CN105219456B - Oil product compound antioxidizing and antigum agent and preparation method thereof - Google Patents
Oil product compound antioxidizing and antigum agent and preparation method thereof Download PDFInfo
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- 230000003064 anti-oxidating effect Effects 0.000 title claims abstract description 46
- 150000001875 compounds Chemical class 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 46
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 42
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 23
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 23
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000008117 stearic acid Substances 0.000 claims abstract description 23
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims abstract description 22
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims abstract description 22
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 22
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 22
- QAGGICSUEVNSGH-UHFFFAOYSA-N Diosmetin Natural products C1=C(O)C(OC)=CC=C1C1=CC(=O)C2=CC=C(O)C=C2O1 QAGGICSUEVNSGH-UHFFFAOYSA-N 0.000 claims abstract description 21
- MBNGWHIJMBWFHU-UHFFFAOYSA-N diosmetin Chemical compound C1=C(O)C(OC)=CC=C1C1=CC(=O)C2=C(O)C=C(O)C=C2O1 MBNGWHIJMBWFHU-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229960001876 diosmetin Drugs 0.000 claims abstract description 21
- 235000015428 diosmetin Nutrition 0.000 claims abstract description 21
- 235000011187 glycerol Nutrition 0.000 claims abstract description 21
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims abstract description 19
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims abstract description 19
- GQJDFTIOKVGUOF-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)C(CO)(CO)CO Chemical class OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)C(CO)(CO)CO GQJDFTIOKVGUOF-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 aminomethyl phenyl Chemical group 0.000 claims abstract description 10
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims abstract 6
- 238000003756 stirring Methods 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 16
- UGTHTQWIQKEDEH-BQBZGAKWSA-N L-alanyl-L-prolylglycine zwitterion Chemical compound C[C@H](N)C(=O)N1CCC[C@H]1C(=O)NCC(O)=O UGTHTQWIQKEDEH-BQBZGAKWSA-N 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 claims 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims 1
- 239000002105 nanoparticle Substances 0.000 claims 1
- 150000008301 phosphite esters Chemical class 0.000 claims 1
- 239000000084 colloidal system Substances 0.000 abstract description 15
- 239000000654 additive Substances 0.000 abstract description 7
- 230000000996 additive effect Effects 0.000 abstract description 6
- 238000003860 storage Methods 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 238000002845 discoloration Methods 0.000 abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 54
- 239000003502 gasoline Substances 0.000 description 11
- 239000000295 fuel oil Substances 0.000 description 9
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 4
- 235000019260 propionic acid Nutrition 0.000 description 4
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
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- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The present invention relates to a kind of oil product compound antioxidizing and antigum agent and preparation method thereof, belong to oil gas additive technical field.The oil product includes following component in parts by weight with compound antioxidizing and antigum agent：12 parts of butylated hydroxy anisole, 0.5 1.5 parts of APG, 25 parts of stearic acid, triethylene-glycol double [β (aminomethyl phenyl of 3 tert-butyl group, 4 hydroxyl 5) 0.1 0.2 parts of propionic ester, double 0.1 0.2 parts of (2,4 di-tert-butyl-phenyl) pentaerythritol diphosphites, 12 parts of diosmetin, 13 parts of nano-calcium carbonate, 15 19 parts of ethanol, 5 10 parts of glycerine.The oil product is good with compound antioxidizing and antigum agent stability, does not influence its performance after longer-term storage still, and it can effectively prevent that oil product from occurring discoloration in storage, and can thoroughly remove original colloid in oil product and suppress the formation of colloid, effectively improves the quality of oil product.
Description
Technical field
The invention belongs to oil gas additive technical field, and in particular to a kind of oil product compound antioxidizing and antigum agent and its preparation
Method.
Background technology
Oil product typically refers to a variety of stones such as gasoline, kerosene, diesel oil and lubricating oil that oil is obtained by post-processings such as refinings
Oil product.Wherein gasoline, kerosene and diesel oil are also fuel oil, are widely used in power plants generating electricity, ship boiler fuel, heating furnace combustion
Material, metallurgical furnace and other industrial furnace fuel.Fuel oil is used as last a kind of product in oil refining process, the quality control of its product
There is stronger particularity, fuel oil products are ultimately formed by many factors such as oil variety, processing technology, working depths
Restriction.Fuel oil is mainly what is be made up of the cracking residue oil and straight run residue oil of oil, is characterized in that viscosity is big, containing nonhydrocarbon
Compound, colloid, asphalitine are more.
Whether fuel oil or lubricating oil, gas can add a variety of in process of production in order to ensure its performance,
Additive, and antioxidizing and antigum agent is mainly used in the addition of fuel oil, because fuel oil generally can be more or less containing colloid etc.
Impurity, a small amount of colloid influences little to oil property, if but not in time removing the colloid in oil product, pushing away over time
Move, gum level will gradually increase, and its performance will decline to a great extent fuel oil when in use, rise to and result in blockage, serious shadow
Combustion efficiency is rung, therefore particularly important is just seemed to the research of antioxidizing and antigum agent.
The content of the invention
The invention aims to solve the deficiencies in the prior art, and provide a kind of oil product with compound antioxidizing and antigum agent and
Its preparation method, the oil product is good with compound antioxidizing and antigum agent stability, does not influence its performance after longer-term storage still, and it can be with
Effectively prevent oil product from occurring discoloration in storage, and can thoroughly remove original colloid in oil product and suppress the formation of colloid, have
Effect improves the quality of oil product.
The technical solution adopted by the present invention is as follows：
Oil product compound antioxidizing and antigum agent, including following component in parts by weight：Butylated hydroxy anisole 1-2
Part, the double [β-(3- tertiary butyl-4-hydroxy -5- methylbenzenes of 0.5-1.5 parts of APG, 2-5 parts of stearic acid, triethylene-glycol
Base) 0.1-0.2 parts of propionic ester, double 0.1-0.2 parts of (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, diosmetin 1-
2 parts, 1-3 parts of nano-calcium carbonate, 15-19 parts of ethanol, 5-10 parts of glycerine.
Further, described oil product compound antioxidizing and antigum agent, including following component in parts by weight：Fourth
Double [the β-(the tertiary fourths of 3- of 1.3-1.9 parts of base BHA, 0.8-1.3 parts of APG, 3-4 parts of stearic acid, triethylene-glycol
Base -4- hydroxy-5-methyl bases phenyl) 0.12-0.18 parts of propionic ester, double (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites
0.12-0.17 parts, 1.5-1.8 parts of diosmetin, 1.5-2.5 parts of nano-calcium carbonate, 16-18 parts of ethanol, 6-8 parts of glycerine.
Further, described oil product compound antioxidizing and antigum agent, including following component in parts by weight：Fourth
1.3 parts of base BHA, 0.8 part of APG, 3 parts of stearic acid, triethylene-glycol it is double [β-(3- tertiary butyl-4-hydroxies-
5- aminomethyl phenyls) 0.12 part of propionic ester, double 0.12 part of (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, diosmetin
1.5 parts, 1.5 parts of nano-calcium carbonate, 16 parts of ethanol, 6 parts of glycerine.
Further, described oil product compound antioxidizing and antigum agent, including following component in parts by weight：Fourth
1.9 parts of base BHA, 1.3 parts of APG, 4 parts of stearic acid, triethylene-glycol it is double [β-(3- tertiary butyl-4-hydroxies-
5- aminomethyl phenyls) 0.18 part of propionic ester, double 0.17 part of (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, diosmetin
1.8 parts, 2.5 parts of nano-calcium carbonate, 18 parts of ethanol, 8 parts of glycerine.
The described oil product preparation method of compound antioxidizing and antigum agent, comprises the following steps：, will according to the weight proportion
Nano-calcium carbonate is added in ethanol, is stirred, is obtained mixed liquor A；By butylated hydroxy anisole, APG, stearic acid, two contractings
Triethylene glycol double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester, double (2,4- di-tert-butyl-phenyl) pentaerythrites
Diphosphites and diosmetin are sequentially added in glycerine, are warming up to 45-55 DEG C, and cooling is stood after stirring, must be mixed
Liquid B, then mixed liquor A is added in mixed liquid B, stir, produce the oil product with compound antioxidizing and antigum agent.
Further, the preparation method of the compound antioxidizing and antigum agent of described oil product, wherein the speed of the stirring is
100-150r/min。
Compared with prior art, its advantage is the present invention：
The compound antioxidizing and antigum agent of gained oil product of the invention has after excellent stability, longer-term storage still with excellent
Performance；It can effectively prevent oil product from occurring discoloration because of oxidation in storage, and can thoroughly remove in oil product original colloid simultaneously
Suppress colloid in oil product to re-form, the quality of oil product can be effectively improved, it is ensured that burning quality；In addition, oil product of the present invention is with again
Close antioxidizing and antigum agent preparation method simple and easy to apply, mild condition is easy to control, suitable for a wide range of popularization and application.
Embodiment
With reference to embodiment, the present invention is described in further detail.
It will be understood to those of skill in the art that the following example is merely to illustrate the present invention, and it should not be regarded as limiting this hair
Bright scope.In the examples where no specific technique or condition is specified, according to the technology or condition described by document in the art
Or carried out according to product description.Agents useful for same or the unreceipted production firm person of instrument, are that can be obtained by buying
Conventional products.
Embodiment 1
Oil product compound antioxidizing and antigum agent, including following component in parts by weight：1 part of butylated hydroxy anisole,
Double [the β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester of 0.5 part of APG, 2 parts of stearic acid, triethylene-glycol
0.1 part, double 0.1 part of (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, 1 part of diosmetin, 1 part of nano-calcium carbonate,
15 parts of ethanol, 5 parts of glycerine.
The described oil product preparation method of compound antioxidizing and antigum agent, comprises the following steps：, will according to the weight proportion
Nano-calcium carbonate is added in ethanol, is stirred, is obtained mixed liquor A；By butylated hydroxy anisole, APG, stearic acid, two contractings
Triethylene glycol double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester, double (2,4- di-tert-butyl-phenyl) pentaerythrites
Diphosphites and diosmetin are sequentially added in glycerine, are warming up to 45 DEG C, and cooling is stood after stirring, mixed liquid B is obtained,
Mixed liquor A is added in mixed liquid B again, stirred, the oil product is produced with compound antioxidizing and antigum agent；Wherein described stirring
Speed is 100r/min.
Embodiment 2
Oil product compound antioxidizing and antigum agent, including following component in parts by weight：2 parts of butylated hydroxy anisole,
Double [the β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester of 1.5 parts of APG, 5 parts of stearic acid, triethylene-glycol
0.2 part, double 0.2 part of (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, 2 parts of diosmetin, 3 parts of nano-calcium carbonate,
19 parts of ethanol, 10 parts of glycerine.
The described oil product preparation method of compound antioxidizing and antigum agent, comprises the following steps：, will according to the weight proportion
Nano-calcium carbonate is added in ethanol, is stirred, is obtained mixed liquor A；By butylated hydroxy anisole, APG, stearic acid, two contractings
Triethylene glycol double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester, double (2,4- di-tert-butyl-phenyl) pentaerythrites
Diphosphites and diosmetin are sequentially added in glycerine, are warming up to 55 DEG C, and cooling is stood after stirring, mixed liquid B is obtained,
Mixed liquor A is added in mixed liquid B again, stirred, the oil product is produced with compound antioxidizing and antigum agent；Wherein described stirring
Speed is 150r/min.
Embodiment 3
Oil product compound antioxidizing and antigum agent, including following component in parts by weight：Butylated hydroxy anisole 1.3
Part, the double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic acid of 0.8 part of APG, 3 parts of stearic acid, triethylene-glycol
0.12 part of ester, double 0.12 part of (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, 1.5 parts of diosmetin, nano-calcium carbonate
1.5 parts of calcium, 16 parts of ethanol, 6 parts of glycerine.
The described oil product preparation method of compound antioxidizing and antigum agent, comprises the following steps：, will according to the weight proportion
Nano-calcium carbonate is added in ethanol, is stirred, is obtained mixed liquor A；By butylated hydroxy anisole, APG, stearic acid, two contractings
Triethylene glycol double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester, double (2,4- di-tert-butyl-phenyl) pentaerythrites
Diphosphites and diosmetin are sequentially added in glycerine, are warming up to 50 DEG C, and cooling is stood after stirring, mixed liquid B is obtained,
Mixed liquor A is added in mixed liquid B again, stirred, the oil product is produced with compound antioxidizing and antigum agent；Wherein described stirring
Speed is 120r/min.
Embodiment 4
Oil product compound antioxidizing and antigum agent, including following component in parts by weight：Butylated hydroxy anisole 1.9
Part, the double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic acid of 1.3 parts of APG, 4 parts of stearic acid, triethylene-glycol
0.18 part of ester, double 0.17 part of (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, 1.8 parts of diosmetin, nano-calcium carbonate
2.5 parts of calcium, 18 parts of ethanol, 8 parts of glycerine.
The described oil product preparation method of compound antioxidizing and antigum agent, comprises the following steps：, will according to the weight proportion
Nano-calcium carbonate is added in ethanol, is stirred, is obtained mixed liquor A；By butylated hydroxy anisole, APG, stearic acid, two contractings
Triethylene glycol double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester, double (2,4- di-tert-butyl-phenyl) pentaerythrites
Diphosphites and diosmetin are sequentially added in glycerine, are warming up to 53 DEG C, and cooling is stood after stirring, mixed liquid B is obtained,
Mixed liquor A is added in mixed liquid B again, stirred, the oil product is produced with compound antioxidizing and antigum agent；Wherein described stirring
Speed is 130r/min.
Comparative example 1
The difference of comparative example 1 and embodiment 4 is：Diosmetin is not added, it is specific as follows：
Oil product compound antioxidizing and antigum agent, including following component in parts by weight：Butylated hydroxy anisole 1.9
Part, the double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic acid of 1.3 parts of APG, 4 parts of stearic acid, triethylene-glycol
0.18 part of ester, double 0.17 part of (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, 2.5 parts of nano-calcium carbonate, ethanol 18
Part, 8 parts of glycerine.
The described oil product preparation method of compound antioxidizing and antigum agent, comprises the following steps：, will according to the weight proportion
Nano-calcium carbonate is added in ethanol, is stirred, is obtained mixed liquor A；By butylated hydroxy anisole, APG, stearic acid, two contractings
Triethylene glycol double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester and double (2,4- di-tert-butyl-phenyl) pentaerythrites
Diphosphites are sequentially added in glycerine, are warming up to 53 DEG C, and cooling is stood after stirring, mixed liquid B is obtained, then by mixed liquor
A is added in mixed liquid B, is stirred, and produces the oil product with compound antioxidizing and antigum agent；The speed of wherein described stirring is
130r/min。
Comparative example 2
The difference of comparative example 2 and embodiment 4 is：Diosmetin and double (2,4- di-tert-butyl-phenyl) Ji Wusi are not added
Alcohol diphosphites, it is specific as follows：
Oil product compound antioxidizing and antigum agent, including following component in parts by weight：Butylated hydroxy anisole 1.9
Part, the double [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic acid of 1.3 parts of APG, 4 parts of stearic acid, triethylene-glycol
0.18 part of ester, 2.5 parts of nano-calcium carbonate, 18 parts of ethanol, 8 parts of glycerine.
The described oil product preparation method of compound antioxidizing and antigum agent, comprises the following steps：, will according to the weight proportion
Nano-calcium carbonate is added in ethanol, is stirred, is obtained mixed liquor A；By butylated hydroxy anisole, APG, stearic acid, two contractings
Triethylene glycol is double, and [β-(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propionic ester sequentially adds in glycerine, is warming up to 53 DEG C, stirs
Mix uniform rear stand to cool down, obtain mixed liquid B, then mixed liquor A is added in mixed liquid B, stir, produce the oil product with again
Close antioxidizing and antigum agent；The speed of wherein described stirring is 130r/min.
1-4 of embodiment of the present invention products obtained therefroms, the products obtained therefrom of comparative example 1 and 2 are separately added into being not added with for phase homogenous quantities
In the gasoline of any additive, adding proportion is that, per the addition above-mentioned additives of 6g in 1000g gasoline, the gum level of the gasoline is
20%, meanwhile, take the gasoline for being not added with any additive of same quality as blank example, the performance of gasoline, inspection are tested after 60 days
Survey result as shown in table 1：
The performance detection data of table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Reference examples 1 | Reference examples 2 | Blank example | |
| Gasoline gum content, % after 60 days | Do not detect | Do not detect | Do not detect | Do not detect | 10 | 14 | 32 |
| Gasoline color changes | Significant change is not produced | Significant change is not produced | Significant change is not produced | Significant change is not produced | Significant change is not produced | Significant change is not produced | Deepen |
As seen from the above table, oil product obtained by 1-4 of the embodiment of the present invention can effectively prevent oil product color with compound antioxidizing and antigum agent
Deepen, and can thoroughly remove original colloid in gasoline and suppress re-forming for colloid in oil product, oil product can be effectively improved
Quality, it is ensured that burning quality, and the performance of the products obtained therefrom of reference examples 1 and 2 is then poor, although removing colloid effect is not good, still
Formation to colloid is still inhibited, and the content for being not added with colloid in the fuel oil of any additive then increases, in addition,
Oil product obtained by 1-4 of the embodiment of the present invention is also prevented from gasoline with compound antioxidizing and antigum agent and changed colour because of caused by oxidation.
Claims (6)
1. the compound antioxidizing and antigum agent of oil product, it is characterised in that including following component in parts by weight：Butylhydroxy
Double [the β-(the 3- tert-butyl groups of 1-2 parts of anisole, 0.5-1.5 parts of APG, 2-5 parts of stearic acid, triethylene-glycol
- 4- hydroxyl -5- aminomethyl phenyls) 0.1-0.2 parts of propionic ester, double (2,4- di-tert-butyl-phenyl) pentaerythrites two
0.1-0.2 parts of phosphite ester, 1-2 parts of diosmetin, 1-3 parts of nano-calcium carbonate, 15-19 parts of ethanol, glycerine 5-
10 parts.
2. the compound antioxidizing and antigum agent of the oil product according to claim 1, it is characterised in that including in parts by weight
Following component：1.3-1.9 parts of butylated hydroxy anisole, 0.8-1.3 parts of APG, 3-4 parts of stearic acid, two contractings
Triethylene glycol it is double [β-(the 3- tert-butyl group -4- hydroxyl -5- aminomethyl phenyls) 0.12-0.18 parts of propionic ester, it is double (2,
4- di-tert-butyl-phenyls) 0.12-0.17 parts of pentaerythritol diphosphites, 1.5-1.8 parts of diosmetin, nano-sized carbon
Sour calcium 1.5-2.5 parts, 16-18 parts of ethanol, 6-8 parts of glycerine.
3. the compound antioxidizing and antigum agent of the oil product according to claim 1, it is characterised in that including according to parts by weight
The following component of meter：1.3 parts of butylated hydroxy anisole, 0.8 part of APG, 3 parts of stearic acid, triethylene-glycol
Double [β-(the 3- tert-butyl group -4- hydroxyl -5- aminomethyl phenyls) 0.12 part of propionic ester, double (2,4- di-tert-butyl-phenyls
) 0.12 part of pentaerythritol diphosphites, 1.5 parts of diosmetin, 1.5 parts of nano-calcium carbonate, 16 parts of ethanol, third
6 parts of triol.
4. the compound antioxidizing and antigum agent of the oil product according to claim 1, it is characterised in that including according to parts by weight
The following component of meter：1.9 parts of butylated hydroxy anisole, 1.3 parts of APG, 4 parts of stearic acid, triethylene-glycol
Double [β-(the 3- tert-butyl group -4- hydroxyl -5- aminomethyl phenyls) 0.18 part of propionic ester, double (2,4- di-tert-butyl-phenyls
) 0.17 part of pentaerythritol diphosphites, 1.8 parts of diosmetin, 2.5 parts of nano-calcium carbonate, 18 parts of ethanol, third
8 parts of triol.
5. the preparation method of the compound antioxidizing and antigum agent of oil product described in claim 1, it is characterised in that comprise the following steps
：According to weight proportion, nano-calcium carbonate is added in ethanol, stirs, obtains mixed liquor A；By butylated hydroxy anisole,
APG, stearic acid, triethylene-glycol it is double [β-(the 3- tert-butyl group -4- hydroxyl -5- aminomethyl phenyls) propionic ester,
Double (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites and diosmetin are sequentially added in glycerine, are warming up to
45-55 DEG C, cooling is stood after stirring, mixed liquid B is obtained, then mixed liquor A is added in mixed liquid B, is stirred,
The oil product is produced with compound antioxidizing and antigum agent.
6. the preparation method of the compound antioxidizing and antigum agent of oil product according to claim 5, it is characterised in that the stirring
Speed be 100-150r/min.
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| CN101121901A (en) * | 2007-08-21 | 2008-02-13 | 李超平 | Methanol gasoline for vehicle |
| CN101531930A (en) * | 2009-04-09 | 2009-09-16 | 武汉工程大学 | Low temperature resistant alcohol clean fuel oil and preparation method |
| CN102304113A (en) * | 2011-07-06 | 2012-01-04 | 南京泽朗医药科技有限公司 | Method for separating and purifying diosmetin |
| CN103396901A (en) * | 2013-07-31 | 2013-11-20 | 肇庆欧迪斯实业有限公司 | Foam type throttle cleaning aerosol |
| CN104327890A (en) * | 2014-09-19 | 2015-02-04 | 金景达(北京)环保动力科技有限公司 | Environmentally-friendly high-efficiency methanol gasoline composite additive |
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| US20070204505A1 (en) * | 2006-03-02 | 2007-09-06 | Novus International Inc. | Gasoline fuel compositions having increased oxidative stability |
| DE102009033161A1 (en) * | 2009-07-13 | 2011-01-27 | Schülke & Mayr GmbH | Additive for the bactericidal and anticorrosive finishing of fuels |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101121901A (en) * | 2007-08-21 | 2008-02-13 | 李超平 | Methanol gasoline for vehicle |
| CN101531930A (en) * | 2009-04-09 | 2009-09-16 | 武汉工程大学 | Low temperature resistant alcohol clean fuel oil and preparation method |
| CN102304113A (en) * | 2011-07-06 | 2012-01-04 | 南京泽朗医药科技有限公司 | Method for separating and purifying diosmetin |
| CN103396901A (en) * | 2013-07-31 | 2013-11-20 | 肇庆欧迪斯实业有限公司 | Foam type throttle cleaning aerosol |
| CN104327890A (en) * | 2014-09-19 | 2015-02-04 | 金景达(北京)环保动力科技有限公司 | Environmentally-friendly high-efficiency methanol gasoline composite additive |
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