CN105199233A - 一种具有改性加工性的软性聚烯烃组合物 - Google Patents

一种具有改性加工性的软性聚烯烃组合物 Download PDF

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Publication number
CN105199233A
CN105199233A CN201510727117.4A CN201510727117A CN105199233A CN 105199233 A CN105199233 A CN 105199233A CN 201510727117 A CN201510727117 A CN 201510727117A CN 105199233 A CN105199233 A CN 105199233A
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parts
modification
polyolefin composition
flexible polyolefin
processibility
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刘姝
王晓宁
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Liaoning Shihua University
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Liaoning Shihua University
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Priority to CN201510727117.4A priority Critical patent/CN105199233A/zh
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明提供一种具有改性加工性的软性聚烯烃组合物,包括以下组分:聚丙烯组分60-80份;橡胶组分30-70份;减粘剂10-25份;硅烷偶合剂3-8份。所述聚丙烯组分为丙烯均聚物或与另一种α-烯烃的丙烯共聚物。所述橡胶组分为无定形乙烯-α-烯烃共聚物或苯乙烯-基热塑性弹性体。所述减粘剂为1-丁烯的均聚物或共聚物。本发明的有益效果是产品质量好、制造成本低、有利于工业化推广。

Description

一种具有改性加工性的软性聚烯烃组合物
技术领域
本发明属于聚烯烃烯烃产品技术领域,尤其是涉及一种具有改性加工性的软性聚烯烃组合物。
背景技术
聚烯烃是烯烃经过加聚反应形成的高分子化合物。由于原料丰富,价格低廉,容易加工成型,综合性能优良,因此是一类产量最大,应用十分广泛的高分子材料。其中以聚乙烯、聚丙烯最为重要。
对聚烯烃进行改性,使其具有更加优越的性能,进一步延展了聚烯烃的应用范围。具有改性加工性的软性聚烯烃组合物,可良好的应用于医疗、汽车、包装、消费品行业,在注塑制造成品领域具有良好的应用前景。
发明内容
本发明的目的是提供一种具有改性加工性的软性聚烯烃组合物,采用熔融减粘剂代理减粘裂化以改进聚烯烃材料的加工性能,可有效提高产品的质量。
本发明的技术方案是:本发明的具有改性加工性的软性聚烯烃组合物,包括以下组分:
聚丙烯组分60-80份;
橡胶组分20-70份;
减粘剂2-25份;
硅烷偶合剂3-8份。
优选的,所述聚丙烯组分为丙烯均聚物或与另一种α-烯烃的丙烯共聚物。
优选的,所述橡胶组分为无定形乙烯-α-烯烃共聚物或苯乙烯-基热塑性弹性体。
优选的,所述减粘剂为1-丁烯的均聚物或共聚物。
本发明具有的优点和积极效果是:
1、硅烷偶合剂的添加,可增加组合物各组分的混合亲和力,改善混溶性,使得组合物具有良好的均一性。
2、制造成本低,便于工业化生产,绿色环保,无污染。
具体实施方式
实施例1:
本实施例的一种具有改性加工性的软性聚烯烃组合物,包括以下组分:
丙烯均聚物60份;
无定形乙烯-α-烯烃共聚物30份;
1-丁烯的均聚物7份;
硅烷偶合剂3份。
实施例2:
本实施例的一种具有改性加工性的软性聚烯烃组合物,包括以下组分:
包括以下组分:
3-甲基-1-丁烯的丙烯共聚物70份;
苯乙烯-基热塑性弹性体20份;
1-丁烯的均聚物5份;
硅烷偶合剂5份。
实施例3:
本实施例的一种具有改性加工性的软性聚烯烃组合物,包括以下组分:
丙烯均聚物65份;
苯乙烯-基热塑性弹性体20份;
1-丁烯的均聚物15份;
硅烷偶合剂5份。
实施例4:
本实施例的一种具有改性加工性的软性聚烯烃组合物,包括以下组分:
丙烯均聚物75份;
无定形乙烯-α-烯烃共聚物20份;
1-丁烯的均聚物2份;
硅烷偶合剂3份。
以上对本发明的四个实施例进行了详细说明,但所述内容仅为本发明的较佳实施例,不能被认为用于限定本发明的实施范围。凡依本发明申请范围所作的均等变化与改进等,均应仍归属于本发明的专利涵盖范围之内。

Claims (4)

1.一种具有改性加工性的软性聚烯烃组合物,其特征在于:包括以下组分:
聚丙烯组分60-80份;
橡胶组分20-70份;
减粘剂2-25份;
硅烷偶合剂3-8份。
2.根据权利要求1所述的一种具有改性加工性的软性聚烯烃组合物,其特征在于:所述聚丙烯组分为丙烯均聚物或与另一种α-烯烃的丙烯共聚物。
3.根据权利要求1所述的一种具有改性加工性的软性聚烯烃组合物,其特征在于:所述橡胶组分为无定形乙烯-α-烯烃共聚物或苯乙烯-基热塑性弹性体。
4.根据权利要求2所述的一种具有改性加工性的软性聚烯烃组合物,其特征在于:所述减粘剂为1-丁烯的均聚物或共聚物。
CN201510727117.4A 2015-10-28 2015-10-28 一种具有改性加工性的软性聚烯烃组合物 Pending CN105199233A (zh)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102666709A (zh) * 2009-11-17 2012-09-12 巴塞尔聚烯烃意大利有限责任公司 具有改进加工性的软聚烯烃组合物

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102666709A (zh) * 2009-11-17 2012-09-12 巴塞尔聚烯烃意大利有限责任公司 具有改进加工性的软聚烯烃组合物

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