CN105199568A - Paint for vacuum coating of car lights - Google Patents

Paint for vacuum coating of car lights Download PDF

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Publication number
CN105199568A
CN105199568A CN201410297719.6A CN201410297719A CN105199568A CN 105199568 A CN105199568 A CN 105199568A CN 201410297719 A CN201410297719 A CN 201410297719A CN 105199568 A CN105199568 A CN 105199568A
Authority
CN
China
Prior art keywords
paint
coating
solvent
car light
acrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410297719.6A
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Chinese (zh)
Inventor
庄建平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Feixiang Paint Industry Co Ltd
Original Assignee
Jiangsu Feixiang Paint Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Feixiang Paint Industry Co Ltd filed Critical Jiangsu Feixiang Paint Industry Co Ltd
Priority to CN201410297719.6A priority Critical patent/CN105199568A/en
Publication of CN105199568A publication Critical patent/CN105199568A/en
Pending legal-status Critical Current

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Abstract

The invention relates to paint for vacuum coating of car lights. The paint comprises the following ingredients in percentage by weight: 40-50% of polyester acrylic resin, 10-15% of a TM acrylic monomer, 18-25% of a TP acrylic monomer, 5-10% of phenolic aldehyde epoxy resin, 6-11% of a photoinitiator, 0.5-1.5% of one or additives, 5-10% of ethyl ester and the balance of a solvent, wherein the solvent is a mixture of butyl propionate and ethyl ester; the ratio of butyl propionate to ethyl ester is 1:2.4; the photoinitiator is an ultraviolet light absorbent; the additives comprise one or more of a drying agent, a toughening agent, an antifoaming agent, a leveling agent, a photostabilizer, an accelerating agent, a dispersing agent and the like. Compared with like vacuum paint, the paint provided by the invention has the advantages that the cost is reduced by about 40%, convenience is brought for construction, and the one-time qualification rate is high.

Description

The coating that car light vacuum is covered with paint, lacquer, colour wash, etc.
Technical field
The present invention relates to a kind of based on the photo-cured coating of acrylic resin, vibrin, novolac epoxy, be particularly suitable for vacuum spraying in various automobile lamp.
Background technology
Photo-cured coating is various in style, major part is used for light industry product external decoration and covers with paint, lacquer, colour wash, etc., as products such as televisor, refrigerator, washing machine, power trucks, but be do not reach particular requirement for automobile lamp interior trim, as the sticking power that coating combines, in thermo-optical, there are depainting and moire spot, cause light source not focus on, after life-time service, coating paint film itself is anti-yellow, brings some problems such as wretched insufficiency to the luminance brightness of car light.
Summary of the invention
Technical problem to be solved by this invention is to provide the coating of the car light vacuum covering with paint that a kind of sticking power is good, thermotolerance is high.
For solving the problems of the technologies described above, the invention provides a kind of car light vacuum cover with paint, lacquer, colour wash, etc. coating, its component and weight percent as follows: polyester acrylate resin 40-50%, TM Acrylic Acid Monomer 10-15%, TP Acrylic Acid Monomer 18-25%, novolac epoxy 5-10%, light trigger 6-11%, auxiliary agent 0.5-1.5%, solvent 5-10%.
Described solvent mixes by proportioning 1:2.4 with the third butyl ester, ethyl ester.
Described light trigger is ultraviolet absorbers.
Described auxiliary agent comprises one or more of siccative, toughner, defoamer, flow agent, photostabilizer, promotor, dispersion agent etc.
The preparation method of the coating that above-mentioned car light vacuum is covered with paint, lacquer, colour wash, etc. comprises the steps:
(1) get the third butyl ester, ethyl ester generates solvent a by proportioning 1:2.4 mix and blend;
(2) first polyester acrylate resin is mixed with solvent a, form resin mixture liquor b;
(3) again resin mixture liquor b is added M Acrylic Acid Monomer, TP Acrylic Acid Monomer, novolac epoxy successively under low rate mixing; Then successively by light trigger, auxiliary agent spraying addition method, feed intake while stirring, feed intake and after terminating, within moderate-speed mixer 3-5 minute, namely make the coating of this car light vacuum covering with paint again.
Technique effect of the present invention: the coating that (1) car light of the present invention vacuum is covered with paint, lacquer, colour wash, etc. has carried out effective adjustment to coating internal chemical structure, molecular structure, the molecule content of coating is between 15000-35000, the depainting that modified resin coating of changing over exists, dark moire, anti-yellow phenomenon, coating is improved in secondary coating postadhesion power, molecular density improves has repaired dark moire phenomenon, and due to the thermotolerance of novolac epoxy, make coating paint film not anti-yellow under long-term trial state, thus improve the sharpness of paint film; (2) this coating cost compared with similar effect lacquer reduces about 40%, easy construction and disposable qualification rate is high.
Embodiment
Embodiment 1
The coating that the car light vacuum of the present embodiment is covered with paint, lacquer, colour wash, etc., its component and weight percent as follows: polyester acrylate resin 40%, TM Acrylic Acid Monomer 15%, TP Acrylic Acid Monomer 18%, novolac epoxy 10%, light trigger 11%, auxiliary agent 1%, solvent 5%.
Described solvent mixes by proportioning 1:2.4 with the third butyl ester, ethyl ester.
Described light trigger is ultraviolet absorbers.
Described auxiliary agent comprises one or more of siccative, toughner, defoamer, flow agent, photostabilizer, promotor, dispersion agent etc.
The preparation method of the coating that above-mentioned car light vacuum is covered with paint, lacquer, colour wash, etc. comprises the steps:
(1) get the third butyl ester, ethyl ester generates solvent a by proportioning 1:2.4 mix and blend;
(2) first polyester acrylate resin is mixed with solvent a, form resin mixture liquor b;
(3) again resin mixture liquor b is added M Acrylic Acid Monomer, TP Acrylic Acid Monomer, novolac epoxy successively under low rate mixing; Then successively by light trigger, auxiliary agent spraying addition method, feed intake while stirring, feed intake and after terminating, within moderate-speed mixer 3-5 minute, namely make the coating of this car light vacuum covering with paint again.
Embodiment 2
The coating that the car light vacuum of the present embodiment is covered with paint, lacquer, colour wash, etc., its component and weight percent as follows: polyester acrylate resin 45%, TM Acrylic Acid Monomer 10%, TP Acrylic Acid Monomer 20%, novolac epoxy 6%, light trigger 8%, auxiliary agent 1%, solvent 10%.
Described solvent mixes by proportioning 1:2.4 with the third butyl ester, ethyl ester.
Described light trigger is ultraviolet absorbers.
Described auxiliary agent comprises one or more of siccative, toughner, defoamer, flow agent, photostabilizer, promotor, dispersion agent etc.
The preparation method of the coating that above-mentioned car light vacuum is covered with paint, lacquer, colour wash, etc. comprises the steps:
(1) get the third butyl ester, ethyl ester generates solvent a by proportioning 1:2.4 mix and blend;
(2) first polyester acrylate resin is mixed with solvent a, form resin mixture liquor b;
(3) again resin mixture liquor b is added M Acrylic Acid Monomer, TP Acrylic Acid Monomer, novolac epoxy successively under low rate mixing; Then successively by light trigger, auxiliary agent spraying addition method, feed intake while stirring, feed intake and after terminating, within moderate-speed mixer 3-5 minute, namely make the coating of this car light vacuum covering with paint again.
Coating detection method in above-described embodiment 1, embodiment 2:
Sticking power detects: sticking power, by hot and cold facture, after first paintings test plate (panel) being boiled 15 minutes in 100 DEG C of boiling water, then will to be coated with in refrigerated tank that test plate (panel) puts into-20 DEG C maintenance 15 minutes, finally etc. painting test plate (panel) separate at normal temperatures cold after carry out cross cut test; Cross cut test refers to the measuring method that standard GB/T/T9286-1998 " cross cut test of paint and varnish paint film " specify.This standard adopting by equivalent international standard ISO2409:1992.The standard specifies when penetrating into ground with cartesian mesh pattern cut coating, evaluate a kind of experimental technique of the resistance that coating departs from from ground.Test-results is divided into 0 ~ 5 grade, and 0 grade stands intact, and after testing, the paint adhesion of the application is 1 grade, is therefore better than 3 to 4 grades of prior art.
Color inhibition check: paintings test plate (panel) is put into light-source box, by 24 hours inspection and do continuously 1000 hours detect after and former test plate (panel) contrast, with within taking off of inspection panel standard yellowing 10% for standard, after testing, taking off of the coating yellowing of the application is 3-4%.
Moire detects: will be coated with test plate (panel) and pass through after cold-heat treatment, and put 2-3 hour at normal temperature, and after testing, painting test plate (panel) is flawless, without moire.

Claims (5)

1. car light vacuum cover with paint, lacquer, colour wash, etc. a coating, it is characterized in that: its component and weight percent as follows: polyester acrylate resin 40-50%, TM Acrylic Acid Monomer 10-15%, TP Acrylic Acid Monomer 18-25%, novolac epoxy 5-10%, light trigger 6-11%, auxiliary agent 0.5-1.5%, solvent 5-10%.
2. the coating of car light vacuum covering with paint as claimed in claim 1, is characterized in that: described solvent mixes by proportioning 1:2.4 with the third butyl ester, ethyl ester.
3. the coating of car light vacuum covering with paint as claimed in claim 1, is characterized in that: described light trigger is ultraviolet absorbers.
4. the coating covered with paint, lacquer, colour wash, etc. of car light vacuum as claimed in claim 1, is characterized in that: described auxiliary agent comprise siccative, toughner, defoamer, flow agent, photostabilizer, promotor, dispersion agent one or more.
5. a preparation method for the coating of car light vacuum covering with paint according to claim 1, is characterized in that comprising the steps:
(1) get the third butyl ester, ethyl ester generates solvent a by proportioning 1:2.4 mix and blend;
(2) first polyester acrylate resin is mixed with solvent a, form resin mixture liquor b;
(3) again resin mixture liquor b is added M Acrylic Acid Monomer, TP Acrylic Acid Monomer, novolac epoxy successively under low rate mixing; Then successively by light trigger, auxiliary agent spraying addition method, feed intake while stirring, feed intake and after terminating, within moderate-speed mixer 3-5 minute, namely make the coating of this car light vacuum covering with paint again.
CN201410297719.6A 2014-06-29 2014-06-29 Paint for vacuum coating of car lights Pending CN105199568A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410297719.6A CN105199568A (en) 2014-06-29 2014-06-29 Paint for vacuum coating of car lights

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410297719.6A CN105199568A (en) 2014-06-29 2014-06-29 Paint for vacuum coating of car lights

Publications (1)

Publication Number Publication Date
CN105199568A true CN105199568A (en) 2015-12-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410297719.6A Pending CN105199568A (en) 2014-06-29 2014-06-29 Paint for vacuum coating of car lights

Country Status (1)

Country Link
CN (1) CN105199568A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1281011A (en) * 1999-07-19 2001-01-24 湖南亚大化工建材有限公司 Ultraviolet solidified primer or surface paint for vacuum plating
CN103627311A (en) * 2012-08-21 2014-03-12 上海大桥化工有限公司 Vacuum plating UV-curable priming paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1281011A (en) * 1999-07-19 2001-01-24 湖南亚大化工建材有限公司 Ultraviolet solidified primer or surface paint for vacuum plating
CN103627311A (en) * 2012-08-21 2014-03-12 上海大桥化工有限公司 Vacuum plating UV-curable priming paint

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Application publication date: 20151230

RJ01 Rejection of invention patent application after publication