CN105199664A - Sealing compound for battery and preparation method thereof - Google Patents
Sealing compound for battery and preparation method thereof Download PDFInfo
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- CN105199664A CN105199664A CN201510565575.2A CN201510565575A CN105199664A CN 105199664 A CN105199664 A CN 105199664A CN 201510565575 A CN201510565575 A CN 201510565575A CN 105199664 A CN105199664 A CN 105199664A
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Abstract
The invention discloses a sealing compound for a battery and a preparation method thereof, belonging to the technical field of battery sealing materials. The sealing glue for the battery comprises the following raw materials in parts by weight: 10-20 parts of gasoline, 10-20 parts of aromatic oil, 45-55 parts of asphalt, 10-20 parts of nonylphenol polyoxyethylene ether, 10-20 parts of modified epoxy resin and 1-5 parts of fumed silica. The sealing compound for the battery has good cohesiveness, sealing property and creep resistance, and also has good aging resistance, high-temperature stability and temperature sensitivity; the concrete expression is as follows: no deformation and no flowing at high temperature, good adhesion at low temperature, no cracking, easy coating, no peculiar smell and long service life.
Description
Technical Field
The invention belongs to the technical field of battery sealing materials, and particularly relates to a sealing compound for a battery and a preparation method thereof.
Background
With the progress of science and technology and the rapid development of information, people can not get out of batteries in fast-paced production and life. Although, batteries have been constantly changing and revolutionizing since their birth. However, the most widely used is the zinc-manganese battery, and the electrolyte of the zinc-manganese battery mainly comprises ammonium chloride, zinc chloride and water in certain proportion. If the sealing performance of the battery is poor, water in the electrolyte is volatilized to influence the normal operation of the battery; oxygen in the air also enters the interior of the cell to oxidize the zinc and reduce the service life of the cell. Therefore, the sealing plays an important role in the battery, and the quality of the sealing directly determines the quality of the zinc-manganese battery.
At present, the zinc-manganese battery sealing compound mainly comprises three types, namely an asphalt series, a rubber series and an epoxy series, and the asphalt series battery sealing compound has good cohesiveness and ageing resistance, but has certain environmental protection problem; the rubber series battery sealing compound has good creep resistance and sealing performance, can improve the storage stability of the battery, but has much higher cost than the asphalt series; the epoxy series battery sealing compound also has the problems of high brittleness, poor impact resistance and low peeling strength.
Disclosure of Invention
The invention provides a sealing adhesive for a battery and a preparation method thereof, and solves the problems of poor caking property, easy aging and high cost of the sealing adhesive for the battery in the prior art.
The invention relates to a sealing compound for a battery, which is mainly realized by the following technical scheme: the feed comprises the following raw materials in parts by weight: 10-20 parts of gasoline, 10-20 parts of aromatic oil, 45-55 parts of asphalt, 10-20 parts of nonylphenol polyoxyethylene ether, 10-20 parts of modified epoxy resin and 1-5 parts of fumed silica.
The invention relates to a preparation method of sealing compound for a battery, which is mainly realized by the following technical scheme: the method comprises the following steps: 1) Heating asphalt at 150-200 ℃ for 2-5h, adding modified epoxy resin, nonylphenol polyoxyethylene ether and fumed silica, and uniformly stirring to obtain a crude product; 2) When the temperature of the crude product obtained in the step 1) is cooled to 80-120 ℃, adding gasoline and aromatic oil into the crude product, uniformly stirring, filtering and packaging to obtain the product.
The invention has the beneficial effects that: under the synergistic cooperation effect of gasoline, aromatic oil, asphalt, nonylphenol polyoxyethylene ether, modified epoxy resin and fumed silica, the battery sealing adhesive is condensed into a battery sealing adhesive with good cohesiveness, sealing property and creep resistance through heating and vulcanization; the sealing glue for the battery has the advantages of aging resistance, high-temperature stability and temperature sensitivity, no deformation and no flowing at high temperature, good adhesion at low temperature, no cracking, easy coating, no peculiar smell and long service life.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to specific embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without inventive step based on the embodiments of the present invention, are within the scope of protection of the present invention.
The invention discloses a sealing adhesive for a battery, which comprises the following raw materials in parts by weight: 10-20 parts of gasoline, 10-20 parts of aromatic oil, 45-55 parts of asphalt, 10-20 parts of nonylphenol polyoxyethylene ether, 10-20 parts of modified epoxy resin and 1-5 parts of fumed silica.
The invention discloses a preparation method of sealing compound for a battery, which comprises the following steps: 1) Heating asphalt at 150-200 ℃ for 2-5h, adding modified epoxy resin, nonylphenol polyoxyethylene ether and fumed silica, and uniformly stirring to obtain a crude product; 2) When the temperature of the crude product obtained in the step 1) is cooled to 80-120 ℃, adding gasoline and aromatic oil into the crude product, uniformly stirring, filtering and packaging to obtain the product.
Example one
The invention discloses a preparation method of sealing compound for a battery, which comprises the following steps: 1) Heating 45 parts by weight of asphalt at 150 ℃ for 2 hours, adding 10 parts by weight of modified epoxy resin, 10 parts by weight of nonylphenol polyoxyethylene ether and 1 part by weight of fumed silica, and uniformly stirring to obtain a crude product; 2) And (2) when the temperature of the crude product obtained in the step 1) is cooled to 80 ℃, adding 10 parts by weight of gasoline and 10 parts by weight of aromatic oil into the crude product, uniformly stirring, filtering and packaging to obtain the product.
Example two
The invention discloses a preparation method of sealing compound for a battery, which comprises the following steps: 1) Heating 50 parts by weight of asphalt at 180 ℃ for 3.5 hours, adding 15 parts by weight of modified epoxy resin, 15 parts by weight of nonylphenol polyoxyethylene ether and 3 parts by weight of fumed silica, and uniformly stirring to obtain a crude product; 2) And (2) when the temperature of the crude product obtained in the step 1) is cooled to 100 ℃, adding 15 parts by weight of gasoline and 15 parts by weight of aromatic oil into the crude product, uniformly stirring, filtering and packaging to obtain the product.
EXAMPLE III
The invention discloses a preparation method of sealing compound for a battery, which comprises the following steps: 1) Heating 55 parts by weight of asphalt at 200 ℃ for 5 hours, adding 20 parts by weight of modified epoxy resin, 20 parts by weight of nonylphenol polyoxyethylene ether and 5 parts by weight of fumed silica, and uniformly stirring to obtain a crude product; 2) And (2) when the temperature of the crude product obtained in the step 1) is cooled to 120 ℃, adding 20 parts by weight of gasoline and 20 parts by weight of aromatic oil into the crude product, uniformly stirring, filtering and packaging to obtain the product.
The three battery sealing adhesives obtained in the first to third embodiments and a certain commercially available battery sealing adhesive are subjected to performance detection by referring to a related test method of a battery sealing agent SH/T0421-92 petrochemical industry standard, and the test results are shown in Table 1; as can be seen from Table 1, the sealing compound for the battery of the invention meets the requirements of indexes in relevant standards, and the softening points of the sealing compound for the battery are both 20 ℃; the rotational viscosity at 100 ℃ is still more than 280 mPas so as to ensure that the coating material can not flow down from the zinc cylinder and the carbon rod at the coating temperature; the high-temperature flowing experiment is qualified, which shows that the sealing compound for the battery can not emerge from the battery when being applied to the battery, and has good sealing effect; the adhesion rate is not less than 95% at-20 ℃, which shows that the adhesive has good adhesion at low temperature and is not easy to crack. Compared with the commercially available battery sealing compound, the sealing compound for the battery has obvious advantages.
Table 1 comparison table of sealing compound performance test results
Note (1): referring to the method of SH/T0421-92, the test temperature is changed to 45 ℃;
note (2): referring to the method of SH/T0421-92, the test temperature was changed from ambient to-20 ℃ and the test samples were cooled in a freezer at-20 ℃ for 1h.
Therefore, compared with the prior art, the invention has the beneficial effects that: under the synergistic cooperation effect of gasoline, aromatic oil, asphalt, nonylphenol polyoxyethylene ether, modified epoxy resin and fumed silica, the sealing adhesive for the battery, which has good cohesiveness, sealing property and creep resistance, is formed by heating, vulcanizing and coagulating; the sealing adhesive for the battery has the advantages of ageing resistance, high-temperature stability and temperature sensitivity, no deformation and flowing at high temperature, good adhesion at low temperature, no cracking, easy coating, no peculiar smell and long service life.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and should not be taken as limiting the scope of the present invention, which is intended to cover any modifications, equivalents, improvements, etc. within the spirit and scope of the present invention.
Claims (2)
1. The sealing glue for the battery is characterized by comprising the following raw materials in parts by weight:
10-20 parts of gasoline, 10-20 parts of aromatic oil, 45-55 parts of asphalt, 10-20 parts of nonylphenol polyoxyethylene ether, 10-20 parts of modified epoxy resin and 1-5 parts of fumed silica.
2. The method for preparing a sealing compound for a battery as claimed in claim 1, comprising the steps of:
1) Heating asphalt at 150-200 ℃ for 2-5h, adding modified epoxy resin, nonylphenol polyoxyethylene ether and fumed silica, and uniformly stirring to obtain a crude product;
2) When the temperature of the crude product obtained in the step 1) is cooled to 80-120 ℃, adding gasoline and aromatic oil into the crude product, uniformly stirring, filtering and packaging to obtain the product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510565575.2A CN105199664A (en) | 2015-09-08 | 2015-09-08 | Sealing compound for battery and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510565575.2A CN105199664A (en) | 2015-09-08 | 2015-09-08 | Sealing compound for battery and preparation method thereof |
Publications (1)
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CN105199664A true CN105199664A (en) | 2015-12-30 |
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CN201510565575.2A Pending CN105199664A (en) | 2015-09-08 | 2015-09-08 | Sealing compound for battery and preparation method thereof |
Country Status (1)
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2015
- 2015-09-08 CN CN201510565575.2A patent/CN105199664A/en active Pending
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