CN105256345A - Rustproof composite electroplating bath - Google Patents
Rustproof composite electroplating bath Download PDFInfo
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- CN105256345A CN105256345A CN201510657726.7A CN201510657726A CN105256345A CN 105256345 A CN105256345 A CN 105256345A CN 201510657726 A CN201510657726 A CN 201510657726A CN 105256345 A CN105256345 A CN 105256345A
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Abstract
The invention discloses a rustproof composite electroplating bath. The rustproof composite electroplating bath is prepared from, by weight, 500-550 parts of nickel aminosulfonate, 20-25 parts of cobaltous sulfate, 30-38 parts of nickel chloride, 30-35 parts of boric acid, 0.6-0.8 part of lauryl sodium sulfate, 0.3-0.6 part of sodium 1-undecanesulfonate, 4-6 parts of styrene, 0.2-0.3 part of azodiisobutyronitrile, 9-11 parts of titanium dioxide, 7-8 parts of bentonite, 2-3 parts of polyethylene glycol, 0.7-1 part of sodium carbonate, 3-5 parts of barium petroleum sulfonate, 0.3-0.5 part of AEO, 5-6 parts of glycine, and a proper amount of deionized water. The electroplating bath is good in stability; a nano plating layer obtained through the method is good in binding force, high in hardness, good in abrasion resistance, excellent in rustproof performance and worthy of popularization.
Description
Technical field
The present invention relates to electroplate liquid technical field, particularly relate to a kind of antirust composite plating solution.
Background technology
Scaffolding refers to that working-yard is the various supports that operative also solves vertically and horizontal transport is set up.The generic term on building circle, refers to construction site be used in the higher place that cannot directly construct of exterior wall, inside fitting or floor height, works up and down or perimeter security net is gone along with sb. to guard him and high-altitude installation component etc. mainly for workmen.Scaffolding makes material to be had usually: bamboo and wood, steel pipe or synthetic materials etc.Some engineering is also worked as template with scaffolding and is used, and the department such as this external advertising, municipal administration, traffic road and bridge, mine is also extensively used.The scaffolding of current tube material is more, common buildings engineering length consuming time, and scaffolding is outside exposed, run into severe weather to get rusty easily, corrode, in order to economize on resources, extend work-ing life of scaffolding, the performance of the aspect such as wear-resisting, anticorrosion, antirust can be reached by material surface modifying method.The composite deposite that wherein prepared by composite plating mode has become the effective means of wear-resisting erosion resistance.This kind of preparation method has the advantages such as cost is low, heat-resistant antifriction good, consumptive material is few.
Plating, also known as metal electrodeposition technology, is immerse workpiece containing in the solution for metal refining salt, and applies negative charge to workpiece, deposit the process of one deck and the compact metal of workpiece or alloy layer at workpiece surface.The ultimate principle of plating makes the metal ion in solution, on solution and plating piece interface, reduction reaction occur by various electric field action, generates atoms metal and be deposited on metallic surface to form coating.Composite plating, also known as dispersion plating, is to be dispersed in electroplate liquid by one or more insoluble solia particles by the method for metal electrodeposition carry out electroplating thus form special coating.Composite plating preparation method does not need High Temperature High Pressure when operating, and consumes the energy few, and equipment is simple, and cost is low, and processing condition are easy to control, so become the focus of electroplating technology research.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of antirust composite plating solution.
The present invention is achieved by the following technical solutions:
A kind of antirust composite plating solution, is made up of the raw material of following weight part: nickel sulfamic acid 500-550, rose vitriol 20-25, nickelous chloride 30-38, boric acid 30-35, sodium lauryl sulphate 0.6-0.8, undecyl sodium sulfonate 0.3-0.6, vinylbenzene 4-6, Diisopropyl azodicarboxylate 0.2-0.3, titanium dioxide 9-11, wilkinite 7-8, polyoxyethylene glycol 2-3, sodium carbonate 0.7-1, barium mahogany sulfonate 3-5, aliphatic alcohol polyethenoxy alcohol 0.3-0.5, glycine 5-6, deionized water are appropriate.
The antirust composite plating solution of described one, be made up of following concrete steps:
(1) by the deionized water dissolving of polyoxyethylene glycol by 5 times amount, then titanium dioxide ultrasonic disperse is added even, wilkinite and sodium carbonate are blended in constant temperature process 2-3h under 350-400 ° of C, the ultrasonic 20-25min of above-mentioned solution for continuous is added to after naturally cooling, filter, product deionized water is cleaned in neutral, then puts into air dry oven and dry, for subsequent use;
(2) a certain amount of aqueous ethanolic solution is added by the flask that mechanical stirring rod, reflux condensing tube, nitrogen protection and thermometer be housed, add product stirring 24-28h prepared by undecyl sodium sulfonate, vinylbenzene and step (1) again, add Diisopropyl azodicarboxylate again and be heated to 60-65 ° of C reaction 2-3h, then reaction mixture is put into ice-water bath and stop polymerization, filter, with ethanolic soln cleaning several, for subsequent use after vacuum-drying 4-5h;
(3) glycine is added in deionized water dissolves, then add nickel sulfamic acid, rose vitriol, nickelous chloride and sodium lauryl sulphate and be uniformly dissolved, be slowly heated to 45-60 ° of C, regulate pH value to 2-4 with ammoniacal liquor, obtain basic nickel plating bath for subsequent use;
(4) product prepared by step (2) is added in basic nickel plating solution prepared by step (3), then adds all the other remaining material ultrasonic agitation 30-40min, mechanical stirring 0.5-1h, leave standstill the particle of removing particle diameter >=5 μm, can composite plating solution be obtained.
The antirust composite plating solution of described one, the electroplating technology selected is: the time of plating is 35-45min, and the temperature of electroplate liquid is 45-60 ° of C, and current density is 2.3-3.4A/dm
2.
Advantage of the present invention is: the present invention adopts insulating material vinylbenzene to be coated on insoluble solid titanium dioxide and bentonitic surface, solve electrically conductive particles and adhere to the difficult problem that cathode surface makes surfaceness increase, prevent the tendency of easily reuniting between nanoparticle, and make coating have good solidity to corrosion, wear resistance and lower frictional coefficient, by bentonite modified process, add porosity and titanium dioxide composite ultraphonic, cohesiveness between the two can be improved, and give play to antirust, corrosion-resistant and increase bonding waits effect, this bath stability is good, adopt the nano-deposit bonding force obtained in this way good, hardness is high, wear resistance is good, particularly there is good rustless property, be worthy to be popularized.
Embodiment
A kind of antirust composite plating solution, is made up of the raw material of following weight part (kilogram): nickel sulfamic acid 500, rose vitriol 20, nickelous chloride 30, boric acid 30, sodium lauryl sulphate 0.6, undecyl sodium sulfonate 0.3, vinylbenzene 4, Diisopropyl azodicarboxylate 0.2, titanium dioxide 9, wilkinite 7, polyoxyethylene glycol 2, sodium carbonate 0.7, barium mahogany sulfonate 3, aliphatic alcohol polyethenoxy alcohol 0.3, glycine 5, deionized water are appropriate.
The antirust composite plating solution of described one, be made up of following concrete steps:
(1) by the deionized water dissolving of polyoxyethylene glycol by 5 times amount, then titanium dioxide ultrasonic disperse is added even, wilkinite and sodium carbonate are blended in constant temperature process 2h under 350 ° of C, the ultrasonic 20min of above-mentioned solution for continuous is added to after naturally cooling, filter, product deionized water is cleaned in neutral, then puts into air dry oven and dry, for subsequent use;
(2) a certain amount of aqueous ethanolic solution is added by the flask that mechanical stirring rod, reflux condensing tube, nitrogen protection and thermometer be housed, add product stirring 24h prepared by undecyl sodium sulfonate, vinylbenzene and step (1) again, add Diisopropyl azodicarboxylate again and be heated to 60 ° of C reaction 2h, then reaction mixture is put into ice-water bath and stop polymerization, filter, with ethanolic soln cleaning several, for subsequent use after vacuum-drying 4h;
(3) glycine is added in deionized water dissolves, then add nickel sulfamic acid, rose vitriol, nickelous chloride and sodium lauryl sulphate and be uniformly dissolved, be slowly heated to 45 ° of C, regulate pH value to 2 with ammoniacal liquor, obtain basic nickel plating bath for subsequent use;
(4) product prepared by step (2) is added in basic nickel plating solution prepared by step (3), then adds all the other remaining material ultrasonic agitation 30min, mechanical stirring 0.5h, leave standstill the particle of removing particle diameter >=5 μm, can composite plating solution be obtained.
The antirust composite plating solution of described one, the electroplating technology selected is: the time of plating is 35min, and the temperature of electroplate liquid is 45 ° of C, and current density is 2.3A/dm
2.
Plating piece is carried out plate last series of processes and enter plating tank, nickel anode plating front surface activation treatment, carry out electroplating processes according to the electroplate liquid of preparation afterwards, carry out performance test to plated film, result is as follows:
Abrasion loss (10-3mm
3): 9, porosity (individual/cm
2): 0.9, bonding force: do not peel off, salt fog (120 hours): without considerable change.
Claims (3)
1. an antirust composite plating solution, it is characterized in that, be made up of the raw material of following weight part: nickel sulfamic acid 500-550, rose vitriol 20-25, nickelous chloride 30-38, boric acid 30-35, sodium lauryl sulphate 0.6-0.8, undecyl sodium sulfonate 0.3-0.6, vinylbenzene 4-6, Diisopropyl azodicarboxylate 0.2-0.3, titanium dioxide 9-11, wilkinite 7-8, polyoxyethylene glycol 2-3, sodium carbonate 0.7-1, barium mahogany sulfonate 3-5, aliphatic alcohol polyethenoxy alcohol 0.3-0.5, glycine 5-6, deionized water are appropriate.
2. a kind of antirust composite plating solution according to claim 1, is characterized in that, be made up of following concrete steps:
(1) by the deionized water dissolving of polyoxyethylene glycol by 5 times amount, then titanium dioxide ultrasonic disperse is added even, wilkinite and sodium carbonate are blended in constant temperature process 2-3h under 350-400 ° of C, the ultrasonic 20-25min of above-mentioned solution for continuous is added to after naturally cooling, filter, product deionized water is cleaned in neutral, then puts into air dry oven and dry, for subsequent use;
(2) a certain amount of aqueous ethanolic solution is added by the flask that mechanical stirring rod, reflux condensing tube, nitrogen protection and thermometer be housed, add product stirring 24-28h prepared by undecyl sodium sulfonate, vinylbenzene and step (1) again, add Diisopropyl azodicarboxylate again and be heated to 60-65 ° of C reaction 2-3h, then reaction mixture is put into ice-water bath and stop polymerization, filter, with ethanolic soln cleaning several, for subsequent use after vacuum-drying 4-5h;
(3) glycine is added in deionized water dissolves, then add nickel sulfamic acid, rose vitriol, nickelous chloride and sodium lauryl sulphate and be uniformly dissolved, be slowly heated to 45-60 ° of C, regulate pH value to 2-4 with ammoniacal liquor, obtain basic nickel plating bath for subsequent use;
(4) product prepared by step (2) is added in basic nickel plating solution prepared by step (3), then adds all the other remaining material ultrasonic agitation 30-40min, mechanical stirring 0.5-1h, leave standstill the particle of removing particle diameter >=5 μm, can composite plating solution be obtained.
3. a kind of antirust composite plating solution according to claim 1-2, it is characterized in that, the electroplating technology selected is: the time of plating is 35-45min, and the temperature of electroplate liquid is 45-60 ° of C, and current density is 2.3-3.4A/dm
2.
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| CN201510657726.7A CN105256345A (en) | 2015-10-10 | 2015-10-10 | Rustproof composite electroplating bath |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109183085A (en) * | 2018-08-16 | 2019-01-11 | 张家港市东威新材料技术开发有限公司 | A kind of preparation method of nickel-titania coextruded film |
| CN109423668A (en) * | 2017-09-01 | 2019-03-05 | 泉州市同兴反光材料有限公司 | A kind of four square plate process flows making reflecting mould |
| CN109423669A (en) * | 2017-09-01 | 2019-03-05 | 泉州市同兴反光材料有限公司 | A kind of circular slab process flow making reflecting mould |
| CN114808048A (en) * | 2021-05-31 | 2022-07-29 | 上海亿尚金属有限公司 | Chemical nickel electroplating solution and electroplating process thereof |
| CN116065217A (en) * | 2022-12-26 | 2023-05-05 | 吉姆西半导体科技（无锡）有限公司 | Preparation method of polishing pad finisher for CMP and polishing pad modulator |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5481129A (en) * | 1977-12-13 | 1979-06-28 | Matsushita Electric Ind Co Ltd | Composite plating method |
| CN1500916A (en) * | 2002-11-19 | 2004-06-02 | 宝山钢铁股份有限公司 | Gradient composite deposite for continuous casting crystallizer copper plate and production method thereof |
| CN1683600A (en) * | 2005-02-24 | 2005-10-19 | 上海交通大学 | Composite electroforming preparing process for nano silicon carbide particle reinforced nickel base composite material |
| CN1796609A (en) * | 2004-12-23 | 2006-07-05 | 襄樊化通化工有限责任公司 | Technique for plating alnico in copper plate type of crystallizer of conticaster |
| CN102286769A (en) * | 2011-06-10 | 2011-12-21 | 沈阳理工大学 | Preparation method of new self-lubricating wear-resistant carbon microsphere-nickel composite coating |
| CN102773434A (en) * | 2012-08-01 | 2012-11-14 | 西峡龙成特种材料有限公司 | Nanocomposite electroplating layer copper plate of continuous casting crystallizer and preparation process of nanocomposite electroplating layer copper plate |
| CN103014819A (en) * | 2011-09-27 | 2013-04-03 | 肖云捷 | Wearable compound layer material for machine parts and manufacturing method and equipment thereof |
| CN103193916A (en) * | 2013-04-02 | 2013-07-10 | 复旦大学 | Preparation method of polymeric microspheres for electrophoretic display |
| CN103806077A (en) * | 2012-11-12 | 2014-05-21 | 无锡三洲冷轧硅钢有限公司 | Method of preparing super-hydrophobic alloy membrane through composite electroplating by utilizing modified asphalt and perfluororesin |
| CN104562107A (en) * | 2014-12-23 | 2015-04-29 | 佛山科学技术学院 | Highly-corrosion-resistant environment-friendly black tin-cobalt alloy electroplating liquid and electroplating method thereof. |
-
2015
- 2015-10-10 CN CN201510657726.7A patent/CN105256345A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5481129A (en) * | 1977-12-13 | 1979-06-28 | Matsushita Electric Ind Co Ltd | Composite plating method |
| CN1500916A (en) * | 2002-11-19 | 2004-06-02 | 宝山钢铁股份有限公司 | Gradient composite deposite for continuous casting crystallizer copper plate and production method thereof |
| CN1796609A (en) * | 2004-12-23 | 2006-07-05 | 襄樊化通化工有限责任公司 | Technique for plating alnico in copper plate type of crystallizer of conticaster |
| CN1683600A (en) * | 2005-02-24 | 2005-10-19 | 上海交通大学 | Composite electroforming preparing process for nano silicon carbide particle reinforced nickel base composite material |
| CN102286769A (en) * | 2011-06-10 | 2011-12-21 | 沈阳理工大学 | Preparation method of new self-lubricating wear-resistant carbon microsphere-nickel composite coating |
| CN103014819A (en) * | 2011-09-27 | 2013-04-03 | 肖云捷 | Wearable compound layer material for machine parts and manufacturing method and equipment thereof |
| CN102773434A (en) * | 2012-08-01 | 2012-11-14 | 西峡龙成特种材料有限公司 | Nanocomposite electroplating layer copper plate of continuous casting crystallizer and preparation process of nanocomposite electroplating layer copper plate |
| CN103806077A (en) * | 2012-11-12 | 2014-05-21 | 无锡三洲冷轧硅钢有限公司 | Method of preparing super-hydrophobic alloy membrane through composite electroplating by utilizing modified asphalt and perfluororesin |
| CN103193916A (en) * | 2013-04-02 | 2013-07-10 | 复旦大学 | Preparation method of polymeric microspheres for electrophoretic display |
| CN104562107A (en) * | 2014-12-23 | 2015-04-29 | 佛山科学技术学院 | Highly-corrosion-resistant environment-friendly black tin-cobalt alloy electroplating liquid and electroplating method thereof. |
Non-Patent Citations (2)
| Title |
|---|
| 张允诚等: "《电镀手册》", 31 January 2007, 国防工业出版社 * |
| 彭大署: "《金属塑性加工原理》", 30 April 2014, 中南大学出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109423668A (en) * | 2017-09-01 | 2019-03-05 | 泉州市同兴反光材料有限公司 | A kind of four square plate process flows making reflecting mould |
| CN109423669A (en) * | 2017-09-01 | 2019-03-05 | 泉州市同兴反光材料有限公司 | A kind of circular slab process flow making reflecting mould |
| CN109183085A (en) * | 2018-08-16 | 2019-01-11 | 张家港市东威新材料技术开发有限公司 | A kind of preparation method of nickel-titania coextruded film |
| CN114808048A (en) * | 2021-05-31 | 2022-07-29 | 上海亿尚金属有限公司 | Chemical nickel electroplating solution and electroplating process thereof |
| CN114808048B (en) * | 2021-05-31 | 2024-04-30 | 上海亿尚金属有限公司 | Electroless nickel plating solution and plating process thereof |
| CN116065217A (en) * | 2022-12-26 | 2023-05-05 | 吉姆西半导体科技（无锡）有限公司 | Preparation method of polishing pad finisher for CMP and polishing pad modulator |
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