CN105256613A - Printing and dyeing auxiliary agent, and preparation method and application thereof - Google Patents
Printing and dyeing auxiliary agent, and preparation method and application thereof Download PDFInfo
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- CN105256613A CN105256613A CN201510728892.1A CN201510728892A CN105256613A CN 105256613 A CN105256613 A CN 105256613A CN 201510728892 A CN201510728892 A CN 201510728892A CN 105256613 A CN105256613 A CN 105256613A
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Abstract
The invention provides a printing and dyeing auxiliary agent. The printing and dyeing auxiliary agent is prepared from the following raw materials: 20 to 35 parts by weight of polyethylene glycol diamine, 35 to 45 weight parts of N-hydroxymethyl acrylamide, 2 to 4 weight parts of sodium dodecylbenzene sulfonate, 2 to 4 weight parts of ammonium persulfate, 4 to 8 weight parts of di-rhamnolipid, 12 to 18 parts by weight off plant extract, 3 to 5 weight parts of tannin, 3 to 7 weight parts of sodium taurate, 4 to 6 weight parts of 1-carboxy-N,N,N-trimethylmethanaminium inner salt, 2 to 5 weight parts of europium chloride, 28 to 38 weight parts of ethyl alcohol and 12 to 15 weight parts of polyethylene glycol 600. The printing and dyeing auxiliary agent prepared by the preparation method has good effects on improving color fastness, protecting color, and preventing color fading, and also has the functions of resisting bacteria and preventing static electricity.
Description
Technical field
The invention belongs to printing technology field, relate to a kind of printing and dyeing assistant and its production and use.
Background technology
Printing and dyeing are necessary operations of fabric treating, the clothes worn in people's daily life, bedding used, ornamental curtain, dirt-proof boot, suspension member, in preparation, all relate to the technique of printing and dyeing process, and the fabric of dyefastness difference encounter water, sweat stain, Exposure to Sunlight, saliva or physical friction time, dyestuff easily comes off and fades, affect attractive in appearance, and the dye molecule come off or heavy metal ion can be absorbed by the body and health risk by skin.Thus usually adopt auxiliary agent in dyeing and printing process, it is for improving the effect, increase COLOR FASTNESS etc. of dyeing.
Although there is multiple dyeing assistant in prior art, but it is hyperchromic, protect look performance still not ideal enough, antibacterial, anti-static function or exist disappearance or effect poor, along with the raising of public life quality, require also to aggravate to the multi-functional fabric such as antibacterial, antistatic, these make the printing and dyeing assistant in existing market can not meet the demand of people far away.
CN103757944A discloses a kind of compound printing and dyeing assistant and its production and use.Described compound printing and dyeing assistant is by polyethyleneoxide diamine, N hydroxymethyl acrylamide, neopelex, ammonium persulfate, two rhamnolipid, plant extracts, tannic acid, sodium taurocholate, 1-carboxy-N; β-naphthoxy triazine, silica, europium chloride, ethanol and Macrogol 600 are composite forms for N, N-trimethyl second lactone, tetradecyl chloride base dimethyl benzyl ammonium, 1-phenoxy group-2-propyl alcohol, 2-p-sulfonic acid base phenylamino-4-chloro-6-.This auxiliary agent is by introducing specific component of polymer, plant extracts, quaternary ammonium salt, natural amino acid, Natural ester, and form rare earth compounding and increase other suitable ingredients shown by composite and synergy excellent hyperchromic, protect look and improve the technique effect of COLOR FASTNESS, and show the function with certain antibacterial, antistatic.But the compound printing and dyeing assistant of this invention is prepared by 16 kinds of raw materials, and complicated component, the granularity for composition silica also there are certain requirements.
Summary of the invention
The object of the present invention is to provide a kind of printing and dyeing assistant and its production and use.
For reaching this object, the present invention by the following technical solutions:
On the one hand, the invention provides a kind of printing and dyeing assistant, described printing and dyeing assistant is prepared by following raw material:
The consumption of polyethyleneoxide diamine described in the raw material of printing and dyeing assistant of the present invention is 20-35 weight portion, such as 20 weight portions, 21 weight portions, 22 weight portions, 23 weight portions, 24 weight portions, 25 weight portions, 26 weight portions, 27 weight portions, 28 weight portions, 29 weight portions, 30 weight portions, 31 weight portions, 32 weight portions, 33 weight portions, 34 weight portions or 35 weight portions, be preferably 25-30 weight portion.The weight average molecular weight of polyethyleneoxide diamine of the present invention is 1000-4000Da, such as 1000-2000Da, 2000-3000Da or 3000-4000Da.
The consumption of N hydroxymethyl acrylamide described in the raw material of printing and dyeing assistant of the present invention is 35-45 weight portion, such as 35 weight portions, 36 weight portions, 37 weight portions, 38 weight portions, 39 weight portions, 40 weight portions, 41 weight portions, 42 weight portions, 43 weight portions, 44 weight portions or 45 weight portions, be preferably 38-42 weight portion.
The consumption of neopelex described in the raw material of printing and dyeing assistant of the present invention is 2-4 weight portion, such as 2 weight portions, 2.5 weight portions, 3 weight portions, 3.5 weight portions or 4 weight portions.
The consumption of ammonium persulfate described in the raw material of printing and dyeing assistant of the present invention is 2-4 weight portion, such as 2 weight portions, 2.5 weight portions, 3 weight portions, 3.5 weight portions or 4 weight portions.
Described in the raw material of printing and dyeing assistant of the present invention, the consumption of two rhamnolipid is 4-8 weight portion, such as 4 weight portions, 5 weight portions, 6 weight portions, 7 weight portions or 8 weight portions.
Plant extracts described in the raw material of printing and dyeing assistant of the present invention is the mixture of yellow cinnamon leaf extract, white orchid extract, rhizome of chuanxiong extract, and in this mixture, the mass ratio of three is 1:1:1; Plant extracts consumption is 12-18 weight portion, such as 12 weight portions, 13 weight portions, 14 weight portions, 15 weight portions, 16 weight portions, 17 weight portions or 18 weight portions.
Plant extracts of the present invention adopts following steps preparation: take yellow cinnamon leaf, white orchid or rhizome of chuanxiong separately, add the water soaking being equivalent to plant 10-15 times quality respectively to spend the night, then the ethanol being equivalent to plant 6-8 times quality is added, 40-50min is extracted under microwave 120-180w, extract complete, after filtering, concentrated filtrate is to the 1/30-1/25 of volume, and then freeze drying obtains yellow cinnamon leaf extract, white orchid extract, rhizome of chuanxiong extract respectively.
The consumption of tannic acid described in the raw material of printing and dyeing assistant of the present invention is 3-5 weight portion, such as 3 weight portions, 3.5 weight portions, 4 weight portions, 4.5 weight portions or 5 weight portions.
The consumption of sodium taurocholate described in the raw material of printing and dyeing assistant of the present invention is 3-7 weight portion, such as 3 weight portions, 3.5 weight portions, 4 weight portions, 4.5 weight portions, 5 weight portions, 5.5 weight portions, 6 weight portions, 6.5 weight portions or 7 weight portions.
1-carboxy-N described in the raw material of printing and dyeing assistant of the present invention, the consumption of N, N-trimethyl second lactone is 4-6 weight portion, such as 4 weight portions, 4.5 weight portions, 5 weight portions, 5.5 weight portions or 6 weight portions.
The consumption of europium chloride described in the raw material of printing and dyeing assistant of the present invention is 2-5 weight portion, such as 2 weight portions, 2.5 weight portions, 3 weight portions, 3.5 weight portions, 4 weight portions, 4.5 weight portions or 5 weight portions.
The consumption of ethanol described in the raw material of printing and dyeing assistant of the present invention is 28-38 weight portion, such as 28 weight portions, 29 weight portions, 30 weight portions, 31 weight portions, 32 weight portions, 33 weight portions, 34 weight portions, 35 weight portions, 36 weight portions, 37 weight portions or 38 weight portions, be preferably 30-35 weight portion.
The consumption of Macrogol 600 described in the raw material of printing and dyeing assistant of the present invention is 12-15 weight portion, such as 12 weight portions, 12.5 weight portions, 13 amount parts, 13.5 weight portions, 14 weight portions, 14.5 weight portions or 15 weight portions.
On the other hand, the invention provides a kind of preparation method of printing and dyeing assistant of the present invention, comprise the following steps:
(1) after polyethyleneoxide diamine, N hydroxymethyl acrylamide, neopelex and plant extracts are dropped in proportion stirring in reactor, be warming up to 105-115 DEG C, add ammonium persulfate, insulation reaction 1.5-3h, be cooled to 55-60 DEG C and obtain reactant liquor;
(2) by two rhamnolipid, tannic acid, sodium taurocholate, 1-carboxy-N, N, N-trimethyl second lactone and ethanol add above-mentioned reactant liquor successively, are warming up to 65-75 DEG C, continue to stir 0.5-1.5h, obtain mixed liquor;
(3) finally add in above-mentioned mixed liquor by europium chloride and Macrogol 600, stirred at ambient temperature dispersion 20-30min, then ultrasonic 20-30min under ultrasonic wave 50-70w, can obtain required compound printing and dyeing assistant.
Printing and dyeing assistant of the present invention can be used as cation dyes auxiliary agent, fabric dyeing assistant or fabric-treating agent.
Compared with prior art, the present invention has following beneficial effect: printing and dyeing assistant of the present invention has good raising COLOR FASTNESS, protects look, fade-proof effect, and have function that is antibacterial, antistatic concurrently, fully meet the work requirements of field of printing and dyeing, there is industrial prospect and market value widely.
Detailed description of the invention
Technical scheme of the present invention is further illustrated below by detailed description of the invention.Those skilled in the art should understand, described embodiment is only help to understand the present invention, should not be considered as concrete restriction of the present invention.
The preparation of plant extracts
Take 200g yellow cinnamon leaf, white orchid and rhizome of chuanxiong respectively, add 2000g water soaking respectively to spend the night, then 1200g ethanol is added, 50min is extracted under microwave power 150W, extract complete, after filtering, concentrated filtrate is to 1/30 of volume, then freeze drying, yellow cinnamon leaf extract, white orchid extract and rhizome of chuanxiong extract can be obtained respectively, be mixed to get plant extracts of the present invention with mass ratio 1:1:1.
Embodiment 1
(1) after be the polyethyleneoxide diamine of 1000-2000Da by the weight average molecular weight of 20 weight portions, 40 weight portion N hydroxymethyl acrylamides, 4 weight portion neopelexes and 17 weight portion plant extractss drop into and stir in reactor, be warming up to 115 DEG C, add 2 weight portion ammonium persulfates, insulation reaction 1.5h, is cooled to 55 DEG C and obtains reactant liquor;
(2) by two for 6 weight portions rhamnolipid, 5 weight portion tannic acids, 3 weight portion sodium taurocholates, 5 weight portion 1-carboxy-N, N, N-trimethyl second lactone and 30 parts by weight of ethanol add above-mentioned reactant liquor successively, are warming up to 70 DEG C and continue to stir 0.5h, obtain mixed liquor;
(3) by 2 weight portion europium chlorides and 12 weight portion Macrogol 600s, add in above-mentioned mixed liquor, stirred at ambient temperature dispersion 20min, then ultrasonic 20min under ultrasonic power 50W, can obtain required compound printing and dyeing assistant.
Embodiment 2
(1) after be the polyethyleneoxide diamine of 2000-3000Da by the weight average molecular weight of 35 weight portions, 35 weight portion N hydroxymethyl acrylamides, 2 weight portion neopelexes and 12 weight portion plant extractss drop into and stir in reactor, be warming up to 110 DEG C, add 3 weight portion ammonium persulfates, insulation reaction 2h, is cooled to 60 DEG C and obtains reactant liquor;
(2) by two for 8 weight portions rhamnolipid, 3 weight portion tannic acids, 7 weight portion sodium taurocholates, 4 weight portion 1-carboxy-N, N, N-trimethyl second lactone and 28 parts by weight of ethanol add above-mentioned reactant liquor successively, are warming up to 75 DEG C and continue to stir 1h, obtain mixed liquor;
(3) by 5 weight portion europium chlorides and 14 weight portion Macrogol 600s, add in above-mentioned mixed liquor, stirred at ambient temperature dispersion 25min, then ultrasonic 30min under ultrasonic power 60W, can obtain required compound printing and dyeing assistant.
Embodiment 3
(1) after be the polyethyleneoxide diamine of 3000-4000Da by the weight average molecular weight of 28 weight portions, 45 weight portion N hydroxymethyl acrylamides, 3 weight portion neopelexes and 18 weight portion plant extractss drop into and stir in reactor, be warming up to 105 DEG C, add 4 weight portion ammonium persulfates, insulation reaction 3h, is cooled to 55 DEG C and obtains reactant liquor;
(2) by two for 4 weight portions rhamnolipid, 4 weight portion tannic acids, 5 weight portion sodium taurocholates, 6 weight portion 1-carboxy-N, N, N-trimethyl second lactone and 38 parts by weight of ethanol add above-mentioned reactant liquor successively, are warming up to 65 DEG C and continue to stir 1.5h, obtain mixed liquor;
(3) by 3 weight portion europium chlorides and 15 weight portion Macrogol 600s, add in above-mentioned mixed liquor, stirred at ambient temperature dispersion 30min, then ultrasonic 25min under ultrasonic power 70W, can obtain required compound printing and dyeing assistant.
Comparative example 1
Adopt the compound printing and dyeing assistant prepared in CN103757944A as comparative example of the present invention, namely prepare comparative example printing and dyeing assistant as follows:
(1) by 5g weight average molecular weight be polyethyleneoxide diamine, 25gN-n-methylolacrylamide, 1g neopelex, 2g yellow cinnamon leaf extract, 2g white orchid extract, the 2g rhizome of chuanxiong extract of 1000-2000, after stirring in above-mentioned part by weight input reactor, be warming up to 120 DEG C, add 3g ammonium persulfate, insulation reaction 1h, is cooled to 55 DEG C and obtains reactant liquor;
(2) by two for 3g rhamnolipid, 1g tannic acid, 2g sodium taurocholate, 0.5g1-carboxy-N, N, N-trimethyl second lactone, 1.5g tetradecyl chloride base dimethyl benzyl ammonium, 1g1-phenoxy group-2-propyl alcohol, 1g2-p-sulfonic acid base phenylamino-4-chloro-6-β-naphthoxy triazine and 20g ethanol add above-mentioned reactant liquor successively, be warming up to 70 DEG C to continue to stir 1h, obtain mixed liquor;
(3) finally by leftover materials 5g silica (particle diameter is 200nm), 0.5g europium chloride and 5g Macrogol 600, add in above-mentioned mixed liquor, stirred at ambient temperature dispersion 20min, then ultrasonic 15min under ultrasonic power 60W, can obtain contrast compound printing and dyeing assistant.
Performance test
To the performance test of printing and dyeing assistant
(1) 0.1g cation dyes (0.023g cationic yellow x-8gl is got respectively, 0.035g Cationic Red X-GRL, 0.042g cationic blue x-grrl, three kinds of dyestuffs mix mutually), add printing and dyeing assistant prepared by 0.081g embodiment 1-3 wherein respectively, then add 150ml demineralized water and be made into dyeing liquor, dyeing and finishing silk material 5g, carry out Coloration experiment, adopt comparative example auxiliary agent to carry out Coloration experiment as a control group in an identical manner.DYED FABRICS quality results is in table 1.
Table 1 printing and dyeing assistant water-fast, resistance to is soaped, perspiration resistance, rub resistance and color fastness to light
Note: credit rating is divided into 5 grades, the larger representation quality of numeral is better.
(2) effective chlorine 20mg/L is selected according to the test condition in GB GB/T8433-1998 " textile color stability test colour fastness to chlorinated water ", PH7.5, temperature 27 DEG C, bath raio 100:1,60 minutes time, the chlorination water colour fastness of above-mentioned obtained printing and dyeing silk is tested.DYED FABRICS the results are shown in Table 2, and evaluate sample discoloration according to GB/T250, the variable color of higher grade is less, and anti-chlorination water effect is better.
The colour fastness to chlorinated water of table 2 printing and dyeing assistant
Note: credit rating is divided into 5 grades, the larger representation quality of numeral is better.
From the experimental result of above-mentioned table 1 and table 2, the color fastness to water of the printing and dyeing assistant of embodiments of the invention, fastness to soaping, colour fastness to perspiration, colour fastness to rubbing and color fastness to light are better than the COLOR FASTNESS or suitable with it of the compound printing and dyeing assistant of the complicated ingredient of comparative example 1, and the relatively simple oligomict printing and dyeing assistant that namely prepared by the present invention can make dyeing material obtain good fixation, effect of color protection.
(3) method of above-mentioned (1) is adopted to carry out Coloration experiment to wool fibre, then according to national GB/T20944.2-2007 " the evaluation part 2 of antibacterial textile performance: absorption process ", measure the bacteriostasis property of the dried wool fibre of dyeing after 5 standard wash, printing and dyeing assistant prepared by the printing and dyeing assistant experimental group comparative example 1 wherein prepared with embodiment 1-3 is for control group.Result display is as shown in table 3:
The anti-microbial property of table 3 printing and dyeing assistant
(4) method of above-mentioned (1) is adopted to carry out Coloration experiment to dacron, then on YGL342D type fabric anti-static instrument, carry out antistatic half-life mensuration according to the method for FZ/T01042-1996 to dried DYED FABRICS, printing and dyeing assistant prepared by the printing and dyeing assistant experimental group comparative example 1 wherein prepared with embodiment 1-3 is for control group.Result display is as shown in table 4:
The antistatic property of table 4 printing and dyeing assistant
From the experimental result of above-mentioned table 3 and table 4, the fabric adopting compound printing and dyeing assistant of the present invention to dye or fiber show than comparative example 1 better antistatic property.
Comprehensively above-mentioned; the present invention utilizes polyethyleneoxide diamine, N hydroxymethyl acrylamide, neopelex, plant extracts, two rhamnolipid, tannic acid, sodium taurocholate, 1-carboxy-N; N; N-trimethyl second lactone and ethanol and europium chloride and Macrogol 600 are raw material; pass through the method for the invention; according to specified weight part ratio, described raw material is prepared into printing and dyeing assistant; this printing and dyeing assistant show excellent hyperchromic, protect look and improve the technique effect of COLOR FASTNESS, and unexpectedly possessed antibacterial, the electrostatic-proof function of fabric finishing agent.
Applicant states, the present invention illustrates method detailed of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned method detailed, does not namely mean that the present invention must rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (9)
1. a printing and dyeing assistant, is characterized in that, described printing and dyeing assistant is prepared by following raw material:
2. printing and dyeing assistant according to claim 1, is characterized in that, the consumption of described polyethyleneoxide diamine is 25-30 weight portion.
3. printing and dyeing assistant according to claim 1 and 2, is characterized in that, the weight average molecular weight of described polyethyleneoxide diamine is 1000-4000Da.
4. the printing and dyeing assistant according to any one of claim 1-3, is characterized in that, the consumption of described N hydroxymethyl acrylamide is 38-42 weight portion.
5. the printing and dyeing assistant according to any one of claim 1-4, is characterized in that, described plant extracts is the mixture of yellow cinnamon leaf extract, white orchid extract, rhizome of chuanxiong extract, and in this mixture, the mass ratio of three is 1:1:1.
6. the printing and dyeing assistant according to any one of claim 1-5, it is characterized in that, described plant extracts adopts following steps preparation: take yellow cinnamon leaf, white orchid or rhizome of chuanxiong separately, add the water soaking being equivalent to plant 10-15 times quality respectively to spend the night, then the ethanol being equivalent to plant 6-8 times quality is added, 40-50min is extracted under microwave 120-180w, extract complete, after filtering, concentrated filtrate is to the 1/30-1/25 of volume, and then freeze drying obtains yellow cinnamon leaf extract, white orchid extract, rhizome of chuanxiong extract respectively.
7. the printing and dyeing assistant according to any one of claim 1-6, is characterized in that, the consumption of described ethanol is 30-35 weight portion.
8. the preparation method of the printing and dyeing assistant according to any one of claim 1-7, is characterized in that, comprises the following steps:
(1) after polyethyleneoxide diamine, N hydroxymethyl acrylamide, neopelex and plant extracts are dropped in proportion stirring in reactor, be warming up to 105-115 DEG C, add ammonium persulfate, insulation reaction 1.5-3h, be cooled to 55-60 DEG C and obtain reactant liquor;
(2) by two rhamnolipid, tannic acid, sodium taurocholate, 1-carboxy-N, N, N-trimethyl second lactone and ethanol add above-mentioned reactant liquor successively, are warming up to 65-75 DEG C, continue to stir 0.5-1.5h, obtain mixed liquor;
(3) finally add in above-mentioned mixed liquor by europium chloride and Macrogol 600, stirred at ambient temperature dispersion 20-30min, then ultrasonic 20-30min under ultrasonic wave 50-70w, can obtain required compound printing and dyeing assistant.
9. the purposes of the printing and dyeing assistant according to any one of claim 1-8, is characterized in that, described printing and dyeing assistant is used as cation dyes auxiliary agent, fabric dyeing assistant or fabric-treating agent.
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| CN201510728892.1A CN105256613A (en) | 2015-10-30 | 2015-10-30 | Printing and dyeing auxiliary agent, and preparation method and application thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107869072A (en) * | 2017-12-15 | 2018-04-03 | 苏州润弘贸易有限公司 | Antistatic printing assistant |
| CN107881814A (en) * | 2017-11-29 | 2018-04-06 | 苏州润弘贸易有限公司 | New printing and dyeing assistant |
| CN107904995A (en) * | 2017-11-29 | 2018-04-13 | 苏州润弘贸易有限公司 | Printing and dyeing assistant |
| CN107905001A (en) * | 2017-11-29 | 2018-04-13 | 苏州润弘贸易有限公司 | A kind of printing and dyeing assistant |
| CN107956151A (en) * | 2017-12-15 | 2018-04-24 | 苏州润弘贸易有限公司 | Antistatic dyeing paste |
| CN107956156A (en) * | 2017-11-29 | 2018-04-24 | 苏州润弘贸易有限公司 | A kind of modified printing and dyeing assistant |
| CN109403069A (en) * | 2018-08-20 | 2019-03-01 | 绍兴华星丝织印染有限公司 | A kind of dyeing of TR looped fabric |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103757944A (en) * | 2014-01-14 | 2014-04-30 | 傅科杰 | Composite printing and dyeing auxiliary as well as preparation method and application of auxiliary |
-
2015
- 2015-10-30 CN CN201510728892.1A patent/CN105256613A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103757944A (en) * | 2014-01-14 | 2014-04-30 | 傅科杰 | Composite printing and dyeing auxiliary as well as preparation method and application of auxiliary |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107881814A (en) * | 2017-11-29 | 2018-04-06 | 苏州润弘贸易有限公司 | New printing and dyeing assistant |
| CN107904995A (en) * | 2017-11-29 | 2018-04-13 | 苏州润弘贸易有限公司 | Printing and dyeing assistant |
| CN107905001A (en) * | 2017-11-29 | 2018-04-13 | 苏州润弘贸易有限公司 | A kind of printing and dyeing assistant |
| CN107956156A (en) * | 2017-11-29 | 2018-04-24 | 苏州润弘贸易有限公司 | A kind of modified printing and dyeing assistant |
| CN107869072A (en) * | 2017-12-15 | 2018-04-03 | 苏州润弘贸易有限公司 | Antistatic printing assistant |
| CN107956151A (en) * | 2017-12-15 | 2018-04-24 | 苏州润弘贸易有限公司 | Antistatic dyeing paste |
| CN109403069A (en) * | 2018-08-20 | 2019-03-01 | 绍兴华星丝织印染有限公司 | A kind of dyeing of TR looped fabric |
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Application publication date: 20160120 |