CN104206389A - Pesticide composition containing tolfenpyrad and ZJ4042 - Google Patents
Pesticide composition containing tolfenpyrad and ZJ4042 Download PDFInfo
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- CN104206389A CN104206389A CN201410484503.0A CN201410484503A CN104206389A CN 104206389 A CN104206389 A CN 104206389A CN 201410484503 A CN201410484503 A CN 201410484503A CN 104206389 A CN104206389 A CN 104206389A
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- pesticidal combination
- tolfenpyrad
- insecticide
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Abstract
The invention discloses a pesticide composition containing tolfenpyrad and ZJ4042. The pesticide composition containing the tolfenpyrad and the ZJ4042 comprises a first active component which is the tolfenpyrad and a second active component which is 3-chlorine-N1-(2-methyl-4-heptafluoroisopropylphenyl)-N2-(1-methyl-1-cyanoethyl) phthalic diamide according to a mass ratio of (1-50) to (20-1). The pesticide sterilization composition is suitable for being used for preventing and treating lepidoptera type of insect pests.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Pesticidal combination.
Background technology
The resistance problem of pest is global problems.Along with Chemical Control of Harmful Insects continuity, the increase of Pesticide use amount and not scientifical use agricultural chemicals, pest resistance is day by day serious, and the pest species producing resistance is on the increase.Particularly to the Lepidoptera class pest that agricultural production is caused harm serious, its resistance level is higher, resistance development speed is relatively very fast.Simultaneously along with the use of high strength agricultural chemicals, so that Practice for Pesticide Residue in Agricultural Products exceeds standard, environmental pollution and peasant's drug cost increase, and is unfavorable for agricultural sustainable development.
In prior art, existing agricultural chemicals such as Tolfenpyrad etc., when it is used alone, drug cost is higher, not only limits it to a certain extent to apply, and is used alone for a long time and easily causes pest resistance degree constantly to increase.The mixture of different pesticide species is the common methods of preventing and treating agriculture resistant insect.Screened by formulation of pesticide, filter out rational formula, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the generation of pest resistance to insecticide, extending the service life of medicament, is the important means of integrated pest management.
Therefore, the Pesticidal combination of efficient, the low toxicity of research and development, environmental protection and insecticide have positive effect to agricultural sustainable development.
Summary of the invention
The Pesticidal combination that the technical problem to be solved in the present invention can provide a kind of efficient, low toxicity, lasting period long, can be used in control Lepidoptera class pest.
For solving the problem, the technical solution adopted in the present invention is:
A kind of Pesticidal combination, containing two kinds of active components, the first active component is Tolfenpyrad, and second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the quality proportioning of the first active component described and second active ingredient is 1 ~ 50:20 ~ 1.
In Pesticidal combination provided by the invention, the novel pyrazole heterocyclic insecticide that above-mentioned Tolfenpyrad (Tolfenpyrad) Shi Yuan Mitsubishi chemical company (its agricultural chemicals part now belongs to Japanese agricultural chemicals company) develops, its main mechanism is the oxidative phosphorylation stoping insect, there is ovicidal, press down food, oviposition deterrence and bactericidal action, be widely used in the control of insect of the crops such as vegetables, fruit tree, flowers, tealeaves.
In Pesticidal combination provided by the invention, the chloro-N of above-mentioned 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide (hereinafter referred to as " ZJ4042 ") is the novel pesticide that Zhejiang Provincial Chemical Engineering Research Inst is developed voluntarily, shown in structural formula following (I):
The insecticidal activity of this compound and the fipronil bisamide of recent development substantially suitable.Fipronil bisamide, English common name (flubendiamide) is researched and developed by Nihon Nihyaku Co., Ltd, chemical name is the iodo-N-of 3-(2-first sulfonephthalein base-1,1-dimethyl ethane base-N-{4-" 1; 2; the fluoro-1-of 2,2-tetra-(trifluoromethyl) ethyl-o-tolyl } phthalamide, molecular formula is: C
23h
22f
7n
2o
4, belonging to Novel ortho benzenedicarboxamide insecticides, activate calcium release channel in blue Buddhist nun's alkali recipient cell, cause the runaway release of storing calcium ion, is the compounds acting on blue Buddhist nun's alkali (Ryanodine) acceptor of insect cell few in number at present.There is wide spectrum preventive effect to lepidoptera pest, produce without cross resistance with existing insecticide, be suitable for very much the control that existing insecticide produces the insect of resistance.
As preferred mode, the quality proportioning of the first active component above-mentioned and second active ingredient is preferably 1 ~ 10:10 ~ 1, and more preferably 1 ~ 5:5 ~ 1.
Present invention also offers a kind of insecticide, by weight containing 5 ~ 90% above-mentioned Pesticidal combinations, all the other are agriculturally acceptable carrier and auxiliary agent.As preferred embodiment, in described insecticide, contain the Pesticidal combination of by weight 5 ~ 40%.
Carrier of the present invention can be solid or liquid, and any carrier being generally used for preparing insecticides all can use.
Suitable solid carrier comprises: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin such as, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is such as: calcium carbonate, dolomite.Sulfates as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.Plant is such as: citrus pulp, corncob cellulose, rice husk powder, rice husk, large soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride such as, sodium chloride.
Liquid-carrier comprises water and organic solvent.When active ingredient is suspension emulsion, organic solvent plays solubilising and antifreeze effect.Suitable organic solvent comprises aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, such as vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, such as petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol such as, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether such as, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidon such as; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be used alone, also can be used in combination, can also mix together with water.
Auxiliary agent of the present invention can comprise one or more in surfactant, defoamer, thickener, suspending agent and antifreezing agent as required, can also comprise other auxiliary agents that the industry is conventional as required.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; The polycondensation product of the fatty acid containing at least 12 carbon atoms in molecule or fatty amine and oxirane and/expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In the molecule at least containing the sulfuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkali salt, be preferably sodium salt, as the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate and neopelex; The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonylphenol ether of nonionic emulsifier, fatty alcohol-polyoxyethylene ether, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether, styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic emulsifier mainly comprises calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, thermally coupled distillation columns amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention comprises: acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid, to one or more in hydroxyphenyl lignin sulfonic acid sodium salt.
Wetting agent of the present invention comprises: fatty alcohol-polyoxyethylene ether, naphthalene sulfonate, lauryl sodium sulfate, one or more combinations in alkyl phenol resin polyoxyethylene ether sulfate.
Thickener of the present invention comprises xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, gum Arabic, gelatin, one or more in polyvinyl alcohol.Defoamer of the present invention is preferably: bubble enemy, silicone, C
8 ~ 10fatty alcohol, C
10 ~ 20saturated fat acids and acid amides etc.
Insecticide of the present invention can be mixed with missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules according to the method that this area is general.
Pesticidal combination provided by the invention and insecticide are particularly suitable for control Lepidoptera class pest, especially be applicable to the Lepidoptera class pest in control vegetables, paddy rice and cotton, described Lepidoptera class pest comprises prodenia litura, beet armyworm, diamond-back moth, rice leaf roller and cotton bollworm.
Pesticidal combination of the present invention has following advantage compared to existing technology:
(1) in composition, two kinds of composite reagents show excellent synergistic effect in certain ratio range, and the insecticidal effect of mixed composition is significantly improved compared with its single dose, and has the advantages that quick-acting is good and lasting effect is long;
(2) utilize two kinds of active components to carry out reasonably mixture to the different mode of action of insect, the different mechanism of action, both extended the Pesticide use life-span, delayed again the generation of pest resistance to insecticide;
(3) reduce using dosage, reduce peasant's drug cost.
Embodiment
The following examples illustrate several embodiment of the present invention for being used for, but do not limit the invention to these embodiments.One skilled in the art would recognize that all alternatives, improvement project and the equivalents that present invention encompasses and may comprise in Claims scope.
In following embodiment, material prescription is selected can suit measures to local conditions, on result without substantial impact.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
In following embodiment, evaluate SOP (insecticide volume) with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity, adopt infusion process.
Synergy adopts following method to calculate:
The content (%) of toxicity index × B in using with of content (the %)+B of toxicity index × A in using with of theoretical mixed toxicity index (TTI)=A
If co-toxicity coefficient is greater than 120, show there is synergistic effect; If be less than 80, be indicated as antagonism; If be greater than 80 to be less than 120, be indicated as summation action.
Embodiment 1:ZJ4042 and Tolfenpyrad composition
Table 1 ZJ4042 and Tolfenpyrad are to the effect of wild cabbage diamond-back moth Plutella xylostella synergy
| Process | Proportioning | LC 50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Tolfenpyrad | - | 3.02 | 12.25 | ? | ? |
| ZJ4042 | - | 0.37 | 100.00 | ? | ? |
| Tolfenpyrad: ZJ4042 | 50:1 | 1.56 | 23.72 | 13.97 | 169.75 |
| Tolfenpyrad: ZJ4042 | 20:1 | 1.35 | 27.41 | 16.43 | 166.81 |
| Tolfenpyrad: ZJ4042 | 1:1 | 0.42 | 88.10 | 56.13 | 156.96 |
| Tolfenpyrad: ZJ4042 | 1:10 | 0.24 | 154.17 | 92.02 | 167.53 |
| Tolfenpyrad: ZJ4042 | 1:20 | 0.24 | 154.17 | 95.82 | 160.89 |
Table 2 ZJ4042 and Tolfenpyrad are to the effect of rice leaf roller Cnaphalocrocis medinalis synergy
| Process | Proportioning | LC 50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Tolfenpyrad | - | 10.25 | 12.59 | ? | ? |
| ZJ4042 | - | 1.29 | 100.00 | ? | ? |
| Tolfenpyrad: ZJ4042 | 50:1 | 5.65 | 22.83 | 14.30 | 159.67 |
| Tolfenpyrad: ZJ4042 | 20:1 | 4.65 | 27.74 | 16.75 | 165.64 |
| Tolfenpyrad: ZJ4042 | 1:1 | 1.37 | 94.16 | 56.29 | 167.27 |
| Tolfenpyrad: ZJ4042 | 1:10 | 0.91 | 141.76 | 92.05 | 154.00 |
| Tolfenpyrad: ZJ4042 | 1:20 | 0.81 | 159.26 | 95.84 | 166.18 |
As can be seen from Table 1 and Table 2, the composition of Tolfenpyrad and ZJ4042 is in the scope of 1 ~ 50:20 ~ 1 (by weight), and co-toxicity coefficient is all greater than 120, all shows as synergistic effect to wild cabbage diamond-back moth and paddy rice rice leaf roller.
Embodiment 2:20% Tolfenpyrad ZJ4042 suspending agent
With mass ratio range, be the formula of deionized water according to Tolfenpyrad 18%, ZJ40422%, emulsifier styrylphenol polyoxyethylene poly-oxygen propylene aether 10%, dispersant SOPA-2704%, bentonite 2%, xanthans 0.1%, silicone defoaming agent 0.4%, glycerine 5%, surplus, each component is pulverized in advance, add in sand mill again and grind, the obtained 20% Tolfenpyrad ZJ4042 suspending agent of allotment after high shear mixing.
20% obtained Tolfenpyrad ZJ4042 suspending agent is applied to control wild cabbage diamond-back moth.20% Tolfenpyrad ZJ4042 suspending agent is watered even spraying by 10 grams/acre in wild cabbage diamondback moth larvae occurance peak, and after medicine, the preventive effect of 3 days, 7 days is respectively 92.3%, 94.7%.By same method dispenser, single dose 15% Tolfenpyrad suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 3 days after medicine is respectively 71.2% and 85.7%, the preventive effect of 7 days is respectively 74.3% and 87.9% after medicine.After Tolfenpyrad and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 3:40% Tolfenpyrad ZJ4042 water-dispersible granules
With mass ratio range, be kaolinic formula according to Tolfenpyrad 35%, ZJ40425%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, by each component dry pulverization process, granulation, drying, the obtained 40% Tolfenpyrad ZJ4042 water-dispersible granules of screening preparation.
40% obtained Tolfenpyrad ZJ4042 water-dispersible granules is applied to control wild cabbage prodenia litura.40% Tolfenpyrad ZJ4042 water-dispersible granules is watered even spraying by 10 grams/acre in wild cabbage Spodoptera litura larvae occurrence in peak period, and after medicine, 3 days, 7 days preventive effects are respectively 91.2%, 92.1%.By same method dispenser, single dose 15% Tolfenpyrad suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 3 days after medicine is respectively 72.3% and 85.3%, and after medicine, the preventive effect of 7 days is respectively 71.4% and 85.7%.After Tolfenpyrad and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose, and dosage reduces than single dose.
Embodiment 4:70% Tolfenpyrad ZJ4042 water-dispersible granules
With mass ratio range, be kaolinic formula according to Tolfenpyrad 55%, ZJ404215%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, by each component dry pulverization process, granulation, drying, the obtained 70% Tolfenpyrad ZJ4042 water-dispersible granules of screening preparation.
70% obtained Tolfenpyrad ZJ4042 water-dispersible granules is applied to control rice leaf roller.70% Tolfenpyrad ZJ4042 water-dispersible granules is watered even spraying by 10 grams/acre in a rice leaf roller low instar larvae Sheng phase, and after medicine, 7 days, 14 days preventive effects are respectively 87.1%, 93.1%.By same method dispenser, single dose 15% Tolfenpyrad suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 7 days after medicine is respectively 70.2% and 82.4%, the preventive effect of 14 days is respectively 72.7% and 86.8% after medicine.After Tolfenpyrad and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 5:40% Tolfenpyrad ZJ4042 wetting powder
With mass ratio range, be kaolinic formula according to Tolfenpyrad 35%, ZJ40425%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, by each component dry pulverization process, granulation, drying, the obtained 40% Tolfenpyrad ZJ4042 wetting powder of screening preparation.
The obtained 40% Tolfenpyrad ZJ4042 wetting powder that obtains is applied to control rice leaf roller.40% Tolfenpyrad ZJ4042 wetting powder is watered even spraying by 10 grams/acre in rice leaf roller low instar larvae occurrence in peak period, and after medicine, the preventive effect of 7 days, 14 days is respectively 93.4%, 93.5%.By same method dispenser, single dose 15% Tolfenpyrad suspending agent (formulation rate is 15 grams/acre), 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 7 days after medicine is respectively 71.2% and 82.4%, the preventive effect of 14 days is respectively 72.1% and 85.2% after medicine.After Tolfenpyrad and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 6:20% Tolfenpyrad ZJ4042 oil suspending agent
With mass ratio range, according to the formula of Tolfenpyrad 15%, ZJ40425%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether phosphate 3%, organobentonite 1%, methyl oleate benefit to 100%, after each component being mixed, namely sand milling to certain particle diameter obtains 20% Tolfenpyrad ZJ4042 oil suspending agent.
20% obtained Tolfenpyrad ZJ4042 oil suspending agent is applied to control cotton bollworm.20% Tolfenpyrad ZJ4042 oil suspending agent is watered even spraying by 10 grams/acre in cotton bollworm larvae occurance peak, and after medicine, 3 days, 7 days preventive effects are respectively 92.1%, 93.7%.By same method dispenser, single dose 15% Tolfenpyrad suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 3 days after medicine is respectively 73.1% and 82.7%, the preventive effect of 7 days is respectively 73.1% and 87.5% after medicine.After Tolfenpyrad and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 7:20% Tolfenpyrad ZJ4042 missible oil
With mass ratio range, be the formula of dimethylbenzene according to Tolfenpyrad 15%, ZJ40425%, calcium dodecyl benzene sulfonate 6%, triphen ethyl phenol APEO 6%, NMP 8%, surplus, namely each component mixing and stirring is obtained 20% Tolfenpyrad ZJ4042 missible oil.
20% obtained Tolfenpyrad ZJ4042 missible oil is applied to control beet armyworm.20% Tolfenpyrad ZJ4042 oil suspending agent is watered even spraying by 10 grams/acre in beet exigua larvae occurance peak, and after medicine, 3 days, 7 days preventive effects are respectively 92.7%, 94.5%.By same method dispenser, single dose 15% Tolfenpyrad suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 3 days after medicine is respectively 72.0% and 80.4%, the preventive effect of 7 days is respectively 71.7% and 83.9% after medicine.After Tolfenpyrad and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Claims (8)
1. a Pesticidal combination, it is characterized in that described Pesticidal combination contains two kinds of active components, the first active component is Tolfenpyrad, and second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the quality proportioning of the first active component described and second active ingredient is 1 ~ 50:20 ~ 1.
2., according to Pesticidal combination according to claim 1, it is characterized in that the quality proportioning of the first active component described and second active ingredient is 1 ~ 10:10 ~ 1.
3., according to Pesticidal combination according to claim 2, it is characterized in that the quality proportioning of the first active component described and second active ingredient is 1 ~ 5:5 ~ 1.
4., according to the application of Pesticidal combination according to claim 1, it is characterized in that described Pesticidal combination is formulated into insecticide, in described insecticide containing by weight 5 ~ 90% Pesticidal combination, all the other are agriculturally acceptable carrier and auxiliary agent.
5., according to the application of Pesticidal combination according to claim 4, it is characterized in that the Pesticidal combination containing by weight 5 ~ 40% in described insecticide.
6., according to the application of Pesticidal combination according to claim 4, it is characterized in that described insecticide is formulated into missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules.
7., according to the application of Pesticidal combination according to claim 1, it is characterized in that described Pesticidal combination is used to control Lepidoptera class pest.
8. according to the application of Pesticidal combination according to claim 7, it is characterized in that described Pesticidal combination is used to prevent and treat the Lepidoptera class pest in vegetables, paddy rice and cotton, described Lepidoptera class pest comprises prodenia litura, beet armyworm, diamond-back moth, rice leaf roller and cotton bollworm.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302009A (en) * | 2011-07-12 | 2012-01-04 | 江苏龙灯化学有限公司 | Pesticide composition including Flubendiamide and tolfenpyrad and application thereof |
| CN103039457A (en) * | 2011-10-17 | 2013-04-17 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing tolfenpxrad and flubendiamide and application thereof |
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2014
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302009A (en) * | 2011-07-12 | 2012-01-04 | 江苏龙灯化学有限公司 | Pesticide composition including Flubendiamide and tolfenpyrad and application thereof |
| CN103039457A (en) * | 2011-10-17 | 2013-04-17 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing tolfenpxrad and flubendiamide and application thereof |
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