CN105220846A - A kind of coating process of building fireproof paint - Google Patents
A kind of coating process of building fireproof paint Download PDFInfo
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- CN105220846A CN105220846A CN201510500277.5A CN201510500277A CN105220846A CN 105220846 A CN105220846 A CN 105220846A CN 201510500277 A CN201510500277 A CN 201510500277A CN 105220846 A CN105220846 A CN 105220846A
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Abstract
The invention provides a kind of coating process of novel building fire-retardant coating composition, it is characterized in that: fire-retardant coating composition is coated with on architectural construction surface, each coating thickness is 1mm, 4 hours interval times of each film, to reach after coating thickness requirement under room temperature environment natural drying 48 hours.Described coating composition comprises Acrylate-styrene bipolymer-vinyl acetate terpolymer, self-emulsifying epoxy resin, red phosphorus, aluminium triphosphate, melamine, expansile graphite, glycerine, alkylphenol-polyethenoxy base sulfonate, hydrated ferric oxide, metatitanic acid, Na
2onSiO
2mH
2o and water.The present invention is chosen and preferred component proportion by unique composition, and the coating process adapted imparts the combination property that this architectural fireproof paint is coated with excellence, and it has the overall performances such as outstanding fire line, water proofing property, weatherability, aesthetic property.
Description
Technical field
The present invention relates to the technical field of building, especially a kind of fire-retardant coating composition of building and coating process thereof.
Background technology
In recent years, along with the develop rapidly of Chinese national economy, building trade is advanced by leaps and bounds naturally as mainstay of the national economy industry, and the relevant energy consumption of building also becomes abnormal huge, accounts for 30% of whole society's total energy consumption at the energy built and directly consume in use procedure.Along with country to pay attention to day by day that is energy-conservation, that reduce discharging sustainable development, all kinds of insulating moulding coating, thermal insulation coatings has constantly been there is in building trade and other relevant industries, as polystyrene board and the heat-insulation system such as glue powder polyphenyl particle, polyurethane foam, though can heat-insulation and heat-preservation be realized, but product also exists the shortcomings such as construction is complicated, water proofing property is poor, do not prevent fires, especially about the performance of fire protection flame retarding, concerning the security of the lives and property of people, gas can not reach the expection of people for fireproof performance far away.
Architectural fireproof paint is mainly used in being coated on building surface; when meeting fire, film difficulty itself is fired or does not fire; to substrate, there is good protective effect, won the valuable time for fire extinguishing and personnel withdraw, therefore its investigation and application has more and more been become to the focus of building field.The research starting evening of China's fireproof flame-retardant coating, current fireproof paint mainly contains two kinds, a kind of is adopt the difficult organic polymer fired to be base-material, another is then add fire retardant at coating, representative halogen system, phosphorus system fireproof paint are in development, but in halogen system some bromine class fireproof paints because of environmental issue always controversial.And although the baking of high temperature can be stood for inorganic fireproof coating, its exist attachment poor, the defects such as intensity is low, and film is more crisp.Except functional performancies such as above-mentioned fire lines, architectural fireproof paint also requires easy act, because the shape of building is often very complicated, in addition the structure member part that be combined with each other is difficult to apply in advance especially, must apply by site operation, so architectural fireproof paint must have suitable easy act, or as far as possible few coated with minimizing engineering time or number of times.Simultaneously along with the continuous pursuit that people improve for quality of the life, people are for the aesthetic property also growing interest of building, and this just requires that architectural fireproof paint also will must keep the outward appearance style and features of building as far as possible while satisfied fire prevention, easily construction etc. require.
Although there is the advantages such as environmental protection in the acrylic compounds aqueous fire-proof coating be widely studied at present, but it is still difficult to meet the architectural fireproof paint requirement day by day improved in fire line, water proofing property, weatherability, aesthetic property etc., in the urgent need to developing a kind of novel easy construction, and there is outstanding architectural fireproof paint such as excellent fire line, water proofing property, weatherability, aesthetic property etc.Namely object of the present invention is to provide a kind of and novel has Good All-around Property architectural fireproof paint and corresponding coating process.
Summary of the invention
Namely object of the present invention is to provide a kind of novel coating process with Good All-around Property architectural fireproof paint composition, and this coating composition is chosen by unique composition and made this building fire protection film have excellent fire line, water proofing property, weatherability, aesthetic property etc. with preferred component proportion.
For achieving the above object, present invention employs following technical scheme:
A coating process for novel building fire-retardant coating composition, is characterized in that:
Be coated with on architectural construction surface by fire-retardant coating composition, each coating thickness is 1mm, 4 hours interval times of each film, to reach after coating thickness requirement under room temperature environment natural drying 48 hours.
Described coating composition comprises Acrylate-styrene bipolymer-vinyl acetate terpolymer, self-emulsifying epoxy resin, red phosphorus, aluminium triphosphate, melamine, expansile graphite, glycerine, alkylphenol-polyethenoxy base sulfonate, hydrated ferric oxide, metatitanic acid, Na
2onSiO
2mH
2o and water.
Wherein, with solid 100 parts by weight of Acrylate-styrene bipolymer-vinyl acetate terpolymer, self-emulsifying epoxy resin 20-30 part, red phosphorus 5-10 part, aluminium triphosphate 15-25 part, melamine 20-30 part, expansile graphite 5-10 part, glycerine 15-25 part, alkylphenol-polyethenoxy base sulfonate 5-15 part, hydrated ferric oxide 5-10 part, metatitanic acid 5-10 part, Na
2onSiO
2mH
2o10-20 part, water 100-120 part.
Described architectural construction is steel work, wood structure, cement structures etc.
Described film is transparent or semitransparent.
As preferably, in described Acrylate-styrene bipolymer-vinyl acetate terpolymer, by weight percentage, acrylate accounts for 70-80%, styrene accounts for 5-15%, vinyl acetate accounts for 10-20%, and the weight average molecular weight of copolymer is about 60000-80000, and has the hydroxyl value of 1-10mgKOH/g.
Preferred further, the average grain diameter of described Acrylate-styrene bipolymer-vinyl acetate terpolymer is 0.5-1 μm.
As preferably, described self-emulsifying epoxy resin is the BPA type epoxy resin of epoxy resin equivalent 200-500.
As preferably, the average grain diameter of expansile graphite is 20-40 μm.
As preferably, the number-average molecular weight of alkylphenol-polyethenoxy base sulfonate is about 1000-5000.
As preferably, the average grain diameter of hydrated ferric oxide and metatitanic acid is at 0.25-0.5 μm.
As preferably, Na
2onSiO
2mH
2n=1.8-2.2 in O.
The preparation method of described coating composition is, by Acrylate-styrene bipolymer-vinyl acetate terpolymer, self-emulsifying epoxy resin, red phosphorus, aluminium triphosphate, melamine, expansile graphite, glycerine, alkylphenol-polyethenoxy base sulfonate, hydrated ferric oxide, metatitanic acid, Na
2onSiO
2mH
2o raw material adds in the deionized water of 35-40 DEG C by proportioning successively, fully stirs after 3-5 hour, obtains product of the present invention.
The beneficial effect of the inventive method is: chosen and preferred component proportion by the composition of uniqueness, and the coating process adapted imparts the combination property that this architectural fireproof paint is coated with excellence, it has the overall performances such as outstanding fire line, water proofing property, weatherability, aesthetic property.
Detailed description of the invention
Embodiment 1
By solid 100 parts by weight of Acrylate-styrene bipolymer-vinyl acetate terpolymer, self-emulsifying epoxy resin 20 parts, 5 parts, red phosphorus, aluminium triphosphate 15 parts, melamine 20 parts, expansile graphite 5 parts, glycerine 15 parts, 5 parts, alkylphenol-polyethenoxy base sulfonate, hydrated ferric oxide 5 parts, metatitanic acid 5 parts, Na
2onSiO
2mH
2o10 part proportioning prepares raw material, is added to by ready raw material in 100 parts of deionized waters of 38 DEG C successively, fully stirs after 4 hours, obtains the product of the embodiment of the present invention 1.
In wherein Acrylate-styrene bipolymer-vinyl acetate terpolymer, by weight percentage, acrylate accounts for 75%, styrene accounts for 10%, and vinyl acetate accounts for 15%, and the weight average molecular weight of copolymer is about 70000, and have the hydroxyl value of 5mgKOH/g, average grain diameter is 0.7 μm.Self-emulsifying epoxy resin is the BPA type epoxy resin of epoxy resin equivalent 300.The average grain diameter of expansile graphite is 30 μm.The number-average molecular weight of alkylphenol-polyethenoxy base sulfonate is about 1000-5000.The average grain diameter of hydrated ferric oxide and metatitanic acid is at 0.25 μm.Na
2onSiO
2mH
2n=2.0 in O.
The content of embodiment 2-9 to each component adjusts, and concrete content ratio lists in table 1.
Above-mentioned fire-retardant coating composition is coated with at the surface of steel plate that 5mm is thick, each coating thickness is 1mm, 4 hours interval times of each film, after film 3 times, natural drying 48 hours under room temperature environment, obtains experimental material in order to test the performance of coating composition.
In table 1, the test condition of even compact adds up 1cm under the condition of 10 power microscopes
2number (individual/the cm of film scope inner air vent
2).
In table 1, the test condition of anti-flammability heats for adopting JISA1304 standard heating curves, by the temperature inside K thermocouple monitoring steel plate, the time (min) of 500 DEG C is reached and the dropping situations of foaming body evaluates fire retardant performance by steel inner surface, the evaluation method that the degree that comes off is concrete is, be as the criterion with range estimation, zero: do not come off completely; Δ: less than 20% comes off; ×: come off more than 20%.
In table 1, the test condition of water proofing property is, after test material is immersed in the water 3 days at ambient temperature, the surface state of range estimation film, is specially, zero: film coated surface occurs that the area of bubble or peeling is less than 10%; Δ: film coated surface occurs that the area of bubble or peeling is 10-30%; ×: film coated surface occurs that the area of bubble or peeling is more than 30%.
Below fireproof paint system formulation of the present invention is further described:
Acrylate-styrene bipolymer in coating of the present invention-vinyl acetate terpolymer is a kind of water-base resin of environmental protection, and has excellent anti-flammability, as the main component of coating of the present invention.Wherein acrylate is bulk composition, and itself and cinnamic combination can play well disperse and the composition such as stable red phosphorus, aluminium triphosphate stable system effect and improve the effects such as film compactness, intensity and water resistance, in order to play above-mentioned effect, its content in the copolymer should be at least 5%, if but too high levels and be unfavorable for continue improve its effect, film forming application property can be reduced on the contrary, therefore control its content and be less than 15%.And the combination of vinyl acetate and acrylate has greatly improved for application property tool, significantly can reduce be full of cracks in dry run and wait generation, should 10% be at least to play above-mentioned effect, if but its too high levels can affect the effect of other compositions, thus impact is coated with film strength, compactness etc., therefore controls it and is less than 20%.In addition, when the weight average molecular weight of copolymer is about 60000-80000, hydroxyl value is 1-10mgKOH/g, best fire line, weatherability, water resistance etc. can be obtained, because if its weight average molecular weight is too small, its dispersiveness for component each in system may be caused to be deteriorated, thus affect the performance such as stable and weather-proof anticorrosion of system, excessive, resistance to elevated temperatures is deteriorated can reduce weatherability and fire line etc. on the contrary, and hydroxyl value also obviously can have influence on stability and the weatherability of system, and the effect of charing of significantly foaming.In addition, the average grain diameter of Acrylate-styrene bipolymer-vinyl acetate terpolymer is preferably 0.5-1 μm, to ensure easy act and coating quality.
Self-emulsifying epoxy resin in coating of the present invention is extremely important for the film performance of coating, its interpolation significantly can improve tack and the compactness of film, thus improve the performances such as fire-resistant, weather-proof, the waterproof of film, the stripping of heating post-foaming charring layer can also be prevented simultaneously, in order to play above-mentioned effect, its addition at least should be 20 parts, but its too high interpolation there is no bonus effect, the effect of other components can be affected on the contrary, therefore should control below 30 parts.In addition, in order to make self-emulsifying epoxy resin to fuse mutually with the component in system better, the BPA type epoxy resin of epoxy resin equivalent 200-500 is chosen.
Red phosphorus in coating of the present invention and aluminium triphosphate, red phosphorus has very excellent flame retardant effect, and in order to play the effect of its excellence, its content is preferably more than 5 parts, but its too high levels then can cause the coating of coating and water proofing property to be deteriorated, and therefore preferably controls its content below 10 parts; Aluminium triphosphate is except playing except flame retardant effect with red phosphorus is collaborative, the Corrosion Protection of coating system can also be significantly improved, more than 15 parts should be at least added for playing a role, but too high interpolation then may cause the problem such as coating and water proofing property variation of coating, therefore controls it and is less than 25 parts.
In coating of the present invention, melamine is typical blowing agent, and it has good iris action, the moisture absorption of the materials such as red phosphorus combustion inhibitor can be prevented well, thus improve the water proofing property of coating, and it is also helpful for the transparency improving film, but its content can not be too high, otherwise the fire-retardant whole structure such as grade of coating will be affected, therefore control its content 20-30 part.
Expansile graphite in this coating greatly can improve the expansion multiplying power of system thus improve fire retardant performance, but its too high interpolation can affect the overall performance such as coating, the transparency of film, therefore controls its content 5-10 part.Simultaneously in order to ensure the functional performance of expansile graphite, control its average grain diameter at 20-40 μm.
Glycerine in coating of the present invention can assist the fire resistance of acrylate well, in order to make itself and acrylate synergy fire-retardant, its addition at least should be 15 parts, but too much interpolation can not improve the fire resistance of system, the coating of coating can be caused on the contrary to be deteriorated, therefore to control its content below 25 parts.
Table 1
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | |
| Terpolymer | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 |
| Epoxy resin | 20 | 25 | 30 | 15 | 23 | 25 | 22 | 25 | 22 |
| Red phosphorus | 5 | 7 | 10 | 8 | 7 | 15 | 7 | 9 | 8 |
| Aluminium triphosphate | 15 | 20 | 25 | 22 | 23 | 27 | 13 | 23 | 20 |
| Melamine | 20 | 25 | 30 | 26 | 15 | 22 | 24 | 23 | 24 |
| Expansile graphite | 5 | 8 | 10 | 7 | 8 | 7 | 7 | 6 | 7 |
| Glycerine | 15 | 20 | 25 | 20 | 22 | 20 | 18 | 16 | 22 |
| Sulfonate | 5 | 10 | 15 | 12 | 11 | 15 | 3 | 10 | 1O |
| Hydrated ferric oxide | 5 | 7 | 10 | 8 | 7 | 7 | 5 | - | 5 |
| Metatitanic acid | 5 | 7 | 10 | 8 | 8 | 7 | 5 | 10 | 2 |
| Water glass | 10 | 15 | 20 | 14 | 15 | 15 | 10 | 20 | 5 |
| Water | 100 | 110 | 120 | 120 | 110 | 120 | 120 | 110 | 100 |
| Stomatal number | 5 | 2 | 7 | 12 | 7 | 16 | 15 | 4 | 5 |
| 500 DEG C of times | 30 | 35 | 37 | 32 | 25 | 33 | 27 | 24 | 26 |
| Foaming layer comes off | Δ | ○ | ○ | Δ | × | Δ | × | ○ | × |
| Water proofing property | ○ | ○ | Δ | Δ | Δ | × | × | Δ | ○ |
Alkylphenol-polyethenoxy base sulfonate in coating of the present invention can play finely dispersed effect, it coordinates system of the present invention can play good stabilization, thus be convenient to the storage transport of coating, in order to play above-mentioned effect, should at least add 5 parts, but too high interpolation affects the effect of other compositions on the contrary without lasting effect for raising performance, therefore control it and be less than 15 parts.In addition, number-average molecular weight is about 1000-5000, too smallly can not play enough stably dispersing effects, crosses conference and causes the reductions such as water resistance.
Hydrated ferric oxide in coating of the present invention, metatitanic acid, Na
2onSiO
2mH
2o is as fire-retardant filler, all there is extraordinary heat-proof combustion-resistant performance, what particularly three kinds of filler components can have a gradient in heating process loses the crystallization water, thus improves the heatproof combustion resistance of coating system further, and three kinds of fillers have the significantly collaborative effect improving fire resistance together.Meanwhile, metatitanic acid and Na
2onSiO
2mH
2o can in heating process play stably foaming layer the same as self-emulsifying epoxy resin to a great extent, avoiding it to peel off the effect of division, thus improves fire resistance further, in order to play above-mentioned effect, being at least, hydrated ferric oxide 5 parts, metatitanic acid 5 parts, Na
2onSiO
2mH
2o10 part.But consider the problem such as the transparency, coating, the content controlling three mostly is most, hydrated ferric oxide 10 parts, metatitanic acid 10 parts, Na
2onSiO
2mH
2o20 part.In addition, in order to ensure the obdurability of film and transparent aesthetic property, the average grain diameter of hydrated ferric oxide and metatitanic acid should be controlled at 0.25-0.5 μm.In addition, Na
2onSiO
2mH
2the value of the n in O is preferably between 1.8-2.2, and n value too small being difficult to plays heat-proof combustion-resistant performance, but n value is excessive, will make Na
2onSiO
2dissolubility be deteriorated, thus affect the paintability of coating.
Architectural fireproof paint composition of the present invention is applicable to the surface coating of the various architectural constructions such as steel work, wood structure, cement structures, can be widely used in any needs on fireproof facility and building.
Although the present invention illustrates coating effect of the present invention by above-described embodiment, the present invention is not limited to above-described embodiment.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (8)
1. a coating process for novel building fire-retardant coating composition, is characterized in that:
Be coated with on architectural construction surface by fire-retardant coating composition, each coating thickness is 1mm, 4 hours interval times of each film, to reach after coating thickness requirement under room temperature environment natural drying 48 hours.
Described coating composition comprises Acrylate-styrene bipolymer-vinyl acetate terpolymer, self-emulsifying epoxy resin, red phosphorus, aluminium triphosphate, melamine, expansile graphite, glycerine, alkylphenol-polyethenoxy base sulfonate, hydrated ferric oxide, metatitanic acid, Na
2onSiO
2mH
2o and water.
Wherein, with solid 100 parts by weight of Acrylate-styrene bipolymer-vinyl acetate terpolymer, self-emulsifying epoxy resin 20-30 part, red phosphorus 5-10 part, aluminium triphosphate 15-25 part, melamine 20-30 part, expansile graphite 5-10 part, glycerine 15-25 part, alkylphenol-polyethenoxy base sulfonate 5-15 part, hydrated ferric oxide 5-10 part, metatitanic acid 5-10 part, Na
2onSiO
2mH
2o10-20 part, water 100-120 part.
2. coating process according to claim 1, is characterized in that: described architectural construction is steel work, wood structure, cement structures etc.
3. coating process according to claim 1, is characterized in that: described film is transparent or semitransparent.
4. coating process according to claim 1, it is characterized in that: as preferably, in described Acrylate-styrene bipolymer-vinyl acetate terpolymer, by weight percentage, acrylate accounts for 70-80%, and styrene accounts for 5-15%, and vinyl acetate accounts for 10-20%, the weight average molecular weight of copolymer is about 60000-80000, and has the hydroxyl value of 1-10mgKOH/g.Preferred further, the average grain diameter of described Acrylate-styrene bipolymer-vinyl acetate terpolymer is 0.5-1 μm.
5. coating process according to claim 1, is characterized in that: as preferably, and described self-emulsifying epoxy resin is the BPA type epoxy resin of epoxy resin equivalent 200-500.
6. coating process according to claim 1, is characterized in that: as preferably, and the number-average molecular weight of alkylphenol-polyethenoxy base sulfonate is about 1000-5000.
7. coating process according to claim 1, is characterized in that: as preferably, and the average grain diameter of hydrated ferric oxide and metatitanic acid is at 0.25-0.5 μm.
8. coating process according to claim 1, is characterized in that: as preferably, Na
2onSiO
2mH
2n=1.8-2.2 in O.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105696346A (en) * | 2016-03-08 | 2016-06-22 | 杨超 | Antibacterial and flame-retardant coating for garment fabric |
| CN105780491A (en) * | 2016-03-08 | 2016-07-20 | 杨超 | Preparation method of antibacterial flame-retardant coating for garment fabric |
| WO2017152659A1 (en) * | 2016-03-08 | 2017-09-14 | 杨超 | Method for preparing fire resistant coating for woods |
| EP3406669A4 (en) * | 2016-01-20 | 2019-08-28 | Sekisui Chemical Co., Ltd. | Fire-resistant resin composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2130953C1 (en) * | 1997-09-29 | 1999-05-27 | Общество с ограниченной ответственностью "ГраЭН" | Composition for preparing fireproof material |
| CN102153937A (en) * | 2011-05-13 | 2011-08-17 | 惠东美新塑木型材制品有限公司 | Surface fireproof coating of wood plastic composite material and preparation method of surface fireproof coating |
| CN103045037A (en) * | 2012-12-14 | 2013-04-17 | 中盈长江国际新能源投资有限公司 | Water-based expandable fireproof steel structure coating and preparation method |
| CN104293010A (en) * | 2014-10-20 | 2015-01-21 | 芜湖县双宝建材有限公司 | Water-based ultra-thin steel structure fireproof coating |
-
2015
- 2015-08-14 CN CN201510500277.5A patent/CN105220846B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2130953C1 (en) * | 1997-09-29 | 1999-05-27 | Общество с ограниченной ответственностью "ГраЭН" | Composition for preparing fireproof material |
| CN102153937A (en) * | 2011-05-13 | 2011-08-17 | 惠东美新塑木型材制品有限公司 | Surface fireproof coating of wood plastic composite material and preparation method of surface fireproof coating |
| CN103045037A (en) * | 2012-12-14 | 2013-04-17 | 中盈长江国际新能源投资有限公司 | Water-based expandable fireproof steel structure coating and preparation method |
| CN104293010A (en) * | 2014-10-20 | 2015-01-21 | 芜湖县双宝建材有限公司 | Water-based ultra-thin steel structure fireproof coating |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3406669A4 (en) * | 2016-01-20 | 2019-08-28 | Sekisui Chemical Co., Ltd. | Fire-resistant resin composition |
| CN105696346A (en) * | 2016-03-08 | 2016-06-22 | 杨超 | Antibacterial and flame-retardant coating for garment fabric |
| CN105780491A (en) * | 2016-03-08 | 2016-07-20 | 杨超 | Preparation method of antibacterial flame-retardant coating for garment fabric |
| WO2017152659A1 (en) * | 2016-03-08 | 2017-09-14 | 杨超 | Method for preparing fire resistant coating for woods |
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