CN102952297A - Double-hardness sole and making method thereof - Google Patents
Double-hardness sole and making method thereof Download PDFInfo
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- CN102952297A CN102952297A CN2012103903260A CN201210390326A CN102952297A CN 102952297 A CN102952297 A CN 102952297A CN 2012103903260 A CN2012103903260 A CN 2012103903260A CN 201210390326 A CN201210390326 A CN 201210390326A CN 102952297 A CN102952297 A CN 102952297A
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- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 56
- 229920001971 elastomer Polymers 0.000 claims abstract description 34
- 239000005060 rubber Substances 0.000 claims abstract description 34
- 238000005520 cutting process Methods 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 238000005303 weighing Methods 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 239000006229 carbon black Substances 0.000 claims description 28
- 235000021355 Stearic acid Nutrition 0.000 claims description 14
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 claims description 14
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 14
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 14
- 239000008117 stearic acid Substances 0.000 claims description 14
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 14
- 235000004416 zinc carbonate Nutrition 0.000 claims description 14
- 244000043261 Hevea brasiliensis Species 0.000 claims description 13
- 229920003052 natural elastomer Polymers 0.000 claims description 13
- 229920001194 natural rubber Polymers 0.000 claims description 13
- 230000001737 promoting effect Effects 0.000 claims description 13
- 230000002093 peripheral effect Effects 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 claims description 11
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- 230000003078 antioxidant effect Effects 0.000 claims description 7
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 7
- 239000004200 microcrystalline wax Substances 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 7
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 6
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 6
- 239000011667 zinc carbonate Substances 0.000 claims description 6
- 238000005987 sulfurization reaction Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 abstract description 13
- 239000003562 lightweight material Substances 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- 235000019241 carbon black Nutrition 0.000 description 24
- 238000007796 conventional method Methods 0.000 description 8
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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Abstract
The invention discloses a double-hardness sole and a making method thereof, and aims to provide a double-hardness sole which effectively prevents breaking and is comfortable to wear. The sole is technically characterized in that the peripheries of the half sole and the heel of the sole are made of a low-hardness material; and the keel part in the middle of the heel is made of a high-hardness lightweight material. The making method comprises the following steps of: 1) weighing each component according to the mass part in claims 2 and 3, and preparing the high-hardness material and the low-hardness material according to a conventional rubber preparation method respectively; cutting a sole base layer and the periphery of the heel of the sole with the low-hardness material prepared in the step 1), and cutting a keel with the high-hardness material; and performing die closing production and vulcanizing, namely putting the sole base layer on the bottom of a die, putting the periphery of the heel of the sole on the periphery of the heel of the sole, filling a keel material into a die keel of an upper cover of the die, and performing die closing vulcanization at the temperature between 160 and 180 DEG C, wherein the concave-convex part of the material and the concave-convex part of the die are consistent. The invention belongs to the technical field of shoes.
Description
Technical field
The present invention relates to a kind of making method of sole, specifically, is the making method of two hardness soles, belongs to the footwear technical field.
Technical background
The sole making method of existing two kinds of hardness combinations mainly is that low-durometer material is adopted at the half sole position in the prior art, and high hardness material production is adopted at the whole position of heel (after the pin loin).But the shortcoming of using this technology is that the resistance to oxidation effect of bi-material is different, causes two kinds of hardness combining sites that obvious vestige (rubber look, transparent color more obvious) is arranged, and the bi-material binding site has the risk at the disconnected end that disconnects simultaneously; Because high rigidity spring heel density (proportion) is large, sole is heavy in addition.
Summary of the invention
For the problems referred to above, the present invention discloses two kinds of hardness joint marks of a kind of effective solution problem, effectively avoids the fracture of the disconnected end simultaneously, two hardness soles comfortable and easy to wear and preparation method thereof.
Last technical scheme of the present invention is: this pair hardness sole, half sole and heel peripheral portion adopt low-durometer material to make, and the keel position adopts the high rigidity light material to make in the middle of the heel.
Further, above-mentioned two hardness soles, described low-durometer material comprises the component of following mass parts: cis-1,4-polybutadiene rubber, 24-26 part; Natural rubber SVR-3L5.5-6.5 part; Styrene-butadiene rubber(SBR) 11-13 part; White carbon black 14-16; White carbon black promoting agent DEG7.5-8.5 part; PEG-40005.5-6.5 part; Stearic acid 3.5-4.5 part; Zinc carbonate 2.0-2.4 part; Antideteriorant BHT 1.8-2.2 part; Microcrystalline Wax 1.8-2.2 part; Rubber prevents telling creme 3.8-4.2 part; Altax 5.5-6.5 part.
Further, above-mentioned two hardness soles, described high hardness material comprises the component of following mass parts: cis-1,4-polybutadiene rubber 8-10 part; Natural rubber SVR-3L8-9 part; Styrene-butadiene rubber(SBR) 1.8-2.2 part; High-phenylethylene 24-26 part; White carbon black 13-14 part; 1.5 parts of naphthenic oils; White carbon black promoting agent DEG, 6.5-7.5; PEG-40003.5-4.5 part; Stearic acid 4-5 part; Zinc carbonate 1.8-2.2 part; Antioxidant SP-P4.5-5 part; Altax-802.5-3.5 part.
Further, above-mentioned two hardness soles, the durometer level of described high hardness material is at 70-100 ° of shore A.
Further, above-mentioned two hardness soles, the durometer level of described low-durometer material is at 40-70 ° of shore A.
A technical scheme is after of the present invention: the making method at the bottom of this pair hardness sole shoes comprises the steps: 1 successively) by following mass parts, take by weighing each component, cis-1,4-polybutadiene rubber 24-26 part; Natural rubber SVR-3L5.5-6.5 part; Styrene-butadiene rubber(SBR) 11-13 part; White carbon black 14-16; White carbon black agent DEG7.5-8.5 alive part; PEG-40005.5-6.5 part; Stearic acid 3.5-4.5 part; Zinc carbonate 2.0-2.4 part; Antideteriorant BHT 1.8-2.2 part; Microcrystalline Wax 1.8-2.2 part; Rubber prevents telling creme 3.8-4.2 part; Altax powder 5.5-6.5 part, method for preparing rubber prepares respectively low-durometer material routinely; Take by weighing again: cis-1,4-polybutadiene rubber 8-10 part; Natural rubber SVR-3L 8-9 part; Styrene-butadiene rubber(SBR) 1.8-2.2 part; High-phenylethylene 24-26 part; White carbon black 13-14 part; 1.5 parts of naphthenic oils; White carbon black promoting agent DEG 6.5-7.5 part; PEG-4000 3.5-4.5 part; Stearic acid 4-5 part; Zinc carbonate 1.8-2.2 part; Antioxidant SP-P4.5-5 part; Altax-80,2.5-3.5 part, preparation low-durometer material;
2) at the low-durometer material cutting sole basic unit that step 1) prepares, cutting spring heel keel on the high hardness material;
3) matched moulds production sulfuration, first sole basic unit is positioned over mold bottom, again spring heel is positioned over the peripheral place of spring heel, again keel are embedded in the mould top cover die keel, guarantee that concavo-convex position and the concavo-convex position of mould of expecting are consistent, matched moulds sulfuration between 160-170 ℃.
Further, the making method at the bottom of above-mentioned two hardness sole shoes, described keel comprise the first keel and the second keel.
High hardness material of the present invention has the characteristics of lightweight, has guaranteed that spring heel density is little, and sole is light, and is comfortable and easy to wear.
Description of drawings
Fig. 1 is sole basic unit synoptic diagram;
The peripheral synoptic diagram of Fig. 2 spring heel;
Fig. 3 is the first keel synoptic diagram;
Fig. 4 is the second keel synoptic diagram.
Specific embodiments
For the present invention is described better, below the present invention is described in further detail, but do not consist of any limitation of the invention.
Embodiment 1
A kind of pair of hardness sole half sole and heel peripheral portion adopt low-durometer material to make, and the keel position adopts the high rigidity light material to make in the middle of the heel.Wherein low-durometer material comprises the component of following mass parts: 26 parts of cis-1,4-polybutadiene rubbers; 6.5 parts of SVR-3L; 11 parts in styrene-butadiene rubber(SBR); 16 parts of white carbon blacks; 7.5 parts of white carbon black promoting agent DEG; 6.5 parts of PEG-4000; 3.5 parts of stearic acid; 2.4 parts of zinc carbonates; 1.8 parts of antideteriorant BHTs; 2.2 parts of Microcrystalline Waxes; Anti-3.8 parts of the cremes of telling of rubber; 6.5 parts in altax powder, according to a conventional method method for preparing rubber preparation, 50 ° of shore A of hardness; High hardness material comprises the component of following mass parts: 10 parts of cis-1,4-polybutadiene rubbers; 9 parts of natural rubber SVR-3L; 1.8 parts in styrene-butadiene rubber(SBR); 26 parts of high-phenylethylenes; 13 parts of white carbon blacks; 1.5 parts of naphthenic oils; White carbon black promoting agent DEG, 7.5 parts; 5 parts of PEG-4000; Stearic acid 4-5 part; 2.2 parts of zinc carbonates; Antioxidant SP-P 4.5-5 part; Altax-80 3.5 part, according to a conventional method method for preparing rubber preparation, 95 ° of shore A of hardness.
Embodiment 2
A kind of pair of hardness sole, half sole and heel peripheral portion adopt low-durometer material to make, and the keel position adopts the high rigidity light material to make in the middle of the heel.Wherein, low-durometer material comprises the component of following mass parts: 25 parts of cis-1,4-polybutadiene rubbers; 6.5 parts of natural rubber SVR-3L; 12 parts in styrene-butadiene rubber(SBR); 14 parts of white carbon blacks; 8 parts of white carbon black promoting agent DEG; 6 parts of PEG-4000; 4.5 parts of stearic acid; 2.0 parts of zinc carbonates; 2.2 parts of antideteriorant BHTs; 2.2 parts of Microcrystalline Waxes; Anti-4.1 parts of the cremes of telling of rubber; 6.5 parts in altax powder, according to a conventional method method for preparing rubber preparation, 60 ° of shore A of hardness; High hardness material comprises the component of following mass parts: 9 parts of cis-1,4-polybutadiene rubbers; 9 parts of natural rubber SVR-3L; 2 parts in styrene-butadiene rubber(SBR); 24 parts of high-phenylethylenes; 13.5 parts of white carbon blacks; 1.5 parts of naphthenic oils; White carbon black promoting agent DEG, 6.5; 4 parts of PEG-4000; 4.5 parts of stearic acid; 1.9 parts of zinc carbonates; 5 parts of antioxidant SP-P; Altax-80 3 part, according to a conventional method method for preparing rubber preparation, 90 ° of shore A of hardness.
Embodiment 3
A kind of pair of hardness sole, half sole and heel peripheral portion adopt low-durometer material to make, and the keel position adopts the high rigidity light material to make in the middle of the heel.Wherein, low-durometer material comprises the component of following mass parts: 25 parts of cis-1,4-polybutadiene rubbers; Natural rubber SVR-3L6 part; 12 parts in styrene-butadiene rubber(SBR); 15 parts of white carbon blacks; 7.5 parts of white carbon black promoting agent DEG; 6.5 parts of PEG-4000; 4.5 parts of stearic acid; 2.2 parts of zinc carbonates; 2.2 parts of antideteriorant BHTs; 1.8 parts of Microcrystalline Waxes; Anti-4.2 parts of the cremes of telling of rubber; 4.5 parts in altax powder, according to a conventional method method for preparing rubber preparation, 65 ° of shore A of hardness part.High hardness material comprises the component of following mass parts: 10 parts of cis-1,4-polybutadiene rubbers; Natural rubber SVR-3L9 part; 2.2 parts in styrene-butadiene rubber(SBR); 25 parts of high-phenylethylenes; White carbon black 13.5; 1.5 parts of naphthenic oils; White carbon black promoting agent DEG, 7.5; 4.5 parts of PEG-4000; 5 parts of stearic acid; 1.9 parts of zinc carbonates, 5.3 parts of antioxidant SP-P; Altax-80 3 part, according to a conventional method method for preparing rubber preparation, 85 ° of shore A of hardness.
Embodiment 4
A kind of pair of hardness sole, half sole and heel peripheral portion adopt low-durometer material to make, and the keel position adopts the high rigidity light material to make in the middle of the heel.Wherein, low-durometer material comprises the component of following mass parts: 26 parts of cis-1,4-polybutadiene rubbers; 6 parts of natural rubber SVR-3L; Styrene-butadiene rubber(SBR) 12; 16 parts of white carbon blacks; 8.5 parts of white carbon black promoting agent DEF; 5.5 parts of PEG-4000; 4 parts of stearic acid; 2.2 parts of zinc carbonates; 2.0 parts of antideteriorant BHTs; 1.8 parts of Microcrystalline Waxes; Anti-4.0 parts of the cremes of telling of rubber; 6 parts in rubber accelerator DM powder, according to a conventional method method for preparing rubber preparation, 70 ° of shore A of hardness.High hardness material comprises the component of following mass parts: 9 parts of cis-1,4-polybutadiene rubbers; 9 parts of natural rubber SVR-3L; 2 parts in styrene-butadiene rubber(SBR); 25 parts of high-phenylethylenes; 14 parts of white carbon blacks; 1.5 parts of naphthenic oils; White carbon black promoting agent DEG, 6.8 parts; 4.2 parts of PEG-4000; 4.8 parts of stearic acid; 1.9 parts of zinc carbonates; 5.0 parts of antioxidant SP-P; Altax-80 3.5 part, according to a conventional method method for preparing rubber preparation, 80 ° of shore A of hardness.
Its preparation method is:
Consult Fig. 1 to Fig. 4, sole basic unit 1; The thickness of spring heel periphery 2 designs with peripheral body thickness height, height is according to sole the first keel 31, the actual height of the second keel 32 determines, thickness guarantees that material can not overflow sole basic unit 1, peripheral 2 material of spring heel, during making, open mould and use dead material in the air pressure gun cleaning mould, burr, cutting die severing material sole basic unit 1 is positioned over mold bottom, cutting die severing material spring heel periphery 2 is positioned over the peripheral place of mould heel, cutting die severing material the first keel 31 are embedded in the perpendicular direction mould keel of mould loam cake, guarantee that concavo-convex position and the concavo-convex position of mould of expecting are consistent.Cutting die severing material the second keel 32 are embedded in the mould loam cake widthwise mould keel, guarantee that the recess position of Fig. 4 material embeds in Fig. 3 recess position.Guarantee to vulcanize the matched moulds production sulfuration between 160-170 ℃ of production temperature, guarantee in the matched moulds process that the first keel 31, the second keel 32 can not come off, curing time is finished, and gets the end and carries out rear operation processing, and flow process finishes.
Combination for different hardness is tested with conversion:
Test-results is as follows:
Wherein: American States' standard (ASTM) stretching resistance value:＞=90kg/cm2; Anti tear value:＞=20kg/cm2 of the large end of American States' standard; The large end hardness standard value: of American States' standard (ASTM)＞=65 ° of shoneA; The tortuous standard value of American States' standard (ASTM): 50,000 times flawless; By above analysis, every testing data obviously is better than American States' standard (ASTM).
Claims (7)
1. a two hardness sole is characterized in that, half sole and heel peripheral portion adopt low-durometer material to make, and the keel position adopts the high rigidity light material to make in the middle of the heel.
2. require described pair of hardness sole according to right 1, it is characterized in that, described low-durometer material comprises the component of following mass parts: cis-1,4-polybutadiene rubber, 24-26 part; Natural rubber SVR-3L, 5.5-6.5 part; Styrene-butadiene rubber(SBR), 11-13 part; White carbon black, 14-16; White carbon black promoting agent DEG 7.5-8.5 part; PEG-4000 5.5-6.5 part; Stearic acid 3.5-4.5 part; Zinc carbonate 2.0-2.4 part; Antideteriorant BHT 1.8-2.2 part; Microcrystalline Wax 1.8-2.2 part; Rubber prevents telling creme 3.8-4.2 part; Altax 5.5-6.5 part.
3. require according to claim 1 described pair of hardness sole, it is characterized in that, described high hardness material comprises the component of following mass parts: cis-1,4-polybutadiene rubber 8-10 part; Natural rubber SVR-3L8-9 part; Styrene-butadiene rubber(SBR) 1.8-2.2 part; High-phenylethylene 24-26 part; White carbon black 13-14 part; 1.5 parts of naphthenic oils; White carbon black promoting agent DEG 6.5-7.5 part; PEG-4000 3.5-4.5 part; Stearic acid 4-5 part; Zinc carbonate 1.8-2.2 part; Antioxidant SP-P4.5-5 part; Altax-802.5-3.5 part.
4. require described pair of hardness sole according to right 1 or 2, it is characterized in that, the durometer level of described high hardness material is at 80-95 ° of shore A.
5. require described pair of hardness sole according to right 1 or 3, it is characterized in that, the durometer level of described low-durometer material is at 50-70 ° of shore A.
6. the making method at the bottom of the claimed in claim 1 pair of hardness sole shoes is characterized in that, comprises the steps: successively
1) take by weighing each component by claim 2 and 3 described mass parts, method for preparing rubber prepares respectively high hardness material and low-durometer material routinely;
2) at the low-durometer material cutting sole basic unit that step 1) prepares, cutting spring heel keel on the high hardness material;
3) matched moulds production sulfuration, first sole basic unit is positioned over mold bottom, again spring heel is positioned over the peripheral place of spring heel, again keel are embedded in the mould top cover die keel, guarantee that concavo-convex position and the concavo-convex position of mould of expecting are consistent matched moulds between 160-170 ℃.
7. the making method at the bottom of the according to claim 6 pair of hardness sole shoes is characterized in that described keel comprise the first keel and the second keel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210390326.0A CN102952297B (en) | 2012-10-15 | 2012-10-15 | Double-hardness sole and making method thereof |
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| CN201210390326.0A CN102952297B (en) | 2012-10-15 | 2012-10-15 | Double-hardness sole and making method thereof |
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| CN102952297A true CN102952297A (en) | 2013-03-06 |
| CN102952297B CN102952297B (en) | 2014-08-27 |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103159999A (en) * | 2013-04-03 | 2013-06-19 | 叶建华 | Wear-resistant sole material and preparation method thereof |
| CN103214700A (en) * | 2013-04-20 | 2013-07-24 | 德州市鑫华润聚胺酯工业有限公司 | Double-hardness and double-physical-property rubber sole and preparation technology thereof |
| CN103965523A (en) * | 2014-05-20 | 2014-08-06 | 南京东亚橡塑制品有限公司 | Dual-density sole and preparation method thereof |
| CN104497377A (en) * | 2014-12-07 | 2015-04-08 | 青岛万盈橡胶科技有限公司 | Disc filling adhesive formula and production process thereof |
| CN105218907A (en) * | 2015-11-14 | 2016-01-06 | 际华三五一五皮革皮鞋有限公司 | Rubber cemented shoe |
| CN105295123A (en) * | 2015-11-23 | 2016-02-03 | 东莞市众盛硅橡胶制品有限公司 | Low hardness nitrile butadiene rubber silica-gel powder blend and preparation method thereof |
| CN106220909A (en) * | 2016-08-24 | 2016-12-14 | 际华三五三七制鞋有限责任公司 | Wiping slurry grass green rubber and preparation method thereof reprocessed by liberation Foxing strip for rubber shoes slurry |
| CN106363940A (en) * | 2016-09-29 | 2017-02-01 | 东莞市丹金科技有限公司 | Production process of combined shoe sole |
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| CN107814986A (en) * | 2017-11-03 | 2018-03-20 | 南通龙邦橡塑有限公司 | Double durometer rubber moulding materials and preparation method thereof |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103159999A (en) * | 2013-04-03 | 2013-06-19 | 叶建华 | Wear-resistant sole material and preparation method thereof |
| CN103214700A (en) * | 2013-04-20 | 2013-07-24 | 德州市鑫华润聚胺酯工业有限公司 | Double-hardness and double-physical-property rubber sole and preparation technology thereof |
| CN103214700B (en) * | 2013-04-20 | 2015-04-15 | 德州市鑫华润聚氨酯鞋材股份有限公司 | Double-hardness and double-physical-property rubber sole and preparation technology thereof |
| CN103965523A (en) * | 2014-05-20 | 2014-08-06 | 南京东亚橡塑制品有限公司 | Dual-density sole and preparation method thereof |
| CN104497377A (en) * | 2014-12-07 | 2015-04-08 | 青岛万盈橡胶科技有限公司 | Disc filling adhesive formula and production process thereof |
| CN105218907A (en) * | 2015-11-14 | 2016-01-06 | 际华三五一五皮革皮鞋有限公司 | Rubber cemented shoe |
| CN105295123A (en) * | 2015-11-23 | 2016-02-03 | 东莞市众盛硅橡胶制品有限公司 | Low hardness nitrile butadiene rubber silica-gel powder blend and preparation method thereof |
| CN106220909A (en) * | 2016-08-24 | 2016-12-14 | 际华三五三七制鞋有限责任公司 | Wiping slurry grass green rubber and preparation method thereof reprocessed by liberation Foxing strip for rubber shoes slurry |
| CN106363940B (en) * | 2016-09-29 | 2019-01-25 | 天津安健致远国际贸易有限公司 | Assembled shoe bottom production technology |
| CN106363940A (en) * | 2016-09-29 | 2017-02-01 | 东莞市丹金科技有限公司 | Production process of combined shoe sole |
| CN106883611A (en) * | 2017-03-15 | 2017-06-23 | 湖南科技大学 | It is a kind of to have the inflation technique for pressing tennis ball liner |
| CN107814986A (en) * | 2017-11-03 | 2018-03-20 | 南通龙邦橡塑有限公司 | Double durometer rubber moulding materials and preparation method thereof |
| CN107603185A (en) * | 2017-11-06 | 2018-01-19 | 陈沛栋 | Rubber |
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| CN110092951B (en) * | 2019-05-23 | 2021-06-08 | 昆山多威体育用品有限公司 | Double-hardness physical ability testing shoe rubber substrate and preparation method thereof |
| CN112029186A (en) * | 2020-09-15 | 2020-12-04 | 安踏（中国）有限公司 | Composite response foaming rubber-plastic sole, preparation method thereof and sports shoe |
| CN112029186B (en) * | 2020-09-15 | 2022-09-06 | 安踏（中国）有限公司 | Composite response foaming rubber-plastic sole, preparation method thereof and sports shoe |
| CN113956549A (en) * | 2021-10-26 | 2022-01-21 | 中国石油化工股份有限公司 | High-resilience semitransparent sole material and preparation method thereof |
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