CN105254266A - Method for preparing diatom ooze building and ornament material - Google Patents
Method for preparing diatom ooze building and ornament material Download PDFInfo
- Publication number
- CN105254266A CN105254266A CN201510656089.1A CN201510656089A CN105254266A CN 105254266 A CN105254266 A CN 105254266A CN 201510656089 A CN201510656089 A CN 201510656089A CN 105254266 A CN105254266 A CN 105254266A
- Authority
- CN
- China
- Prior art keywords
- solution
- diatom ooze
- building
- tetra
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 239000011701 zinc Substances 0.000 claims abstract description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 5
- 230000007935 neutral effect Effects 0.000 claims abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims description 7
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- 238000009775 high-speed stirring Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 235000011132 calcium sulphate Nutrition 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims 1
- 229960001763 zinc sulfate Drugs 0.000 claims 1
- 229910000368 zinc sulfate Inorganic materials 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 abstract 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 239000004567 concrete Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- -1 oxygen ion Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Finishing Walls (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a method for preparing a diatom ooze building and ornament material. The method comprises the specific steps that firstly, butyl titanate is added in sulfuric acid of a certain concentration to be stirred fiercely, zinc vitriol and calcium sulfate dihydrate are slowly added, fierce stirring is kept, a small amount of water is slowly added to be stirred till the solution is transparent, and accordingly a solution A is obtained; secondly, the solution A is dissolved in a certain amount of water, a small amount of diatom ooze is added, and a solution B is obtained by stirring; thirdly, a calcium hydroxide solution is added into the solution B, the pH value is adjusted to be neutral, and thus a solution C is obtained; fourthly, the solution C is filtered and dried, and a solid compound D containing diatom ooze, nano-titanium dioxide, zinc oxide and calcium sulfate is obtained; fifthly, the D is added into the diatom ooze to be stirred and mixed at a high speed, and the diatom ooze building and ornament material is obtained. The building and ornament material is synthesized through a chemical method, the antibacterial and odor-eliminating performance of the diatom ooze material is effectively improved, and the adhesive property of the building and ornament material and a wall is enhanced.
Description
Technical field
The invention belongs to building material technical field, particularly relate to a kind of diatom ooze building and ornament materials and preparation method thereof.
Background technology
Diatom ooze is that one has vesicular structure, main containing diatomaceous natural environmental-protective material of construction, having removal formaldehyde, purify air, regulate the multi-functionals such as humidity, fire protection flame retarding, releasing negative oxygen ion, is a kind of Important building finishing material of alternative emulsion paint, wallpaper etc.Single diatom ooze raw material function in sterilizing deodoring is comparatively single, needs composition metal inorganics, promotes its performance.CN103951357A is using nano titanium oxide as photocatalyst agent, and compound has prepared a kind of diatom ooze wall material; CN104478338A is additive with nano titanium oxide, has prepared a kind of diatom ooze spray material.In most of patent report, titanium dioxide is all be combined with diatom ooze by physical method.
Chemical synthesis is a kind of controlled prepared material properity and component, prepares the important method of multifunctional composite, have with low cost, equipment simple, operate the plurality of advantages such as simple and easy.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of diatom ooze building and ornament materials, this matrix material is compounded with diatom ooze, nano titanium oxide, nano zine oxide and calcium sulfate by chemical method, has good antibacterial and remove odor function.
Realize the technical solution of the object of the invention, concrete steps are as follows: first, at finite concentration sulfuric acid (H
2sO
4) in, add butyl (tetra) titanate (Ti (OC
4h
9)
4) vigorous stirring, add Zinc vitriol (ZnSO
47H
2and calcium sulphate dihydrate (CaSO O)
42H
2o), keep vigorous stirring, slowly add a small amount of water, be stirred to solution and present transparence, obtain solution A; Secondly, solution A is dissolved in certain water gaging, adds a small amount of diatom ooze, stir and obtain solution B; Subsequently, joined by aqua calcis in solution B, adjust ph, to neutral, obtains solution C; Then, solution C after filtration, dry, obtain containing diatom ooze, nano-TiO
2, ZnO and CaSO
4solid composite D; Finally, in diatom ooze, add a certain amount of D, through high-speed stirring mixing, obtained diatom ooze building and ornament materials.
The present invention compared with prior art, has remarkable advantage: one, these diatom ooze building and ornament materials are synthesized by chemical method, and preparation method is simple and easy, can be mass; Its two, this diatom ooze building and ornament materials essence by diatom ooze dopen Nano TiO
2, ZnO and CaSO
4ternary complex, effectively improve the antibacterial of diatom ooze material and go peculiar smell performance, enhancing the adhesive property with body of wall, they are three years old, this diatom ooze building and ornament materials applicability is strong, can be used for the multiple places such as decoration household, villa, hotel, has environmental benefit and aesthetic.
Embodiment
Below in conjunction with specific embodiment, technical solution of the present invention is described, these embodiments can not be interpreted as the restriction to technical scheme.
Embodiment 1: prepare diatom ooze building and ornament materials according to following concrete steps.
Step 1, at 50mL sulfuric acid (H
2sO
4, mass concentration 70%) and in solution, add 43g butyl (tetra) titanate (Ti (OC
4h
9)
4), vigorous stirring, slowly adds 3.6g Zinc vitriol ((ZnSO
47H
2o), 1.1g calcium sulphate dihydrate (CaSO
42H
2o), keep vigorous stirring, slowly add 10mL water, continue to be stirred to solution and present transparence, time controling 1h, obtains solution A;
Step 2, solution A join in 100mL water, add 6.4g diatom ooze, and stir, time controling 1h, obtains solution B;
Step 3, drop in solution B by aqua calcis, adjust ph, to neutral, stir and obtains solution C;
Step 4, by solution C filter after filter residue through 110
oc is dried, time controling 24h, obtains containing diatom ooze, nano-TiO
2, ZnO and CaSO
4solid composite D;
Step 5, in 1Kg diatom ooze, add 10g solid D, through high-speed stirring mixing, obtained diatom ooze building and ornament materials.
Embodiment 2: prepare diatom ooze building and ornament materials according to following concrete steps.
Step 1, at 50mL sulfuric acid (H
2sO
4, mass concentration 70%) and in solution, add 55.4g butyl (tetra) titanate (Ti (OC
4h
9)
4), vigorous stirring, slowly adds 9.3g Zinc vitriol ((ZnSO
47H
2o), 2.9g calcium sulphate dihydrate (CaSO
42H
2o), keep vigorous stirring, slowly add 15mL water, continue to be stirred to solution and present transparence, time controling 3h, obtains solution A;
Step 2, solution A join in 100mL water, add 13.8g diatom ooze, and stir, time controling 2h, obtains solution B;
Step 3, with embodiment 1;
Step 4, by solution C filter after filter residue through 150
oc is dried, time controling 8h, obtains containing diatom ooze, nano-TiO
2, ZnO and CaSO
4solid composite D;
Step 5, in 1Kg diatom ooze, add 50g solid D, through high-speed stirring mixing, obtained diatom ooze building and ornament materials.
Embodiment 3: prepare diatom ooze building and ornament materials according to following concrete steps.
Step 1, at 50mL sulfuric acid (H
2sO
4, mass concentration 70%) and in solution, add 50g butyl (tetra) titanate (Ti (OC
4h
9)
4), vigorous stirring, slowly adds 6.0g Zinc vitriol ((ZnSO
47H
2o), 2.0g calcium sulphate dihydrate (CaSO
42H
2o), keep vigorous stirring, slowly add 12mL water, continue to be stirred to solution and present transparence, time controling 2h, obtains solution A;
Step 2, solution A join in 100mL water, add 10g diatom ooze, and stir, time controling 1.5h, obtains solution B;
Step 3, with embodiment 1;
Step 4, by solution C filter after filter residue through 120
oc is dried, time controling 16h, obtains containing diatom ooze, nano-TiO
2, ZnO and CaSO
4solid composite D;
Step 5, in 1Kg diatom ooze, add 30g solid D, through high-speed stirring mixing, obtained diatom ooze building and ornament materials.
Claims (3)
1. a preparation method for diatom ooze building and ornament materials, comprises the following steps:
The first step: be in the sulfuric acid of 70% in mass concentration, add butyl (tetra) titanate, vigorous stirring, slowly add Zinc vitriol and calcium sulphate dihydrate, keep vigorous stirring, slowly add a small amount of water, be stirred to solution and present transparence, obtain solution A, wherein, sulfuric acid and butyl (tetra) titanate mol ratio are 3.5:1-4.5:1, and it is 10%-20% that zinc sulfate accounts for butyl (tetra) titanate mol ratio, and it is 5%-10% that calcium sulfate accounts for butyl (tetra) titanate mol ratio;
Second step: solution A joins in certain water gaging, adds a small amount of diatom ooze, and it accounts for butyl (tetra) titanate mass ratio is 15%-25%, stirs, obtains solution B;
3rd step: aqua calcis is dropped in solution B, adjust ph, to neutral, stir and obtains solution C;
4th step: solution C is filtered and obtains filter residue drying, obtain containing diatom ooze, nano-TiO
2, ZnO and CaSO
4solid composite D;
5th step: add solid D in diatom ooze, through high-speed stirring mixing, obtained diatom ooze building and ornament materials.
2. the preparation method of diatom ooze building and ornament materials according to claim 1, is characterized in that: preparation solution A time controling 1h-3h; Preparation solution B, churning time control 1h-2h; Prepare solid D, bake out temperature controls 100
oc-150
oc, time controling 8h-24h.
3. the preparation method of diatom ooze building and ornament materials according to claim 1, is characterized in that: solid D addition is the 1%-5% of diatom ooze quality.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510656089.1A CN105254266B (en) | 2015-10-13 | 2015-10-13 | A kind of preparation method of diatom ooze building and ornament materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510656089.1A CN105254266B (en) | 2015-10-13 | 2015-10-13 | A kind of preparation method of diatom ooze building and ornament materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105254266A true CN105254266A (en) | 2016-01-20 |
| CN105254266B CN105254266B (en) | 2017-07-11 |
Family
ID=55094271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510656089.1A Active CN105254266B (en) | 2015-10-13 | 2015-10-13 | A kind of preparation method of diatom ooze building and ornament materials |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105254266B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116417A (en) * | 2016-06-29 | 2016-11-16 | 合肥光聚财建筑装饰工程有限公司 | A kind of preparation method of diatom ooze building and ornament materials |
| CN106904934A (en) * | 2017-04-04 | 2017-06-30 | 南京市雨花台区绿宝工业设计服务中心 | A kind of preparation method for building composite coating |
| CN108467218A (en) * | 2018-04-05 | 2018-08-31 | 南京市雨花台区绿宝工业设计服务中心 | A kind of preparation method of fire proofing material |
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| CN104118908A (en) * | 2014-07-31 | 2014-10-29 | 上海交通大学 | Controlled preparation method of ordered titanium dioxide nano-material |
| CN104600271A (en) * | 2015-02-03 | 2015-05-06 | 辽宁工程技术大学 | Preparation method of sodium titanate/graphene composite cathode material of sodium ion battery |
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2015
- 2015-10-13 CN CN201510656089.1A patent/CN105254266B/en active Active
Patent Citations (4)
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| CN101721985A (en) * | 2008-10-10 | 2010-06-09 | 北京化工大学 | Method for preparing sulfur and nitrogen co-doped titanium dioxide with visible light catalytic activity |
| CN103803644A (en) * | 2012-11-14 | 2014-05-21 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method for controlling product crystal form and morphology of titanium-based nanometer material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116417A (en) * | 2016-06-29 | 2016-11-16 | 合肥光聚财建筑装饰工程有限公司 | A kind of preparation method of diatom ooze building and ornament materials |
| CN106904934A (en) * | 2017-04-04 | 2017-06-30 | 南京市雨花台区绿宝工业设计服务中心 | A kind of preparation method for building composite coating |
| CN108467218A (en) * | 2018-04-05 | 2018-08-31 | 南京市雨花台区绿宝工业设计服务中心 | A kind of preparation method of fire proofing material |
| CN108467218B (en) * | 2018-04-05 | 2020-12-11 | 湖南大川新型建材有限公司 | Preparation method of fireproof material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105254266B (en) | 2017-07-11 |
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| CB03 | Change of inventor or designer information |
Inventor after: Liu Shanjiang Inventor after: Liu Zhanchuan Inventor after: Mei Shaofeng Inventor after: Hu Zhongyuan Inventor before: Ji Hongjun |
|
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| TA01 | Transfer of patent application right |
Effective date of registration: 20170621 Address after: 072550 Hebei city of Baoding province Xushui Chenyang Street No. 1 Applicant after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: A small road in Yuhuatai District of Nanjing City, Jiangsu province 210000 City family No. 58 2-505 Applicant before: Ji Hongjun |
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Effective date of registration: 20200306 Address after: 072550 No.53, zone 1, Shenjiazhuang village, Gaolin village, Xushui District, Baoding City, Hebei Province Patentee after: Wang Shuai Address before: 072550 Hebei city of Baoding province Xushui Chenyang Street No. 1 Patentee before: HEBEI CHENYANG INDUSTRY & TRADE GROUP., Ltd. |
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| TR01 | Transfer of patent right |