the first active component described and second active ingredient is 1 ~ 50: 30 ~ 1.
2., according to the agricultural pesticide composition containing Diacloden and ZJ4042 according to claim 1, it is characterized in that: the weight ratio of the first active component described and second active ingredient is 1 ~ 20: 20 ~ 1.
3., according to the agricultural pesticide composition containing Diacloden and ZJ4042 according to claim 2, it is characterized in that: the weight ratio of the first active component described and second active ingredient is 1 ~ 10: 10 ~ 1.
4., according to the agricultural pesticide composition containing Diacloden and ZJ4042 according to claim 3, it is characterized in that: the weight ratio of the first active component described and second active ingredient is 1 ~ 5: 5 ~ 1.
5. containing an agricultural fungicides of Diacloden and ZJ4042, it is characterized in that: contain 5% ~ 90% Pesticidal combination according to claim 1 by weight, all the other are agriculturally acceptable carrier and auxiliary agent.
6., according to a kind of agricultural fungicides containing Diacloden and ZJ4042 according to claim 5, it is characterized in that: by weight containing 30% ~ 80% Pesticidal combination according to claim 1.
7., according to a kind of agricultural fungicides containing Diacloden and ZJ4042 according to claim 6, it is characterized in that: by weight containing 40% ~ 80% Pesticidal combination according to claim 1.
8., according to a kind of agricultural fungicides containing Diacloden and ZJ4042 according to claim 5, it is characterized in that: described insecticide can be mixed with suspending agent, wetting powder, water-dispersible granules, missible oil.
9. according to the agricultural pesticide composition containing Diacloden and ZJ4042 according to claim 1, it is characterized in that: described Pesticidal combination is mainly used in control sucking pest and Lepidoptera class pest, especially prevent and treat sucking pest aphid, leafhopper, plant hopper, aleyrodid and Lepidoptera class pest prodenia litura, beet armyworm, diamond-back moth, cotton bollworm, rice leaf roller, striped rice borer.
10. according to the agricultural pesticide composition containing Diacloden and ZJ4042 according to claim 9, it is characterized in that: described Pesticidal combination is for preventing and treating sucking pest on fruit tree, vegetables, paddy rice, cotton and Lepidoptera class pest.
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| CN201410291078.3A CN105265467A (en) | 2014-06-18 | 2014-06-18 | Agricultural insecticidal composition comprising thiamethoxam and ZJ4042, and insecticide thereof |
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| CN201410291078.3A CN105265467A (en) | 2014-06-18 | 2014-06-18 | Agricultural insecticidal composition comprising thiamethoxam and ZJ4042, and insecticide thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755814A (en) * | 2009-11-17 | 2010-06-30 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing thiamethoxam and flubendiamide |
| CN102273444A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing thiamethoxam |
| CN102907453A (en) * | 2012-11-09 | 2013-02-06 | 中化蓝天集团有限公司 | Pesticide composition for agricultural pests |
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2014
- 2014-06-18 CN CN201410291078.3A patent/CN105265467A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755814A (en) * | 2009-11-17 | 2010-06-30 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing thiamethoxam and flubendiamide |
| CN102273444A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing thiamethoxam |
| CN102907453A (en) * | 2012-11-09 | 2013-02-06 | 中化蓝天集团有限公司 | Pesticide composition for agricultural pests |
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Application publication date: 20160127 |