CN105252432A - Carbon-contained nanotube reinforced nano ceramic binding agent diamond grinding wheel and manufacturing method thereof - Google Patents

Abstract

The invention discloses a carbon-contained nanotube reinforced nano ceramic binding agent diamond grinding wheel. In the preparation process of the grinding wheel, raw materials of nano graphite, beta-eucryptite and the like and nano-scale raw materials of silicon dioxide, aluminum oxide and the like are mixed and calcined firstly to prepare a nano-scale composite nano ceramic binding agent. The nano ceramic binding agent has higher intensity, higher toughness and lower sintering temperature, better high-temperature wettability, lower thermal expansion coefficient and better manoeuvreability for grinding materials compared with a conventional ceramic binding agent. In addition, polyamide fibers are added into the raw production materials of the grinding wheel so as to effectively increase the holding intensity of the grinding materials and the binding agent; the toughness of the diamond grinding wheel can be increased effectively through carbon nano tubes, and the grinding precision is improved. The diamond grinding wheel is good in grinding performance, the grinding speed can be obviously increased, hardness is high, toughness is good, and the grinding wheel is durable.

Description

Nano-grade ceramic binding agent skive that a kind of carbon nanotubes strengthens and preparation method thereof

Technical field

The present invention relates to Technique of Vitrified Diamond Wheels preparing technical field, particularly relate to nano-grade ceramic binding agent skive of a kind of carbon nanotubes enhancing and preparation method thereof.

Background technology

It is high that diamond abrasive has hardness, intensity is high, the characteristics such as wearability is good, be widely used in the grinding tool making grinding hard brittle material and carbide alloy, skive is exactly a wherein common class grinding tool, the classification of the bonding agent used according to skive can be divided into resin anchoring agent diamond grinding wheel, metal anchoring agent diamond wheel and Technique of Vitrified Diamond Wheels etc., wherein vitrified bonded grinding wheel is by vitrified bond, diamond abrasive, filler forms according to certain proportions, form through high temperature sintering, this emery wheel can solve the defect of some resin bond wheels and metal bonded wheel existence, there is grinding efficiency high, cut sharp, self-sharpening is good, the advantages such as rapid heat dissipation, be particularly suitable for high rigidity, the corase grind of high accuracy material and fine grinding.

In the preparation process of Technique of Vitrified Diamond Wheels, selection, firing condition etc. the factor of abrasive material, vitrified bond all can affect the grinding performance of Technique of Vitrified Diamond Wheels, especially the performance of vitrified bond is even more important, traditional bonding agent ubiquity sintering temperature is high, intensity is low, to the infiltration covering property of abrasive material difference etc., directly cause diamond abrasive performance degradation, grinding performance reduces greatly.

Summary of the invention

The object of the invention is exactly the defect in order to make up prior art, nano-grade ceramic binding agent skive providing a kind of carbon nanotubes to strengthen and preparation method thereof.

The present invention is achieved by the following technical solutions:

The nano-grade ceramic binding agent skive that carbon nanotubes strengthens, this emery wheel is made up of the raw material of following weight portion: zirconium carbide ceramics powder 15-20, boron oxide 2-3 that the diamond abrasive 40-50 that particle diameter is 10-20 μm, particle diameter are 10-20 μm, CNT 0.2-0.3, Fypro 3-5, ethanol 10-15, polyvinyl alcohol 2-3, dodecyl sodium sulfate 0.2-0.3, deionized water 100-120.

The nano-grade ceramic binding agent skive that described a kind of carbon nanotubes strengthens, it is characterized in that, described nano-grade ceramic binding agent is made up of the raw material of following weight portion: magnesium silicate 1-2, Nano graphite powder 1-2, beta-eucryptite 2-3, nano silicon 30-40, nano-aluminium oxide 8-10, nano-titanium oxide 5-6, nano zine oxide 1-2, sodium bismuthate 0.1-0.2, diboron trioxide 10-15, nanometer silicon carbide 0.3-0.5, lithia 2-3, its preparation method is: mixed by all raw materials, drop in alumina crucible, calcination processing in high temperature resistance furnace, calcination condition is to 900-1000 DEG C with the ramp of 5-8 DEG C, insulation calcining 2-3h, calcining terminates rear taking-up and carries out shrend, dry, high-energy ball milling process, obtain the powdered ceramic bonding agent that particle diameter is nanoscale.

Nano-grade ceramic binding agent skive that described a kind of carbon nanotubes strengthens and preparation method thereof, its spy is, described preparation method is:

(1) first polyvinyl alcohol, dodecyl sodium sulfate, ethanol are dissolved and is scattered in deionized water, mixed solution is heated to 50-60 DEG C, add nano-grade ceramic binding agent, Fypro, CNT subsequently, high-speed ultrasonic dispersed with stirring 1.5-2h, make finely dispersed nano-solution for subsequent use;

(2) mixed by the solution that diamond abrasive, zirconium carbide ceramics powder are prepared with step (1), mixed slurry heat under 150-180 DEG C of condition dried after being uniformly mixed, remove moisture completely, gained material is broken, crosses 200 mesh sieves;

(3) powder that sieved by step (2) gained mixes with other leftover materials, 230-250 DEG C is warming up to the heating rate of 4-5 DEG C/min after cold moudling, after insulation 30-40min, continue to be warming up to 500-550 DEG C, insulation 80-100min, is warming up to 650-680 DEG C subsequently again, insulation 100-120min, finally by naturally cooling to room temperature, to obtain final product.

The present invention is by the raw material mixed calcining such as silica, alundum (Al2O3) of the raw material such as Nano graphite powder, beta-eucryptite and nanometer scale, be prepared into the composite nano-ceramic bonding agent of nanometer scale, the more conventional vitrified bond of this nano-grade ceramic binding agent has higher intensity, toughness and lower sintering temperature, high-temperature moisture is better, thermal coefficient of expansion is low, good to the holding of abrasive material; In addition the Fypro added in emery wheel raw materials for production effectively can increase the holding intensity of abrasive material and bonding agent, and CNT effectively can increase the toughness of skive, improves grinding accuracy; Diamond wheel grinding performance prepared by the present invention is good, and grinding speed can obtain obvious lifting, and hardness is high, and toughness is good, durable in use.

Detailed description of the invention

This embodiment emery wheel is made up of the raw material of following weight portion: zirconium carbide ceramics powder 15, boron oxide 2, CNT 0.2, Fypro 3, ethanol 10, polyvinyl alcohol 2, dodecyl sodium sulfate 0.2, deionized water 100 that the diamond abrasive 40 that particle diameter is 10 μm, particle diameter are 10 μm.

Nano-grade ceramic binding agent is wherein made up of the raw material of following weight portion: magnesium silicate 1, Nano graphite powder 1, β eucryptite 2, nano silicon 30, nano-aluminium oxide 8, nano-titanium oxide 5, nano zine oxide 1, sodium bismuthate 0.1, diboron trioxide 10, nanometer silicon carbide 0.3, lithia 2, its preparation method is: mixed by all raw materials, drop in alumina crucible, calcination processing in high temperature resistance furnace, calcination condition is with the ramp to 900 DEG C of 5 DEG C, insulation calcining 2h, calcining terminates rear taking-up and carries out shrend, dry, high-energy ball milling process, obtain the powdered ceramic bonding agent that particle diameter is nanoscale.

The preparation method of this skive is:

(1) first polyvinyl alcohol, dodecyl sodium sulfate, ethanol are dissolved and is scattered in deionized water, mixed solution is heated to 50 DEG C, add nano-grade ceramic binding agent, Fypro, CNT subsequently, high-speed ultrasonic dispersed with stirring 1.5h, make finely dispersed nano-solution for subsequent use;

(2) mixed by the solution that diamond abrasive, zirconium carbide ceramics powder are prepared with step (1), mixed slurry heat under 150 DEG C of conditions dried after being uniformly mixed, remove moisture completely, gained material is broken, crosses 200 mesh sieves;

(3) powder that sieved by step (2) gained mixes with other leftover materials, 230 DEG C are warming up to the heating rate of 4 DEG C/min after cold moudling, after insulation 30min, continue to be warming up to 500 DEG C, insulation 80min, is warming up to 650 DEG C subsequently again, insulation 100min, finally by naturally cooling to room temperature, to obtain final product.

The grinding wheel performance index that the present embodiment prepares is as follows:

Being ground material in test is high-speed steel, and grinding method is flat surface grinding mode, emery wheel peripheral speed: 150m/s, the speed of table: 0.05m/s, grinding depth: 0.025mm.

The more traditional diamond wheel grinding of the emery wheel prepared of the present embodiment improves 185% than average, and wear extent on average reduces by 62%, and the roughness of surface of high speed steel is only 0.04 μm, and maximum grinding speed can reach 190m/s.

Claims (3)

1. the nano-grade ceramic binding agent skive of a carbon nanotubes enhancing, it is characterized in that, this emery wheel is made up of the raw material of following weight portion: zirconium carbide ceramics powder 15-20, boron oxide 2-3 that the diamond abrasive 40-50 that particle diameter is 10-20 μm, particle diameter are 10-20 μm, CNT 0.2-0.3, Fypro 3-5, ethanol 10-15, polyvinyl alcohol 2-3, dodecyl sodium sulfate 0.2-0.3, deionized water 100-120.

2. the nano-grade ceramic binding agent skive of a kind of carbon nanotubes enhancing as claimed in claim 1, it is characterized in that, described nano-grade ceramic binding agent is made up of the raw material of following weight portion: magnesium silicate 1-2, Nano graphite powder 1-2, beta-eucryptite 2-3, nano silicon 30-40, nano-aluminium oxide 8-10, nano-titanium oxide 5-6, nano zine oxide 1-2, sodium bismuthate 0.1-0.2, diboron trioxide 10-15, nanometer silicon carbide 0.3-0.5, lithia 2-3, its preparation method is: mixed by all raw materials, drop in alumina crucible, calcination processing in high temperature resistance furnace, calcination condition is to 900-1000 DEG C with the ramp of 5-8 DEG C, insulation calcining 2-3h, calcining terminates rear taking-up and carries out shrend, dry, high-energy ball milling process, obtain the powdered ceramic bonding agent that particle diameter is nanoscale.

3. nano-grade ceramic binding agent skive of strengthening of a kind of carbon nanotubes as claimed in claim 1 and preparation method thereof, its spy is, described preparation method is:

(1) first polyvinyl alcohol, dodecyl sodium sulfate, ethanol are dissolved and is scattered in deionized water, mixed solution is heated to 50-60 DEG C, add nano-grade ceramic binding agent, Fypro, CNT subsequently, high-speed ultrasonic dispersed with stirring 1.5-2h, make finely dispersed nano-solution for subsequent use;

(2) mixed by the solution that diamond abrasive, zirconium carbide ceramics powder are prepared with step (1), mixed slurry heat under 150-180 DEG C of condition dried after being uniformly mixed, remove moisture completely, gained material is broken, crosses 200 mesh sieves;

(3) powder that sieved by step (2) gained mixes with other leftover materials, 230-250 DEG C is warming up to the heating rate of 4-5 DEG C/min after cold moudling, after insulation 30-40min, continue to be warming up to 500-550 DEG C, insulation 80-100min, is warming up to 650-680 DEG C subsequently again, insulation 100-120min, finally by naturally cooling to room temperature, to obtain final product.