CN201902241U - Generating device utilizing discharge smoke waste heat of gas turbine engine - Google Patents
Generating device utilizing discharge smoke waste heat of gas turbine engine Download PDFInfo
- Publication number
- CN201902241U CN201902241U CN2010206767565U CN201020676756U CN201902241U CN 201902241 U CN201902241 U CN 201902241U CN 2010206767565 U CN2010206767565 U CN 2010206767565U CN 201020676756 U CN201020676756 U CN 201020676756U CN 201902241 U CN201902241 U CN 201902241U
- Authority
- CN
- China
- Prior art keywords
- gas turbine
- fuel cell
- turbine engine
- pipeline
- reforming reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Fuel Cell (AREA)
Abstract
The utility model discloses a generating device utilizing the discharge smoke waste heat of a gas turbine engine. The generating device comprises a reforming reactor, a refining device, a pressure boosting device and a fuel cell, wherein the reforming reactor, the refining device, the pressure boosting device and the fuel cell are connected in sequence through pipelines, a heat supply pipeline of the reforming reactor is connected with a smoke discharge pipeline of a gas turbine of a gas turbine engine, and the fuel cell is communicated with an air compressor of the gas turbine engine through a pipeline. Methanol reforming is performed by utilizing the discharge smoke waste heat of the gas turbine engine, so as to prepare hydrogen; and the prepared hydrogen is used for a fuel cell generating system, the grade of the discharge smoke waste heat of the gas turbine engine is promoted through thermochemical reaction, and the discharge smoke waste heat is converted into synthesis gas for reaction, so that the energy consumption for preparing hydrogen through methanol is effectively reduced. The generating device efficiently utilizes the unreacted gas in the fuel cell system, lowers the nitrogen oxide emission and fuel consumption of the gas turbine engine, and improves the fuel utilization and generating efficiency of the system.
Description
Technical field
The utility model relates to a kind of electricity generating device, especially a kind of device that utilizes the generating of gas turbine smoke discharging residual heat.
Background technique
Gas turbine is a kind of hot merit converting apparatus that grows up in recent decades, after nineteen thirty-nine Switzerland BBC company develops the electric generation gas turbine of the first in the world platform 4000kW, especially in the last few years liquids and gases fuel was widely-used, and gas turbine is comparatively fast developed.Gas turbine has had 60 years of development history, and its performance, efficient and technical merit have had large increase.Based on the strategy of economic development and the demand of international competition, many countries first develop advanced gas turbine technology the emphasis in field as national science and technology.The eighties in 20th century, it is two keys in the economy of energy that gas turbine engineering circle has proposed high thermal efficiency and suitability of fuel.Because of modern gas turbines have pollute little, gas adaptability strong, start outstanding advantage such as fast, that power is big is used widely in fields such as generating, aviation, naval vessel, military and Mechanical Driven.In the afterbody afterheat utilization process of gas turbine, usually connect exhaust heat boiler at present, produce the steam of certain grade, be used for the combustion and steam combined cycle, thereby improved the generating efficiency of system to a certain extent.Yet, since the restriction of gas turbine tail flue gas temperature, the situation of pressure or sub-high pressure during the steam that exhaust heat boiler produces is in mostly, thus cause the hot effect rate of changeing of steam side circuit not high.At present, the system of combustion and steam combined cycle heat is changeed the effect rate usually between 55%～60%.In addition, the tail flue gas of gas turbine also usually is used for lithium bromide absorbing type refrigeration, obtains a part of cold.Above-mentioned these gas turbine tail flue gas afterheat utilization processes just relate to the conversion between the heat energy, do not improve the grade of gas turbine tail flue gas waste heat, thereby can not increase substantially the cycle efficiency in afterbody waste heat downstream.
Fuel cell is the electricity generating device that a kind of chemical energy that directly will be stored in fuel and the oxygenant is converted into electric energy efficiently, because fuel cell does not relate to burning in the course of the work, only generate water by electrochemical reaction, thereby be not subjected to the restriction of Carnot's cycle, its energy conversion efficiency obviously improves, and in conversion process of energy, the discharging of pollutant seldom.According to the difference of using the electrolyte kind, fuel cell can be divided into: alkaline fuel cell (AFC), Proton Exchange Membrane Fuel Cells (PEMFC), phosphatic acid fuel cell (PAFC), molten carbonate fuel cell (MCFC) and Solid Oxide Fuel Cell (SOFC).Usually MCFC and SOFC are high-temperature fuel cell, in these two kinds of fuel cells, generally adopt the rock gas inside reforming to make hydrogen, with airborne oxygen generation electrochemical reaction output electric energy.
Therefore, designing a kind of device that utilizes the cogeneration of gas turbine tail flue gas, is the present technical issues that need to address.
Summary of the invention
Technical problem to be solved in the utility model provides a kind of device that utilizes the cogeneration of gas turbine tail flue gas.
The technical scheme in the invention for solving the technical problem is:
A kind of device that utilizes the generating of gas turbine smoke discharging residual heat, form by reforming reactor, purifying plant, increasing apparatus and fuel cell, reforming reactor, purifying plant, increasing apparatus and fuel cell link to each other successively by pipeline, the heat supply pipeline of reforming reactor is connected with the gas exhaust duct of the combustion gas turbine of gas turbine generator, and fuel cell is communicated with the air pressure mechanism of qi of gas turbine generator by pipeline.
The technical scheme in the invention for solving the technical problem can also be:
The Waste gas outlet of fuel cell of the present utility model links to each other with firing chamber in the gas turbine by pipeline.
Fuel cell described in the utility model is alkaline fuel cell (AFC), Proton Exchange Membrane Fuel Cells (PEMFC), phosphatic acid fuel cell (PAFC), molten carbonate fuel cell (MCFC) or Solid Oxide Fuel Cell (SOFC).
Principle of the present utility model is to utilize the smoke discharging residual heat of gas turbine to carry out methanol recapitalization to produce hydrogen, and gained hydrogen is used for fuel cell generation, improve the tradition of gas turbine smoke discharging residual heat and utilized mode, effectively reduced the energy consumption of hydrogen from methyl alcohol, realized purpose of energy saving.
The utility model is achieved in that the smoke evacuation of coming out from the combustion gas turbine of gas turbine enters reforming reactor, adding mol ratio in reforming reactor is water and the methyl alcohol of 1.5～2:1, and the smoke discharging residual heat of water and methyl alcohol absorption gas turbine carries out thermal chemical reaction [CH under the effect of catalyzer
3OH(g)+H
2O(g) → 3H
2+ CO
2Δ H=50.7kJ/mol], reacted synthetic gas (mainly contains H
2With CO
2) promptly to get purity after separating by purifying plant be 80～90% hydrogen.Then that purity is higher hydrogen enters fuel cell after boosting through increasing apparatus, isolating air in certain amount from the air blower outlet of gas turbine enters fuel cell in addition, the higher hydrogen of airborne oxygen and purity reacts in fuel cell, the output electric energy.
The part water vapor that the unreacting gas of fuel cell and fuel cell produce enters in the firing chamber of gas turbine jointly.
The used catalyzer of preceding method preferably part by weight is 5～14: 3～10: 4～13 Cu, ZnO and Al
2O
3
The reaction temperature of water and methyl alcohol is 150 ℃～300 ℃ in the reforming reactor, and reaction pressure is 1bar～10bar.
Compared with prior art, the utility model utilizes the smoke discharging residual heat of gas turbine to carry out methanol recapitalization and produces hydrogen, and gained hydrogen is used for fuel cell generation, utilizing thermal chemical reaction that the smoke discharging residual heat of gas turbine is carried out grade promotes and is transformed in the reacting synthesis gas, improve the tradition of utilizing the gas turbine smoke discharging residual heat to produce steam and utilized mode, for hydrogen from methyl alcohol provides new thinking, effectively reduce the energy consumption of hydrogen from methyl alcohol.The utility model has efficiently utilized the unreacting gas in the fuel cell system simultaneously, has reduced the discharging and the fuel consumption of gas turbine nitrogen oxide, has improved the fuel availability and the generating efficiency of system, has realized corresponding energy-conservation purpose.
Description of drawings
Fig. 1 is the system schematic of model utility.
Embodiment
A kind of device that utilizes the generating of gas turbine smoke discharging residual heat, form by reforming reactor 1, purifying plant 2, increasing apparatus 3 and fuel cell 4, reforming reactor 1, purifying plant 2, increasing apparatus 3 and fuel cell 4 link to each other successively by pipeline, the heat supply pipeline of reforming reactor 1 is connected with the gas exhaust duct of the combustion gas turbine 7 of gas turbine generator 8, and fuel cell 4 is communicated with the air pressure mechanism of qi 5 of gas turbine generator by pipeline.The Waste gas outlet of fuel cell 4 links to each other with firing chamber 6 in the gas turbine by pipeline.Described fuel cell 4 is alkaline fuel cell (AFC), Proton Exchange Membrane Fuel Cells (PEMFC), phosphatic acid fuel cell (PAFC), molten carbonate fuel cell (MCFC) or Solid Oxide Fuel Cell (SOFC).
Embodiment 1: utilize the method for gas turbine smoke discharging residual heat to be: the smoke evacuation (500 ℃) of coming out from the combustion gas turbine 7 of gas turbine enters reforming reactor 1, the adding mol ratio is 1.8: 1 water and a methyl alcohol (25 ℃) in reforming reactor 1, is 6: 3: 4 Cu/ZnO/Al at part by weight
2O
3The smoke discharging residual heat of water and methyl alcohol absorption gas turbine carries out thermal chemical reaction: CH under the catalysis
3OH(g)+H
2O(g) → 3H
2+ CO
2, reaction temperature is 260 ℃, reaction pressure is 5bar, reaction back temperature of exhaust fume is reduced to 180 ℃, generation mainly contain H
2With CO
2Synthetic gas (260 ℃) obtain purity after separating by PSA purifying plant 2 and be about 90% hydrogen.Gained hydrogen boosts to through increasing apparatus 3 and enters Solid Oxide Fuel Cell (SOFC) 4 after pressure is 6bar～7bar, isolate air in certain amount (280 ℃) from air pressure mechanism of qi 5 outlets of gas turbine in addition and enter Solid Oxide Fuel Cell 4, airborne oxygen and purity are that 90% hydrogen (800 ℃～1000 ℃) in fuel cell 4 reacts, export certain electric energy, generating efficiency (HHV) is about 65%.The part water vapor that the unreacting gas of fuel cell 4 and fuel cell 4 produces enters in the firing chamber 6 of gas turbine recycling jointly.
Utilize the used device (see figure 1) of gas turbine smoke discharging residual heat according to the method described above, comprise reforming reactor 1, PSA purifying plant 2, increasing apparatus 3 and Solid Oxide Fuel Cell 4, reforming reactor 1 links to each other with the gas exhaust duct of combustion gas turbine 7 in the gas turbine, reforming reactor 1, PSA purifying plant 2, link to each other successively by pipeline between increasing apparatus 3 and the Solid Oxide Fuel Cell 4, and the air pressure mechanism of qi 5 in the gas turbine and Solid Oxide Fuel Cell 4 link to each other by pipeline, and firing chamber in Solid Oxide Fuel Cell 4 and the gas turbine 6 links to each other by pipeline.
Comprise the power generation system of utilizing gas turbine smoke discharging residual heat equipment therefor, by air pressure mechanism of qi 5, firing chamber 6, gas turbine and reforming reactor 1 that combustion gas turbine 7 and generator 8 are formed, PSA purifying plant 2, increasing apparatus 3, Solid Oxide Fuel Cell 4 constitutes, reforming reactor 1 links to each other with the gas exhaust duct of combustion gas turbine 7 in the gas turbine, reforming reactor 1, PSA purifying plant 2, link to each other successively by pipeline between increasing apparatus 3 and the Solid Oxide Fuel Cell 4, and the air pressure mechanism of qi 5 in the gas turbine links to each other with Solid Oxide Fuel Cell 4 by pipeline, and Solid Oxide Fuel Cell 4 links to each other with firing chamber 6 in the gas turbine by pipeline.In this power generation system, the generating efficiency of generator 8 is about 35% in the gas turbine, and the generating efficiency of fuel cell 4 is about 65%, and total generating efficiency is 67%, has improved 12% approximately than the gas turbine and the fuel cell integrated system generating efficiency of routine.
Embodiment 2: the smoke evacuation (480 ℃) of coming out from the combustion gas turbine 7 of gas turbine enters reforming reactor 1, adds mol ratio and be 1.5: 1 water and methyl alcohol (25 ℃) in reforming reactor 1, is 14: 10: 13 Cu/ZnO/Al at part by weight
2O
3The smoke discharging residual heat of water and methyl alcohol absorption gas turbine carries out thermal chemical reaction: CH under the catalysis
3OH(g)+H
2O(g) → 3H
2+ CO
2, reaction temperature is 200 ℃, reaction pressure is 10bar, reaction back temperature of exhaust fume is reduced to 160 ℃, generation mainly contain H
2With CO
2Synthetic gas (200 ℃) to obtain purity after separating by PSA purifying plant 2 be 85% hydrogen.Gained hydrogen boosts to through increasing apparatus 3 and enters molten carbonate fuel cell (MCFC) 4 after pressure is 6bar～7bar, isolate air in certain amount (260 ℃) from air pressure mechanism of qi 5 outlets of gas turbine in addition and enter molten carbonate fuel cell 4, airborne oxygen and purity are that 85% hydrogen (600 ℃～700 ℃) in fuel cell 4 reacts, export certain electric energy, generating efficiency (HHV) is about 60%.The part water vapor that the unreacting gas of fuel cell 4 and fuel cell 4 produces enters in the firing chamber 6 of gas turbine recycling jointly.
Utilize the used device (see figure 1) of gas turbine smoke discharging residual heat with embodiment 1 according to the method described above, wherein said fuel cell 4 is molten carbonate fuel cell (MCFC).
Comprise the power generation system of utilizing gas turbine smoke discharging residual heat equipment therefor, by air pressure mechanism of qi 5, firing chamber 6, gas turbine and reforming reactor 1 that combustion gas turbine 7 and generator 8 are formed, PSA purifying plant 2, increasing apparatus 3, molten carbonate fuel cell 4 constitutes, reforming reactor 1 links to each other with the gas exhaust duct of combustion gas turbine 7 in the gas turbine, reforming reactor 1, PSA purifying plant 2, link to each other successively by pipeline between increasing apparatus 3 and the molten carbonate fuel cell 4, and the air pressure mechanism of qi 5 in the gas turbine links to each other with molten carbonate fuel cell 4 by pipeline, and molten carbonate fuel cell 4 links to each other with firing chamber 6 in the gas turbine by pipeline.In this power generation system, the generating efficiency of generator 8 is about 35% in the gas turbine, and the generating efficiency of fuel cell 4 is about 60%, and total generating efficiency is 63%, has improved 8% approximately than the gas turbine and the fuel cell integrated system generating efficiency of routine.
Embodiment 3: utilize the method for gas turbine smoke discharging residual heat to be: the smoke evacuation (520 ℃) of coming out from the combustion gas turbine 7 of gas turbine enters reforming reactor 1, the adding mol ratio is 2: 1 water and a methyl alcohol (25 ℃) in reforming reactor 1, is 9: 4: 5 Cu/ZnO/Al at part by weight
2O
3The smoke discharging residual heat of water and methyl alcohol absorption gas turbine carries out thermal chemical reaction: CH under the catalysis
3OH(g)+H
2O(g) → 3H
2+ CO
2, reaction temperature is 150 ℃～200 ℃, reaction pressure is 6bar～8bar, reaction back temperature of exhaust fume is reduced to 200 ℃, generation mainly contain H
2With CO
2Synthetic gas (180 ℃) to obtain purity after separating by purifying plant 2 be 80% hydrogen.Gained hydrogen can enter fuel cell generation, also can store to be used for the hydrogenation station.
Utilize the device of gas turbine smoke discharging residual heat according to the method described above, comprise reforming reactor 1 and purifying plant 2, reforming reactor 1 links to each other with the gas exhaust duct of combustion gas turbine 7 in the gas turbine, links to each other by pipeline between purifying plant 2 and the reforming reactor 1; Purifying plant 2 links to each other with fuel cell generation with pressurization device by pipeline or is connected with hydrogen storage tank, as the fuel source at hydrogenation station.
Claims (3)
1. device that utilizes gas turbine smoke discharging residual heat generating, form by reforming reactor (1), purifying plant (2), increasing apparatus (3) and fuel cell (4), reforming reactor (1), purifying plant (2), increasing apparatus (3) and fuel cell (4) link to each other successively by pipeline, it is characterized in that: the heat supply pipeline of reforming reactor (1) is connected with the gas exhaust duct of the combustion gas turbine (7) of gas turbine generator (8), and fuel cell (4) is communicated with the air pressure mechanism of qi (5) of gas turbine generator by pipeline.
2. a kind of device that utilizes gas turbine smoke discharging residual heat generating according to claim 1 is characterized in that: the Waste gas outlet of fuel cell (4) links to each other with firing chamber (6) in the gas turbine by pipeline.
3. a kind of device that utilizes the generating of gas turbine smoke discharging residual heat according to claim 1 and 2 is characterized in that: described fuel cell (4) is alkaline fuel cell (AFC), Proton Exchange Membrane Fuel Cells (PEMFC), phosphatic acid fuel cell (PAFC), molten carbonate fuel cell (MCFC) or Solid Oxide Fuel Cell (SOFC).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010206767565U CN201902241U (en) | 2010-12-23 | 2010-12-23 | Generating device utilizing discharge smoke waste heat of gas turbine engine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010206767565U CN201902241U (en) | 2010-12-23 | 2010-12-23 | Generating device utilizing discharge smoke waste heat of gas turbine engine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN201902241U true CN201902241U (en) | 2011-07-20 |
Family
ID=44272841
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010206767565U Expired - Fee Related CN201902241U (en) | 2010-12-23 | 2010-12-23 | Generating device utilizing discharge smoke waste heat of gas turbine engine |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN201902241U (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102562314A (en) * | 2012-01-11 | 2012-07-11 | 哈尔滨工程大学 | Plasma catalysis based chemical heat extraction cycle gas turbine device |
| CN102661200A (en) * | 2012-05-17 | 2012-09-12 | 沈阳航空航天大学 | Fuel cell/gas turbine hybrid power system with catalytic combustor |
| CN104126058A (en) * | 2012-02-23 | 2014-10-29 | 昭和电工株式会社 | Power generation apparatus, power generation method, decomposition-gas boiler and decomposition-gas turbine |
| US9077006B2 (en) | 2013-03-15 | 2015-07-07 | Exxonmobil Research And Engineering Company | Integrated power generation and carbon capture using fuel cells |
| US9077007B2 (en) | 2013-03-15 | 2015-07-07 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using fuel cells |
| CN105258384A (en) * | 2015-11-26 | 2016-01-20 | 中国科学院工程热物理研究所 | Combined cooling heating and power system integrating thermochemical process |
| US9556753B2 (en) | 2013-09-30 | 2017-01-31 | Exxonmobil Research And Engineering Company | Power generation and CO2 capture with turbines in series |
| US9755258B2 (en) | 2013-09-30 | 2017-09-05 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using solid oxide fuel cells |
| US9819042B2 (en) | 2013-09-30 | 2017-11-14 | Exxonmobil Research And Engineering Company | Fuel cell integration within a heat recovery steam generator |
| CN113036178A (en) * | 2021-03-03 | 2021-06-25 | 江苏大学 | Engine and solid oxide fuel cell combined power system |
| US11211621B2 (en) | 2018-11-30 | 2021-12-28 | Exxonmobil Research And Engineering Company | Regeneration of molten carbonate fuel cells for deep CO2 capture |
| US11335937B2 (en) | 2019-11-26 | 2022-05-17 | Exxonmobil Research And Engineering Company | Operation of molten carbonate fuel cells with high electrolyte fill level |
| US11424469B2 (en) | 2018-11-30 | 2022-08-23 | ExxonMobil Technology and Engineering Company | Elevated pressure operation of molten carbonate fuel cells with enhanced CO2 utilization |
| US11476486B2 (en) | 2018-11-30 | 2022-10-18 | ExxonMobil Technology and Engineering Company | Fuel cell staging for molten carbonate fuel cells |
| US11664519B2 (en) | 2019-11-26 | 2023-05-30 | Exxonmobil Research And Engineering Company | Fuel cell module assembly and systems using same |
| US11695122B2 (en) | 2018-11-30 | 2023-07-04 | ExxonMobil Technology and Engineering Company | Layered cathode for molten carbonate fuel cell |
| US11742508B2 (en) | 2018-11-30 | 2023-08-29 | ExxonMobil Technology and Engineering Company | Reforming catalyst pattern for fuel cell operated with enhanced CO2 utilization |
| US11888187B2 (en) | 2018-11-30 | 2024-01-30 | ExxonMobil Technology and Engineering Company | Operation of molten carbonate fuel cells with enhanced CO2 utilization |
| US11978931B2 (en) | 2021-02-11 | 2024-05-07 | ExxonMobil Technology and Engineering Company | Flow baffle for molten carbonate fuel cell |
-
2010
- 2010-12-23 CN CN2010206767565U patent/CN201902241U/en not_active Expired - Fee Related
Cited By (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102562314A (en) * | 2012-01-11 | 2012-07-11 | 哈尔滨工程大学 | Plasma catalysis based chemical heat extraction cycle gas turbine device |
| CN104126058B (en) * | 2012-02-23 | 2016-07-06 | 昭和电工株式会社 | TRT, electricity-generating method, decomposition gas boiler and decomposition gas turbine |
| CN104126058A (en) * | 2012-02-23 | 2014-10-29 | 昭和电工株式会社 | Power generation apparatus, power generation method, decomposition-gas boiler and decomposition-gas turbine |
| US9567875B2 (en) | 2012-02-23 | 2017-02-14 | Showa Denko K.K. | Power generation apparatus, power generation method, decomposition-gas turbine and decomposition-gas boiler |
| CN102661200A (en) * | 2012-05-17 | 2012-09-12 | 沈阳航空航天大学 | Fuel cell/gas turbine hybrid power system with catalytic combustor |
| US9650246B2 (en) | 2013-03-15 | 2017-05-16 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells in fischer-tropsch synthesis |
| US9455463B2 (en) | 2013-03-15 | 2016-09-27 | Exxonmobil Research And Engineering Company | Integrated electrical power and chemical production using fuel cells |
| US9178234B2 (en) | 2013-03-15 | 2015-11-03 | Exxonmobil Research And Engineering Company | Integrated power generation using molten carbonate fuel cells |
| US10676799B2 (en) | 2013-03-15 | 2020-06-09 | Exxonmobil Research And Engineering Company | Integrated electrical power and chemical production using fuel cells |
| US9257711B2 (en) | 2013-03-15 | 2016-02-09 | Exxonmobil Research And Engineering Company | Integrated carbon capture and chemical production using fuel cells |
| US9263755B2 (en) | 2013-03-15 | 2016-02-16 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells in iron and steel processing |
| US9343763B2 (en) | 2013-03-15 | 2016-05-17 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells for synthesis of nitrogen compounds |
| US9343764B2 (en) | 2013-03-15 | 2016-05-17 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells in methanol synthesis |
| US9362580B2 (en) | 2013-03-15 | 2016-06-07 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells in a refinery setting |
| US9077005B2 (en) | 2013-03-15 | 2015-07-07 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells in Fischer-Tropsch synthesis |
| US9419295B2 (en) | 2013-03-15 | 2016-08-16 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using fuel cells at a reduced electrical efficiency |
| US9923219B2 (en) | 2013-03-15 | 2018-03-20 | Exxonmobile Research And Engineering Company | Integrated operation of molten carbonate fuel cells |
| US9520607B2 (en) | 2013-03-15 | 2016-12-13 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells with fermentation processes |
| US9553321B2 (en) | 2013-03-15 | 2017-01-24 | Exxonmobile Research And Engineering Company | Integrated power generation and carbon capture using fuel cells |
| US10093997B2 (en) | 2013-03-15 | 2018-10-09 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells in iron and steel processing |
| US9077007B2 (en) | 2013-03-15 | 2015-07-07 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using fuel cells |
| US9647284B2 (en) | 2013-03-15 | 2017-05-09 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells in Fischer-Tropsch synthesis |
| US9077006B2 (en) | 2013-03-15 | 2015-07-07 | Exxonmobil Research And Engineering Company | Integrated power generation and carbon capture using fuel cells |
| US9735440B2 (en) | 2013-03-15 | 2017-08-15 | Exxonmobil Research And Engineering Company | Integration of molten carbonate fuel cells in fischer-tropsch synthesis |
| US9077008B2 (en) | 2013-03-15 | 2015-07-07 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using fuel cells |
| US9786939B2 (en) | 2013-03-15 | 2017-10-10 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using fuel cells |
| US9941534B2 (en) | 2013-03-15 | 2018-04-10 | Exxonmobil Research And Engineering Company | Integrated power generation and carbon capture using fuel cells |
| US9755258B2 (en) | 2013-09-30 | 2017-09-05 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using solid oxide fuel cells |
| US9819042B2 (en) | 2013-09-30 | 2017-11-14 | Exxonmobil Research And Engineering Company | Fuel cell integration within a heat recovery steam generator |
| US9556753B2 (en) | 2013-09-30 | 2017-01-31 | Exxonmobil Research And Engineering Company | Power generation and CO2 capture with turbines in series |
| US10283802B2 (en) | 2013-09-30 | 2019-05-07 | Exxonmobil Research And Engineering Company | Fuel cell integration within a heat recovery steam generator |
| CN105258384A (en) * | 2015-11-26 | 2016-01-20 | 中国科学院工程热物理研究所 | Combined cooling heating and power system integrating thermochemical process |
| US11742508B2 (en) | 2018-11-30 | 2023-08-29 | ExxonMobil Technology and Engineering Company | Reforming catalyst pattern for fuel cell operated with enhanced CO2 utilization |
| US11211621B2 (en) | 2018-11-30 | 2021-12-28 | Exxonmobil Research And Engineering Company | Regeneration of molten carbonate fuel cells for deep CO2 capture |
| US11424469B2 (en) | 2018-11-30 | 2022-08-23 | ExxonMobil Technology and Engineering Company | Elevated pressure operation of molten carbonate fuel cells with enhanced CO2 utilization |
| US11476486B2 (en) | 2018-11-30 | 2022-10-18 | ExxonMobil Technology and Engineering Company | Fuel cell staging for molten carbonate fuel cells |
| US11616248B2 (en) | 2018-11-30 | 2023-03-28 | ExxonMobil Technology and Engineering Company | Elevated pressure operation of molten carbonate fuel cells with enhanced CO2 utilization |
| US11695122B2 (en) | 2018-11-30 | 2023-07-04 | ExxonMobil Technology and Engineering Company | Layered cathode for molten carbonate fuel cell |
| US11843150B2 (en) | 2018-11-30 | 2023-12-12 | ExxonMobil Technology and Engineering Company | Fuel cell staging for molten carbonate fuel cells |
| US11888187B2 (en) | 2018-11-30 | 2024-01-30 | ExxonMobil Technology and Engineering Company | Operation of molten carbonate fuel cells with enhanced CO2 utilization |
| US11335937B2 (en) | 2019-11-26 | 2022-05-17 | Exxonmobil Research And Engineering Company | Operation of molten carbonate fuel cells with high electrolyte fill level |
| US11664519B2 (en) | 2019-11-26 | 2023-05-30 | Exxonmobil Research And Engineering Company | Fuel cell module assembly and systems using same |
| US11888199B2 (en) | 2019-11-26 | 2024-01-30 | ExxonMobil Technology and Engineering Company | Operation of molten carbonate fuel cells with high electrolyte fill level |
| US11978931B2 (en) | 2021-02-11 | 2024-05-07 | ExxonMobil Technology and Engineering Company | Flow baffle for molten carbonate fuel cell |
| CN113036178A (en) * | 2021-03-03 | 2021-06-25 | 江苏大学 | Engine and solid oxide fuel cell combined power system |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN201902241U (en) | Generating device utilizing discharge smoke waste heat of gas turbine engine | |
| CN113944544A (en) | Energy system based on renewable energy and hydrogen methanolization and energy utilization method | |
| Yu et al. | Hydrogen-based combined heat and power systems: A review of technologies and challenges | |
| CN110921622A (en) | Methanol steam and hydrogen mixed gas integrated high-pressure hydrogen production system and method thereof | |
| CN110921623A (en) | Hydrogen separation and water gas reforming integrated high-pressure hydrogen production system and method thereof | |
| CN211998812U (en) | Methanol steam and hydrogen mixed gas integrated high-pressure hydrogen production system | |
| CN110835094A (en) | Methanol steam and hydrogen mixed gas integrated ultrahigh pressure hydrogen production system and method thereof | |
| CN116544466A (en) | Combined power generation system of thermal ammonia turbine and proton exchange membrane fuel cell | |
| CN202797151U (en) | Fuel battery system of electromobile | |
| CN110661014B (en) | Efficient low-concentration gas power generation system and control method thereof | |
| CN211998811U (en) | Reforming and separating integrated medium-pressure hydrogen production system | |
| CN211998802U (en) | Hydrogen separation and water gas reforming integrated medium-pressure hydrogen production system | |
| CN211998813U (en) | Methanol steam and hydrogen mixed gas integrated medium-pressure hydrogen production system | |
| CN211998804U (en) | Methanol steam and hydrogen mixed gas integrated ultrahigh pressure hydrogen production system | |
| CN213112522U (en) | Reforming and separating integrated high-pressure hydrogen production system | |
| CN211998801U (en) | Hydrogen separation and water gas reforming integrated high-pressure hydrogen production system | |
| CN209312923U (en) | A kind of fuel-cell device | |
| CN211998808U (en) | Hydrogen separation and water gas reforming integrated ultrahigh pressure hydrogen production system | |
| CN211847143U (en) | Hydrogen separation and water gas reforming integrated low-pressure hydrogen production system | |
| CN112786934A (en) | Phosphoric acid fuel cell power system taking methanol as raw material and power generation method thereof | |
| CN102966389A (en) | Smoke extraction waste heat recycling method of combustion gas turbine | |
| CN102966388A (en) | Smoke extraction waste heat recycling device of combustion gas turbine | |
| CN112886621A (en) | Renewable electric energy storage system | |
| CN110817799A (en) | Reforming and separating integrated ultrahigh-pressure hydrogen production system and hydrogen production method thereof | |
| CN110817794A (en) | Hydrogen separation and water gas reforming integrated ultrahigh-pressure hydrogen production system and method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Guantao Xin Neng living beings Thermal Power Co., Ltd Assignor: Hebei New Energy Power Group Co., Ltd. Contract record no.: 2013130000110 Denomination of utility model: Generating device utilizing discharge smoke waste heat of gas turbine engine Granted publication date: 20110720 License type: Exclusive License Record date: 20131009 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110720 Termination date: 20141223 |
|
| EXPY | Termination of patent right or utility model |