CN106433817B - A kind of diesel fuel additives and its synthesis technique - Google Patents
A kind of diesel fuel additives and its synthesis technique Download PDFInfo
- Publication number
- CN106433817B CN106433817B CN201610977681.6A CN201610977681A CN106433817B CN 106433817 B CN106433817 B CN 106433817B CN 201610977681 A CN201610977681 A CN 201610977681A CN 106433817 B CN106433817 B CN 106433817B
- Authority
- CN
- China
- Prior art keywords
- parts
- diesel fuel
- fuel additives
- methyl
- intermixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a kind of diesel fuel additives and its synthesis technique, diesel fuel additives component includes 5 15 parts of cetyl trimethylammonium bromide in parts by weight, 3 10 parts of oleic acid, 4 12 parts of acetamide, 8 15 parts of dimethyl carbonate, 7 15 parts of glycerine, 10 20 parts of detergent-dispersant additive, 5 15 parts of dimethyl oxalate, 3 12 parts of 5 methyl, 2 heptene, 4 ketone, 5 15 parts of ethylene glycol monobutyl ether, 26 parts of the dilute manganese tricarbonyl of methyl ring penta 2, preparation technology of the present invention is simple, preparation process is environment friendly and pollution-free, obtained diesel fuel additives can improve the efficiency of combustion of diesel oil, friction and the noise of engine can be reduced, extend the service life of engine.
Description
Technical field
The present invention relates to additive preparing technical field, specially a kind of diesel fuel additives and its synthesis technique.
Background technology
In the last few years, as the continuous improvement of world industry and mechanization degree, various countries increasingly increase to diesel oil demand
Add, need to largely use secondary processing diesel oil, especially catalytic cracking diesel oil.But existing catalytic cracking is unsatisfactory, causes
The utilization rate of diesel oil is low.Therefore, it is necessary to additive be added, to improve the utilization rate of diesel oil.Diesel fuel additives is fuel oil additive
One of which, fuel oil additive generally comprises gasoline additive, diesel fuel additives, is to make up matter existing for fuel oil itself
It is insufficient existing for amount problem and the motor vehicle machine-building limit.But existing additives function is relatively simple, oil-saving effect is not
Substantially, and the service life of engine can not be improved.
The content of the invention
It is an object of the invention to provide a kind of diesel fuel additives and its synthesis technique, to solve to carry in above-mentioned background technology
The problem of going out.
To achieve the above object, the present invention provides following technical scheme：A kind of diesel fuel additives, diesel fuel additives component are pressed
Parts by weight include cetyl trimethylammonium bromide 5-15 parts, oleic acid 3-10 parts, acetamide 4-12 parts, dimethyl carbonate 8-15
Part, glycerine 7-15 parts, detergent-dispersant additive 10-20 parts, dimethyl oxalate 5-15 parts, 5- methyl-2-hepten-4-one 3-12 parts,
Ethylene glycol monobutyl ether 5-15 parts, the dilute manganese tricarbonyl 2-6 parts of methyl ring penta 2.
Preferably, preferable composition proportion is：10 parts of cetyl trimethylammonium bromide, 6 parts of oleic acid, 8 parts of acetamide, carbon
12 parts of dimethyl phthalate, 11 parts of glycerine, 15 parts of detergent-dispersant additive, 10 parts of dimethyl oxalate, 7 parts of 5- methyl-2-hepten-4-ones,
4 parts of the dilute manganese tricarbonyl of 10 parts of ethylene glycol monobutyl ether, methyl ring penta 2.
Preferably, its synthesis technique comprises the following steps：
A, add in stirred tank and stir after mixing cetyl trimethylammonium bromide, oleic acid, acetamide, dimethyl carbonate
Mix, stirred tank rotating speed is 2000 revs/min, mixing time 10min, and standing obtains intermixture A；
B, glycerine, detergent-dispersant additive, dimethyl oxalate, 5- methyl-2-hepten-4-ones, mixing are added in intermixture A
Adding in reactor and stir afterwards, temperature of reaction kettle is 30 DEG C, is stirred continuously in reactor temperature-rise period, mixing time 10min,
Standing obtains intermixture B；
C, ethylene glycol monobutyl ether, penta 2 dilute manganese tricarbonyl of methyl ring are added in intermixture B, adds stirring after mixing again
Stirred at normal temperatures in kettle, stirred tank rotating speed is 1000 revs/min, mixing time 15min, stands 1h, that is, obtains diesel oil addition
Agent.
Compared with prior art, the beneficial effects of the invention are as follows：Preparation technology of the present invention is simple, and preparation process environmental protection is without dirt
Dye, obtained diesel fuel additives can improve the efficiency of combustion of diesel oil, can reduce friction and the noise of engine, extend engine
Service life；In addition, the synthesis technique that the present invention uses is simple to operate, it is well mixed, can further improves additive
Activity.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only it is part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, ordinary skill
The every other embodiment that personnel are obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
The present invention provides a kind of technical scheme：A kind of diesel fuel additives, diesel fuel additives component include ten in parts by weight
Six alkyl trimethyl ammonium bromide 5-15 parts, oleic acid 3-10 parts, acetamide 4-12 parts, dimethyl carbonate 8-15 parts, glycerine 7-15
Part, detergent-dispersant additive 10-20 parts, dimethyl oxalate 5-15 parts, 5- methyl-2-hepten-4-one 3-12 parts, ethylene glycol monobutyl ether
5-15 parts, the dilute manganese tricarbonyl 2-6 parts of methyl ring penta 2.
Embodiment one：
Diesel fuel additives component includes 5 parts of cetyl trimethylammonium bromide, 3 parts of oleic acid, acetamide 4 in parts by weight
Part, 8 parts of dimethyl carbonate, 7 parts of glycerine, 10 parts of detergent-dispersant additive, 5 parts of dimethyl oxalate, 5- methyl-2-hepten-4-ones 3
Part, 5 parts of ethylene glycol monobutyl ether, 2 parts of the dilute manganese tricarbonyl of methyl ring penta 2.
The synthesis technique of the present embodiment comprises the following steps：
A, add in stirred tank and stir after mixing cetyl trimethylammonium bromide, oleic acid, acetamide, dimethyl carbonate
Mix, stirred tank rotating speed is 2000 revs/min, mixing time 10min, and standing obtains intermixture A；
B, glycerine, detergent-dispersant additive, dimethyl oxalate, 5- methyl-2-hepten-4-ones, mixing are added in intermixture A
Adding in reactor and stir afterwards, temperature of reaction kettle is 30 DEG C, is stirred continuously in reactor temperature-rise period, mixing time 10min,
Standing obtains intermixture B；
C, ethylene glycol monobutyl ether, penta 2 dilute manganese tricarbonyl of methyl ring are added in intermixture B, adds stirring after mixing again
Stirred at normal temperatures in kettle, stirred tank rotating speed is 1000 revs/min, mixing time 15min, stands 1h, that is, obtains diesel oil addition
Agent.
Embodiment two：
Diesel fuel additives component includes 15 parts of cetyl trimethylammonium bromide, 10 parts of oleic acid, acetamide in parts by weight
12 parts, 15 parts of dimethyl carbonate, 15 parts of glycerine, 20 parts of detergent-dispersant additive, 15 parts of dimethyl oxalate, 5- methyl -2- heptene -4-
12 parts of ketone, 15 parts of ethylene glycol monobutyl ether, 6 parts of the dilute manganese tricarbonyl of methyl ring penta 2.
The synthesis technique of the present embodiment comprises the following steps：
A, add in stirred tank and stir after mixing cetyl trimethylammonium bromide, oleic acid, acetamide, dimethyl carbonate
Mix, stirred tank rotating speed is 2000 revs/min, mixing time 10min, and standing obtains intermixture A；
B, glycerine, detergent-dispersant additive, dimethyl oxalate, 5- methyl-2-hepten-4-ones, mixing are added in intermixture A
Adding in reactor and stir afterwards, temperature of reaction kettle is 30 DEG C, is stirred continuously in reactor temperature-rise period, mixing time 10min,
Standing obtains intermixture B；
C, ethylene glycol monobutyl ether, penta 2 dilute manganese tricarbonyl of methyl ring are added in intermixture B, adds stirring after mixing again
Stirred at normal temperatures in kettle, stirred tank rotating speed is 1000 revs/min, mixing time 15min, stands 1h, that is, obtains diesel oil addition
Agent.
Embodiment three：
Diesel fuel additives component includes 7 parts of cetyl trimethylammonium bromide, 4 parts of oleic acid, acetamide 5 in parts by weight
Part, 9 parts of dimethyl carbonate, 8 parts of glycerine, 12 parts of detergent-dispersant additive, 6 parts of dimethyl oxalate, 5- methyl-2-hepten-4-ones 5
Part, 7 parts of ethylene glycol monobutyl ether, 3 parts of the dilute manganese tricarbonyl of methyl ring penta 2.
The synthesis technique of the present embodiment comprises the following steps：
A, add in stirred tank and stir after mixing cetyl trimethylammonium bromide, oleic acid, acetamide, dimethyl carbonate
Mix, stirred tank rotating speed is 2000 revs/min, mixing time 10min, and standing obtains intermixture A；
B, glycerine, detergent-dispersant additive, dimethyl oxalate, 5- methyl-2-hepten-4-ones, mixing are added in intermixture A
Adding in reactor and stir afterwards, temperature of reaction kettle is 30 DEG C, is stirred continuously in reactor temperature-rise period, mixing time 10min,
Standing obtains intermixture B；
C, ethylene glycol monobutyl ether, penta 2 dilute manganese tricarbonyl of methyl ring are added in intermixture B, adds stirring after mixing again
Stirred at normal temperatures in kettle, stirred tank rotating speed is 1000 revs/min, mixing time 15min, stands 1h, that is, obtains diesel oil addition
Agent.
Example IV：
Diesel fuel additives component includes 14 parts of cetyl trimethylammonium bromide, 9 parts of oleic acid, acetamide 10 in parts by weight
Part, 13 parts of dimethyl carbonate, 14 parts of glycerine, 18 parts of detergent-dispersant additive, 13 parts of dimethyl oxalate, 5- methyl-2-hepten-4-ones
10 parts, 13 parts of ethylene glycol monobutyl ether, 5 parts of the dilute manganese tricarbonyl of methyl ring penta 2.
The synthesis technique of the present embodiment comprises the following steps：
A, add in stirred tank and stir after mixing cetyl trimethylammonium bromide, oleic acid, acetamide, dimethyl carbonate
Mix, stirred tank rotating speed is 2000 revs/min, mixing time 10min, and standing obtains intermixture A；
B, glycerine, detergent-dispersant additive, dimethyl oxalate, 5- methyl-2-hepten-4-ones, mixing are added in intermixture A
Adding in reactor and stir afterwards, temperature of reaction kettle is 30 DEG C, is stirred continuously in reactor temperature-rise period, mixing time 10min,
Standing obtains intermixture B；
C, ethylene glycol monobutyl ether, penta 2 dilute manganese tricarbonyl of methyl ring are added in intermixture B, adds stirring after mixing again
Stirred at normal temperatures in kettle, stirred tank rotating speed is 1000 revs/min, mixing time 15min, stands 1h, that is, obtains diesel oil addition
Agent.
Embodiment five：
Diesel fuel additives component includes 10 parts of cetyl trimethylammonium bromide, 6 parts of oleic acid, acetamide 8 in parts by weight
Part, 12 parts of dimethyl carbonate, 11 parts of glycerine, 15 parts of detergent-dispersant additive, 10 parts of dimethyl oxalate, 5- methyl-2-hepten-4-ones
7 parts, 10 parts of ethylene glycol monobutyl ether, 4 parts of the dilute manganese tricarbonyl of methyl ring penta 2.
The synthesis technique of the present embodiment comprises the following steps：
A, add in stirred tank and stir after mixing cetyl trimethylammonium bromide, oleic acid, acetamide, dimethyl carbonate
Mix, stirred tank rotating speed is 2000 revs/min, mixing time 10min, and standing obtains intermixture A；
B, glycerine, detergent-dispersant additive, dimethyl oxalate, 5- methyl-2-hepten-4-ones, mixing are added in intermixture A
Adding in reactor and stir afterwards, temperature of reaction kettle is 30 DEG C, is stirred continuously in reactor temperature-rise period, mixing time 10min,
Standing obtains intermixture B；
C, ethylene glycol monobutyl ether, penta 2 dilute manganese tricarbonyl of methyl ring are added in intermixture B, adds stirring after mixing again
Stirred at normal temperatures in kettle, stirred tank rotating speed is 1000 revs/min, mixing time 15min, stands 1h, that is, obtains diesel oil addition
Agent.
Experimental example：
Rate of economizing gasoline and consumption are carried out after additive made from ordinary diesel oil additive and various embodiments of the present invention is added into diesel oil
Oil mass detection, obtain data such as following table：
| Rate of economizing gasoline（%） | Fuel consumption（L） | |
| Common additives | 3.2 | 11.5 |
| Embodiment one | 10.5 | 8.2 |
| Embodiment two | 12.2 | 8.1 |
| Embodiment three | 11.8 | 8.5 |
| Example IV | 11.3 | 8.5 |
| Embodiment five | 13.5 | 7.8 |
From above table data, additive, which is made, in embodiment five can reach optimum efficiency.
Preparation technology of the present invention is simple, and preparation process is environment friendly and pollution-free, and obtained diesel fuel additives can improve the combustion of diesel oil
Efficiency is burnt, friction and the noise of engine can be reduced, extends the service life of engine；In addition, the synthesis that the present invention uses
Technological operation is simple, is well mixed, and can further improve the activity of additive.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (3)
- A kind of 1. diesel fuel additives, it is characterised in that：Diesel fuel additives component includes cetyl trimethyl bromine in parts by weight Change ammonium 5-15 parts, oleic acid 3-10 parts, acetamide 4-12 parts, dimethyl carbonate 8-15 parts, glycerine 7-15 parts, detergent-dispersant additive 10-20 parts, dimethyl oxalate 5-15 parts, 5- methyl-2-hepten-4-one 3-12 parts, ethylene glycol monobutyl ether 5-15 parts, methyl ring Penta 2 dilute manganese tricarbonyl 2-6 parts.
- A kind of 2. diesel fuel additives according to claim 1, it is characterised in that：Preferably composition proportion is：Cetyl 10 parts of trimethylammonium bromide, 6 parts of oleic acid, 8 parts of acetamide, 12 parts of dimethyl carbonate, 11 parts of glycerine, 15 parts of detergent-dispersant additive, 10 parts of dimethyl oxalate, 7 parts of 5- methyl-2-hepten-4-ones, 10 parts of ethylene glycol monobutyl ether, the dilute manganese tricarbonyl 4 of methyl ring penta 2 Part.
- A kind of 3. synthesis technique of diesel fuel additives according to claim 1, it is characterised in that：Its synthesis technique include with Lower step：A, add in stirred tank and stir after mixing cetyl trimethylammonium bromide, oleic acid, acetamide, dimethyl carbonate, stir Kettle rotating speed is mixed as 2000 revs/min, mixing time 10min, standing obtains intermixture A；B, glycerine, detergent-dispersant additive, dimethyl oxalate, 5- methyl-2-hepten-4-ones are added in intermixture A, is added after mixing Enter in reactor and stir, temperature of reaction kettle is 30 DEG C, is stirred continuously in reactor temperature-rise period, mixing time 10min, is stood Obtain intermixture B；C, ethylene glycol monobutyl ether, penta 2 dilute manganese tricarbonyl of methyl ring are added in intermixture B, is added again in stirred tank after mixing Stir at normal temperatures, stirred tank rotating speed is 1000 revs/min, mixing time 15min, stands 1h, that is, obtains diesel fuel additives.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610977681.6A CN106433817B (en) | 2016-11-08 | 2016-11-08 | A kind of diesel fuel additives and its synthesis technique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610977681.6A CN106433817B (en) | 2016-11-08 | 2016-11-08 | A kind of diesel fuel additives and its synthesis technique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106433817A CN106433817A (en) | 2017-02-22 |
| CN106433817B true CN106433817B (en) | 2017-12-05 |
Family
ID=58207438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610977681.6A Active CN106433817B (en) | 2016-11-08 | 2016-11-08 | A kind of diesel fuel additives and its synthesis technique |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106433817B (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009203448A (en) * | 2008-02-26 | 2009-09-10 | San Sekiyu Kk | Additive for fuel for industrial machine |
| CN104250570A (en) * | 2014-09-22 | 2014-12-31 | 辽宁科技大学 | Energy-saving and environment-friendly curing agent for diesel engine system and preparation method thereof |
| CN104818058A (en) * | 2015-04-01 | 2015-08-05 | 李晓楠 | Gasoline anti-knock additive and preparation method thereof |
| CN104789279B (en) * | 2015-04-29 | 2016-08-03 | 安徽中禄新能源科技开发有限公司 | A kind of abrasive compression ignition engine alcohol hydrogen oil and preparation method thereof |
| CN105001927A (en) * | 2015-06-25 | 2015-10-28 | 青岛文晟汽车零部件有限公司 | Diesel oil additive |
-
2016
- 2016-11-08 CN CN201610977681.6A patent/CN106433817B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106433817A (en) | 2017-02-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107629765B (en) | Engine water-free cooling liquid and preparation method thereof | |
| CN106381179B (en) | A kind of gasoline additive and preparation method thereof | |
| CN106433817B (en) | A kind of diesel fuel additives and its synthesis technique | |
| CN102827654A (en) | Cleaning fuel for vehicle | |
| CN102373101B (en) | High-cleaning aged fuel | |
| CN106118763B (en) | A kind of composite diesel additive and preparation method | |
| CN101353602A (en) | Fuel additive | |
| CN102051241A (en) | High-efficiency high-cleanness diesel oil additive and emulsified diesel oil comprising same | |
| CN105385476A (en) | Energy-saving and environment-friendly gasoline nursing additive and preparation method thereof | |
| CN110551538A (en) | oil-saving emission-reducing diesel detergent and preparation method thereof | |
| CN101942349B (en) | High-environmental-protection clean gasoline additive and preparation method thereof | |
| CN102329664A (en) | Novel series environment-friendly and energy-saving fuel oil | |
| CN103740416A (en) | Environment-friendly fuel modified by biological enzyme | |
| CN105950236A (en) | Efficient fuel additive | |
| CN104531237A (en) | Clean energy-saving diesel | |
| CN111635795A (en) | Compound auxiliary agent for alcohol gasoline and preparation method thereof | |
| CN105670719A (en) | High-quality low-residual-carbon biomass diesel composite additive and preparation method thereof | |
| CN101665731B (en) | Composition of diesel cetane-number improver | |
| CN101215482A (en) | Fluid fuel for alcohol hydrocarbon diesel engine and preparation method thereof | |
| CN105331404A (en) | Environment-friendly gasoline additive and preparation method thereof | |
| CN105695006B (en) | A kind of fuel saving diesel detersive and preparation method thereof | |
| CN109536217A (en) | A kind of methanol gasoline and preparation method thereof | |
| CN103952192A (en) | Methanol fuel additive for vehicles and preparation method of methanol fuel additive | |
| CN104711046B (en) | A kind of NEW TYPE OF COMPOSITE clean diesel | |
| CN103992841B (en) | One facilitates antirust oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20171109 Address after: 243000 Anhui city of Ma'anshan province high tech Zone at 1669 North Road Huo sparkle Building No. 2 Applicant after: MA'ANSHAN NUMEN INTELLECTUAL PROPERTY MANAGEMENT SERVICES CO., LTD. Address before: 243000 Anhui province Ma'anshan City mountain mine village 2 Building No. 501 Applicant before: Feng Jin |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180702 Address after: 322005 Tong Yi Road, Yi Ting Town, Yiwu, Zhejiang Province, No. 22 Patentee after: Zhejiang Amperex Technology Limited with U.S. Address before: 243000 2, 1669 north section of Huo Li Shan Road, Ma'anshan high tech Zone, Anhui Patentee before: MA'ANSHAN NUMEN INTELLECTUAL PROPERTY MANAGEMENT SERVICES CO., LTD. |