CN105237966B - Isomeric crosslinking technology toughened and reinforced recovered PBT and PET alloy and preparation method thereof - Google Patents
Isomeric crosslinking technology toughened and reinforced recovered PBT and PET alloy and preparation method thereof Download PDFInfo
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- CN105237966B CN105237966B CN201510746866.1A CN201510746866A CN105237966B CN 105237966 B CN105237966 B CN 105237966B CN 201510746866 A CN201510746866 A CN 201510746866A CN 105237966 B CN105237966 B CN 105237966B
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Abstract
The invention relates to a polymer material and a preparation method thereof, and concretely relates to an isomeric crosslinking technology toughened and reinforced recovered PBT and PET alloy and a preparation method thereof. The method comprises the following steps: carrying out air blasting drying on the recovered PBT and PET alloy at 120DEG C for 24h; and weighing dried recovered PBT and PET alloy, a crosslinking master batch and a nucleating agent according to weight proportions, adding the weighed materials into a high speed mixer, mixing for 4-6min, and carrying out extruding granulation by adopting a double screw extruder at 220-260DEG C under a screw rotating speed of 140r/min to obtain the isomeric crosslinking technology toughened and reinforced recovered PBT and PET alloy. Toughening adopted in traditional recovery methods and realized through increasing the amount of an elastomer toughening agent usually causes decrease of the tensile property of the recovered PBT and PET alloy and influences the integral mechanical performances; and the reinforcing and toughening effects of the recovered PBT and PET alloy can be realized, an isomeric crosslinking technology is introduced to make the regenerated material have very good toughness and strength without adding a compatilizer in the regeneration process of the recovered PBT and PET alloy, so the toughened and reinforced recovered PBT and PET alloy has extremely great market popularization values.
Description
Technical field
The present invention relates to a kind of macromolecular material and preparation method thereof, more particularly to a kind of isomerism cross-linking method is toughness reinforcing
Strengthen and reclaim pbt and pet alloy and preparation method thereof.
Background technology
Pbt and pet alloy widely uses in terminal consumer products, correspondingly there is also in a large number recuperable pbt and
Pet alloy, the shortage with petroleum resources and the increasingly stringent of environmental conservation, the application of regeneration pbt and pet alloy progressively increases
Many.Because the market competition is extremely fierce, a lot of pbt and pet alloy products produce commercial city and begin with regeneration pbt and pet alloy
Material carrys out reduces cost.But reclaim pbt and pet alloy because of aging action, its mechanical property especially erosion-resisting characteristics can not show a candle to pbt and
Pet alloy virgin material is it is therefore desirable to can be reused after being modified.
Polybutylene terephthalate (PBT) (pbt) is 20th century 70 with the alloy of polyethylene terephthalate (pet)
The thermoplastic polyester alloy material that age grows up, have that price is low, cold temperature impact is good, excellent combination property the features such as,
Can be used for part of automotive upholstery, appliance shell, electronic apparatus and instrument and meter etc., in national economy and new high-tech industry
In have a wide range of applications, be a kind of indispensable new material, but pbt and pet alloy use as engineering plastics, its time
There is the shortcomings of notch sensitivity is strong, notch impact strength is low, heat distortion temperature is low, shrinkage factor is big in rewinding, significantly limit
The application of this alloy regeneration material.
Content of the invention
It is an object of the invention to provide a kind of toughness reinforcing enhancing of isomerism cross-linking method reclaims pbt and pet alloy and its system
Preparation Method, after isomerism cross-linking method, also may be used while being improved and reclaimed pbt and pet alloy impact property with crosslinked master batch
To improve the tensile property reclaiming nylon;And the introducing of isomerism cross-linking method can make recovery pbt and the regeneration of pet alloy
During need not add compatilizer that the toughness of regeneration nylon and intensity can also be made fine;Isomerism cross-linking method also improves back
Receive the heat distortion temperature of pbt and pet alloy.
The purpose of the present invention is achieved through the following technical solutions:
The toughness reinforcing enhancing of isomerism cross-linking method reclaims pbt and pet alloy, based on mass weight part, includes:
Reclaim 60~80 parts of pbt and pet alloy;
10~30 parts of toughener;
10~30 parts of crosslinked master batch;
5~10 parts of nucleator.
The toughness reinforcing enhancing of described isomerism cross-linking method reclaims pbt and pet alloy, and described toughener is poe, sbr, pet/
At least one in pbt/epdm toughener.
The toughness reinforcing enhancing of described isomerism cross-linking method reclaims pbt and pet alloy, and described cross-linking agent is peroxidating diisopropyl
At least one in benzene, dibenzoyl peroxide.
The toughness reinforcing enhancing of described isomerism cross-linking method reclaims pbt and pet alloy, and described crosslinked master batch is by a material b material
Form with producing water preparation three step part, based on mass weight part, include:
A expects composition: reclaims 70~90 parts of pbt and pet alloy
Silane crosslinker: 1~3 part of vinyltrimethoxy silane
Initiator: 1~3 part of cumyl peroxide
B expects composition: reclaims 1~3 part of pbt and pet alloy
Catalyst: 0~1 part of dibutyl tin laurate
Antioxidant: 0~1 part of antioxidant 1010
Produce water preparation composition: acid and metal-oxide respectively account for 0~1 part with arbitrary proportion mixing.
The toughness reinforcing enhancing of described isomerism cross-linking method reclaims pbt and pet alloy, and the acid in described product water preparation is Hard Fat
At least one in acid, mineral acid.
The toughness reinforcing enhancing of described isomerism cross-linking method reclaims pbt and pet alloy, the metal-oxide in described product water preparation
For at least one in zinc oxide, stannum oxide.
Described isomerism cross-linking method toughness reinforcing strengthen reclaim pbt and pet alloy, described nucleator be na2co3,
At least one in nahco3.
Isomerism cross-linking method is toughness reinforcing to strengthen the preparation method reclaiming pbt and pet alloy, includes following step including method
Rapid:
A, weigh 95 parts of a material by mass fraction, after 4 parts of b material mixing, put into extruding pelletization in double screw extruder, Ran Houzai
Produce water preparation with 1 part and mix homogeneously and put into double screw extruder extruding pelletization and form crosslinked master batch;
B, first will reclaim pbt and pet alloy forced air drying 24 hours under the conditions of 120 DEG C, by weight ratio will be crosslinked female
Grain, recovery pbt and pet alloy, nucleator are put into high-speed mixer high speed and are mixed 4~6 minutes so as to uniform mix;
C, the material of mix homogeneously in above-mentioned high-speed mixer is added in double screw extruder hopper to carry out melting mixed
Refining, extruding pelletization obtain regenerating pbt and pet alloy.
The toughness reinforcing enhancing of described isomerism cross-linking method reclaims pbt and pet alloy preparation method, described double screw extruder
Extruder temperature control between 220 DEG C -260 DEG C.
Advantages of the present invention with effect is:
After isomerism cross-linking method, also may be used while being improved and reclaimed pbt and pet alloy impact property with crosslinked master batch
To improve the tensile property reclaiming nylon;And the introducing of isomerism cross-linking method can make recovery pbt and the regeneration of pet alloy
During need not add compatilizer that the toughness of regeneration nylon and intensity can also be made fine;Isomerism cross-linking method also improves back
Receive the heat distortion temperature of pbt and pet alloy.
Specific embodiment
With reference to embodiment, the present invention is described in detail.
With reference to specific embodiment, the present invention is described further:
Embodiment 1-3, in each embodiment, the weight distribution ratio of each component is as shown in table 1.Each component is weighed by proportioning,
Mix 5 minutes in homogenizer, discharging, the raw material of compound is placed in double screw extruder and makes material, the temperature of extruder
220 DEG C -260 DEG C of degree, rotating speed 140r/min, prepares batten, is shown in Table 3 by corresponding standard testing (see Table 2) results of property.
Table 1: formula composition (part) of embodiment 1-3 and comparative example 1
90 parts of pbt and pet alloy is reclaimed in a material of crosslinked master batch;2.5 parts of vinyltrimethoxy silane;Peroxidating two
2.5 parts of isopropylbenzene.3 parts of pbt and pet alloy is reclaimed in b material;0.5 part of dibutyl tin laurate;0.5 part of antioxidant 1010
Produce in water preparation: 0.5 part of stearic acid;0.5 part of zinc oxide and with 1:1 ratio mixing.
Table 2: Mechanics Performance Testing standard
Table 3: the Mechanics Performance Testing of the regeneration pbt and pet alloy in embodiment 1-3 and comparative example 1
From the mechanical experimental results of table 3 embodiment 1-3 and comparative example 1 knowable to us: toughness reinforcing using merely
When agent, improve the tensile property that can reduce material while reclaiming pbt and pet alloy impact property;Using isomerism
After cross-linking method, the stretching reclaiming nylon while being improved and reclaimed pbt and pet alloy impact property with crosslinked master batch, can also be improved
Performance;And being introduced into of isomerism cross-linking method can make need not add compatilizer in recovery pbt and the regenerative process of pet alloy
Toughness and the intensity of regeneration nylon can also be made fine;Isomerism cross-linking method also improves the heat change reclaiming pbt and pet alloy
Shape temperature.
Above by specific embodiment, the present invention is further illustrated, but these embodiments are only exemplary
, any restriction is not constituted to protection scope of the present invention.It will be appreciated by those skilled in the art that in the spirit without departing from the present invention
In the case of protection domain, technical solutions and their implementation methods of the present invention can be carried out multiple equivalencings, modification or
Improve, these all should fall within the scope of protection of the present invention.Protection scope of the present invention is defined by appended claim.
Claims (7)
1. toughness reinforcing enhancing of isomerism cross-linking method reclaims pbt and pet alloy it is characterised in that in parts by mass, includes:
Reclaim 60~80 parts of pbt and pet alloy;
10~30 parts of toughener;
10~30 parts of crosslinked master batch;
5~10 parts of nucleator;
Described crosslinked master batch is made up of a material b material and product water preparation three part, in parts by mass, includes:
A expects composition: reclaims 70~90 parts of pbt and pet alloy
Silane crosslinker: 1~3 part of vinyltrimethoxy silane
Initiator: 1~3 part of cumyl peroxide
B expects composition: reclaims 1~3 part of pbt and pet alloy
Catalyst: 0~1 part of dibutyl tin laurate, wherein catalyst content are not 0
Antioxidant: 0~1 part of antioxidant 1010
Produce water preparation composition: acid and metal-oxide respectively account for 0~1 part with arbitrary proportion mixing, and wherein acid and metal-oxide contain
Amount is not 0.
2. toughness reinforcing enhancing of isomerism cross-linking method according to claim 1 reclaims pbt and pet alloy it is characterised in that institute
State at least one that toughener is in poe, sbr, pet/pbt/epdm toughener.
3. isomerism cross-linking method according to claim 1 toughness reinforcing strengthen reclaim pbt and pet alloy it is characterised in that: institute
State the acid producing in water preparation be stearic acid, at least one in mineral acid.
4. isomerism cross-linking method according to claim 1 toughness reinforcing strengthen reclaim pbt and pet alloy it is characterised in that: institute
State the metal-oxide producing in water preparation be zinc oxide, at least one in stannum oxide.
5. isomerism cross-linking method according to claim 1 toughness reinforcing strengthen reclaim pbt and pet alloy it is characterised in that: institute
Stating nucleator is na2co3、nahco3In at least one.
6. isomerism cross-linking method is toughness reinforcing strengthens the preparation method reclaiming pbt and pet alloy it is characterised in that including following walking
Rapid:
A, weigh 95 parts of a material by mass fraction, after 4 parts of b material mixing, put into extruding pelletization in double screw extruder, then again with 1
Part product water preparation mix homogeneously is put into double screw extruder extruding pelletization and is formed crosslinked master batch;
B, first will reclaim pbt and pet alloy forced air drying 24 hours under the conditions of 120 DEG C, by weight ratio by crosslinked master batch, return
Receive pbt and pet alloy, nucleator is put into high-speed mixer high speed and mixed 4~6 minutes so as to uniform mix;
C, the material of mix homogeneously in above-mentioned high-speed mixer is added in double screw extruder hopper carry out melting mixing, squeeze
Go out pelletize to obtain regenerating pbt and pet alloy;
A expects composition: reclaims 70~90 parts of pbt and pet alloy
Silane crosslinker: 1~3 part of vinyltrimethoxy silane
Initiator: 1~3 part of cumyl peroxide
B expects composition: reclaims 1~3 part of pbt and pet alloy
Catalyst: 0~1 part of dibutyl tin laurate, wherein catalyst content are not 0
Antioxidant: 0~1 part of antioxidant 1010
Produce water preparation composition: acid and metal-oxide respectively account for 0~1 part with arbitrary proportion mixing, and wherein acid and metal-oxide contain
Amount is not 0.
7. toughness reinforcing enhancing of isomerism cross-linking method according to claim 6 reclaims pbt and pet alloy preparation method, and it is special
Levy and be: the extruder temperature of described double screw extruder controls between 220 DEG C -260 DEG C.
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CN106496769B (en) * | 2016-09-21 | 2019-12-03 | 沈阳化工大学 | A kind of isomerism cross-linking method containing L-POSS crosslinking agent is modified to recycle PP and preparation method thereof |
CN106810832A (en) * | 2016-12-26 | 2017-06-09 | 沈阳化工大学 | Modified polyethylene terephthalate of isomerism containing condensed cyclic structure crosslinking agent and preparation method thereof |
CN106832805A (en) * | 2016-12-26 | 2017-06-13 | 沈阳化工大学 | Modified polybutylene terephthalate (PBT) of isomerism containing condensed cyclic structure crosslinking agent and preparation method thereof |
CN106832804A (en) * | 2016-12-26 | 2017-06-13 | 沈阳化工大学 | Modified polybutylene terephthalate (PBT) of isomerism containing Sakyamuni, the founder of Buddhism's structure crosslinking agent and preparation method thereof |
CN106751710B (en) * | 2016-12-28 | 2019-01-01 | 沈阳化工大学 | A kind of isomerism MODIFIED PP O and preparation method thereof containing Sakyamuni, the founder of Buddhism's structure crosslinking agent |
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CN101649100A (en) * | 2009-09-18 | 2010-02-17 | 登封鼎盛工程塑料制品有限公司 | Multifunctional polyester master batch |
CN101747596A (en) * | 2008-12-11 | 2010-06-23 | 王世和 | Preparation method of recycled polyester chip microfilaments and usage thereof |
US20140031466A1 (en) * | 2012-07-30 | 2014-01-30 | Sabic Innovation Plastics IP B.V. | Process for the preparation of modified poly(alkylene terephthalate) employing an in-situ titanium-containing catalyst and compositions derived therefrom |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101747596A (en) * | 2008-12-11 | 2010-06-23 | 王世和 | Preparation method of recycled polyester chip microfilaments and usage thereof |
CN101649100A (en) * | 2009-09-18 | 2010-02-17 | 登封鼎盛工程塑料制品有限公司 | Multifunctional polyester master batch |
US20140031466A1 (en) * | 2012-07-30 | 2014-01-30 | Sabic Innovation Plastics IP B.V. | Process for the preparation of modified poly(alkylene terephthalate) employing an in-situ titanium-containing catalyst and compositions derived therefrom |
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