CN105218897A - A kind of Novel rubber plastic alloy foaming large end - Google Patents
A kind of Novel rubber plastic alloy foaming large end Download PDFInfo
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Abstract
The present invention relates to a kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by following raw material: first part's formula is in mass ratio: nitrile rubber, rubber and plastic alloy, zinc oxide, octadecanoic acid, magnesium oxide, N-sec.-propyl-N '-diphenyl-para-phenylene diamine, 2,2,4-trimethylammonium-1,2-dihyaroquinoline, strengthening agent, coumarone indene resin, o-phthalic acid dibutyl ester and whipping agent; Second section adds sulphur, accelerant CZ, Vulcanization accelerator TMTD and accelerator dibenzothiazyl disulfide on first part basis.This foaming large end, not only has softness, good springiness, the advantages such as proportion is little, and wear resisting property is good.
Description
Technical field
The invention belongs to foaming technical field of the large end, be specifically related to a kind of Novel rubber plastic alloy foaming large end.
Background technology
Current various soles mostly by natural rubber as raw material, through over-mastication, add other batchings internally mix of carrying out mixing and make the rubber boots large end, cost is all comparatively controlled, and the performances such as hardness all can adjust as required, has substantially met the requirement of people.Due to employing is natural rubber, needs to plasticate, labor intensive material resources, increases cost.Another aspect carbon black carries out sizing material reinforcement, and in preparation process, the acid-basicity of rubber unvulcanizate is difficult to control, and is difficult to meet the sulfuration process to postorder.In order to increase the flexibility of rubber boots, usually in sizing material, add whipping agent, the foam hole that then use of whipping agent produces have impact on the wear resistance of shoes.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and provide a kind of Novel rubber plastic alloy to foam at the large end, the advantages such as this foaming large end not only has softness, good springiness, and proportion is little, and wear resisting property is good.
In order to achieve the above object, the present invention adopts following technical scheme:
The invention provides a kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.259-34.53, rubber and plastic alloy 21.74-23.02, zinc oxide 2.50-2.85, octadecanoic acid 1.08-1.13, magnesium oxide 0.51-0.56, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.51-0.56, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.70-0.77, strengthening agent 28.16-30.69, coumarone indene resin 1.53-1.68, o-phthalic acid dibutyl ester 8.62-8.98, whipping agent 2.10-2.25, second section is the add-on on first part every kilogram basis, and it is sulphur 6-7g, accelerant CZ 7.5-8g, Vulcanization accelerator TMTD 1-2g, accelerator dibenzothiazyl disulfide 5.5-6.5g.
According to the above-mentioned Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.259-34.53, rubber and plastic alloy 21.74-23.02, zinc oxide 2.50-2.85, octadecanoic acid 1.08-1.13, magnesium oxide 0.51-0.56, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.51-0.56, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.70-0.77, strengthening agent 28.16-30.69, coumarone indene resin 1.53-1.68, o-phthalic acid dibutyl ester 8.62-8.98, whipping agent 2.10-2.25, second section is the add-on on first part every kilogram basis, and it is sulphur 6g, accelerant CZ 8g, Vulcanization accelerator TMTD 2g, accelerator dibenzothiazyl disulfide 6g.
According to the above-mentioned Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.35-34.45, rubber and plastic alloy 21.8-23.0, zinc oxide 2.50-2.85, octadecanoic acid 1.10-1.12, magnesium oxide 0.52-0.55, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.53-0.55, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.73-0.75, strengthening agent 28.6-30.6, coumarone indene resin 1.58-1.63, o-phthalic acid dibutyl ester 8.65-8.95, whipping agent 2.15-2.20, second section is the add-on on first part every kilogram basis, and it is sulphur 6g, accelerant CZ 8g, Vulcanization accelerator TMTD 2g, accelerator dibenzothiazyl disulfide 6g.
According to the above-mentioned Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.4, rubber and plastic alloy 22.0, zinc oxide 2.65, octadecanoic acid 1.12, magnesium oxide 0.55, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.54,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.75, strengthening agent 29.5, coumarone indene resin 1.62, o-phthalic acid dibutyl ester 8.85, whipping agent 2.15; Second section is the add-on on first part every kilogram basis, and it is sulphur 6g, accelerant CZ 8g, Vulcanization accelerator TMTD 2g, accelerator dibenzothiazyl disulfide 6g.
Described rubber and plastic alloy is that the paracril of 5:3 and PVC form by weight ratio.
Described strengthening agent is carbon black N339, carbon black N330, carbon black N220 or white carbon black.
Compared with prior art, the beneficial effect that obtains of the present invention:
1. in the present invention's formula, add rubber-plastic alloy, add the hardness of bipeltate and endure property, compensate for bipeltate and wear the givey phenomenon of appearance for a long time; Whipping agent adopts microcapsule foamer, expansion density uniformity, outward appearance aperture dense uniform; The use of nitrile rubber, not only increases wear resisting property, and use also can be worn in the applicable large end under various soda acid and oiliness environment, and what meet the large end wears performance, has increased substantially the wear resisting property of sizing material.
2. at the bottom of the glue adopting formula of the present invention to obtain, the method for DIN detects in accordance with international practices, and through the test of third party laboratory, this kind of rubber and plastic alloy foaming density of the large end is 0.54g/cm
3, DIN abrasion are 47mm
3, hardness is 67 Shao Er hardness C; 40000 times folding quality meets the requirements, and the weight saving at the large end of foaming 30%.These performance index are better than national standard, serve good effect.
Embodiment
Below in conjunction with embodiment, the present invention is further described, but do not limit content of the present invention.
Below relate to whipping agent purchased from Rui'an City Zhong Wei rubber and plastics auxiliaries company limited.
embodiment 1
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.259-34.53, rubber and plastic alloy 21.74-23.02, zinc oxide 2.50-2.85, octadecanoic acid 1.08-1.13, magnesium oxide 0.51-0.56, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.51-0.56, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.70-0.77, strengthening agent 28.16-30.69, coumarone indene resin 1.53-1.68, o-phthalic acid dibutyl ester 8.62-8.98, whipping agent 2.10-2.25, second section is the add-on on first part every kilogram basis, and it is sulphur 6-7g, accelerant CZ 7.5-8g, Vulcanization accelerator TMTD 1-2g, accelerator dibenzothiazyl disulfide 5.5-6.5g.
Through the test of third party laboratory, the rubber and plastic alloy foaming density of the large end that the present embodiment obtains is 0.540 ~ 0.543g/cm
3, DIN abrasion are 46.98 ~ 47.02mm
3, hardness is 67 ~ 68 Shao Er hardness C; 40000 times folding quality meets the requirements.
embodiment 2
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.4, rubber and plastic alloy 22.0, zinc oxide 2.65, octadecanoic acid 1.12, magnesium oxide 0.55, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.54,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.75, white carbon black 29.5, coumarone indene resin 1.62, o-phthalic acid dibutyl ester 8.85, whipping agent 2.15; Second section is the add-on on first part every kilogram basis, and it is sulphur 6g, accelerant CZ 8g, Vulcanization accelerator TMTD 2g, accelerator dibenzothiazyl disulfide 6g.
embodiment 3
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.26, rubber and plastic alloy 21.82, zinc oxide 2.65, octadecanoic acid 1.12, magnesium oxide 0.54, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.53,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.72, carbon black N33928.19, coumarone indene resin 1.57, o-phthalic acid dibutyl ester 8.73, whipping agent 2.13; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.4g, accelerant CZ 7.8g, Vulcanization accelerator TMTD 1.4g, accelerator dibenzothiazyl disulfide 5.6g.
embodiment 4
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.28, rubber and plastic alloy 22.02, zinc oxide 2.75, octadecanoic acid 1.09, magnesium oxide 0.52, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.55,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.72, white carbon black 28.43, coumarone indene resin 1.55, o-phthalic acid dibutyl ester 8.93, whipping agent 2.15; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.2g, accelerant CZ 7.6g, Vulcanization accelerator TMTD 1.3g, accelerator dibenzothiazyl disulfide 5.8g.
embodiment 5
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.59, rubber and plastic alloy 23.0, zinc oxide 2.75, octadecanoic acid 1.12, magnesium oxide 0.53, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.53,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.76, carbon black N22029.16, coumarone indene resin 1.59, o-phthalic acid dibutyl ester 8.72, whipping agent 2.12; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.2g, accelerant CZ 7.9g, Vulcanization accelerator TMTD 1.4g, accelerator dibenzothiazyl disulfide 5.8g.
embodiment 6
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 34.53, rubber and plastic alloy 22.45, zinc oxide 2.52, octadecanoic acid 1.09, magnesium oxide 0.53, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.55,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.72, carbon black N22029.69, coumarone indene resin 1.58, o-phthalic acid dibutyl ester 8.83, whipping agent 2.14; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.6g, accelerant CZ 7.7g, Vulcanization accelerator TMTD 1.6g, accelerator dibenzothiazyl disulfide 5.9g.
embodiment 7
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.623, rubber and plastic alloy 21.82, zinc oxide 2.55, octadecanoic acid 1.12, magnesium oxide 0.53, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.51,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.72, carbon black N33029.24, coumarone indene resin 1.56, o-phthalic acid dibutyl ester 8.78, whipping agent 2.19; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.2g, accelerant CZ 7.9g, Vulcanization accelerator TMTD 1.2g, accelerator dibenzothiazyl disulfide 5.8g.
embodiment 8
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 34.12, rubber and plastic alloy 21.93, zinc oxide 2.65, octadecanoic acid 1.09, magnesium oxide 0.52, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.53,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.72, carbon black N33928.2, coumarone indene resin 1.59, o-phthalic acid dibutyl ester 8.94, whipping agent 2.16; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.9g, accelerant CZ 7.9g, Vulcanization accelerator TMTD 1.5g, accelerator dibenzothiazyl disulfide 6g.
embodiment 9
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.842, rubber and plastic alloy 21.98, zinc oxide 2.81, octadecanoic acid 1.08, magnesium oxide 0.53, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.52,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.74, white carbon black 29.28, coumarone indene resin 1.63, o-phthalic acid dibutyl ester 8.64, whipping agent 2.13; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.4g, accelerant CZ 7.6g, Vulcanization accelerator TMTD 1.8g, accelerator dibenzothiazyl disulfide 6.2g.
embodiment 10
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.746, rubber and plastic alloy 22.34, zinc oxide 2.68, octadecanoic acid 1.12, magnesium oxide 0.53, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.55,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.73, carbon black N33928.73, coumarone indene resin 1.59, o-phthalic acid dibutyl ester 8.83, whipping agent 2.12; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.5g, accelerant CZ 7.6g, Vulcanization accelerator TMTD 1.3g, accelerator dibenzothiazyl disulfide 5.6g.
embodiment 11
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.659, rubber and plastic alloy 22.86, zinc oxide 2.67, octadecanoic acid 1.09, magnesium oxide 0.53, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.55,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.76, carbon black N22029.17, coumarone indene resin 1.56, o-phthalic acid dibutyl ester 8.76, whipping agent 2.19; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.3g, accelerant CZ 7.6g, Vulcanization accelerator TMTD 1.4g, accelerator dibenzothiazyl disulfide 5.7g.
embodiment 12
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.85, rubber and plastic alloy 21.79, zinc oxide 2.75, octadecanoic acid 1.13, magnesium oxide 0.54, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.53,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.73, white carbon black 28.54, coumarone indene resin 1.58, o-phthalic acid dibutyl ester 8.67, whipping agent 2.14; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.6g, accelerant CZ 7.5g, Vulcanization accelerator TMTD 1.6g, accelerator dibenzothiazyl disulfide 5.8g.
embodiment 13
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 34.53, rubber and plastic alloy 21.74, zinc oxide 2.85, octadecanoic acid 1.08, magnesium oxide 0.56, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.51,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.77, carbon black N33928.16, coumarone indene resin 1.68, o-phthalic acid dibutyl ester 8.62, whipping agent 2.25; Second section is the add-on on first part every kilogram basis, and it is sulphur 6g, accelerant CZ 8g, Vulcanization accelerator TMTD 1g, accelerator dibenzothiazyl disulfide 6.5g.
embodiment 14
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.29, rubber and plastic alloy 22.75, zinc oxide 2.70, octadecanoic acid 1.11, magnesium oxide 0.53, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.52,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.76, carbon black N33929.24, coumarone indene resin 1.59, o-phthalic acid dibutyl ester 8.74, whipping agent 2.16; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.2g, accelerant CZ 7.8g, Vulcanization accelerator TMTD 1.3g, accelerator dibenzothiazyl disulfide 5.9g.
embodiment 15
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 34.03, rubber and plastic alloy 22.84, zinc oxide 2.60, octadecanoic acid 1.09, magnesium oxide 0.52, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.55,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.75, carbon black N33028.49, coumarone indene resin 1.58, o-phthalic acid dibutyl ester 8.79, whipping agent 2.15; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.8g, accelerant CZ 7.6g, Vulcanization accelerator TMTD 1.4g, accelerator dibenzothiazyl disulfide 5.6g.
embodiment 16
A kind of Novel rubber plastic alloy foaming large end, be prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.735, rubber and plastic alloy 21.72, zinc oxide 2.55, octadecanoic acid 1.13, magnesium oxide 0.52, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.54,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.76, strengthening agent 29.32, coumarone indene resin 1.57, o-phthalic acid dibutyl ester 8.73, whipping agent 2.18; Second section is the add-on on first part every kilogram basis, and it is sulphur 6.1g, accelerant CZ 7.6g, Vulcanization accelerator TMTD 1.2g, accelerator dibenzothiazyl disulfide 5.8g.
Through the test of third party laboratory, the rubber and plastic alloy foaming density of the large end that embodiment 2 ~ 16 obtains is 0.540 ~ 0.543g/cm
3, DIN abrasion are 46.98 ~ 47.02mm
3, hardness is 67 ~ 68 Shao Er hardness C; 40000 times folding quality meets the requirements.
Claims (6)
1. a Novel rubber plastic alloy foaming large end, it is characterized in that being prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.259-34.53, rubber and plastic alloy 21.74-23.02, zinc oxide 2.50-2.85, octadecanoic acid 1.08-1.13, magnesium oxide 0.51-0.56, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.51-0.56, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.70-0.77, strengthening agent 28.16-30.69, coumarone indene resin 1.53-1.68, o-phthalic acid dibutyl ester 8.62-8.98, whipping agent 2.10-2.25, second section is the add-on on first part every kilogram basis, and it is sulphur 6-7g, accelerant CZ 7.5-8g, Vulcanization accelerator TMTD 1-2g, accelerator dibenzothiazyl disulfide 5.5-6.5g.
2. the Novel rubber plastic alloy foaming large end according to claim 1, it is characterized in that being prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.259-34.53, rubber and plastic alloy 21.74-23.02, zinc oxide 2.50-2.85, octadecanoic acid 1.08-1.13, magnesium oxide 0.51-0.56, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.51-0.56, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.70-0.77, strengthening agent 28.16-30.69, coumarone indene resin 1.53-1.68, o-phthalic acid dibutyl ester 8.62-8.98, whipping agent 2.10-2.25, second section is the add-on on first part every kilogram basis, and it is sulphur 6g, accelerant CZ 8g, Vulcanization accelerator TMTD 2g, accelerator dibenzothiazyl disulfide 6g.
3. the Novel rubber plastic alloy foaming large end according to claim 2, it is characterized in that being prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.35-34.45, rubber and plastic alloy 21.8-23.0, zinc oxide 2.50-2.85, octadecanoic acid 1.10-1.12, magnesium oxide 0.52-0.55, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.53-0.55, 2, 2, 4-trimethylammonium-1, 2-dihyaroquinoline 0.73-0.75, strengthening agent 28.6-30.6, coumarone indene resin 1.58-1.63, o-phthalic acid dibutyl ester 8.65-8.95, whipping agent 2.15-2.20, second section is the add-on on first part every kilogram basis, and it is sulphur 6g, accelerant CZ 8g, Vulcanization accelerator TMTD 2g, accelerator dibenzothiazyl disulfide 6g.
4. the Novel rubber plastic alloy foaming large end according to claim 3, it is characterized in that being prepared from by following two portions raw material: first part is prepared from by the raw material of following weight part: first part's formula is in mass ratio: nitrile rubber 33.4, rubber and plastic alloy 22.0, zinc oxide 2.65, octadecanoic acid 1.12, magnesium oxide 0.55, N-sec.-propyl-N '-diphenyl-para-phenylene diamine 0.54,2,2,4-trimethylammonium-1,2-dihyaroquinoline 0.75, strengthening agent 29.5, coumarone indene resin 1.62, o-phthalic acid dibutyl ester 8.85, whipping agent 2.15; Second section is the add-on on first part every kilogram basis, and it is sulphur 6g, accelerant CZ 8g, Vulcanization accelerator TMTD 2g, accelerator dibenzothiazyl disulfide 6g.
5. the Novel rubber plastic alloy according to claim 1 foaming large end, it is characterized in that: described rubber and plastic alloy is that the paracril of 5:3 and PVC form by weight ratio.
6., at the bottom of extremely cold-resistant high elasticity abrasion-proof glue according to claim 1, it is characterized in that: described strengthening agent is carbon black N339, carbon black N330, carbon black N220 or white carbon black.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107857914A (en) * | 2017-11-29 | 2018-03-30 | 际华三五五皮革皮鞋有限公司 | A kind of abrasion-resistive hard glue bottom of suitable footwear heel and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20050071388A (en) * | 2005-05-20 | 2005-07-07 | 주식회사 한솔테크 | Rubber coated fabric comprising the rubber sheet |
| CN101987889A (en) * | 2009-08-07 | 2011-03-23 | 焦玉怀 | Rubber and plastic alloy material |
| CN103102522A (en) * | 2012-11-14 | 2013-05-15 | 际华三五一五皮革皮鞋有限公司 | Oilproof and wear-resistant sizing material for special environment and preparation method thereof |
| CN103275439A (en) * | 2013-06-21 | 2013-09-04 | 苏州市景荣科技有限公司 | Ageing-resistant HPVC foaming sole material |
| CN103483736A (en) * | 2013-09-24 | 2014-01-01 | 吴江市董鑫塑料包装厂 | Soft PVC foaming shoe sole plastic |
| CN103724730A (en) * | 2013-12-20 | 2014-04-16 | 柳州日高橡胶制品有限责任公司 | Rubber and preparation method thereof |
| CN104448437A (en) * | 2014-12-16 | 2015-03-25 | 天津市富华皮革制品有限公司 | Oil-resistant anti-static rubber shoe sole and preparation method thereof |
-
2015
- 2015-11-14 CN CN201510774558.XA patent/CN105218897A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20050071388A (en) * | 2005-05-20 | 2005-07-07 | 주식회사 한솔테크 | Rubber coated fabric comprising the rubber sheet |
| CN101987889A (en) * | 2009-08-07 | 2011-03-23 | 焦玉怀 | Rubber and plastic alloy material |
| CN103102522A (en) * | 2012-11-14 | 2013-05-15 | 际华三五一五皮革皮鞋有限公司 | Oilproof and wear-resistant sizing material for special environment and preparation method thereof |
| CN103275439A (en) * | 2013-06-21 | 2013-09-04 | 苏州市景荣科技有限公司 | Ageing-resistant HPVC foaming sole material |
| CN103483736A (en) * | 2013-09-24 | 2014-01-01 | 吴江市董鑫塑料包装厂 | Soft PVC foaming shoe sole plastic |
| CN103724730A (en) * | 2013-12-20 | 2014-04-16 | 柳州日高橡胶制品有限责任公司 | Rubber and preparation method thereof |
| CN104448437A (en) * | 2014-12-16 | 2015-03-25 | 天津市富华皮革制品有限公司 | Oil-resistant anti-static rubber shoe sole and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杜少勋编著: "《运动鞋及其设计》", 31 March 2004, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107857914A (en) * | 2017-11-29 | 2018-03-30 | 际华三五五皮革皮鞋有限公司 | A kind of abrasion-resistive hard glue bottom of suitable footwear heel and preparation method thereof |
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