CN105247124B - Fiber structure - Google Patents

Fiber structure Download PDF

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Publication number
CN105247124B
CN105247124B CN201480030187.8A CN201480030187A CN105247124B CN 105247124 B CN105247124 B CN 105247124B CN 201480030187 A CN201480030187 A CN 201480030187A CN 105247124 B CN105247124 B CN 105247124B
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China
Prior art keywords
fiber
weight
fiber structure
ratio
less
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CN201480030187.8A
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CN105247124A (en
Inventor
松本晃
松本晃一
田畑次郎
安达行
安达一行
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Toray Industries Inc
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Toray Industries Inc
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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B17/00Selection of special materials for underwear
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/26Electrically protective, e.g. preventing static electricity or electric shock
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/18Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/08Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated carboxylic acids or unsaturated organic esters, e.g. polyacrylic esters, polyvinyl acetate
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes

Abstract

The present invention provides a kind of electrostatic for being not likely to produce crack in Pi when wearing, and is not likely to produce fold after washing, the heat insulating ability with excellent in te pins of durability and wears the fiber structure and the dress material using the fiber structure of comfortableness.The fiber construct of the present invention contains viscose rayon yarn series fiber with the ratio more than 30 weight % and less than 40 weight %, cation dyeable polyester fiber is contained with the ratio more than 30 weight % and less than 40 weight %, polyacrylic synthetic fibers are contained with the ratio more than 25 weight % and less than 30 weight %, polyurethane series elastic fiber is contained with the ratio more than 5 weight % and less than 10 weight %, the voltage that is charged by friction of the fiber structure is below 1500V, and based on JISL0217103 methods wash 5 times after the easy-care properties according to AATCC124 law regulations be more than 3 grades.

Description

Fiber structure
Technical field
The present invention relates to having both moisture absorption heating, heat insulating ability and wearing the fiber structure of comfortableness and using the fiber The dress material of works.Particularly, the present invention relates to being preferred for undershirt or T-shirt of directly contact human skin etc., and when wearing The electrostatic of crack in Pi is not likely to produce, the fiber structure and dress material of fold after washing, is not likely to produce.
Background technology
At present, as the fibre with moisture retention, using by rear processing the cloth and silks such as fabric are applied with for example The product of the moisturizing ingredients such as squalane.But, this be present in the characteristics such as moisture retention by the rear fibre for obtaining of processing The problem of washing resistance difference, solves countermeasure as which, and substantial amounts of binding agent is usually used (with reference to patent documentation 1.).
In contrast, the method for improving washing resistance as binding agent is not used, can enumerate following method.Concrete and Speech, it is proposed that after the fiber structure for making to be made up of synthetic fibers has adhered functional protein material, by aqueous alkali And/or aqueous solution of anionic surfactant implements the method for post processing (with reference to patent documentation 2.).In addition, it is proposed that to containing The fiber structure of cellulose fibre applies metallic compound and natural sex functional agent and has carried out being crosslinked containing for modification processing There is the fibre of cellulose fibre (with reference to patent documentation 3.).
But, in these existing motions, even if washing resistance is improved, in the dress material purposes of directly contact skin Also of paramount importance safety and pliability can be damaged, therefore, it cannot be said that meeting washing resistance and wearing comfortableness this two side Face, there is also problem from from the viewpoint of mitigation carrying capacity of environment in recent years.
In addition, as the means for improving heat insulating ability, it is proposed that many schemes, by the insulation materials such as lining, cotton for wadding and dress material The fiber structure that this three-decker is constituted is (with reference to patent documentation 4.).But, in the motion, there is following problem:Due to face Expect to use to improve the purpose of windproof and heat insulating ability, thus produce when wearing sultry, additionally, due to for three-decker, so Quality is thick, it is impossible to towards purposes such as underwears.
In addition, especially as the fiber structure for being preferred for the undershirt or T-shirt of directly contact human skin etc., for example A kind of fiber structure is proposed, it is fine which contains polyacrylic synthesis with the ratio below more than 30 weight % 47 weight % Dimension, contains viscose rayon yarn series fiber with the ratio below more than 20 weight % 30 weight %, with more than 30 weight % 45 weights The ratio of amount below % contains cationic dyeable polyester fiber, and is contained with the ratio below more than 3 weight % 10 weight % poly- Urethane system elastic fiber is formed (with reference to patent documentation 5.).But, in the motion, due to the polypropylene as hydrophobic polymer Acid is the containing ratio height of synthetic fibers and polyester fiber, so there is the problem for easily producing electrostatic when wearing.Additionally, there are The mixed rate of polyacrylic synthetic fibers is high, and fiber structure easily produces the problem of balling-up.
Prior art literature
Patent documentation
Patent documentation 1:Japanese Unexamined Patent Publication 2-300301 publication
Patent documentation 2:Japanese Unexamined Patent Publication 10-131047 publication
Patent documentation 3:Japanese Unexamined Patent Publication 2002-88649 publications
Patent documentation 4:Japanese Patent Publication 7-59762 publication
Patent documentation 5:Japanese Unexamined Patent Publication 2010-216053 publications
Content of the invention
Invent problem to be solved
Present inventors etc. are had made intensive studies for solving above-mentioned problem, are as a result found:The viscose glue by using blending The silk of artificial silk series fiber, i.e. viscose rayon yarn series fiber, cationic dyeable polyester fiber, polyacrylic synthetic fibers, poly- Urethane system elastic fiber, and its component ratio optimization is made, can obtain the electrostatic that crack in Pi is not likely to produce when wearing, wash Fold is not likely to produce after washing, and the heat insulating ability having excellent washing resistance and wears the excellent fiber structure of comfortableness.
That is, present invention aim to address above-mentioned problem, there is provided be not likely to produce the electrostatic of crack in Pi when wearing, washing After be not likely to produce fold, the heat insulating ability with excellent in te pins of durability and wear the fiber structure of comfortableness and tied using the fiber The dress material of structure thing.
Means for solving the problems
The present invention is to realize above-mentioned problem, with following element.
The fiber structure of the present invention, contains viscose rayon yarn system with the ratio more than 30 weight % and less than 40 weight % Fiber, contains cation dyeable polyester fiber with the ratio more than 30 weight % and less than 40 weight %, with more than 25 weights Measure % and the ratio less than 30 weight % contains polyacrylic synthetic fibers, with more than 5 weight % and less than 10 weight % Ratio contains polyurethane series elastic fiber, and the voltage that is charged by friction of the fiber structure is below 1500V, and is based on JIS The easy-care properties of the AATCC124 law regulations after the washing 5 times of 103 methods of L0217 (2011 editions) are more than 3 grades.
According to the preferred mode of the fiber structure of the present invention, the moisture absorption heating performance of the fiber structure is 2.6 More than DEG C.
According to the preferred mode of the fiber structure of the present invention, the residual moisture rate of described fiber structure is changed into Less than 30% time is within 40 minutes.
According to the preferred mode of the fiber structure of the present invention, the insulation rate of described fiber structure be 14% with On.
According to the preferred mode of the fiber structure of the present invention, the balling-up of described fiber structure is more than 2.5 grades.
According to the preferred mode of the fiber structure of the present invention, described cation dyeable polyester long fibre contains and has The fiber of odd-shaped cross section.
According to the preferred mode of the fiber structure of the present invention, described fiber structure is the knitting of single layer structure Thing.
Using the fiber structure of the present invention, the dress material of the present invention can be obtained.
Invention effect
According to the present invention, the electrostatic of crack in Pi is not likely to produce when wearing, be not likely to produce fold after washing, resistance to having The long moisture retention of property, even and if texture material thickness, also possess heat insulating ability and absorb-discharge humid, therefore, can obtain being suitable as with Wear the fiber structure for using and the dress materials for using the fiber structure such as undershirt or T-shirt for the purpose of comfortableness.
Specific embodiment
Below, the embodiment of the fiber structure of the present invention is described in detail.
The fiber structure of the present invention, contains viscose rayon yarn system with the ratio more than 30 weight % and less than 40 weight % Fiber, contains cation dyeable polyester fiber with the ratio more than 30 weight % and less than 40 weight %, with more than 25 weights Measure % and the ratio less than 30 weight % contains polyacrylic synthetic fibers, with more than 5 weight % and less than 10 weight % Ratio contains polyurethane series elastic fiber.
As described above, for the fiber structure of the present invention, contained with the ratio more than 30 weight % and less than 40 weight % Viscose rayon yarn series fiber is important.The ratio of viscose rayon yarn series fiber preferably 32~38 weight %, more preferably 33 ~36 weight %.By containing the viscose rayon yarn series fiber for having more than 30 weight %, the guarantor with excellent in te pins of durability can be obtained Moist fiber structure.Due to having the moisture retention, so as to fiber construct is not likely to produce the quiet of crack in Pi when wearing Electricity, and also there is moisture absorption heating.
In fiber structure, electrostatic produce number by with the JIS-L1094-2008 " bands of knitted fabric and fabric The voltage that is charged by friction determined on the basis of electrical test method " is judged.Be charged by friction voltage more low be difficult to produce electrostatic, More high easier generation electrostatic.From this point of view, be charged by friction voltage for below 1500V is also the fiber construct of the present invention Important.By voltage being charged by friction for below 1500V, be not likely to produce the electrostatic of crack in Pi when wearing.It is charged by friction electricity Pressure is preferably below 1000V, more preferably below 500V.
In the fiber structure of the present invention, if the ratio of viscose rayon yarn series fiber is more than 40 weight %, viscous In the characteristic of glue artificial silk series fiber, fold after washing, is easily produced, in addition heat insulating ability reduces.
Viscose rayon yarn series fiber used in as the present invention, from from the viewpoint of improving heat insulating ability, is preferably with thin The form of yarn is used.In addition, for spun yarn number, due to undershirt or T-shirt for directly contact human skin etc., therefore, with Cotton number meter preferably uses 30S~100S.In addition, the filament denier of spun yarn is constituted according to its use, preferably 0.5 point Spy~2.5 dtexs.
For the present invention fiber structure, with more than 30 weight % and less than 40 weight % ratio contain cation can Metachromia polyester fiber is important.By using cationic dyeable polyester fiber, compared with common polyester fiber, can be with low Temperature is dyeed, therefore, it can with and with polyacrylic synthetic fibers identical dyestuff dyeed.In addition, sun from Sub- dyeable polyester fiber is due to obtaining excellent color emissivity and firmness with 105 DEG C~115 DEG C of dyeing temperature, it is possible to The polyurethane series elastic fiber for preventing causes to deteriorate because of heat.
In addition, being washed by fiber construct containing the cation dyeable polyester fiber for having more than 30 weight %, can be suppressed Fold is produced afterwards.For the fold after the washing, by the washing side on the basis of 103 methods of JIS L0217 (version in 2011) Method, the fold sense that the copy that is recorded using AATCC124 is produced on the surface to the sample after 5 washings of enforcement carry out series Evaluate.If the easy-care properties of the washing 5 AATCC124 law regulations hereafter are more than 3 grades, it is judged as that fold sense is few.
In addition, if the ratio of cation dyeable polyester fiber is more than 40 weight %, then poly- in cation dyeable In the characteristic of ester fiber, the moisture retention of fiber structure reduces, and therefore, is charged by friction voltage raising, and moisture absorption heating also drops Low.The ratio of cation dyeable polyester fiber is preferably 32~36 weight %, more preferably 33~35% weight %.
In addition, as cation dyeable polyester fiber, for preferably comprising the embodiment of the fiber with odd-shaped cross section. By containing the fiber with odd-shaped cross section, even if can achieve during diaphoresis, knitted fabric (fiber structure) suction antiperspirant also can be rapid Ground is dried, and prevents the effect of cold of body.In the present invention, refer to using cross sectional shape not containing the fiber with odd-shaped cross section Same fiber of more than two kinds.For example, the fiber in the section beyond being used together with circular section including the fiber with circular section Situation, only it is made up of the fiber of the odd-shaped cross section having a case that beyond circular section i.e. using of more than two kinds with different different Situation of the fiber of tee section etc..Thus, it is possible to form many trickle spaces, the water picked up by surface tension can be improved The diffusion velocity that divides.
In addition, the filament denier of cation dyeable polyester fiber, from absorption of perspiration excellent from the viewpoint of, preferably The embodiment of 0.8~1.8 dtex.Wherein, if filament denier is preferably below 1.0 dtexs, even if having not containing The fiber of odd-shaped cross section and only using the homogeneous fiber in fibre section in the case of, it is also possible to obtain absorption of perspiration excellent fiber knot Structure thing.
Cation dyeable polyester fiber used in as the present invention, such as spun yarn or long fibre etc. can be used.From From the viewpoint of improving easy-care properties, it is the embodiment for preferably being used with long stapled form.In this case, due to for directly Undershirt or T-shirt of contact human body etc., so total fiber number is preferably 50 dtex~200 dtexs.
In addition, for making common polyester for cation fibre, such as it is generally known that by usual copolymerization in the polyester The 5- sodium sulfonate M-phthalic acids composition of 1.0~3.0 moles of % is realizing.
For the fiber structure of the present invention, polyacrylic acid is contained with the ratio more than 25 weight % and less than 30 weight % Be synthetic fibers be important.By the polyacrylic synthetic fibers containing 25 weight %, fiber structure can be given Heat insulating ability.If the ratio of polyacrylic synthetic fibers is more than 30 weight %, in the spy of polyacrylic synthetic fibers Property on, the moisture retention of fiber structure reduces, and therefore, is charged by friction voltage raising, and moisture absorption heating also reduces.Polyacrylic acid It is ratio preferably 26~28 weight % of synthetic fibers.
The filamentary fiber number for constituting polyacrylic synthetic fibers is preferably 0.6~2.2 dtex.More soft for realizing Feel and heat insulating ability are improved, and preferably polyacrylic synthetic fibers are fine denier, but when filament denier is less than 0.6 dtex, Sometimes spinnability is deteriorated, additionally, it is possible to cause the intensity decreases of spun yarn.In addition, if filament denier is more than 2.2 dtexs, then Especially as purposes such as the underwears for being directly used in skin, there is the trend that feel is hardened.Therefore, polyacrylic synthetic fibers Filamentary fiber number is more preferably more than 0.6 dtex below 1.5 dtexs.Polyacrylic synthesis used in as the present invention is fine Dimension, from from the viewpoint of improving heat insulating ability, uses preferably in the form of spun yarn.From undershirt or T-shirt for directly contact skin Deng from the viewpoint of, spun yarn number is preferably 30S~100S in terms of cotton number.
In addition, in the present invention, it is also preferred that use above-mentioned viscose rayon yarn series fiber and polyacrylic synthetic fibers The spun yarn of blending.
And, the present invention fiber structure in, with more than 5 weight % and less than 10 weight % ratio use poly- ammonia Ester system elastic fiber is important.Thus, it is possible to increase the space of appropriate degree of stretching and knitted fabric interannular, hereby it is achieved that can be with The action of body is swimmingly followed, the effect for wearing comfortableness is further improved.
Polyurethane series synthetic fibers used in as the present invention, due to the undershirt that directly contacts with human skin or T-shirt Deng, preferably use total fiber number for 15T~45T, and preferably 1~3 long filament.
As the fiber structure of the present invention, woven fabric, fabric and non-woven fabrics etc. are suitably enumerated.In addition, in woven fabric Or in the case of fabric, viscose rayon yarn series fiber, cation dyeable polyester fiber and polyacrylic synthetic fibers can With using long fibre and spun yarn any one, but the mode as preferred fiber structure, in order to be used for directly contact skin Undershirt or T-shirt etc. and realize various performances, by blending, viscose rayon yarn series fiber and polyacrylic synthetic fibers is thin Yarn and cation dyeable polyester fiber form long fibre, and are woven into fabric containing polyurethane series synthetic fibers.
In the fiber structure of the present invention, as described above, friction proof voltage is below 1500V, and easy-care properties are weights for more than 3 grades Want.
In the present invention, the moisture absorption heating performance of the fiber structure of the present invention is preferably more than 2.6 DEG C.Moisture absorption heating performance More high more preferred, if more than 2.6 DEG C, then can feel when wearing warm.Moisture absorption heating performance refers to, is fed through silicon The dry air (below humidity 10%RH) of glue container, makes samples dried more than 30 minutes, when stablizing relative to specimen temperature Surface temperature A, during sending into the air of the humidity for having passed through ion exchange water about 90%RH of about 30 minutes after reading Specimen surface temperature maximum temperature reached B, moisture absorption heating performance are the temperature (DEG C) which differs from B-A.Therefore, if moisture pick-up propertiess are high Viscose rayon yarn series fiber ratio increase, then moisture absorption heating performance improve, but if the ratio of viscose rayon yarn series fiber Increase, then, in the characteristic of viscose rayon yarn series fiber, easily produce fold after washing, in addition heat insulating ability reduces.
In addition, in the present invention, fiber structure, the residual moisture rate of the present invention are changed into for less than 30% time and are preferably Less than 40 minutes.Residual moisture rate is the index for drying easness when fiber structure is spontaneously wet out by water, and specifically, Deca is about The water of 0.3g, reads the quality (g) after Deca, reads trying to achieve through the quality (g) of unit interval after Deca.If made Ratio for hydrophobic cation dyeable polyester fiber or polyacrylic synthetic fibers increases, then residual moisture rate is carried Height, but voltage raising is charged by friction, moisture absorption heating also reduces.
And, in the present invention, the insulation rate of the fiber structure of the present invention is preferably more than 14.0%.Insulation rate gets over Gao Yue It is preferred that, if more than 14.0%, then can feel when wearing warm.Heat insulating ability is dress material easily radiating or not easy heat radiation Index.On fiber properties, if the low cation dyeable polyester fiber of pyroconductivity or polyacrylic synthetic fibers Ratio increases, then heat insulating ability is improved, but is charged by friction voltage raising, and moisture absorption heating also reduces.
Additionally, in the present invention, the balling-up of the fiber structure of the present invention is (on the basis of JISL1076A methods (version in 2011) Determine) it is preferably more than 2-3 levels (more than 2.5 grades).In pilling testing, can confirm that when wearing in surface of cloth generation The occurrence degree of ball top.If balling-up is less than 2 grades, it is judged as that in wearing ball top is produced in a large number and easily observed.For reality More than existing 2-3 levels (more than 2.5 grades), the composition of fiber structure is set to viscose rayon yarn series fiber more than 30 weight % and low In 40 weight %, cation dyeable polyester fiber more than 30 weight % and is less than 40 weight %, polyacrylic synthetic fibers It is important more than 25 weight % and less than the ratio of 30 weight %.Particularly, if polyacrylic synthetic fibers are more than 30 Weight %, then balling-up deteriorate.
In addition, by the composition of the fiber structure of the present invention is set to viscose rayon yarn series fiber more than 30 weight % and 40 weight % are less than, cation dyeable polyester fiber more than 30 weight % and is less than 40 weight %, and polyacrylic synthesis is fine Ratio of the dimension more than 25 weight % and less than 30 weight %, when dyeing to fiber structure, by with reactive dye pair Viscose rayon yarn series fiber is dyeed, fine to cation dyeable polyester fiber and polyacrylic synthesis with the dye of positive ion Dimension is dyeed, it is also possible to carry out the performance of only shallow Lycoperdon polymorphum Vitt by only carrying out black dyeing with reactive dye, and only with sun Ionic dye carries out black dyeing and carries out the performance of not too deep Lycoperdon polymorphum Vitt.
As the mode of the fiber structure of the present invention, due to undershirt or T-shirt for directly contact human skin etc., institute To be preferably the fabric of single layer structure.So, by making the fabric of single layer structure, wearing by the fiber structure system Into dress material when, viscose rayon yarn series fiber is set to more than 30 weight % and less than 40 weight %, cation dyeable is gathered Ester fiber is set to, more than 30 weight % and less than 40 weight %, polyacrylic synthetic fibers are set to more than 25 weight % and low In 30 weight %, and it is set to, more than 5 weight % and less than 10 weight %, can balancedly contact flesh by polyurethane series elastic fiber Skin.For example, if these materials solely contact skin, such as in the case that only viscose rayon yarn series fiber is contacted, at which In characteristic, dress material is felt to feel nice and cool very much.In addition, only cation dyeable polyester fiber or polyacrylic synthetic fibers contact In the case of, in their characteristic, feel very sultry.In addition, in the case that only polyurethane series elastic fiber is contacted, feeling non- Often tacky.
Additionally, in the fiber structure of the present invention, except above-mentioned viscose rayon yarn series fiber, cation dyeable polyester Outside fiber, polyacrylic synthetic fibers and polyurethane series elastic fiber, it is also possible to containing not being the usual of cation-dyeable Polyester fiber, the copolymerization polyester fiber of the 3rd composition, polyamide-based fiber, acetic ester fiber, cotton, fiber crops in the polyester And the protein fibre such as the regenerated celulose fibre and Pilus Caprae seu Oviss beyond native cellulose fibre, the viscose rayon yarn such as paper pulp etc..Structure Fiber into fiber structure is each other using mixed fibre, blending, mixed method of knitting and interweave etc..
The fiber structure of the present invention is except the coat such as T-shirt, cold-proof jacket clothes, sport pants, skirt, tightss, spat, woman style Outside the dress materials such as the underwear such as vest next to the skin and medicated underpants, the dress material purposes being dressed on body is applied also for, is preferred for various clothing Material.
Embodiment
Here, the evaluation methodology of each performance of embodiment etc. is as follows.
(1) voltage is charged by friction:
It is charged by friction charging property examination of the voltage by the woven fabric and fabric on the basis of JIS-L1094 (version in 2011) Proved recipe method is measured.
(2) easy-care properties:
As for easy-care properties, the copy that is recorded by AATCC124 is to passing through with 103 methods of JIS L0217 (version in 2011) On the basis of the fold sense implemented produced by after the 5 washings, surface of sample of washing methods carry out series evaluation.
(3) moisture absorption heating:
As for moisture absorption heating, the sample of about 10cm × 10cm sizes is installed in closed container, and can determine The mode installation surface thermometer sensor of the temperature of sample is simultaneously read out by recording gauge.After specimen temperature measure starts, The dry air (below humidity 10%RH) of silica gel container has been fed through in interior atmosphere from 20 DEG C of indoor temperature of measure Make samples dried.Make samples dried more than 30 minutes, relative to surface temperature A of specimen temperature when stable, send into after reading Specimen surface temperature during the air of the humidity for the having passed through ion exchange water about 90%RH of about 30 minutes is up to up to temperature Degree B, is differed from B-A as moisture absorption heating performance (DEG C).
(4) residual moisture rate becomes for less than 30% time (rapid-drying properties):
After placing 24 hours in atmosphere of the sample of about 10cm × 10cm sizes under 20 DEG C × 65%RH, reading quality G (g), the water in same atmosphere to the sample Deca about 0.3g read quality Go (g) after Deca, and after reading Deca Quality Gx (g) through the unit interval.Quality after relative to Deca, ask the residual moisture rate (%) obtained by following formula into Time (minute) for 30%.
Residual moisture rate (%)={ (Gx-G)/(Go-G) } × 100.
(5) insulation rate:
Insulation rate is determined on the basis of 8.28 heat insulating abilities 8.28.1A methods (constant temperature method) of JIS L1096 (version in 2011).
(6) balling-up
Balling-up is determined on the basis of JISL1076A methods (version in 2011).
Following judgement series.
The situation of No. 5 degree of 5 grades of standard photographs.
The situation of the intermediate degree of No. 4 and No. 5 of 4-5 levels (4.5 grades) standard photographs
The situation of No. 4 degree of 4 grades of standard photographs.
The situation of the intermediate degree of No. 3 and No. 4 of 3-4 levels (3.5 grades) standard photographs
The situation of No. 3 degree of 3 grades of standard photographs.
The situation of the intermediate degree of No. 2 and No. 3 of 2-3 levels (2.5 grades) standard photographs
The situation of No. 2 degree of 2 grades of standard photographs
The situation of the intermediate degree of No. 1 and No. 2 of 1-2 levels (1.5 grades) standard photographs
No. 1 of 1 grade of standard photographs or the situation more than its degree.
(7) hue evaluation of Lycoperdon polymorphum Vitt
The fabric of the only black dyeing of reactive dye dyeing is made during dyeing, and also makes the black dye of only cationic dyeing The fabric of color, reactive dye, the dye of positive ion compare the fabric of the fabric of black dyeing and white dyeing, evaluate the tone of gray scale.
(embodiment 1)
With mixer to viscose rayon tow (1.4 dtex of filament denier, length 38mm, ダ イ ワ ボ ウ レ ヨ Application (strain) makes) 55 weight % and it is applied with the acrylic beam (filament denier of 0.4owf% tetraalkyl adipates 1.0 dtexs, length 45mm, eastern beautiful (strain) " ト レ ロ Application " (registered trade mark)) 45 weight % carry out mixed cotton, obtain 1/64s (number) Spun yarn.
By the spun yarn for so obtaining, section be circular cross-section fiber and section for star cross section fiber the sun that mixes of section from Sub- dyeable polyester fiber filament (84 dtex of total fiber number, 48 long filaments, eastern beautiful (strain) " テ ト ロ Application " (registered trade mark)), polyurethane Fiber (22 dtex of total fiber number, 2 long filaments, オ ペ ロ Application テ ッ Network ス systems " ラ イ Network ラ " (registered trade mark)) with kettle footpath 76.2cm, every Setting away from 28/2.54cm of number, stringer number 40 and course count 62 is interleaved with plain stitch, obtains fabric.
By the fabric for obtaining by continuous lax/concise-dry (175 DEG C of temperature, 25 seconds time)-setting-tuck-dyeing (115 DEG C of liquid flowing dyeing temperature)-dry (112 DEG C of temperature)-setting operation carries out Colour Difference, obtains poly- with dress material weight ratio meter Acrylic fibers are 27 weight %, viscose rayon fibers are 33 weight %, section mixed-cation dyeable polyester fiber For 34 weight % and polyurethane elastomeric fiber be 6 weight %, weight per unit area be 150g/m2Dress material.
Evaluate dress material obtained above be charged by friction voltage, easy-care properties, moisture absorption heating, rapid-drying properties, heat insulating ability and rise Ball.In addition, make the only fabric of the black dyeing of reactive dye dyeing and the only black dyeing of cationic dyeing during dyeing knitting Thing, evaluates the tone of gray scale respectively.The results are shown in table 1.Voltage is charged by friction for below 2000V, 3 grades of easy-care properties, moisture absorption are sent out Hot, rapid-drying properties and heat insulating ability are good, in addition, balling-up is also 2-3 levels (2.5 grades), as the tone of gray scale, as long as only anti- Dyeing is answered, is then only white gray scale, as long as only cationic dyeing, be then only black gray scale.Obtain conduct Dress material purposes, particularly underwear should possess with high functional fabric.
(embodiment 2)
With mixer to viscose rayon tow (1.4 dtex of filament denier, length 38mm, ダ イ ワ ボ ウ レ ヨ Application (strain) make) 55 weight %, be applied with 0.4owf tetraalkyl adipate acrylic beam (filament denier 1.0 Dtex, length 38mm, eastern beautiful (strain) " ト レ ロ Application " (registered trade mark)) 45 weight % carry out mixed cotton, obtain 1/64s's (number) Spun yarn.
By the spun yarn for so obtaining, cation dyeable polyester fiber filament (84 points of the total fiber number that section is circular cross-section Spy, 96 long filaments, eastern beautiful (strain) " テ ト ロ Application " (registered trade mark)), polyurethane series elastic fiber (22 dtex of total fiber number, 2 long filaments, オ ペ ロ Application テ ッ Network ス systems " ラ イ Network ラ " (registered trade mark)) with kettle footpath 76.2cm, 28/2.54cm of gauge number, stringer number 42 The setting of 58/2.54cm of root/2.54cm and course count is interleaved with plain stitch, obtains fabric.
By the fabric for obtaining by continuous lax/concise-dry (175 DEG C of temperature, 25 seconds time)-setting-tuck-dyeing The operation of (115 DEG C of liquid flowing dyeing temperature)-dry (112 DEG C of temperature)-setting carries out Colour Difference, obtains the weight ratio with dress material Meter acrylic is 27 weight %, viscose rayon fibers are 33 weight %, circular cross-section cation dyeable polyester Fiber be 34 weight % and polyurethane elastomeric fiber be 6 weight %, weight per unit area be 145g/m2Dress material.
Evaluate the dress material for obtaining and be charged by friction voltage, easy-care properties, moisture absorption heating, rapid-drying properties, heat insulating ability and balling-up. In addition, the fabric and the fabric of the only black dyeing of cationic dyeing of the only black dyeing of reactive dye dyeing during dyeing, is made, The tone of gray scale is evaluated respectively.The results are shown in table 1.As a result, obtaining high functional braiding similarly to Example 1 Thing.Confirm with regard to rapid-drying properties, by using filament denier be below 1.0 dtexs highly answer processed filament as circular cross-section Cation dyeable polyester fiber, obtains the performance same with section hybrid process silk.In addition, balling-up is also 2-3 levels (2.5 Level), as the tone of gray scale, dye as long as only reactive dye, be then only white gray scale, contaminate as long as only the dye of positive ion Color, then be only black gray scale.
(comparative example 1)
With mixer to viscose rayon fibers beam (1.4 dtex of filament denier, length 38mm, ダ イ ワ ボ ウ レ ヨ Application (strain) is made) 35 weight %, (ultimate fibre is fine to be applied with the acrylic beam of tetraalkyl adipate of 0.4owf% Spend 1.0 dtexs, length 45mm, eastern beautiful (strain) " ト レ ロ Application " (registered trade mark)) 65 weight % carry out mixed cotton, obtain 1/64s ( Number) spun yarn.
By the spun yarn for so obtaining, section be circular cross-section fiber and section for star cross section fiber the sun that mixes of section from Sub- dyeable polyester fiber filament (84 dtex of total fiber number, 48 long filaments, eastern beautiful (strain) " テ ト ロ Application " (registered trade mark)), polyurethane Elastic fiber (22 dtex of total fiber number, 2 long filaments, オ ペ ロ Application テ ッ Network ス systems " ラ イ Network ラ " (registered trade mark)) is with kettle footpath The setting of 76.2cm, 28/2.54cm of gauge number, stringer number 40 and course count 62 is interleaved with plain stitch, obtains base Cloth.
By the fabric for obtaining similarly to Example 1 by continuous lax/concise-dry (175 DEG C of temperature, 25 Second) operation of-setting-tuck-dyeing (115 DEG C of liquid flowing dyeing temperature)-drying (112 DEG C of temperature)-setting carries out Colour Difference, It is 21 weight %, section mixing to obtain with dress material weight ratio meter acrylic as 39 weight %, viscose rayon fibers Cationic dyeable polyester fiber be 34 weight % and polyurethane fiber be 6 weight %, weight per unit area be 150g/m2's Dress material.
Evaluate dress material obtained above be charged by friction voltage, easy-care properties, moisture absorption heating, rapid-drying properties, heat insulating ability and rise Ball.In addition, make the only fabric of the black dyeing of reactive dye dyeing and the only black dyeing of cationic dyeing during dyeing knitting Thing, and evaluate the tone of gray scale.The results are shown in table 1.Its result is that easy-care properties, rapid-drying properties and heat insulating ability are high, but is charged by friction Voltage is 2500V, and moisture absorption heating is also 2.3 DEG C, easily produces electrostatic, and the also low result of moisture absorption heating.In addition, rising Ball is 2 grades, as the tone of gray scale, dyes as long as only reactive dye, then for being close to white gray scale, contaminate as long as only cation Material dyeing, then for being close to black gray scale.
(comparative example 2)
With mixer to viscose rayon fibers beam (1.4 dtex of filament denier, length 38mm, ダ イ ワ ボ ウ レ ヨ Application (strain) is made) 50 weight %, (ultimate fibre is fine to be applied with the acrylic beam of tetraalkyl adipate of 0.4owf% Spend 1.0 dtexs, length 45mm, eastern beautiful (strain) " ト レ ロ Application " (registered trade mark)) 50 weight % carry out mixed cotton, obtain 1/64s ( Number) spun yarn.
By the spun yarn for so obtaining, section be circular cross-section fiber and section for star cross section fiber the sun that mixes of section from Sub- dyeable dacron long filament (- 48 long filament of 84 dtex of total fiber number, eastern beautiful (strain) " テ ト ロ Application " (registered trade mark)), polyurethane bullet Property fiber (22 dtex of total fiber number, 2 long filaments, オ ペ ロ Application テ ッ Network ス systems " ラ イ Network ラ " (registered trade mark)) with kettle footpath 76.2cm, 28/2.54cm of gauge number, stringer number 40, the setting of course count 62 are interleaved with plain stitch, obtain fabric.
By the fabric for obtaining similarly to Example 1 by continuous lax/concise-dry (175 DEG C of temperature, 25 Second) operation of-setting-tuck-dyeing (115 DEG C of liquid flowing dyeing temperature)-drying (112 DEG C of temperature)-setting carries out Colour Difference, It is 30 weight %, section mixing to obtain with dress material weight ratio meter acrylic as 30 weight %, viscose rayon fibers Cationic dyeable polyester fiber be 34 weight % and polyurethane series fiber be 6 weight %, weight per unit area be 150g/m2 Dress material.
Evaluate dress material obtained above be charged by friction voltage, easy-care properties, moisture absorption heating, rapid-drying properties, heat insulating ability and rise Ball.In addition, make the only fabric of the black dyeing of reactive dye dyeing and the only black dyeing of cationic dyeing during dyeing knitting Thing, and evaluate the tone of gray scale.The results are shown in table 1.Its result is that easy-care properties, rapid-drying properties and heat insulating ability are high, but is charged by friction Voltage is 1700V, and moisture absorption heating is also 2.5 DEG C, easily produces electrostatic and the also low result of moisture absorption heating.In addition, rising Ball is 2 grades.As for the tone of gray scale, dye as long as only reactive dye, be then only white gray scale, contaminate as long as only cation Material dyeing, then be only black gray scale.
(comparative example 3)
Obtain the acrylic beam (filament denier only by the tetramethyl adipate for being applied with 0.4owf% 1.0 dtexs, length 45mm, eastern beautiful (strain) " ト レ ロ Application " (registered trade mark)) constitute, the spun yarn of 1/64s (number).
By the spun yarn for so obtaining, section be circular cross-section fiber and section for star cross section fiber the sun that mixes of section from Sub- dyeable dacron long filament (84 dtex of total fiber number, 48 long filaments, eastern beautiful (strain) " テ ト ロ Application " (registered trade mark)), polyurethane series Elastic fiber (22 dtex of total fiber number, 2 long filaments, オ ペ ロ Application テ ッ Network ス systems " ラ イ Network ラ " (registered trade mark)) is with kettle footpath The setting of 76.2cm, 28/2.54cm of gauge number, stringer number 40 and course count 62 is interleaved with plain stitch, obtains base Cloth.
By the fabric for obtaining similarly to Example 1 by continuous lax/concise-dry (175 DEG C of temperature, 25 Second) operation of-setting-tuck-dyeing (115 DEG C of liquid flowing dyeing temperature)-drying (112 DEG C of temperature)-setting carries out Colour Difference, It is 0 weight %, section mixing sun to obtain with dress material weight ratio meter acrylic as 60 weight %, viscose rayon fibers Ion dyeable dacron be 34 weight % and polyurethane fiber be 6 weight %, weight per unit area be 150g/m2Clothing Material.
Evaluate dress material obtained above be charged by friction voltage, easy-care properties, moisture absorption heating, rapid-drying properties, heat insulating ability and rise Ball.In addition, make the only fabric of the black dyeing of reactive dye dyeing and the only black dyeing of cationic dyeing during dyeing knitting Thing, and evaluate the tone of gray scale.The results are shown in table 1.Its result is that easy-care properties, rapid-drying properties and heat insulating ability are very high, but rubs It is also 0.4 DEG C that electrified voltage is 5000V and moisture absorption heating, is very easy to produce electrostatic and moisture absorption heating also low-down knot Really.In addition, balling-up is 1-2 levels (1.5 grades), as the tone of gray scale, dye as long as only reactive dye, then for white, that is, do not contaminate Color, in addition, as long as only cationic dyeing, then for black.
(comparative example 4)
Obtain only by viscose rayon fibers beam (1.4 dtex of filament denier, length 38mm, ダ イ ワ ボ ウ レ ヨ Application (strain) is made) constitute, the spun yarn of 1/64s (number).
By the spun yarn for so obtaining, section be circular cross-section fiber and section for star cross section fiber section mixed-cation Dyeable dacron long filament (84 dtex of total fiber number, 48 long filaments, eastern beautiful (strain) " テ ト ロ Application " (registered trade mark)), polyurethane series bullet Property fiber (22 dtex of total fiber number, 2 long filaments, オ ペ ロ Application テ ッ Network ス systems " ラ イ Network ラ " (registered trade mark)) with kettle footpath 76.2cm, The setting of 28/2.54cm of gauge number, stringer number 40 and course count 62 is interleaved with plain stitch, obtains fabric.
By the fabric for obtaining similarly to Example 1 by continuous lax/concise-dry (175 DEG C of temperature, 25 Second) operation of-setting-tuck-dyeing (115 DEG C of liquid flowing dyeing temperature)-drying (112 DEG C of temperature)-setting carries out Colour Difference, It is 60 weight %, section mixing sun to obtain with dress material weight ratio meter acrylic as 0 weight %, viscose rayon fibers Ion dyeable dacron be 34 weight %, polyurethane fiber be 6 weight %, weight per unit area be 150g/m2Dress material.
Evaluate dress material obtained above, be charged by friction voltage, easy-care properties, moisture absorption heating, rapid-drying properties, heat insulating ability and Balling-up.In addition, making the only fabric of the black dyeing of reactive dye dyeing and the only black dyeing of cationic dyeing during dyeing Fabric, and evaluate the tone of gray scale.The results are shown in table 1.Its result is up to for being charged by friction voltage, moisture absorption heating and balling-up 3 grades, but the low-down result of easy-care properties, rapid-drying properties and heat insulating ability.As for the tone of gray scale, dye as long as only reactive dye, It is then only black gray scale, as long as only cationic dyeing, is then only white gray scale.
(comparative example 5)
With mixer to viscose rayon fibers beam (1.4 dtex of filament denier, length 38mm, ダ イ ワ ボ ウ レ ヨ Application (strain) make) 55 weight %, be applied with 0.4owf% tetraalkyl adipate acrylic acid beam (1.0 points of filament denier Spy, length 45mm, eastern beautiful (strain) " ト レ ロ Application " (registered trade mark)) 45 weight % carry out mixed cotton, obtain the thin of 1/64s (number) Yarn.
By the spun yarn for so obtaining, polyurethane elastomeric fiber (22 dtex of total fiber number, 2 long filaments, オ ペ ロ Application テ ッ Network ス systems " ラ イ Network ラ " (registered trade mark)) with the setting of kettle footpath 76.2cm, 28/2.54cm of gauge number, stringer number 40 and course count 62 It is interleaved with plain stitch, obtains fabric.
By the fabric for obtaining similarly to Example 1 by continuous lax/concise-dry (175 DEG C, 25 seconds of temperature)-fixed The operation of shape-tuck-dyeing (115 DEG C of liquid flowing dyeing temperature)-drying (112 DEG C of temperature)-setting carries out Colour Difference, obtain with Dress material weight ratio meter acrylic is 42 weight %, viscose rayon fibers are 52 weight %, section mixed-cation Dyeable dacron be 0 weight % and polyurethane fiber be 6 weight %, weight per unit area be 150g/m2Dress material.
Evaluate dress material obtained above be charged by friction voltage, easy-care properties, moisture absorption heating, rapid-drying properties, heat insulating ability and rise Ball.In addition, making the fabric of the only fabric of the black dyeing of reactive dye and the only black dyeing of the dye of positive ion during dyeing, and comment The tone of valency gray scale.The results are shown in table 1.In comparative example 5, high for being charged by friction voltage, moisture absorption heating and heat insulating ability, but exempt from Boiling hot property and the low-down result of rapid-drying properties.In addition, balling-up is 2 grades.As for the tone of gray scale, only dyeed by reactive dye and Identical tone is by cationic dyeing only.
[table 1]

Claims (8)

1. a kind of fiber structure, it is characterised in that viscose glue people is contained with the ratio more than 30 weight % and less than 40 weight % A series fiber is made, cation dyeable polyester fiber is contained with the ratio more than 30 weight % and less than 40 weight %, to exceed The 25 weight % and ratio less than 30 weight % contains polyacrylic synthetic fibers, more than 5 weight % and to be less than 10 weights The ratio of amount % contains polyurethane series elastic fiber, and the voltage that is charged by friction of the fiber structure is below 1500V, and is based on It is more than 3 grades that 103 methods of JIS L0217 wash the easy-care properties of after 5 times, AATCC124 law regulations.
2. fiber structure according to claim 1, the moisture absorption heating performance of fiber structure is more than 2.6 DEG C.
3. fiber structure according to claim 1 and 2, the residual moisture rate of fiber structure be changed into less than 30% when Between within 40 minutes.
4. fiber structure according to claim 1, the insulation rate of fiber structure is more than 14%.
5. fiber structure according to claim 1, the balling-up of fiber structure is more than 2.5 grades.
6. fiber structure according to claim 1, cation dyeable polyester fiber contain the fibre with odd-shaped cross section Dimension.
7. fiber structure according to claim 1, fiber structure are formed by the knitted fabric of single layer structure.
8. a kind of dress material, has used the fiber structure any one of claim 1~7.
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