CN105256566B - A kind of method that utilization ethylene glycol phenyl ether improves sizing adhesive formula - Google Patents
A kind of method that utilization ethylene glycol phenyl ether improves sizing adhesive formula Download PDFInfo
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- CN105256566B CN105256566B CN201510742897.XA CN201510742897A CN105256566B CN 105256566 B CN105256566 B CN 105256566B CN 201510742897 A CN201510742897 A CN 201510742897A CN 105256566 B CN105256566 B CN 105256566B
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- ethylene glycol
- phenyl ether
- glycol phenyl
- acrylate
- phosphate ester
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Abstract
The present invention relates to a kind of method that utilization ethylene glycol phenyl ether improves sizing adhesive formula, belong to textile processing field.Described method refers to sizing in phosphate ester starch, acrylate and water with adding ethylene glycol phenyl ether in adhesive formula, wherein, phosphate ester starch quality is the 3 5% of phosphate ester starch, acrylate, ethylene glycol phenyl ether and water gross mass, acrylate quality is the 3 5% of phosphate ester starch, acrylate, ethylene glycol phenyl ether and water gross mass, and ethylene glycol phenyl ether quality is the 0.1 2% of phosphate ester starch, acrylate, ethylene glycol phenyl ether and water gross mass.In the mixing sizing of phosphate ester starch and solid propenoic acid ester with ethylene glycol phenyl ether is added in adhesive, the permeability of mixing sizing adhesive and the covering property of yam surface sizing adhesive can be obviously improved, so as to improve the effect of starching.
Description
Technical field
The present invention relates to a kind of method that utilization ethylene glycol phenyl ether improves sizing adhesive formula, belong to textile process skill
Art field.
Background technology
During weaving, warp thread can produce the reciprocating motion of 4000 times or so during warp beam to fell in the effect of heald frame.
In the process, the effect played as the adhesive of protection warp thread performance is increase strength, reduces filoplume etc..Textile process
The species of three conventional big adhesives of industry is：Starch, acrylic compounds and polyvinyl alcohol.The performance of adhesive is viscous to padding
The performance through yarn plays an important role after mixture.Therefore, in order to protect warp thread, warp thread is carried out to pad adhesive, adhesive is to warp
The protection of yarn is main in terms of two：One is that adhesive is impregnated with and enters yarn interior, and the cohesive force between increase fiber forms leaching
Permeable layers, improve the ultimate strength and elongation of warp thread；Two be that adhesive is coated in yam surface, coats filoplume, forms quilt
Coating, improves the wearability of warp thread.Such as Chinese public publication《Polymer material science and engineering》, at 2009 8 publication date
Month, article name is the texture and performance of phosphate ester starch/polyacrylate blending film, and the document is described by phosphorus
Acid esters starch is aided with polyacrylate slurry, to improve the pliability of serous coat, and its weak point is that only phosphate ester starch is aided with
Third polyene acid esters come improve it is flexible to warp yam surface serous coat when the pliability of serous coat is not still well positioned to meet weaving will
Ask, such as Chinese public publication《Cotton textile technology》, in November, 2010 publication date, article name is maleic anhydride esterification propylene
The research of acid esters grafting starch, the document describes one kind using the acrylic ester grafted starch of maleic anhydride esterification to improve
The flexible method of serous coat, its weak point is that this starch-grafted technological process is long, takes more, high energy consumption, such as Chinese patent
Publication number CN102329437A, publication date 2012 year 01 month 25 days, a kind of entitled degradable starch composite pulp of innovation and creation
Material, this application case discloses one kind using plant amylum, Ultra Tex 2, polyacrylic acid, starch and PVA compoundings
Slurry, although its weak point is the toughness increase so that serous coat, is unable to fast degradation, pollutes environment after PVA desizing.Such as
Chinese public publication《Cotton textile technology》, in July, 2012 publication date, article name is aqueous polyurethane to starch size
Modifying function, the document illustrates the addition aqueous polyurethane component in starch size, can improve adhesion strength, and improve serous coat
Mechanical property, its weak point for plus improvement of the aqueous polyurethane to size film property be not well positioned to meet warp sizing still
Condition.
The content of the invention
For above-mentioned problem, improve sizing using ethylene glycol phenyl ether it is an object of the invention to provide one kind and use viscous
The method of mixture prescription, to achieve these goals, its technical solution is：
A kind of method that utilization ethylene glycol phenyl ether improves sizing adhesive formula, including by phosphate ester starch, acrylic acid
Sizing adhesive formula and stir and heat through switching on power that ester and water component are constituted, heating temperature range is 95-100
DEG C, the time of heating is 1 hour, wherein including two steps：The first step is stirring, and the time of stirring is 20 minutes；Second step
It is insulation, the time of insulation is 40 minutes.Mixing speed scope is the 200-400 revs/min of sizing being made adhesive, described
Method refer to sizing in phosphate ester starch, acrylate and water with adding ethylene glycol phenyl ether in adhesive formula, wherein, phosphorus
Acid esters starch quality is the 3-5% of phosphate ester starch, acrylate, ethylene glycol phenyl ether and water gross mass, and acrylate quality is phosphorus
Acid esters starch, acrylate, the 3-5% of ethylene glycol phenyl ether and water gross mass, ethylene glycol phenyl ether quality is phosphate ester starch, propylene
The 0.1-2% of acid esters, ethylene glycol phenyl ether and water gross mass.
As a result of above technical scheme, there is hydroxyl with the ethylene glycol phenyl ether molecular structure added in adhesive in sizing
Base and ehter bond, good affinity is respectively provided with to phosphate ester starch and acrylate.Ehter bond and phosphoric acid in ethylene glycol phenyl ether
The hydroxyl of hydroxyl and phosphate ester starch in ester bond formation hydrogen bond in ester bond and acrylate in ester starch, ethylene glycol phenyl ether
Base can also form hydrogen bond.By ethylene glycol phenyl ether formation hydrogen bond the molecule of phosphate ester starch molecule and acrylate can be caused to exist
Preferably can mutually it be fused in solution, the membrane structure optimization of the liquid formation of adhesive, viscosity stabilization.Sizing adhesive exists
Distribution form on yarn is divided into two kinds, that is, is coated to being impregnated with, and the rate of being impregnated with shows that sizing adhesive enters yarn interior
Ability, covering rate reflects protective value of the sizing adhesive to yarn.Through the adhesive energy of the sizing after this PROCESS FOR TREATMENT
Enough to penetrate into well in yarn, yarn is impregnated with rate in increase sizing process, so that the cohesive force between adding fiber, is carried
The high strength and stretching property of guarantor of yarn.
Embodiment
A kind of method that utilization ethylene glycol phenyl ether improves sizing adhesive formula, including by phosphate ester starch, acrylic acid
Sizing adhesive formula and stir and heat through switching on power that ester and water component are constituted, heating temperature range is 95-100
DEG C, the time of heating is 1 hour, wherein including two steps：The first step is stirring, and the time of stirring is 20 minutes；Second step
It is insulation, the time of insulation is 40 minutes.Mixing speed scope is the 200-400 revs/min of sizing being made adhesive, described
Method refer to sizing in phosphate ester starch, acrylate and water with adding ethylene glycol phenyl ether in adhesive formula, wherein, phosphorus
Acid esters starch quality is the 3-5% of phosphate ester starch, acrylate, ethylene glycol phenyl ether and water gross mass, and acrylate quality is phosphorus
Acid esters starch, acrylate, the 3-5% of ethylene glycol phenyl ether and water gross mass, ethylene glycol phenyl ether quality is phosphate ester starch, propylene
The 0.1-2% of acid esters, ethylene glycol phenyl ether and water gross mass.
As stated above.
Embodiment 1
1L container bottoms are placed in electronics day chessboard precise 30g phosphate ester starches and 30g acrylate slurry of solids, together
When weigh 1g ethylene glycol phenyl ethereal solution add container, added water into container, make phosphate ester starch, acrylate, ethylene glycol phenyl
The gross weight of ether and water reaches 1kg, and solution is stirred, and container is placed in 100 DEG C of water-baths and heated, while using stirring
Device is stirred to the mixed liquor in container, and mixing speed is set as 300 revs/min, is stirred 20 minutes, when adhesive is pasted completely
After change, stop stirring, sealed container with film, continue mashing off 40 minutes in 95-100 DEG C of water-bath.It is prepared into and changes
Ready cotton rove, is wound on special sizing frame, the bonding that sizing frame is submerged by the sizing adhesive dealt with problems arising from an accident afterwards
Starching is carried out in agent, is taken out after 5 minutes, is placed in 80 DEG C of baking ovens and dries 30 minutes.
Embodiment 2
1L container bottoms are placed in electronics day chessboard precise 50g phosphate ester starches and 50g acrylate slurry of solids, together
When weigh 20g ethylene glycol phenyl ethereal solution add container, added water into container, make phosphate ester starch, acrylate, ethylene glycol phenyl
The gross weight of ether and water reaches 1kg, and solution is stirred, and container is placed in 100 DEG C of water-baths and heated, while using stirring
Device is stirred to the mixed liquor in container, and mixing speed is set as 300 revs/min, is stirred 20 minutes, when adhesive is pasted completely
After change, stop stirring, sealed container with film, continue mashing off 40 minutes in 95-100 DEG C of water-bath.It is prepared into and changes
Ready cotton rove, is wound on special sizing frame, the bonding that sizing frame is submerged by the sizing adhesive dealt with problems arising from an accident afterwards
Starching is carried out in agent, is taken out after 5 minutes, is placed in 80 DEG C of baking ovens and dries 30 minutes.
Embodiment 3
1L container bottoms are placed in electronics day chessboard precise 40g phosphate ester starches and 40g acrylate slurry of solids, together
When weigh 10g ethylene glycol phenyl ethereal solution add container, added water into container, make phosphate ester starch, acrylate, ethylene glycol phenyl
The gross weight of ether and water reaches 1kg, and solution is stirred, and container is placed in 100 DEG C of water-baths and heated, while using stirring
Device is stirred to the mixed liquor in container, and mixing speed is set as 300 revs/min, is stirred 20 minutes, when adhesive is pasted completely
After change, stop stirring, sealed container with film, continue mashing off 40 minutes in 95-100 DEG C of water-bath.It is prepared into and changes
Ready cotton rove, is wound on special sizing frame, the bonding that sizing frame is submerged by the sizing adhesive dealt with problems arising from an accident afterwards
Starching is carried out in agent, is taken out after 5 minutes, is placed in 80 DEG C of baking ovens and dries 30 minutes.
To contrast the technological merit of the technical program, with electronics day chessboard precise 40g phosphate ester starches and 40g acrylic acid
Ester slurry of solids is placed in 1L container bottoms, is added water into container, makes phosphate ester starch, and the gross weight of acrylate and water reaches
1kg, solution is stirred, and container is placed in 100 DEG C of water-baths and heated, while using agitator to the mixed liquor in container
It is stirred, mixing speed is set as 300 revs/min, stirs 20 minutes, after adhesive is gelatinized completely, stops stirring, use
Film seals container, continues mashing off 40 minutes in 95-100 DEG C of water-bath.Ready cotton rove is wound on spy afterwards
On the sizing frame of system, starching is carried out in the adhesive that sizing frame is submerged, is taken out after 5 minutes, is placed in 80 DEG C of baking ovens and dries 30
Minute.Obtained sample is as former state.The rove sample of embodiment 1, embodiment 2, embodiment 3 and former state is placed in constant temperature permanent
Lower 24 hours of wet environment, temperature is 20 DEG C, and humidity is 65%.Then tension failure test is carried out to sample, sample clamping distance is
5cm, draw speed is 50mm/min.Obtain data such as table 1：
The adhesion values and elongation of the starching rove sample of table 1
| Sample | Adhesion values/N | Elongation/% |
| As former state | 45.03±3.68 | 8.01±0.90 |
| Embodiment 1 | 59.56±4.68 | 8.99±0.39 |
| Embodiment 2 | 69.28±5.11 | 10.43±0.57 |
| Embodiment 3 | 65.95±6.02 | 9.70±0.42 |
Claims (1)
1. a kind of method that utilization ethylene glycol phenyl ether improves sizing adhesive formula, including by phosphate ester starch, acrylate
Stir and heat with the sizing adhesive formula of water component composition and through switching on power, heating temperature range is 95-100
DEG C, the time of heating is 1 hour, wherein including two steps：The first step is stirring, and the time of stirring is 20 minutes；Second step
It is insulation, the time of insulation is 40 minutes, and mixing speed is the 200-400 revs/min of sizing being made adhesive, and its feature exists
In：Described method refers to sizing in phosphate ester starch, acrylate and water with adding ethylene glycol phenyl ether in adhesive formula,
Wherein, phosphate ester starch quality is the 3-5% of phosphate ester starch, acrylate, ethylene glycol phenyl ether and water gross mass, acrylate
Quality is the 3-5% of phosphate ester starch, acrylate, ethylene glycol phenyl ether and water gross mass, and ethylene glycol phenyl ether quality is that phosphate forms sediment
Powder, acrylate, the 0.1-2% of ethylene glycol phenyl ether and water gross mass.
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| CN201510742897.XA CN105256566B (en) | 2015-11-04 | 2015-11-04 | A kind of method that utilization ethylene glycol phenyl ether improves sizing adhesive formula |
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| CN105256566B true CN105256566B (en) | 2017-08-08 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666336A (en) * | 2013-11-21 | 2014-03-26 | 江苏博思源防火材料科技有限公司 | Preparation method for adhesive |
| CN104928924A (en) * | 2015-06-29 | 2015-09-23 | 青岛麦科三维高新技术有限公司 | Starch textile size |
| CN104928927A (en) * | 2015-06-30 | 2015-09-23 | 青岛精石通精密机械制造有限公司 | Energy-saving environment-friendly modified starch size |
-
2015
- 2015-11-04 CN CN201510742897.XA patent/CN105256566B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666336A (en) * | 2013-11-21 | 2014-03-26 | 江苏博思源防火材料科技有限公司 | Preparation method for adhesive |
| CN104928924A (en) * | 2015-06-29 | 2015-09-23 | 青岛麦科三维高新技术有限公司 | Starch textile size |
| CN104928927A (en) * | 2015-06-30 | 2015-09-23 | 青岛精石通精密机械制造有限公司 | Energy-saving environment-friendly modified starch size |
Non-Patent Citations (2)
| Title |
|---|
| 磷酸酯淀粉/聚丙烯酸酯共混膜的织态结构与性能;乔志勇等;《高分子材料科学与工程》;20090831;第25卷(第8期);第72-75页 * |
| 聚丙稀酸酯乳液的开发与应用;关键等;《四川化工与腐蚀控制》;20001231;第3卷(第4期);第26-29页 * |
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