CN105255274A - Water-based environment-friendly metallic paint and preparing method thereof - Google Patents
Water-based environment-friendly metallic paint and preparing method thereof Download PDFInfo
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- CN105255274A CN105255274A CN201510859622.4A CN201510859622A CN105255274A CN 105255274 A CN105255274 A CN 105255274A CN 201510859622 A CN201510859622 A CN 201510859622A CN 105255274 A CN105255274 A CN 105255274A
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Abstract
The invention provides water-based environment-friendly metallic paint and a preparing method thereof. The water-based environment-friendly metallic paint is mainly prepared from, by mass, 50-70 parts of perfluorocarbon emulsion, 10-20 parts of coalescing agent, 1-3 parts of propylene glycol, 0.4-0.7 part of nanometer silver oxide, 8-10 parts of waterborne type aluminum paste, 10-16 parts of water, 0.2-0.5 part of PH regulator and normal additives. The preparing method comprises the steps of A, soaking waterborne type aluminum paste in water for a while to obtain a waterborne type aluminum paste solution for use; B, evenly mixing and stirring other raw materials and the waterborne type aluminum paste solution, and adjusting viscosity to obtain the water-based environment-friendly metallic paint. The water-based environment-friendly metallic paint has the advantages of being high in weather resistance and antifouling property, short in surface drying time, capable of facilitating construction, free of APEO, environmentally friendly, low in VOC content and excellent in mould resistance.
Description
Technical field
The present invention relates to paint field, in particular to a kind of aqueous, environmental protective metallic paint and preparation method thereof.
Background technology
The development of water-borne coatings is along with the continuous propelling of industrialization, urbanization process, and environmental quality has more and more important impact to people's physical and mental health, and thus environmental quality receives increasing concern.Aqueous, environmental protective metallic paint has that hardness is high, damage resistant, strong adhesion; the feature of salt spray resistance, acid and alkali-resistance, water-fast, oil resistant, ultraviolet light, ageing-resistant, anti-low temperature, wet-heat resisting; it take water as thinner; nonpoisonous and tasteless, pollution-free, without the three wastes; do not fire not quick-fried, ensure that environment protection and security against fire, ensured that laborer's is healthy; therefore be widely used in every field, especially external wall of building field.
Application number is disclose a kind of fluorine-containing aqueous metallic paint and preparation method thereof in the patent of 200810183406.2, be made up of the raw material of following parts by weight: fluorine-containing and acrylic monomer are through emulsion 35-60 part of letex polymerization, deionized water 20-35 part, aqueous dispersant 0.2-0.6 part, water-based solubility promoter 4-8 part, water-based metal powder 5-9 part, propylene glycol 0.5-3 part, defoamer 0.02-0.08 part, sanitas 0.02-0.1 part, mould inhibitor 0.02-0.1 part, PH conditioning agent 0.1-0.5 part, water-based thickener 0.5-1.5 part.The preparation method of this fluorine-containing aqueous metallic paint is: added successively in container by each raw material, and in temperature 20-50 DEG C of stirring, adjusting viscosity and pH value, filter and package.Obtained fluorine-containing aqueous metallic paint can direct spraying, and add water construction, resistant and good weatherability, and tint retention lastingly, but owing to it using more water-based solubility promoter, causes VOC content higher.
In view of this, special proposition the present invention.
Summary of the invention
The first object of the present invention is to provide a kind of aqueous, environmental protective metallic paint, described aqueous, environmental protective metallic paint solves the technical problem of above appearance, there is weather resistance and antifouling property is strong, surface drying time is short, and easy construction and not containing alkylphenol polyoxyethylene compounds (APEO), environmentally friendly, there is lower VOC, the advantages such as fungus resistance energy is excellent.
The second object of the present invention is the preparation method providing a kind of described aqueous, environmental protective metallic paint, and it is simple, easy to operate that the method has preparation method, can well retain the advantages such as the effective constituent of each raw material.
In order to realize above-mentioned purpose of the present invention, spy by the following technical solutions:
Embodiments provide a kind of aqueous, environmental protective metallic paint, obtain primarily of following raw material: in mass fraction, fluorine carbon emulsion 50-70 part, film coalescence aid 10-20 part, propylene glycol 1-3 part, nano phase ag_2 o 0.4-0.7 part, water aluminum-silver slurry 8-10 part, water 10-16 part, PH conditioning agent 0.2-0.5 part and conventional additives.
In prior art, a large amount of water-based solubility promoters is employed when preparing aqueous metallic paint, conventional water-based solubility promoter comprises water miscible DPM, DEB, PM or EB solvent, but these amount of solvent conferences cause the VOC of paint vehicle higher, fungus resistance can be deteriorated, therefore in order to solve above technical problem, the invention provides a kind of aqueous, environmental protective metallic paint, in its raw material except normally adding a small amount of propylene glycol, no longer additionally add other water-based solubility promoters, energy-conserving and environment-protective.
In the present invention, the major ingredient of painting is fluorine carbon emulsion, and dosage is 50-70 part, it can also be 60,62 or 65 parts etc., this emulsion has 3-5 times that fabulous resistance to soiling, super-weathering resistance, chemical resistance are then ordinary emulsion, and after film forming, transparency is high, and nontoxic.Film coalescence aid has the characteristic that can promote macromolecular compound plastic flow and recoverable deformation, can improve coalescent performance, and selected film coalescence aid is preferably 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, and this auxiliary agent film-formation result is good.Nano phase ag_2 o has the effect improving anti-microbial property and well suppress cooperating microorganisms, and its add-on controls between 0.4-0.7 part, and unsuitable dosage is excessive, can have influence on resistance to soiling, super-weathering resistance, the chemical resistance of finished product paint own.The potential of hydrogen of the adjustable paint vehicle of PH conditioning agent, because the stability that alkali all can have influence on itself crossed by paint vehicle peracid, 2-methyl-2-hydroxyl-1-propyl alcohol preferably selected by PH conditioning agent.Noticeablely to be, water aluminum-silver slurry 8-10 part is included in raw material of the present invention, water 10-16 part, the proportioning GPRS of water and water aluminum-silver slurry is good, under this suitable proportioning, final finished paint surface flatness is high, fine and smooth and have stronger metal effect, and have heat resistanceheat resistant acid resistance, opacifying power is also stronger.In order to improve the uniformity coefficient of obtained finished product paint vehicle, when selecting water aluminum-silver slurry, granularity control is below 20 μm for they, more excellent, between 20-25 μm.
Further, aqueous, environmental protective metallic paint obtains primarily of following raw material: in mass fraction, fluorine carbon emulsion 55-65 part, film coalescence aid 15-18 part, propylene glycol 1-2 part, nano phase ag_2 o 0.5-0.6 part, water aluminum-silver slurry 8-9 part, water 10-15 part, PH conditioning agent 0.2-0.4 part and conventional additives.
Need being of explanation, proportioning raw materials of the present invention is all contriver's more excellent consumptions by a large amount of creative experiments optimizations, the aqueous, environmental protective metallic paint that only guarantee is prepared under these raw materials of interpolation and this proportioning raw materials prerequisite has excellent properties, the general proportioning raw materials of aqueous metallic paint of the prior art is unreasonable, be unfavorable for that the raw material addition of environmental protection is excessive on the contrary, the raw material that can improve paint vehicle performance does not but add, the present invention combines all technical problems in prior art, strictly control the addition of each raw material, and in order to improve the performance of paint vehicle, a large amount of experiments be have also been made to the screening of raw material type, make it more reasonable.
In addition, the present invention has carried out the selection of kind and consumption to conventional additives used, preferably includes following component: in mass fraction, wetting agent 0.15-0.35 part, sanitas 0.15-0.35 part, thickening material 0.8-1.8 part, flow agent 0.5-0.9 part, defoamer 0.3-0.5 part.
Wherein, thickening material is the swelling vinylformic acid of alkali, urethane or both mixtures; Be preferably both mixtures, in mass fraction, alkali swelling acrylic thickener 0.5-1 part, all the other are polyurethane thickener, and described defoamer is silicone antifoam agent, and described wetting agent is alkyl polyoxyethylene ether, described sanitas is BIT.
The Main Function of wetting agent is the surface tension or the interfacial tension that reduce water, make solid surface energy soak by water, better merge mutually between each raw material, flow agent can make coating in the process of drying and forming-film, form smooth, a smooth and uniform film, sanitas can play the effect postponing the corruption that microorganism growth and chemical transformation cause, and preferably selects BIT, this sanitas environmental protection, little to harm.Defoamer can reduce the surface tension of each raw material, thus reach suppress foam produce effect, select silicone antifoam agent low price and also defoaming effect good.Finally, thickening material can increase the viscosity of product, reach desirable viscosity, the thickening material selected by the present invention is mainly two kinds of water miscible high-environmental type materials, the swelling acrylic thickener of alkali and polyurethane thickener, and concrete addition preferably controls in suitable scope, because easy to use when paint vehicle is in suitable range of viscosities, not easily drip and be easily coated with flat, without turn-ups, therefore adding proportion is also an important index, directly has influence on the performance of finished product paint.
Present invention also offers a kind of preparation method of aqueous, environmental protective metallic paint, comprise the steps:
(A) water aluminum-silver slurry liquid is obtained after first described water aluminum-silver slurry being soaked for some time in described water, for subsequent use;
(B) by all the other raw materials and water aluminum-silver slurry liquid mixing and stirring, and after adjusting viscosity, to obtain final product.
The preparation method of the aqueous, environmental protective metallic paint that the embodiment of the present invention provides is simple, easy to operate, effective constituent in each raw material of reservation that can be complete, more crucial operation steps is first to soak water aluminum-silver slurry to make it disperse fully, so that fully mix with other raw materials, the time of soaking preferably controls between 1-2h, overlong time can extend the whole technological operation cycle virtually, and the time is too short can not make water aluminum-silver slurry fully disperse again.
Further, preferably provide tandem in the process of each raw materials to add successively, therefore in described step (B), first add fluorine carbon emulsion successively, film coalescence aid, defoamer, PH conditioning agent, propylene glycol, after wetting agent and sanitas stir, add nano phase ag_2 o high-speed stirring again, finally add after thickening material, flow agent and water aluminum-silver slurry liquid stirs successively, adjustment viscosity and get final product.More excellent, in described step (B), last adding successively after thickening material, flow agent and water aluminum-silver slurry liquid stir adjusts in the step of viscosity, first add polyurethane thickener, flow agent and water aluminum-silver slurry liquid to stir, then add alkali swelling acrylic thickener adjustment viscosity.Preferably adding the swelling acrylic thickener of alkali is to adjust viscosity, and it is proper that general viscosity is adjusted to 100 ± 3KU.The restriction of order of addition is similar according to Nature comparison, the reason that the component being easy to merge mutually is added together, thus has put into practice out preferably raw material order of addition.
In addition, the speed at every turn adding raw material stirring is slightly different, and first add fluorine carbon emulsion successively, film coalescence aid, defoamer, PH conditioning agent, propylene glycol, the stir speed (S.S.) that wetting agent and sanitas stir controls at 100-200rad/min; Preferably, then add nano phase ag_2 o stir stir speed (S.S.) control at 300-400rad/min; Last add the stir speed (S.S.) that polyurethane thickener, flow agent and water aluminum-silver slurry liquid stirs successively and control at 200-300rad/min.Early stage, stir speed (S.S.) was slow add nano phase ag_2 o after then need high-speed stirring could by more even for its ratio of mixture, after stirring for some time, the later stage turns down speed again after other raw materials of interpolation, the different in kind that such basis often plants raw material arranges velocity gradient, whole technical process more rationally and achieve stdn, easy manipulation, the product performance obtained are better.
Compared with prior art, beneficial effect of the present invention is:
(1) a kind of aqueous, environmental protective metallic paint is embodiments provided, this aqueous, environmental protective metallic paint has weather resistance and antifouling property is strong, surface drying time is short, and easy construction and not containing alkylphenol polyoxyethylene compounds (APEO), environmentally friendly, have lower VOC, fungus resistance can be excellent;
(2) embodiment of the present invention is selected by specific raw material and proportioning, the aqueous, environmental protective metallic paint obtained has good pollution resistance, super-weathering resistance, chemical resistance, finished product paint surface flatness is high, fine and smooth and have stronger metal effect, and there is heat resistanceheat resistant acid resistance, opacifying power is also stronger, applied widely, meet the demand of different crowd;
(3) embodiment of the present invention additionally provides a kind of preparation method of aqueous, environmental protective metallic paint, method is simple, easy to operate, effective constituent in each raw material of reservation that can be complete, preferably raw material order of addition has been put into practice out by raw material nature difference, to also have in each step preferably stir speed (S.S.), more rationally and achieve stdn, easily manipulate, the product performance obtained are better in whole technical process.
(4) aqueous, environmental protective metallic paint of the present invention is short for time of drying, easily constructs, and raw material used is all bought by market, and raw material is easy to get.
Embodiment
Below in conjunction with embodiment, embodiment of the present invention are described in detail, but it will be understood to those of skill in the art that the following example only for illustration of the present invention, and should not be considered as limiting the scope of the invention.Unreceipted actual conditions person in embodiment, the condition of conveniently conditioned disjunction manufacturers suggestion is carried out.Agents useful for same or the unreceipted production firm person of instrument, be and can buy by commercially available the conventional products obtained.
Embodiment 1
The composition of raw materials of aqueous, environmental protective metallic paint is as follows:
The preparation method of aqueous, environmental protective metallic paint is as follows:
1) first water aluminum-silver slurry 8kg and water 16kg are mixed in a reservoir rear more than the 2h that soaks and form water aluminum-silver slurry liquid, for subsequent use;
2) all the other raw materials and water aluminum-silver slurry liquid are put into whipping appts, after carrying out mixing and stirring, adjustment viscosity to 100 ± 3KU, carries out finished product packing, can form sale.
Embodiment 2
The composition of raw materials of aqueous, environmental protective metallic paint is as follows:
The preparation method of aqueous, environmental protective metallic paint is as follows:
1) soak 1h after first being mixed in a reservoir with water 10kg by the water aluminum-silver slurry 10kg of granularity below 20 μm and form water aluminum-silver slurry liquid, for subsequent use;
2) by fluorine carbon emulsion, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate, silicone antifoam agent, 2-methyl-2-hydroxyl-1-propyl alcohol, propylene glycol, alkyl polyoxyethylene ether and 1, 2-benzisothiazole-3-ketone puts into whipping appts, after carrying out mixing and stirring under the speed of 100rad/min, add nano phase ag_2 o again to stir under the speed of 300rad/min, finally add polyacrylic acid, the swelling vinylformic acid of alkali and water aluminum-silver slurry liquid stir under the speed of 300rad/min, and adjust viscosity to 100 ± 3KU, carry out finished product packing, sale can be formed.
Embodiment 3
The composition of raw materials of aqueous, environmental protective metallic paint is as follows:
The preparation method of aqueous, environmental protective metallic paint is as follows:
1) soak 2h after first being mixed in a reservoir with water 15kg by the water aluminum-silver slurry 9kg of granularity between 20-25 μm and form water aluminum-silver slurry liquid, for subsequent use;
2) by fluorine carbon emulsion, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate, silicone antifoam agent, 2-methyl-2-hydroxyl-1-propyl alcohol, propylene glycol, alkyl polyoxyethylene ether and 1, 2-benzisothiazole-3-ketone puts into whipping appts, after carrying out mixing and stirring under the speed of 200rad/min, add nano phase ag_2 o again to stir under the speed of 400rad/min, finally add polyacrylic acid, urethane and water aluminum-silver slurry liquid stir under the speed of 200rad/min, and add alkali swelling acrylic thickener adjustment viscosity to 100 ± 3KU, carry out finished product packing, sale can be formed.
Embodiment 4
The composition of raw materials of aqueous, environmental protective metallic paint is as follows:
The preparation method of aqueous, environmental protective metallic paint is as follows:
1) soak 2h after first being mixed in a reservoir with water 13kg by the water aluminum-silver slurry 9.5kg of granularity between 20-25 μm and form water aluminum-silver slurry liquid, for subsequent use;
2) by fluorine carbon emulsion, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate, silicone antifoam agent, 2-methyl-2-hydroxyl-1-propyl alcohol, propylene glycol, alkyl polyoxyethylene ether and 1, 2-benzisothiazole-3-ketone puts into whipping appts, after carrying out mixing and stirring under the speed of 150rad/min, add nano phase ag_2 o again to stir under the speed of 350rad/min, finally add polyacrylic acid, urethane and water aluminum-silver slurry liquid stir under the speed of 250rad/min, and add alkali swelling acrylic thickener adjustment viscosity to 100 ± 3KU, carry out finished product packing, sale can be formed.
Experimental example 1
In the GB/T9755-2001 exterior wall coating material of synthetic resin emulsion national standard of employing shown in following table, GB24408-2009 exterior coating for building, the method for limits of harmful substances national standard and GB/T1741-2007 paint film fungus resistance assay method national Specification detects aqueous, environmental protective metallic paint prepared by the present embodiment 1-4, and using application number be the fluorine-containing aqueous metallic paint for preparing of the embodiment 1 in the patent of 200810183406.2 as comparative example 1, properties is as shown in table 1:
The performance of aqueous, environmental protective metallic paint prepared by table 1 embodiment 1
As can be seen from upper table 1, the embodiment of the present invention can produce special flash of light metal effect, reach the surface effect general with aluminium-plastic panel, as shown in table 1, surface drying time is short, easy construction, there is good weather resistance and antifouling property, and not lower containing APEO, VOC, germ resistance, fungus resistance can be excellent.
The raw material of various embodiments of the present invention is all by commercially available acquisition, as the fluorine carbon emulsion 4311B of Changxing, Taiwan chemical company, the nano phase ag_2 o JMACLP10 of Clariant chemical industry, the alkyl polyoxyethylene ether LCN407 of Ke Laien, the Liquid BPF IPACIDEBIT20 of Ke Laien, the polyurethane thickener RM-8W of ROHM AND HAAS, the flow agent 2020 of ROHM AND HAAS, the swelling acrylic thickener TT-935 of alkali of ROHM AND HAAS, the aluminium-silver slurry BK600 of your water aluminum-silver slurry company limited of Bake, the silicone antifoam agent SN-154 of NOPOC.
Although illustrate and describe the present invention with specific embodiment, however it will be appreciated that can to make when not deviating from the spirit and scope of the present invention many other change and amendment.Therefore, this means to comprise all such changes and modifications belonged in the scope of the invention in the following claims.
Claims (10)
1. an aqueous, environmental protective metallic paint, it is characterized in that, obtain primarily of following raw material: in mass fraction, fluorine carbon emulsion 50-70 part, film coalescence aid 10-20 part, propylene glycol 1-3 part, nano phase ag_2 o 0.4-0.7 part, water aluminum-silver slurry 8-10 part, water 10-16 part, PH conditioning agent 0.2-0.5 part and conventional additives.
2. aqueous, environmental protective metallic paint according to claim 1, it is characterized in that, obtain primarily of following raw material: in mass fraction, fluorine carbon emulsion 55-65 part, film coalescence aid 15-18 part, propylene glycol 1-2 part, nano phase ag_2 o 0.5-0.6 part, water aluminum-silver slurry 8-9 part, water 10-15 part, PH conditioning agent 0.2-0.4 part and conventional additives.
3. a kind of aqueous, environmental protective metallic paint according to claim 1 and 2, it is characterized in that, described conventional additives comprises following component: in mass fraction, wetting agent 0.15-0.35 part, sanitas 0.15-0.35 part, thickening material 0.8-1.8 part, flow agent 0.5-0.9 part, defoamer 0.3-0.5 part.
4. a kind of aqueous, environmental protective metallic paint according to claim 3, is characterized in that, described thickening material is the swelling vinylformic acid of alkali, urethane or both mixtures; Be preferably both mixtures, in mass fraction, alkali swelling acrylic thickener 0.5-1 part, all the other are polyurethane thickener.
5. a kind of aqueous, environmental protective metallic paint according to claim 3, it is characterized in that, described film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, described defoamer is silicone antifoam agent, and described PH conditioning agent is 2-methyl-2-hydroxyl-1-propyl alcohol, and described wetting agent is alkyl polyoxyethylene ether, described sanitas is BIT;
Preferably, the granularity of described water aluminum-silver slurry is below 20 μm; The granularity of described water aluminum-silver slurry is more preferably between 20-25 μm.
6. the preparation method of a kind of aqueous, environmental protective metallic paint described in any one of claim 1-5, is characterized in that, comprise the steps:
(A) water aluminum-silver slurry liquid is obtained after first described water aluminum-silver slurry being soaked for some time in described water, for subsequent use;
(B) by all the other raw materials and water aluminum-silver slurry liquid mixing and stirring, and after adjusting viscosity, to obtain final product.
7. the preparation method of a kind of aqueous, environmental protective metallic paint according to claim 6, is characterized in that, in described step (A), soak time is 1-2h.
8. the preparation method of a kind of aqueous, environmental protective metallic paint according to claim 6, it is characterized in that, in described step (B), first add fluorine carbon emulsion successively, film coalescence aid, defoamer, PH conditioning agent, propylene glycol, after wetting agent and sanitas stir, add nano phase ag_2 o again to stir, finally add after thickening material, flow agent and water aluminum-silver slurry liquid stirs successively, adjustment viscosity and get final product.
9. the preparation method of a kind of aqueous, environmental protective metallic paint according to claim 8, it is characterized in that, in described step (B), last adding successively after thickening material, flow agent and water aluminum-silver slurry liquid stir adjusts in the step of viscosity, first add polyurethane thickener, flow agent and water aluminum-silver slurry liquid to stir, then add alkali swelling acrylic thickener adjustment viscosity.
10. the preparation method of a kind of aqueous, environmental protective metallic paint according to claim 9, it is characterized in that, in described step (B), first add fluorine carbon emulsion successively, film coalescence aid, defoamer, PH conditioning agent, propylene glycol, the stir speed (S.S.) that wetting agent and sanitas stir controls at 100-200rad/min; Preferably, then the stir speed (S.S.) adding nano phase ag_2 o high-speed stirring control at 300-400rad/min; Last add the stir speed (S.S.) that polyurethane thickener, flow agent and water aluminum-silver slurry liquid stirs successively and control at 200-300rad/min.
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| CN201510859622.4A CN105255274A (en) | 2015-11-30 | 2015-11-30 | Water-based environment-friendly metallic paint and preparing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112795246A (en) * | 2021-01-15 | 2021-05-14 | 湖州和悦新材料科技股份有限公司 | Water-based fluorocarbon outdoor paint and preparation method thereof |
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| CN101117484A (en) * | 2007-08-28 | 2008-02-06 | 深圳市广田环保涂料有限公司 | Metal-pseudo fluorine-carbon paint for building exterior wall and method for making same |
| CN101717600A (en) * | 2009-12-23 | 2010-06-02 | 山西北辰涂料有限公司 | Single-component aqueous fluorocarbon paint and preparation method thereof |
| CN102002288A (en) * | 2010-10-15 | 2011-04-06 | 上海富臣化工有限公司 | Water-based environment friendly metallic paint and preparation method thereof |
| CN104497734A (en) * | 2014-12-15 | 2015-04-08 | 青岛益群漆业集团有限公司 | Extra-weather-resistant environment-friendly metallic paint |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101117484A (en) * | 2007-08-28 | 2008-02-06 | 深圳市广田环保涂料有限公司 | Metal-pseudo fluorine-carbon paint for building exterior wall and method for making same |
| CN101717600A (en) * | 2009-12-23 | 2010-06-02 | 山西北辰涂料有限公司 | Single-component aqueous fluorocarbon paint and preparation method thereof |
| CN102002288A (en) * | 2010-10-15 | 2011-04-06 | 上海富臣化工有限公司 | Water-based environment friendly metallic paint and preparation method thereof |
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