CN105198524A - Additive for treating sludge and preparing method thereof - Google Patents

Additive for treating sludge and preparing method thereof Download PDF

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Publication number
CN105198524A
CN105198524A CN201510546450.5A CN201510546450A CN105198524A CN 105198524 A CN105198524 A CN 105198524A CN 201510546450 A CN201510546450 A CN 201510546450A CN 105198524 A CN105198524 A CN 105198524A
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China
Prior art keywords
parts
additive
mud
sludge
weight
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CN201510546450.5A
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Chinese (zh)
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CN105198524B (en
Inventor
吴迪
马可
郭艳玲
魏东
曾蓉
杨剑
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Yunnan Yinfa Green Environmental Protection Industry Co Ltd
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Yunnan Yinfa Green Environmental Protection Industry Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Treatment Of Sludge (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses an additive for treating sludge and a preparing method thereof and belongs to the technical field of sludge treatment. The additive is prepared from, by weight, 5-25 parts of ferrous sulfide, 30-60 parts of magnesium oxide, 1-15 parts of ammonium bicarbonate, 1-15 parts of urea, 1-15 parts of calcium phosphate, 1-15 parts of calcium silicate, 1-15 parts of potassium sulphate and 5-25 parts of plant ash. The additive has the advantages that municipal sludge and river sediment can be effectively treated, waste materials are recycled, artificial soil is made to be used for landscape planting, mine ecological restoration and other projects, and environment benefits, economic benefits and social benefits are high.

Description

A kind of additive for the treatment of mud and preparation method thereof
Technical field
The invention belongs to technical field of sludge treatment, be specifically related to a kind of additive for the treatment of mud and preparation method thereof.
Background technology
China's municipal sludge (80% water ratio) output is huge, 2,000 ten thousand tons can be reached every year, and current Sludge Disposal Techniques is implemented of a high price in China, suitability is limited, mud is difficult to all to be dissolved, the harmlessness disposing rate of mud is only less than 25%, and mud besieged city phenomenon highlights all the more; Channel cleanout as a kind of important channel of apparatus for treating river water pollution, but government and enviromental protection enterprise in the face of the handling problems of desilting bed mud out in a dilemma equally.
" harness the river and do not control mud, equal not harness the river ", municipal sludge and river bottom mud water content high, perishable, have strong stink, and containing parasitic ovum, pathogenic micro-organism and heavy metal, security becomes the obstacle that restriction recycling sludge utilizes.But the simple landfill of mud or stacking can cause secondary pollution, costly, municipal sludge and river bottom mud become another source of pollution to incineration disposal already, and city sewage treatment works is absorbed in how-do-you-do.
Summary of the invention
The object of this invention is to provide a kind of additive for the treatment of mud, this additive can effectively process municipal sludge and river bottom mud.
Another object of the present invention is to provide the preparation method of above-mentioned additive, this preparation method's simple possible.
The technical solution used in the present invention is a kind of additive for the treatment of mud, and this additive is made up of the component of following parts by weight: Iron sulfuret 5 ~ 25 parts, 30 ~ 60 parts, magnesium oxide, 1 ~ 15 part, bicarbonate of ammonia, 1 ~ 15 part, urea, 1 ~ 15 part, calcium phosphate, Calucium Silicate powder 1 ~ 15 part, potassium sulfate 1 ~ 15 part and plant ash 5 ~ 25 parts.
As preferably, this additive is made up of the component of following parts by weight: Iron sulfuret 10 ~ 20 parts, 40 ~ 50 parts, magnesium oxide, 1 ~ 10 part, bicarbonate of ammonia, 1 ~ 10 part, urea, 1 ~ 10 part, calcium phosphate, Calucium Silicate powder 1 ~ 10 part, potassium sulfate 1 ~ 10 part and plant ash 10 ~ 20 parts.
Particularly preferred, this additive is made up of the component of following parts by weight: Iron sulfuret 15 parts, 45 parts, magnesium oxide, 5 parts, bicarbonate of ammonia, 5 parts, urea, 5 parts, calcium phosphate, Calucium Silicate powder 5 parts, potassium sulfate 5 parts and plant ash 15 parts.
Prepare a method for described additive, comprise the following steps: by weight, by described each component mixing, to obtain final product.
A method for lignin-sludge, comprises the following steps: by pending drying sludge to water ratio≤20%, and compost, then adds additive, mixing.
Compost can utilize the microorganism in mud to carry out oxygenolysis to the organism in mud, finally makes it be converted into the higher humic-like substance of stability, and kills most of pathogenic bacteria and parasite in mud, reach innoxious object.
Preferably, the time of described compost is 72 hours.
Mud is after compost treatment, add above-mentioned additive, the nutritive element in mud can be supplemented, simultaneously to the heavy metal stabilization/solidification in mud, objectionable constituent in strict control mud, city sewage sludge reclamation is utilized, turns waste into wealth, make artificial soil in the engineerings such as landscape planting and Mine ecology reparation.
Preferably, the interpolation weight of described additive is 1% ~ 20% of gained mud weight after pending drying sludge, specifically depending on mud Middle nutrition element and Leaching of Heavy Metals concentration.
Beneficial effect of the present invention is:
(1) additive of the present invention is made up of jointly Iron sulfuret, magnesium oxide, bicarbonate of ammonia, urea, calcium phosphate, Calucium Silicate powder, potassium sulfate and plant ash, interacts.Objectionable constituent in mud can be carried out stabilization or solidification by the component of these additives effectively, can also supplement the nutrition of mud, thus can process municipal sludge and river bottom mud well.
(2) by drying sludge dehydration, compost and interpolation additive three of the present invention road technique, organic matter abundant in mud and plant desired nutritional element can be made full use of, objectionable constituent in strict control mud, recycling sludge is utilized, turn waste into wealth, make artificial soil in the engineerings such as landscape planting and Mine ecology reparation.This technology has good environment, economic benefit and social benefit, is the particular embodiment of developing a circular economy and building a resource-conserving and environment-friendly society, and integrates have important test and reference to the utilization of resources of pollutent and environmental protection industry.
Embodiment
For making those skilled in the art understand production technique of the present invention and technique effect in detail, introduce application of the present invention and technique effect further with concrete production instance below.
Embodiment 1
The preparation of additive
By weight, take Iron sulfuret 15 parts, 45 parts, magnesium oxide, 5 parts, bicarbonate of ammonia, 5 parts, urea, 5 parts, calcium phosphate, Calucium Silicate powder 5 parts, potassium sulfate 5 parts and plant ash 15 parts, mixing, obtains additive.
Embodiment 2
The preparation of additive
By weight, take Iron sulfuret 20 parts, 50 parts, magnesium oxide, 1 part, bicarbonate of ammonia, 1 part, urea, 10 parts, calcium phosphate, Calucium Silicate powder 10 parts, potassium sulfate 1 part and plant ash 10 parts, mixing, obtains additive.
Embodiment 3
The preparation of additive
By weight, take Iron sulfuret 10 parts, 40 parts, magnesium oxide, 10 parts, bicarbonate of ammonia, 10 parts, urea, 1 part, calcium phosphate, Calucium Silicate powder 1 part, potassium sulfate 10 parts and plant ash 20 parts, mixing, obtains additive.
Embodiment 4
The preparation of additive
By weight, take Iron sulfuret 5 parts, 30 parts, magnesium oxide, 1 part, bicarbonate of ammonia, 1 part, urea, 1 part, calcium phosphate, Calucium Silicate powder 1 part, potassium sulfate 1 part and plant ash 25 parts, mixing, obtains additive.
Embodiment 5
The preparation of additive
By weight, take Iron sulfuret 25 parts, 60 parts, magnesium oxide, 15 parts, bicarbonate of ammonia, 15 parts, urea, 15 parts, calcium phosphate, Calucium Silicate powder 15 parts, potassium sulfate 15 parts and plant ash 5 parts, mixing, obtains additive.
Embodiment 6
The present embodiment mud used picks up from sewage work of Kunming, Yunnan city, and this Sewage Plant mainly processes the sanitary sewage in Kunming district, and after sewage disposal, all effluent index all reach emission standard.Mud drying dehydration to water ratio is 12% and compost after 72 hours, and physics and chemistry and Hygienic Index reach, and " urban wastewater treatment firm sludge disposal afforestation shale " (CJ248-2007) requires (see table 1).Embodiment 1 gained additive is added the mud after compost by 6% in mass ratio, mixing, maintenance, its physics and chemistry, nutrient and pollutent index reach, and " urban wastewater treatment firm sludge disposal afforestation shale " (CJ248-2007) requires (see table 2).Mud after additive improvement is used for the plantation of Kunming factory landscape planting band herbs and shrubs plant, rate of emergence reaches 94% (see table 2).
Physics and chemistry and Hygienic Index after table 1 municipal sludge drying and dehydrating, compost
Sequence number Item controlled Numerical value Standard limited value
1 Water ratio (%) 14 <40
2 Excrement colibacillus group bacterium value (mL/) 0.018 >0.01
3 Worm egg mortality ratio (%) 98 >95
The physics and chemistry of the municipal sludge of table 2 after additive of the present invention improvement, nutrient and pollutent index
Embodiment 7
The present embodiment bed mud used picks up from certain heavy metal contamination river course domestic, Fields of Qujing City in Yunnan, and this river course washes away by heavy metal contamination river throughout the year, and bed mud heavy metal accumulation amount is larger.This bed mud drying dehydration to water ratio is 3% and compost after 72 hours, and physics and chemistry and Hygienic Index reach, and " urban wastewater treatment firm sludge disposal afforestation shale " (CJ248-2007) requires (see table 3).In mass ratio 10% embodiment 2 gained additive added the mud after compost and evenly mix and stir, maintenance, its physics and chemistry, nutrient and pollutent index reach, and " urban wastewater treatment firm sludge disposal afforestation shale " (CJ248-2007) requires (see table 4).Mud after additive improvement of the present invention is used for river course periphery Mine ecology reparation plantation herbs and shrubs plant, rate of emergence reaches 93% (see table 4).
Physics and chemistry and Hygienic Index after table 3 river bottom mud drying and dehydrating, compost
Sequence number Item controlled After process Standard limited value
1 Water ratio (%) 11 <40
2 Excrement colibacillus group bacterium value (ml/) 0.025 >0.01
3 Worm egg mortality ratio (%) 97 >95
The physics and chemistry of the river bottom mud of table 4 after additive of the present invention improvement, nutrient and pollutent index
According to " urban wastewater treatment firm sludge disposal afforestation shale " (CJ248-2007), the fertilizer (artificial soil) be modified to using municipal sludge as starting material, (CJ248-2007) requirement that physics and chemistry, nutrient, health, pollutent index and seed germination index need reach " urban wastewater treatment firm sludge disposal afforestation shale ", wherein heavy metal is in mg/kg dewatered sludge, reflection be the total concn of heavy metal.(CJ248-2007) requirement that if heavy metal total concn exceedes " urban wastewater treatment firm sludge disposal afforestation shale ", but its leaching concentration meets " agricultural irrigation water quality standard " (GB5084-92) requirement, it is qualified that heavy metal toxicity examination is considered as.
The fertilizer (artificial soil) be modified to using river bottom mud as starting material, physics and chemistry, nutrient, health, pollutent index and seed germination index, temporarily without corresponding standard-required, can perform by " urban wastewater treatment firm sludge disposal afforestation shale " (CJ248-2007) requirement.
Finally it should be noted that, above embodiment is the unrestricted technical scheme of the present invention in order to explanation only, although with reference to above-described embodiment to invention has been detailed description, those skilled in the art are to be understood that, still can modify to the present invention or equivalent replacement, and not departing from any modification or partial replacement of the spirit and scope of the present invention, it all should be encompassed in right of the present invention.

Claims (7)

1. the additive for the treatment of mud, it is characterized in that, this additive is made up of the component of following parts by weight: Iron sulfuret 5 ~ 25 parts, 30 ~ 60 parts, magnesium oxide, 1 ~ 15 part, bicarbonate of ammonia, 1 ~ 15 part, urea, 1 ~ 15 part, calcium phosphate, Calucium Silicate powder 1 ~ 15 part, potassium sulfate 1 ~ 15 part and plant ash 5 ~ 25 parts.
2. a kind of additive for the treatment of mud according to claim 1, it is characterized in that, this additive is made up of the component of following parts by weight: Iron sulfuret 10 ~ 20 parts, 40 ~ 50 parts, magnesium oxide, 1 ~ 10 part, bicarbonate of ammonia, 1 ~ 10 part, urea, 1 ~ 10 part, calcium phosphate, Calucium Silicate powder 1 ~ 10 part, potassium sulfate 1 ~ 10 part and plant ash 10 ~ 20 parts.
3. a kind of additive for the treatment of mud according to claim 2, it is characterized in that, this additive is made up of the component of following parts by weight: Iron sulfuret 15 parts, 45 parts, magnesium oxide, 5 parts, bicarbonate of ammonia, 5 parts, urea, 5 parts, calcium phosphate, Calucium Silicate powder 5 parts, potassium sulfate 5 parts and plant ash 15 parts.
4. prepare a method for additive described in any one of claim 1-3, it is characterized in that, comprise the following steps: by weight, by described each component mixing, to obtain final product.
5. a method for lignin-sludge, is characterized in that, comprises the following steps: by pending drying sludge to water ratio≤20%, and then compost adds additive described in claim 1-3 any one, mixing.
6. the method for a kind of lignin-sludge according to claim 5, it is characterized in that, the time of described compost is 72 hours.
7. the method for a kind of lignin-sludge according to claim 5, it is characterized in that, the interpolation weight of described additive is 1% ~ 20% of gained mud weight after pending drying sludge.
CN201510546450.5A 2015-08-31 2015-08-31 A kind of additive and preparation method thereof for handling sludge Expired - Fee Related CN105198524B (en)

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CN105198524B CN105198524B (en) 2018-12-18

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105601063A (en) * 2016-01-19 2016-05-25 赵东星 Sludge solidifying agent for treating sludge in river channels and method for preparing sludge solidifying agent
CN106701093A (en) * 2016-11-23 2017-05-24 产俊涛 Lead contaminated soil repair agent and preparation method and application thereof
CN106797820A (en) * 2017-01-12 2017-06-06 清华大学 Recovery of ecologic environment in a mine nutrition earthing with municipal sludge as main matrix and preparation method thereof
CN107235698A (en) * 2016-01-30 2017-10-10 合肥智慧龙图腾知识产权股份有限公司 A kind of municipal sludge processing curing agent and preparation method thereof
CN109336345A (en) * 2018-11-29 2019-02-15 福州宇澄环保工程设计有限公司 A kind of black and odorous water bed mud biological modification agent

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1594225A (en) * 2004-06-18 2005-03-16 李成义 Series special fertilizer prepared by urban sludge and its preparation method
CN101648832A (en) * 2009-08-08 2010-02-17 占达东 Special fertilizer for gum trees
CN102372515A (en) * 2010-08-24 2012-03-14 徐向金 Organic fertilizer produced by using sludge
CN102701883A (en) * 2012-06-28 2012-10-03 农悦锋 Compound microbial fertilizer prepared from papermaking sludge
CN103992146A (en) * 2014-05-04 2014-08-20 张良 Activated sludge fertilizer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1594225A (en) * 2004-06-18 2005-03-16 李成义 Series special fertilizer prepared by urban sludge and its preparation method
CN101648832A (en) * 2009-08-08 2010-02-17 占达东 Special fertilizer for gum trees
CN102372515A (en) * 2010-08-24 2012-03-14 徐向金 Organic fertilizer produced by using sludge
CN102701883A (en) * 2012-06-28 2012-10-03 农悦锋 Compound microbial fertilizer prepared from papermaking sludge
CN103992146A (en) * 2014-05-04 2014-08-20 张良 Activated sludge fertilizer

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105601063A (en) * 2016-01-19 2016-05-25 赵东星 Sludge solidifying agent for treating sludge in river channels and method for preparing sludge solidifying agent
CN107235698A (en) * 2016-01-30 2017-10-10 合肥智慧龙图腾知识产权股份有限公司 A kind of municipal sludge processing curing agent and preparation method thereof
CN106701093A (en) * 2016-11-23 2017-05-24 产俊涛 Lead contaminated soil repair agent and preparation method and application thereof
CN106797820A (en) * 2017-01-12 2017-06-06 清华大学 Recovery of ecologic environment in a mine nutrition earthing with municipal sludge as main matrix and preparation method thereof
CN106797820B (en) * 2017-01-12 2020-08-04 清华大学 Mine ecological restoration nutrition covering soil with municipal sludge as main matrix and preparation method thereof
CN109336345A (en) * 2018-11-29 2019-02-15 福州宇澄环保工程设计有限公司 A kind of black and odorous water bed mud biological modification agent

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