CN105244522A - Aluminium-water reaction high-energy system apparatus - Google Patents

Aluminium-water reaction high-energy system apparatus Download PDF

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Publication number
CN105244522A
CN105244522A CN201510705522.6A CN201510705522A CN105244522A CN 105244522 A CN105244522 A CN 105244522A CN 201510705522 A CN201510705522 A CN 201510705522A CN 105244522 A CN105244522 A CN 105244522A
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combustion chamber
water
chamber
vortex
wall
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CN201510705522.6A
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龚光波
龚毅
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/08Fuel cells with aqueous electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The invention provides an aluminium-water reaction high-energy system apparatus, and the apparatus at least comprises a vortex reaction chamber. The exterior of the vortex reaction chamber is successively provided with a first combustion chamber, a second combustion chamber and a heat-energy power generation system; the vortex reaction chamber, the first combustion chamber, the second combustion chamber and the heat-energy power generation system together form a four-layer concentric jacket kettle; the vortex reaction chamber, the first combustion chamber, the second combustion chamber and the heat-energy power generation system are inside provided with a cleaning pipe, a charge pipe, a water-supplementing pipe, a first-order automatic igniter, a second-order automatic igniter, a first-order automatic exhaust valve, a second-order automatic exhaust valve, a spiral cooling water pipe and a nano-material outlet; and the exterior of the vortex reaction chamber is also provided with a comprehensive regulation and control chamber, and the comprehensive regulation and control chamber comprises a water pump, an oxygen-increasing valve, a multistage temp measurer and a multistage pressure gauge. The apparatus solves deficiencies in the prior art, by using the apparatus, a nano-material is efficiently produced when the aluminium-water reaction generates high energy, and the apparatus guarantees product friendliness, reduces production cost and possesses industrialization universality.

Description

A kind of aluminum-water reaction high energy systems device
Technical field
The invention provides a kind of aluminum-water reaction high energy systems device, adopt metallic aluminium bar as incendiary agent, utilize Environmental Water as oxidant, belong to energy source and power technical field.
Background technology
Global ship power, except only a few uses nuclear energy, remains so far and uses fossil, bio-fuel-oil.Namely cause the speed of a ship or plane low (45 joint 83 kilometers/hour within), total Cheng Jiqi that continues a journey limited.Because metallic aluminium source is wide, volume energy density is high, react with water and can generate hydrogen, hydrogen-oxygen gas, caloric value is high, and product cleans, therefore uses metal aluminum-water reaction to form desirable underwater propulsion system power resources to have become world's industry and know together.
The developed countries such as the United States, Russia are from the sixties in last century, and China has just begun one's study the eighties metal fuel chemical energy source system.Due to the generated in-situ firm and oxide-film of densification of metallic aluminum surface, the high oxidation performance of aluminium is strangled, react with water and be difficult to startup and cannot continue to carry out.Therefore, adopt the research that superfine aluminium power, aluminium lithium alloy, magnalium metal mixture, aluminium lithium magnesium metal mixture, aluminium lithium magnesium alloy etc. react with water under various conditions, and the reaction test of motlten metal and water is as emerged rapidly in large numbersBamboo shoots after a spring rain.The magnesium water reaction propulsion system of Russia's development is applied on sail body, and the speed of a ship or plane has reached 200 joints (370 kilometers/hour).And the volume energy density of aluminum-water reaction is 1.7 times of the reaction of magnesium water, the aluminum-water reaction propulsion system of research and development a new generation becomes inexorable trend.Metal fuel maybe will bring the hope terminating the fossil energy epoch.Therefore, the metal pulverization of above-mentioned aluminum-water reaction thing, diversification, alloying, reaction starts difficult, can not continue, and flow process is complicated, and cost is high, is difficult to the defects such as popularization, becomes in this area the difficult problem needing solution badly.
Summary of the invention
The invention provides the aluminum-water reaction high energy systems device that a kind of structure is simple, easy to operate, resultant effect is good, solve the deficiency in background technology; The present invention can also High-efficient Production nano material while aluminum-water reaction produces high energy thrust power; This invention ensures that product is friendly, reduce production cost, possessed industrialization popularization.
Realizing the technical scheme that above-mentioned purpose of the present invention adopts is:
A kind of aluminum-water reaction high energy systems device, at least comprise vortex reative cell, the outside of described vortex reative cell is disposed with the first combustion chamber, the second combustion chamber and heat energy power-generating system; Described vortex reative cell, the first combustion chamber, the second combustion chamber and heat energy power-generating system form four layers of concentric locking collar still jointly; The top of vortex reative cell is provided with the charge pipe and filling pipe that are in communication with the outside, and bottom is provided with the scavenge pipe be in communication with the outside; Charge pipe is provided with transformation charging valve, filling pipe is provided with transformation water compensating valve; The wall of vortex reative cell is provided with the one-level automatic exhaust steam valve with the first combustion chamber; The wall of described first combustion chamber is provided with one-level automatic ignitor and the secondary automatic exhaust steam valve with the second combustion chamber; The wall of described second combustion chamber is provided with secondary automatic ignitor and spiral cooling water pipe; The water inlet end of described spiral cooling water pipe leads to the external world through the second chamber wall, and the tail end of spiral cooling water pipe is steam (vapor) outlet; Described steam (vapor) outlet is positioned at the bottom of the second combustion chamber and leads to the external world through the second chamber wall; The bottom of the second combustion chamber is also provided with nano material outlet, and described nano material outlet leads to the external world through the second chamber wall; Described heat energy power-generating system is enclosed within the outside of the second combustion chamber, collects the heat that gives out in the second chamber wall and is converted into electric energy; Also be provided with comprehensive regulation system in described aluminum-water reaction high energy systems device, comprise water pump, oxygenation valve, multistage temperature measurer and multistage measuring cell; Wherein oxygenation valve is positioned at the second combustion chamber, provides the oxygen needed for burning; Water pump is connected with the water inlet end of spiral cooling water pipe, controls hydraulic pressure and inflow; Multistage temperature measurer and multistage measuring cell are all distributed in each layer cover still, monitor temperature and the pressure at each position at any time.
Described heat energy power-generating system is efficient heat energy generator, is provided with metallic plate heat emitters in described efficient heat energy generator.
The material of described vortex reative cell and the wall of the first combustion chamber adopts 304 stainless steels or 314 stainless steels of high strength, and the material of the wall of the second combustion chamber is S31603 stainless steel and 16Mn steel plate IV level forging.
Described one-level automatic ignitor, secondary automatic ignitor, one-level automatic exhaust steam valve and secondary automatic exhaust steam valve are all installed on the water conservancy diversion place of the first chamber wall and the second chamber wall.
In the present invention compared with prior art, have the following advantages:
1, in the present invention, materials are extremely easy, directly use metal aluminium bar and water.Do not need to do any component temporarily, match well, add, activation etc.; Reaction starts soon, reacting completely does not need the external energy, as electricity, fire, oil, gas, magnetic, wind, hot water, steam etc., achieves aluminum-water reaction simple substance, simplification.The vortex reative cell adopted in the application is vortex reactor synthesizer disclosed in Chinese patent " CN201210449241.5 ", in the process that reaction starts, trace catalyst is added in startup material, after adopting assistant chemical can start reaction, sustained response can be ensured under follow-up high pressure, high temperature, vortex energy environment.
2, any discarded object and harmful substance is not produced in the present invention.Aluminum-water reaction in vortex reative cell decomposes with chemical combination and the exothermic reaction of depositing; React in this system, the hydrogen simultaneously produced continuously, oxygen, aluminium ion, aluminium hydroxide form high temperature, high pressure mixing steam flow; In production process, center pressure is greater than skin, and mixed vapour fluid pressurized enters the first and second combustion chambers naturally; Thorough combustion after the second combustion chamber oxygenation, only has high temperature, high pressure and nano aluminium oxide in the second combustion chamber; High temperature is absorbed by spiral cooling tube and metallic plate heat emitters, transfer acting, and overbottom pressure sends nano material.
3, reaction system of the present invention is reasonable, and give full play to the high-energy combustion of elemental metals aluminium and the catalytic of Environmental Water, capacity usage ratio is high.Adopt concentric four layers of cover still system configuration, formed " miniature Ju Neng factory ", reactant and product are in best environment, the simplest flow process, safest regulation and control realize optimum reaction and utilization and recovery simultaneously.Utilize exothermic heat of reaction effect to form high temperature, high pressure, high speed saturated vapor stream, make reactant shorten burning induction time in extremely letter, extremely excellent environment, greatly improve burn rate and combustion efficiency.Reactant and product overlap orderly function in still in multilayer concentric, are fully utilized, and directly can obtain the best energy and high-quality nano-powder material.Be, efficient, energy-conservation, pollution-free.
4, in the application, heat energy power-generating system can be collected heat that the second chamber wall gives out and be converted into electric energy.Both can use traditional hot electron power generation device herein, can efficient heat energy generator have been used again, as Chinese patent " CN2009101759672 ".Traditional hot electron power generation device is made up of reflector and receiver two basic elements of character, and both are little spaced apart by one.Reflector is runaway electron after heating, and electronics arrives gatherer by intermediate space, and forms electrical potential difference between reflector and gatherer.Connect external loading, just become low-voltage dc power supply.And in efficient heat energy generator, being provided with metallic plate heat emitters, it utilizes Hall effect, makes targeted electronic stream and magnetic field relative motion and a kind of equipment generated electricity.Principle is similar to Magnetohydrodynamic(MHD) generator, but this generator replaces plasma jet with targeted electronic stream, and working temperature far below Magnetohydrodynamic(MHD) generator (working temperature only has 700-900 degree Celsius), and does not exist a difficult problem for electrode corrosion.Whole electricity generation system closed loop running, when only having thermionic current to arrive collecting board, part energy is converted into the heat energy of collecting board and loses, and other most of heat energy is all converted to electric energy, so generator is efficient, and an electrodeless corrosion difficult problem.
5, in the application, the sophisticated technologies in industry-by-industry field are merged, define the excellent product of collection.Although invention very early, application has just started, with being then perfect match in this application as efficient heat energy electric organ! Though spiral cooling tube is normal device for another example, so usage can realize heat transfer cleverly, the impassable water in nano material production process is separated admittedly, high-temperature calcination, the serial hang-up such as dispersion pulverizing " cancel all things together " and be readily solved; Vortex reactor especially the applicant oneself invention technology distillation application; Steam (vapor) outlet can with the slitless connections such as state-of-the-art injection dynamical system, turbine power system.
6, the aluminum-water reaction high energy systems apparatus function that provides of the application unique and powerful, there is very large market use prospect.Such as: be applied to sail body propulsion system, the speed of a ship or plane being only second to nuclear energy and the total journey of continuation of the journey can be produced; Be applied to high ferro trailer system, can realize supporting without electrical network running; Be applied to generating, that random scale can be formed, cheap movable type or distributed power generation station, car, group.This not only saves construction and the maintenance of large-scale generation engineering and large-scale conveying electrical network, the more important thing is and relieves Chinese energy safety crisis; Be applied to the production of nano material, its production technology, flow process, energy consumption, cost etc. can be made more to optimize; Also can be applicable to the industry such as rubbish, sewage disposal.
Accompanying drawing explanation
Fig. 1 is the overall structure schematic diagram of aluminum-water reaction high energy systems device provided by the invention;
In figure: 1-vortex reative cell, 2-first combustion chamber, 3-second combustion chamber, 4-heat energy power-generating system, 5-transformation charging valve, 6-transformation water compensating valve, 7-one-level automatic exhaust steam valve, 8-one-level automatic ignitor, 9-secondary automatic exhaust steam valve, 10-secondary automatic ignitor, 11-spiral cooling water pipe, 12-steam (vapor) outlet, 13-nano material exports, 14-water pump, 15-oxygenation valve, the multistage temperature measurer of 16-, the multistage measuring cell of 17-, 18-scavenge pipe.
Embodiment
Below in conjunction with accompanying drawing, detailed specific description is done to the present invention, but protection scope of the present invention is not limited to following examples.
The structure of the aluminum-water reaction high energy systems device that the present embodiment provides as shown in Figure 1, comprises vortex reative cell 1, and the outside of described vortex reative cell 1 is disposed with the first combustion chamber 3, combustion chamber 2, second and heat energy power-generating system 4; Described vortex reative cell 1, first combustion chamber 3, combustion chamber 2, second and heat energy power-generating system 4 be composition four layers of concentric locking collar still jointly; The material of described vortex reative cell 1 and the wall of the first combustion chamber 2 adopts 304 stainless steels or 314 stainless steels of high strength; The material of the wall of the second combustion chamber 3 is S31603 stainless steel and 16Mn steel plate IV level forging.
The top of vortex reative cell 1 is provided with the charge pipe and filling pipe that are in communication with the outside, and bottom is provided with the scavenge pipe 18 be in communication with the outside; Charge pipe is provided with transformation charging valve 5, filling pipe is provided with transformation water compensating valve 6; The wall of vortex reative cell 1 is provided with the one-level automatic exhaust steam valve 7 with the first combustion chamber; The wall of described first combustion chamber is provided with one-level automatic ignitor 8 and the secondary automatic exhaust steam valve 9 with the second combustion chamber; The wall of described second combustion chamber is provided with secondary automatic ignitor 10 and spiral cooling water pipe 11; Described one-level automatic ignitor, secondary automatic ignitor, one-level automatic exhaust steam valve and secondary automatic exhaust steam valve are all installed on the water conservancy diversion place of the first chamber wall and the second chamber wall.
The water inlet end of described spiral cooling water pipe 11 leads to the external world through the second chamber wall, and the tail end of spiral cooling water pipe is steam (vapor) outlet 12; Described steam (vapor) outlet 12 is positioned at the bottom of the second combustion chamber and leads to the external world through the second chamber wall, and the bottom of the second combustion chamber is also provided with nano material outlet 13; Described nano material outlet 13 leads to the external world through the second chamber wall.
Described heat energy power-generating system 4 is enclosed within the outside of the second combustion chamber 3, collects heat that the second chamber wall gives out and is converted into electric energy.Heat energy power-generating system described in the present embodiment is efficient heat energy generator, is provided with metallic plate heat emitters in described efficient heat energy generator; Also be provided with comprehensive regulation system in described aluminum-water reaction high energy systems device, comprise water pump 14, oxygenation valve 15, multistage temperature measurer 16 and multistage measuring cell 17.Wherein oxygenation valve 15 is positioned at the second combustion chamber, there is provided the oxygen needed for burning, water pump 14 is connected with the water inlet end of spiral cooling water pipe 11, controls hydraulic pressure and inflow, multistage temperature measurer 16 and multistage measuring cell 17 are all distributed in each layer cover still, monitor temperature and the pressure at each position at any time.

Claims (4)

1. an aluminum-water reaction high energy systems device, at least comprises vortex reative cell, it is characterized in that: the outside of described vortex reative cell is disposed with the first combustion chamber, the second combustion chamber and heat energy power-generating system; Described vortex reative cell, the first combustion chamber, the second combustion chamber and heat energy power-generating system form four layers of concentric locking collar still jointly; The top of vortex reative cell is provided with the charge pipe and filling pipe that are in communication with the outside, bottom is provided with the scavenge pipe be in communication with the outside, charge pipe is provided with transformation charging valve, filling pipe is provided with transformation water compensating valve, the wall of vortex reative cell is provided with the one-level automatic exhaust steam valve with the first combustion chamber; The wall of described first combustion chamber is provided with one-level automatic ignitor and the secondary automatic exhaust steam valve with the second combustion chamber; The wall of described second combustion chamber is provided with secondary automatic ignitor and spiral cooling water pipe; The water inlet end of described spiral cooling water pipe leads to the external world through the second chamber wall, and the tail end of spiral cooling water pipe is steam (vapor) outlet; Described steam (vapor) outlet is positioned at the bottom of the second combustion chamber and leads to the external world through the second chamber wall, and the bottom of the second combustion chamber is also provided with nano material outlet; Described nano material outlet leads to the external world through the second chamber wall; Described heat energy power-generating system is enclosed within the outside of the second combustion chamber, collects the heat that gives out in the second chamber wall and is converted into electric energy; Also be provided with comprehensive regulation system in described aluminum-water reaction high energy systems device, comprise water pump, oxygenation valve, multistage temperature measurer and multistage measuring cell; Wherein oxygenation valve is positioned at the second combustion chamber, there is provided the oxygen needed for burning, water pump is connected with the water inlet end of spiral cooling water pipe, controls hydraulic pressure and inflow, multistage temperature measurer and multistage measuring cell are all distributed in each layer cover still, monitor temperature and the pressure at each position at any time.
2. aluminum-water reaction high energy systems device according to claim 1, is characterized in that: described heat energy power-generating system is efficient heat energy generator, is provided with metallic plate heat emitters in described efficient heat energy generator.
3. aluminum-water reaction high energy systems device according to claim 1, it is characterized in that: the material of described vortex reative cell and the wall of the first combustion chamber adopts 304 stainless steels or 314 stainless steels of high strength, and the material of the wall of the second combustion chamber is S31603 stainless steel and 16Mn steel plate IV level forging.
4. aluminum-water reaction high energy systems device according to claim 1, is characterized in that: described one-level automatic ignitor, secondary automatic ignitor, one-level automatic exhaust steam valve and secondary automatic exhaust steam valve are all installed on the water conservancy diversion place of the first chamber wall and the second chamber wall.
CN201510705522.6A 2015-10-27 2015-10-27 Aluminium-water reaction high-energy system apparatus Pending CN105244522A (en)

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Application Number Priority Date Filing Date Title
CN201510705522.6A CN105244522A (en) 2015-10-27 2015-10-27 Aluminium-water reaction high-energy system apparatus

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CN105244522A true CN105244522A (en) 2016-01-13

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108916850A (en) * 2018-06-15 2018-11-30 西南科技大学 A kind of hydroreactive metal fuel eddy flow punching press steam generator
CN109058977A (en) * 2018-06-15 2018-12-21 中国人民解放军国防科技大学 Double-combustion-chamber device for combustion of aluminum particles and water
CN111172562A (en) * 2020-01-20 2020-05-19 镇江慧诚新材料科技有限公司 Preparation method of fuel aluminum for aluminum-air battery

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108916850A (en) * 2018-06-15 2018-11-30 西南科技大学 A kind of hydroreactive metal fuel eddy flow punching press steam generator
CN109058977A (en) * 2018-06-15 2018-12-21 中国人民解放军国防科技大学 Double-combustion-chamber device for combustion of aluminum particles and water
CN111172562A (en) * 2020-01-20 2020-05-19 镇江慧诚新材料科技有限公司 Preparation method of fuel aluminum for aluminum-air battery

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Application publication date: 20160113