CN105263610A - 多嵌段共聚物及其使用方法 - Google Patents

多嵌段共聚物及其使用方法 Download PDF

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Publication number
CN105263610A
CN105263610A CN201480023401.7A CN201480023401A CN105263610A CN 105263610 A CN105263610 A CN 105263610A CN 201480023401 A CN201480023401 A CN 201480023401A CN 105263610 A CN105263610 A CN 105263610A
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CN
China
Prior art keywords
membrane
poly
block
pdma
membranes
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Pending
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CN201480023401.7A
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English (en)
Chinese (zh)
Inventor
W·A·菲利普
B·W·布杜尔斯
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University of Notre Dame
Purdue Research Foundation
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University of Notre Dame
Purdue Research Foundation
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Publication of CN105263610A publication Critical patent/CN105263610A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/80—Block polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0011—Casting solutions therefor
    • B01D67/00113—Pretreatment of the casting solutions, e.g. thermal treatment or ageing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0016—Coagulation
    • B01D67/00165—Composition of the coagulation baths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/28—Polymers of vinyl aromatic compounds
    • B01D71/281—Polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/40—Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
    • B01D71/401—Polymers based on the polymerisation of acrylic acid, e.g. polyacrylate
    • B01D71/4011—Polymethylmethacrylate
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/021—Pore shapes
    • B01D2325/0212—Symmetric or isoporous membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B01D2325/02832—1-10 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/04—Characteristic thickness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Water Supply & Treatment (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN201480023401.7A 2013-03-11 2014-03-11 多嵌段共聚物及其使用方法 Pending CN105263610A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201361851615P 2013-03-11 2013-03-11
US61/851,615 2013-03-11
US201361874776P 2013-09-06 2013-09-06
US61/874,776 2013-09-06
PCT/US2014/023497 WO2014164793A2 (en) 2013-03-11 2014-03-11 Multiblock copolymers and methods of use

Publications (1)

Publication Number Publication Date
CN105263610A true CN105263610A (zh) 2016-01-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480023401.7A Pending CN105263610A (zh) 2013-03-11 2014-03-11 多嵌段共聚物及其使用方法

Country Status (6)

Country Link
US (1) US10022679B2 (enExample)
EP (1) EP2969155A4 (enExample)
JP (1) JP6330230B2 (enExample)
KR (1) KR20160020404A (enExample)
CN (1) CN105263610A (enExample)
WO (1) WO2014164793A2 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110187565A (zh) * 2019-05-23 2019-08-30 深圳市华星光电技术有限公司 显示器及其制造方法
CN111032200A (zh) * 2017-07-25 2020-04-17 特拉波雷技术有限公司 来自复杂嵌段共聚物架构的多孔材料
CN119113830A (zh) * 2024-09-11 2024-12-13 哈尔滨工业大学 一种三元多功能立体架构介导的高氨氮选择性聚酰胺反渗透膜的制备方法和应用

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2705077B1 (en) 2011-05-04 2019-11-20 Cornell University Multiblock copolymer films, methods of making same, and uses thereof
AU2014351071B2 (en) * 2013-11-14 2018-05-17 The University Of Melbourne Composite gas separation membrane
US10384167B2 (en) 2013-11-21 2019-08-20 Oasys Water LLC Systems and methods for improving performance of osmotically driven membrane systems
US20170260487A1 (en) * 2014-11-25 2017-09-14 Anheuser-Busch Inbev S.A. Beer or Cider Concentrate
KR101570304B1 (ko) * 2014-11-28 2015-11-19 한국기계연구원 하이브리드 형 액체 여과 구조체
CA3022510C (en) * 2016-04-28 2023-12-19 Terapore Technologies, Inc. Charged isoporous materials for electrostatic separations
TWI757350B (zh) * 2016-10-04 2022-03-11 紐西蘭商艾克福特士技術有限公司 熱感應溶液及其使用方法
EP3541500B1 (en) * 2016-11-17 2021-12-08 Shethji, Jayraj K. Isoporous self-assembled block copolymer films containing high molecular weight hydrophilic additives and methods of making the same
WO2018098023A1 (en) 2016-11-22 2018-05-31 3M Innovative Properties Company Pentablock copolymers
WO2018097988A1 (en) 2016-11-22 2018-05-31 3M Innovative Properties Company Porous membranes including pentablock copolymers and method of making the same
SG11201907674WA (en) 2017-02-22 2019-09-27 Terapore Tech Inc Ligand bound mbp membranes, uses and method of manufacturing
WO2018209121A1 (en) 2017-05-12 2018-11-15 Terapore Technologies, Inc. Chemically resistant fluorinated multiblock polymer structures, methods of manufacturing and use
JP7095231B2 (ja) * 2017-05-19 2022-07-05 Dic株式会社 気体分離膜、積層体、及びガス分離モジュール
US12109541B2 (en) 2017-09-19 2024-10-08 Terapore Technologies, Inc. Chemically resistant isoporous crosslinked block copolymer structure
TW201922681A (zh) 2017-10-03 2019-06-16 紐西蘭商艾克福特士技術有限公司 鹽回收溶液及其使用方法
WO2019178077A1 (en) * 2018-03-12 2019-09-19 Terapore Technologies, Inc. Free standing pleatable block copolymer materials and method of making the same
EP3765179A4 (en) * 2018-03-12 2021-12-29 Terapore Technologies, Inc. Isoporous mesoporous asymmetric block copolymer materials with macrovoids and method of making the same
MX2020010445A (es) * 2018-04-04 2021-01-08 Terapore Tech Inc Dispositivos y sistemas de fraccionamiento de partículas encapsulantes y métodos de uso.
EP3860748A4 (en) * 2018-10-05 2022-08-10 Terapore Technologies, Inc. METHOD OF FILTRATION OF LIQUIDS OR GASES FOR ELECTRONICS MANUFACTURE
US12398243B2 (en) 2018-10-30 2025-08-26 University Of Notre Dame Du Lac Block polymer composite membranes
US11241657B2 (en) * 2019-11-22 2022-02-08 Pall Corporation Filter for removing silica from ultra pure water and method of use
US20220090167A1 (en) * 2020-09-15 2022-03-24 University Of Notre Dame Du Lac Asymmetric nanopore membrane (anm) filtration for high-efficiency virus enrichment and purification
KR102572120B1 (ko) * 2021-05-25 2023-08-30 한국과학기술원 탄소와 귀금속을 포함하는 복합소재의 제조 및 복합구조체의 형성 방법
CN114292373B (zh) * 2022-01-25 2023-03-17 南京工业大学 一种甘油调节液相合成共价有机框架纳米片的方法
CN115608175B (zh) * 2022-10-13 2025-01-07 合肥工业大学 一种二维离子对膜的制备方法及其应用
WO2025039009A1 (en) * 2023-08-17 2025-02-20 Cornell University Porous functionalized multiblock copolymer films, methods of making and using same, and products thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4828705A (en) * 1986-10-31 1989-05-09 Kingston Technologies, Inc. Pressure-dependent anisotropic-transport membrane system
US5098570A (en) * 1990-12-06 1992-03-24 Exxon Research And Engineering Company Multi-block polymer comprising a urea prepolymer chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations
US6458310B1 (en) * 1997-03-04 2002-10-01 University Technologies International, Inc. Process of making a polymeric material having a microporous matrix
CN1829564A (zh) * 2003-06-02 2006-09-06 Ge奥斯莫尼克斯公司 用于处理非水混合物的材料及其制备方法
CN101516481A (zh) * 2006-09-22 2009-08-26 Gkss-盖斯特哈赫特研究中心有限责任公司 均孔膜及其制备方法
CN102203159A (zh) * 2008-11-04 2011-09-28 Lg化学株式会社 聚合物电解质膜

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5911343B2 (ja) * 1979-11-27 1984-03-14 東ソー株式会社 両性イオン交換体
JPS62193604A (ja) * 1986-02-21 1987-08-25 Bio Material Yunibaasu:Kk グラフト重合法による外部刺激応答性膜の製造
RU2166984C2 (ru) 1998-06-15 2001-05-20 Институт высокомолекулярных соединений РАН Способ получения полимерных мультислойных первапорационных мембран
DE19829397A1 (de) * 1998-07-01 2000-01-05 Basf Ag Verwendung mikrophasenseparierter Polymermischungen für die Herstellung von permeablen Membranen
RU2211725C2 (ru) 2000-07-20 2003-09-10 Кононова Светлана Викторовна Способ получения композиционных полимерных диффузионных мембран и диффузионные мембраны, полученные этим способом
CA2502577C (en) * 2002-10-18 2008-11-04 Asahi Kasei Pharma Corporation Hydrophilic microporous membrane
MX279856B (es) 2005-04-07 2010-10-08 Pur Water Purification Prod Materiales filtrantes de agua que comprenden una mezcla de particulas de carbono microporosas y mesoporosas y filtros de agua con materiales filtrantes.
US9233846B2 (en) * 2005-10-14 2016-01-12 The Regents Of The University Of California Formation and encapsulation of molecular bilayer and monolayer membranes
US8505745B2 (en) * 2006-04-11 2013-08-13 Massachusetts Institute Of Technology Fouling resistant membranes formed with polyacrylonitrile graft copolymers
EP2108674A4 (en) * 2007-01-11 2011-04-20 Nitto Denko Corp METHOD FOR PRODUCING A MICROPOROUS POLYMERIC SUBSTANCE, MICRONIC POLYMERIC SUBSTANCE AND DISCONNECTED MEMBRANE
JP2008272636A (ja) 2007-04-26 2008-11-13 Asahi Kasei Corp 多層微多孔膜
WO2009048663A2 (en) * 2007-07-20 2009-04-16 Regents Of The University Of Minnesota Nano-structured polymer composites and process for preparing same
JP2009256592A (ja) * 2008-03-18 2009-11-05 Fujifilm Corp 多孔質膜
JP5519684B2 (ja) 2008-10-28 2014-06-11 アーケマ・インコーポレイテッド 水分流動性ポリマー膜
EP2705077B1 (en) * 2011-05-04 2019-11-20 Cornell University Multiblock copolymer films, methods of making same, and uses thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4828705A (en) * 1986-10-31 1989-05-09 Kingston Technologies, Inc. Pressure-dependent anisotropic-transport membrane system
US5098570A (en) * 1990-12-06 1992-03-24 Exxon Research And Engineering Company Multi-block polymer comprising a urea prepolymer chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations
US6458310B1 (en) * 1997-03-04 2002-10-01 University Technologies International, Inc. Process of making a polymeric material having a microporous matrix
CN1829564A (zh) * 2003-06-02 2006-09-06 Ge奥斯莫尼克斯公司 用于处理非水混合物的材料及其制备方法
CN101516481A (zh) * 2006-09-22 2009-08-26 Gkss-盖斯特哈赫特研究中心有限责任公司 均孔膜及其制备方法
CN102203159A (zh) * 2008-11-04 2011-09-28 Lg化学株式会社 聚合物电解质膜

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
周其华等: "《环境保护知识大全》", 31 December 2000, 吉林科学技术出版社 *
汪多仁: "《绿色净水处理剂》", 30 November 2006, 科学技术文献出版社 *
陈建芳: "《树枝状及星形液晶高分子》", 30 November 2012, 湘潭大学出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111032200A (zh) * 2017-07-25 2020-04-17 特拉波雷技术有限公司 来自复杂嵌段共聚物架构的多孔材料
CN110187565A (zh) * 2019-05-23 2019-08-30 深圳市华星光电技术有限公司 显示器及其制造方法
CN110187565B (zh) * 2019-05-23 2021-11-02 Tcl华星光电技术有限公司 显示器及其制造方法
CN119113830A (zh) * 2024-09-11 2024-12-13 哈尔滨工业大学 一种三元多功能立体架构介导的高氨氮选择性聚酰胺反渗透膜的制备方法和应用

Also Published As

Publication number Publication date
JP2016514049A (ja) 2016-05-19
US20160023171A1 (en) 2016-01-28
US10022679B2 (en) 2018-07-17
JP6330230B2 (ja) 2018-05-30
WO2014164793A2 (en) 2014-10-09
EP2969155A4 (en) 2016-11-23
KR20160020404A (ko) 2016-02-23
WO2014164793A3 (en) 2014-11-27
EP2969155A2 (en) 2016-01-20

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Application publication date: 20160120