CN105218907A - Rubber cemented shoe - Google Patents

Rubber cemented shoe Download PDF

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Publication number
CN105218907A
CN105218907A CN201510774101.9A CN201510774101A CN105218907A CN 105218907 A CN105218907 A CN 105218907A CN 201510774101 A CN201510774101 A CN 201510774101A CN 105218907 A CN105218907 A CN 105218907A
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CN
China
Prior art keywords
parts
rubber
heel
half sole
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510774101.9A
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Chinese (zh)
Inventor
涂正洪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jihua 3515 Leather and Leather Shoe Co Ltd
Original Assignee
Jihua 3515 Leather and Leather Shoe Co Ltd
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Application filed by Jihua 3515 Leather and Leather Shoe Co Ltd filed Critical Jihua 3515 Leather and Leather Shoe Co Ltd
Priority to CN201510774101.9A priority Critical patent/CN105218907A/en
Publication of CN105218907A publication Critical patent/CN105218907A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to a kind of rubber cemented shoe.Comprise half sole and heel, described half sole comprises following component by weight: chloroprene rubber 80 ~ 120 parts, 2 ~ 6 parts, magnesium oxide, stearic acid 0.3 ~ 0.7 part, semi-reinforcing hydrocarbon black 3 ~ 7 parts, 3 ~ 7 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.15 ~ 0.55 part, antioxidant NBC 0.2 ~ 1 part; Described heel comprises following component by weight: chloroprene rubber 80 ~ 120 parts, 2 ~ 6 parts, magnesium oxide, stearic acid 0.3 ~ 0.7 part, semi-reinforcing hydrocarbon black 3 ~ 7 parts, 3 ~ 7 parts, zinc oxide, accelerator CBS 0.3 ~ 0.7 part, antioxidant NBC 0.2 ~ 1 part.The invention has the beneficial effects as follows: half sole and heel adopt the promotor of inhomogeneity, Different Weight part, reach whole footwear curing time consistent, namely the rubber of heel thicker position accelerates vulcanization rate, the rubber of half sole thinner position slows down vulcanization rate, makes the rubber at two positions by same curing time, that same temperature reaches curing time is identical.

Description

Rubber cemented shoe
Technical field
The present invention relates to a kind of rubber cemented shoe.
Background technology
Aborning, in certain temperature, under mold pressing, elasticity is become from plasticity in order to make sizing material, and reach cross-linking density maximization, physical and mechanical properties optimizing time used is rubber item curing time, rubber vulcanization time depends primarily on temperature, but individual product due to rubber thickness uneven, cause curing time inconsistent, affect into the actual using function of footwear, for example, the thinner curing time of half sole is corresponding shorter, heel is thicker, curing time is also just corresponding longer, but as determined curing time according to thinner half sole curing time in actual production, the thicker position rubber of heel rubber then can be caused to owe sulphur, cause functional deficiency, if and the thicker heel curing time of employing determines curing time, then cause half sole position overlong time, form rubber over cure aging, also waste product can be caused to produce.
Summary of the invention
For the deficiencies in the prior art, the problem to be solved in the present invention is, provide a kind of rubber cemented shoe, half sole is consistent with heel curing time.
Technical scheme provided by the invention is, rubber cemented shoe, comprise half sole and heel, described half sole comprises following component by weight: chloroprene rubber 80 ~ 120 parts, 2 ~ 6 parts, magnesium oxide, stearic acid 0.3 ~ 0.7 part, semi-reinforcing hydrocarbon black 3 ~ 7 parts, 3 ~ 7 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.15 ~ 0.55 part, antioxidant NBC 0.2 ~ 1 part;
Described heel comprises following component by weight: chloroprene rubber 80 ~ 120 parts, 2 ~ 6 parts, magnesium oxide, stearic acid 0.3 ~ 0.7 part, semi-reinforcing hydrocarbon black 3 ~ 7 parts, 3 ~ 7 parts, zinc oxide, accelerator CBS 0.3 ~ 0.7 part, antioxidant NBC 0.2 ~ 1 part.
Further, described half sole comprises following component by weight: chloroprene rubber 90 ~ 110 parts, 3 ~ 5 parts, magnesium oxide, stearic acid 0.4 ~ 0.6 part, semi-reinforcing hydrocarbon black 4 ~ 6 parts, 4 ~ 6 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.25 ~ 0.45 part, antioxidant NBC 0.4 ~ 0.8 part;
Described heel comprises following component by weight: chloroprene rubber 90 ~ 110 parts, 3 ~ 5 parts, magnesium oxide, stearic acid 0.4 ~ 0.6 part, semi-reinforcing hydrocarbon black 4 ~ 6 parts, 4 ~ 6 parts, zinc oxide, accelerator CBS 0.4 ~ 0.6 part, antioxidant NBC 0.4 ~ 0.8 part.
Preferably, described half sole comprises following component by weight: chloroprene rubber 100 parts, 4 parts, magnesium oxide, stearic acid 0.5 part, semi-reinforcing hydrocarbon black 5 parts, 5 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.35 part, antioxidant NBC 0.6 part;
Described heel comprises following component by weight: chloroprene rubber 100 parts, 4 parts, magnesium oxide, stearic acid 0.5 part, semi-reinforcing hydrocarbon black 5 parts, 5 parts, zinc oxide, accelerator CBS 0.5 part, antioxidant NBC 0.6 part.
The invention has the beneficial effects as follows: half sole and heel adopt the promotor of inhomogeneity, Different Weight part, reach whole footwear curing time consistent, namely the rubber of heel thicker position accelerates vulcanization rate, the rubber of half sole thinner position slows down vulcanization rate, makes the rubber at two positions by same curing time, that same temperature reaches curing time is identical.
Embodiment
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
Embodiment 1: rubber cemented shoe, comprise half sole and heel, half sole comprises following component by weight: chloroprene rubber 80 ~ 120 parts, 2 ~ 6 parts, magnesium oxide, stearic acid 0.3 ~ 0.7 part, semi-reinforcing hydrocarbon black 3 ~ 7 parts, 3 ~ 7 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.15 ~ 0.55 part, antioxidant NBC 0.2 ~ 1 part; Heel comprises following component by weight: chloroprene rubber 80 ~ 120 parts, 2 ~ 6 parts, magnesium oxide, stearic acid 0.3 ~ 0.7 part, semi-reinforcing hydrocarbon black 3 ~ 7 parts, 3 ~ 7 parts, zinc oxide, accelerator CBS 0.3 ~ 0.7 part, antioxidant NBC 0.2 ~ 1 part.
Embodiment 2: rubber cemented shoe, comprises half sole and heel, and half sole comprises following component by weight: chloroprene rubber 80 parts, magnesium oxide 2, stearic acid 0.3 part, semi-reinforcing hydrocarbon black 3 parts, 3 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.15 part, antioxidant NBC 0.2 part; Heel comprises following component by weight: chloroprene rubber 80 parts, 2 parts, magnesium oxide, stearic acid 0.3 part, semi-reinforcing hydrocarbon black 3 parts, 3 parts, zinc oxide, accelerator CBS 0.3 part, antioxidant NBC 0.2 part.
Embodiment 3: rubber cemented shoe, comprises half sole and heel, and described half sole comprises following component by weight: chloroprene rubber 100 parts, 4 parts, magnesium oxide, stearic acid 0.5 part, semi-reinforcing hydrocarbon black 5 parts, 5 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.35 part, antioxidant NBC 0.6 part; Described heel comprises following component by weight: chloroprene rubber 100 parts, 4 parts, magnesium oxide, stearic acid 0.5 part, semi-reinforcing hydrocarbon black 5 parts, 5 parts, zinc oxide, accelerator CBS 0.5 part, antioxidant NBC 0.6 part.
Embodiment 4: rubber cemented shoe, comprises half sole and heel, and described half sole comprises following component by weight: chloroprene rubber 90 parts, 3 parts, magnesium oxide, stearic acid 0.4 part, semi-reinforcing hydrocarbon black 4 parts, 4 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.25 part, antioxidant NBC 0.4 part; Described heel comprises following component by weight: chloroprene rubber 90 parts, 3 parts, magnesium oxide, stearic acid 0.4 part, semi-reinforcing hydrocarbon black 4 parts, 4 parts, zinc oxide, accelerator CBS 0.4 part, antioxidant NBC 0.4 part.
Embodiment 5: rubber cemented shoe, comprises half sole and heel, and half sole comprises following component by weight: chloroprene rubber 110 parts, 5 parts, magnesium oxide, stearic acid 0.6 part, semi-reinforcing hydrocarbon black 6 parts, 6 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.45 part, antioxidant NBC 0.8 part; Heel comprises following component by weight: chloroprene rubber 110 parts, 5 parts, magnesium oxide, stearic acid 0.6 part, semi-reinforcing hydrocarbon black 6 parts, 6 parts, zinc oxide, accelerator CBS 0.6 part, antioxidant NBC 0.8 part.
Embodiment 6: rubber cemented shoe, comprises half sole and heel, and half sole comprises following component by weight: chloroprene rubber 85 parts, 2.5 parts, magnesium oxide, stearic acid 0.35 part, semi-reinforcing hydrocarbon black 3.5 parts, 3.5 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.2 part, antioxidant NBC 0.3 part; Heel comprises following component by weight: chloroprene rubber 85 parts, 2.5 parts, magnesium oxide, stearic acid 0.35 part, semi-reinforcing hydrocarbon black 3.5 parts, 3.5 parts, zinc oxide, accelerator CBS 0.35 part, antioxidant NBC 0.3 part.
Embodiment 7: rubber cemented shoe, comprises half sole and heel, and half sole comprises following component by weight: chloroprene rubber 95 parts, 3.5 parts, magnesium oxide, stearic acid 0.45 part, semi-reinforcing hydrocarbon black 4.5 parts, 4.5 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.3 part, antioxidant NBC 0.5 part; Heel comprises following component by weight: chloroprene rubber 95 parts, 3.5 parts, magnesium oxide, stearic acid 0.45 part, semi-reinforcing hydrocarbon black 4.5 parts, 4.5 parts, zinc oxide, accelerator CBS 0.45 part, antioxidant NBC 0.5 part.
Embodiment 8: rubber cemented shoe, comprises half sole and heel, and half sole comprises following component by weight: chloroprene rubber 105 parts, 4.5 parts, magnesium oxide, stearic acid 0.55 part, semi-reinforcing hydrocarbon black 5.5 parts, 5.5 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.4 part, antioxidant NBC 0.7 part; Heel comprises following component by weight: chloroprene rubber 105 parts, 4.5 parts, magnesium oxide, stearic acid 0.55 part, semi-reinforcing hydrocarbon black 5.5 parts, 5.5 parts, zinc oxide, accelerator CBS 0.55 part, antioxidant NBC 0.7 part.
Embodiment 9: rubber cemented shoe, comprises half sole and heel, and half sole comprises following component by weight: chloroprene rubber 115 parts, 5.5 parts, magnesium oxide, stearic acid 0.65 part, semi-reinforcing hydrocarbon black 6.5 parts, 6.5 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.5 part, antioxidant NBC 0.9 part; Heel comprises following component by weight: chloroprene rubber 115 parts, 5.5 parts, magnesium oxide, stearic acid 0.65 part, semi-reinforcing hydrocarbon black 6.5 parts, 6.5 parts, zinc oxide, accelerator CBS 0.65 part, antioxidant NBC 0.9 part.
Embodiment 10: rubber cemented shoe, comprises half sole and heel, and half sole comprises following component by weight: chloroprene rubber 120 parts, 6 parts, magnesium oxide, stearic acid 0.7 part, semi-reinforcing hydrocarbon black 7 parts, 7 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.55 part, antioxidant NBC 1 part; Heel comprises following component by weight: chloroprene rubber 120 parts, 6 parts, magnesium oxide, stearic acid 0.7 part, semi-reinforcing hydrocarbon black 7 parts, 7 parts, zinc oxide, accelerator CBS 0.7 part, antioxidant NBC 1 part.

Claims (3)

1. rubber cemented shoe, comprises half sole and heel, it is characterized in that:
Described half sole comprises following component by weight: chloroprene rubber 80 ~ 120 parts, 2 ~ 6 parts, magnesium oxide, stearic acid 0.3 ~ 0.7 part, semi-reinforcing hydrocarbon black 3 ~ 7 parts, 3 ~ 7 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.15 ~ 0.55 part, antioxidant NBC 0.2 ~ 1 part;
Described heel comprises following component by weight: chloroprene rubber 80 ~ 120 parts, 2 ~ 6 parts, magnesium oxide, stearic acid 0.3 ~ 0.7 part, semi-reinforcing hydrocarbon black 3 ~ 7 parts, 3 ~ 7 parts, zinc oxide, accelerator CBS 0.3 ~ 0.7 part, antioxidant NBC 0.2 ~ 1 part.
2. rubber cemented shoe according to claim 1, is characterized in that:
Described half sole comprises following component by weight: chloroprene rubber 90 ~ 110 parts, 3 ~ 5 parts, magnesium oxide, stearic acid 0.4 ~ 0.6 part, semi-reinforcing hydrocarbon black 4 ~ 6 parts, 4 ~ 6 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.25 ~ 0.45 part, antioxidant NBC 0.4 ~ 0.8 part;
Described heel comprises following component by weight: chloroprene rubber 90 ~ 110 parts, 3 ~ 5 parts, magnesium oxide, stearic acid 0.4 ~ 0.6 part, semi-reinforcing hydrocarbon black 4 ~ 6 parts, 4 ~ 6 parts, zinc oxide, accelerator CBS 0.4 ~ 0.6 part, antioxidant NBC 0.4 ~ 0.8 part.
3. rubber cemented shoe according to claim 2, is characterized in that:
Described half sole comprises following component by weight: chloroprene rubber 100 parts, 4 parts, magnesium oxide, stearic acid 0.5 part, semi-reinforcing hydrocarbon black 5 parts, 5 parts, zinc oxide, Vulcanization accelerator TMTD-II 0.35 part, antioxidant NBC 0.6 part;
Described heel comprises following component by weight: chloroprene rubber 100 parts, 4 parts, magnesium oxide, stearic acid 0.5 part, semi-reinforcing hydrocarbon black 5 parts, 5 parts, zinc oxide, accelerator CBS 0.5 part, antioxidant NBC 0.6 part.
CN201510774101.9A 2015-11-14 2015-11-14 Rubber cemented shoe Pending CN105218907A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Publications (1)

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CN105218907A true CN105218907A (en) 2016-01-06

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101255243A (en) * 2008-04-02 2008-09-03 际华三五一四制革制鞋有限公司 Double-density shoe leather fast curing rubber size suitable for injection technique and production method thereof
CN101768297A (en) * 2008-12-26 2010-07-07 际华三五一五皮革皮鞋有限公司 Production formula of flame retardant dual density glue and production technique
CN102952297A (en) * 2012-10-15 2013-03-06 广州市邦尔福鞋材有限公司 Double-hardness sole and making method thereof
CN104479180A (en) * 2014-12-16 2015-04-01 天津市富华皮革制品有限公司 Double-density fast-curing rubber compound and production method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101255243A (en) * 2008-04-02 2008-09-03 际华三五一四制革制鞋有限公司 Double-density shoe leather fast curing rubber size suitable for injection technique and production method thereof
CN101768297A (en) * 2008-12-26 2010-07-07 际华三五一五皮革皮鞋有限公司 Production formula of flame retardant dual density glue and production technique
CN102952297A (en) * 2012-10-15 2013-03-06 广州市邦尔福鞋材有限公司 Double-hardness sole and making method thereof
CN104479180A (en) * 2014-12-16 2015-04-01 天津市富华皮革制品有限公司 Double-density fast-curing rubber compound and production method thereof

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Application publication date: 20160106