CN105190984A - 具有置换盐电极的高电流强度电池组 - Google Patents
具有置换盐电极的高电流强度电池组 Download PDFInfo
- Publication number
- CN105190984A CN105190984A CN201480014953.1A CN201480014953A CN105190984A CN 105190984 A CN105190984 A CN 105190984A CN 201480014953 A CN201480014953 A CN 201480014953A CN 105190984 A CN105190984 A CN 105190984A
- Authority
- CN
- China
- Prior art keywords
- phase
- active metal
- salt
- electrochemical cell
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000003839 salts Chemical class 0.000 title claims abstract description 82
- 238000006073 displacement reaction Methods 0.000 title description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 131
- 239000002184 metal Substances 0.000 claims abstract description 131
- 239000003792 electrolyte Substances 0.000 claims abstract description 91
- 239000011133 lead Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 230000005540 biological transmission Effects 0.000 claims description 12
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- 230000005611 electricity Effects 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 6
- 150000004820 halides Chemical class 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 125000006850 spacer group Chemical group 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- 150000001805 chlorine compounds Chemical group 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 24
- 150000002739 metals Chemical class 0.000 abstract description 16
- 230000007423 decrease Effects 0.000 abstract description 4
- 230000009467 reduction Effects 0.000 abstract description 2
- 229910021645 metal ion Inorganic materials 0.000 description 54
- 210000004027 cell Anatomy 0.000 description 52
- 239000012071 phase Substances 0.000 description 41
- 150000001768 cations Chemical class 0.000 description 25
- 238000004146 energy storage Methods 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 17
- -1 metalloid salt Chemical class 0.000 description 14
- 239000000463 material Substances 0.000 description 12
- 229910052752 metalloid Inorganic materials 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 150000002738 metalloids Chemical class 0.000 description 10
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 9
- 230000032258 transport Effects 0.000 description 9
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000007599 discharging Methods 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 150000001450 anions Chemical class 0.000 description 6
- 229910052787 antimony Inorganic materials 0.000 description 6
- 238000003491 array Methods 0.000 description 6
- 230000036647 reaction Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000005275 alloying Methods 0.000 description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000007790 solid phase Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000011810 insulating material Substances 0.000 description 4
- 239000010416 ion conductor Substances 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005191 phase separation Methods 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- 239000002228 NASICON Substances 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 230000005496 eutectics Effects 0.000 description 3
- 230000037427 ion transport Effects 0.000 description 3
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical class Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 3
- 229910001338 liquidmetal Inorganic materials 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 239000002227 LISICON Substances 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 210000000352 storage cell Anatomy 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- 229910001152 Bi alloy Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- 229910006309 Li—Mg Inorganic materials 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 229910003249 Na3Zr2Si2PO12 Inorganic materials 0.000 description 1
- 229910019069 NaOH—NaBr Inorganic materials 0.000 description 1
- 229910019072 NaOH—NaI Inorganic materials 0.000 description 1
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- 229910001245 Sb alloy Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000905 alloy phase Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- ZASWJUOMEGBQCQ-UHFFFAOYSA-L dibromolead Chemical compound Br[Pb]Br ZASWJUOMEGBQCQ-UHFFFAOYSA-L 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000006023 eutectic alloy Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/399—Cells with molten salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/121—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/138—Primary casings; Jackets or wrappings adapted for specific cells, e.g. electrochemical cells operating at high temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0048—Molten electrolytes used at high temperature
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/117—Inorganic material
- H01M50/119—Metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361781500P | 2013-03-14 | 2013-03-14 | |
| US61/781,500 | 2013-03-14 | ||
| PCT/IB2014/000617 WO2014140792A2 (en) | 2013-03-14 | 2014-03-14 | High amperage batteries with displacement salt electrodes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105190984A true CN105190984A (zh) | 2015-12-23 |
Family
ID=50884952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480014953.1A Pending CN105190984A (zh) | 2013-03-14 | 2014-03-14 | 具有置换盐电极的高电流强度电池组 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10090564B2 (enExample) |
| EP (1) | EP2973837B1 (enExample) |
| JP (1) | JP2016510936A (enExample) |
| KR (1) | KR20150132402A (enExample) |
| CN (1) | CN105190984A (enExample) |
| AU (1) | AU2014229643A1 (enExample) |
| WO (1) | WO2014140792A2 (enExample) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107968230A (zh) * | 2017-11-09 | 2018-04-27 | 新奥科技发展有限公司 | 一种液态金属电池 |
| US10181800B1 (en) | 2015-03-02 | 2019-01-15 | Ambri Inc. | Power conversion systems for energy storage devices |
| US10270139B1 (en) | 2013-03-14 | 2019-04-23 | Ambri Inc. | Systems and methods for recycling electrochemical energy storage devices |
| CN109786862A (zh) * | 2018-12-25 | 2019-05-21 | 大连理工大学 | 一种带抑制流体不稳定性栅格装置的方形截面液态金属电池 |
| US10297870B2 (en) | 2013-05-23 | 2019-05-21 | Ambri Inc. | Voltage-enhanced energy storage devices |
| US10541451B2 (en) | 2012-10-18 | 2020-01-21 | Ambri Inc. | Electrochemical energy storage devices |
| US10608212B2 (en) | 2012-10-16 | 2020-03-31 | Ambri Inc. | Electrochemical energy storage devices and housings |
| US10637015B2 (en) | 2015-03-05 | 2020-04-28 | Ambri Inc. | Ceramic materials and seals for high temperature reactive material devices |
| CN113193179A (zh) * | 2021-03-29 | 2021-07-30 | 西安交通大学 | 一种液态金属电池及其制备方法 |
| US11211641B2 (en) | 2012-10-18 | 2021-12-28 | Ambri Inc. | Electrochemical energy storage devices |
| US11387497B2 (en) | 2012-10-18 | 2022-07-12 | Ambri Inc. | Electrochemical energy storage devices |
| US11411254B2 (en) | 2017-04-07 | 2022-08-09 | Ambri Inc. | Molten salt battery with solid metal cathode |
| US11721841B2 (en) | 2012-10-18 | 2023-08-08 | Ambri Inc. | Electrochemical energy storage devices |
| US11909004B2 (en) | 2013-10-16 | 2024-02-20 | Ambri Inc. | Electrochemical energy storage devices |
| US11929466B2 (en) | 2016-09-07 | 2024-03-12 | Ambri Inc. | Electrochemical energy storage devices |
| US12142735B1 (en) | 2013-11-01 | 2024-11-12 | Ambri, Inc. | Thermal management of liquid metal batteries |
| US12224447B2 (en) | 2018-12-17 | 2025-02-11 | Ambri Inc. | High temperature energy storage systems and methods |
| US12347832B2 (en) | 2013-09-18 | 2025-07-01 | Ambri, LLC | Electrochemical energy storage devices |
| US12374684B2 (en) | 2013-10-17 | 2025-07-29 | Ambri, LLC | Battery management systems for energy storage devices |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9312522B2 (en) | 2012-10-18 | 2016-04-12 | Ambri Inc. | Electrochemical energy storage devices |
| US9520618B2 (en) | 2013-02-12 | 2016-12-13 | Ambri Inc. | Electrochemical energy storage devices |
| US9735450B2 (en) | 2012-10-18 | 2017-08-15 | Ambri Inc. | Electrochemical energy storage devices |
| US9786955B1 (en) | 2013-03-13 | 2017-10-10 | Massachusetts Institute Of Technology | Assembly methods for liquid metal battery with bimetallic electrode |
| US10128543B2 (en) * | 2013-07-08 | 2018-11-13 | Eos Energy Storage, Llc | Molten metal rechargeable electrochemical cell |
| JP2016535392A (ja) | 2013-10-29 | 2016-11-10 | マサチューセッツ インスティテュート オブ テクノロジー | 自己回復液体／固体状態バッテリ |
| US10170799B2 (en) | 2014-12-15 | 2019-01-01 | Massachusetts Institute Of Technology | Multi-element liquid metal battery |
| US10396404B2 (en) | 2015-02-27 | 2019-08-27 | Massachusetts Institute Of Technology | Electrochemical cell with bipolar faradaic membrane |
| US9893385B1 (en) | 2015-04-23 | 2018-02-13 | Ambri Inc. | Battery management systems for energy storage devices |
| CN105206834A (zh) * | 2015-08-31 | 2015-12-30 | 无锡市嘉邦电力管道厂 | 电池及其正极材料 |
| US10511061B2 (en) | 2016-01-13 | 2019-12-17 | University Of Kentucky Research Foundation | Low temperature liquid metal batteries for energy storage applications |
| US20190181439A1 (en) * | 2016-08-10 | 2019-06-13 | The Board Of Trustees Of The Leland Stanford Junior University | Near ambient temperature, high potential secondary battery with liquid electrode materials separated by a solid electrolyte |
| DE102017112515B4 (de) * | 2017-06-07 | 2020-03-26 | Günter Borchardt | Verfahren zum Betreiben eines Speichers für elektrische Energie und Vorrichtung zur Durchführung des Verfahrens |
| EP3762991A4 (en) * | 2018-03-08 | 2021-12-08 | Yi Cui | SOLID ELECTROLYTE MELTED LITHIUM ELECTROCHEMICAL CELLS |
| MX2022002968A (es) * | 2019-09-12 | 2022-06-14 | Ambri Inc | Sistemas y metodos para el almacenamiento de energia a escala de red. |
| US12431480B2 (en) | 2020-08-28 | 2025-09-30 | Pure Lithium Corporation | Methods for forming an energy storage device |
| US12368155B2 (en) | 2020-08-28 | 2025-07-22 | Pure Lithium Corporation | Lithium metal anode and battery |
| US12100828B2 (en) | 2021-01-29 | 2024-09-24 | Pure Lithium Corporation | Microscopically smooth substrates for lithium metal deposition |
| US12027691B2 (en) | 2020-08-28 | 2024-07-02 | Pure Lithium Corporation | Vertically integrated pure lithium metal production and lithium battery production |
| JP7687586B2 (ja) * | 2021-02-18 | 2025-06-03 | スズキ株式会社 | 全固体臭化物イオン電池の製造方法 |
| WO2022240696A1 (en) | 2021-05-12 | 2022-11-17 | Pure Lithium Corporation | Rechargeable battery and electrolysis method of making the same |
| US20220393173A1 (en) * | 2021-06-04 | 2022-12-08 | Pure Lithium Corporation | Lithium Deposition and Battery Using Inorganic Molten Salts |
| US20240072565A1 (en) * | 2022-08-24 | 2024-02-29 | GM Global Technology Operations LLC | Method and system for charging a battery |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012040176A1 (en) * | 2010-09-20 | 2012-03-29 | Massachusetts Institute Of Technology | Alkali metal ion battery with bimetallic electrode |
| CN102498589A (zh) * | 2009-07-20 | 2012-06-13 | 麻省理工学院 | 液体电极蓄电池 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9100936D0 (en) | 1991-01-16 | 1991-02-27 | Secr Defence | Improvements relating to high temperature secondary batteries |
| JPH09139232A (ja) * | 1995-09-14 | 1997-05-27 | Toshiba Corp | リチウム電池 |
| US6361901B1 (en) | 1998-07-23 | 2002-03-26 | Massachusetts Institute Of Technology | Self-doped microphase separated block copolymer electrolyte |
| EP1414100A4 (en) * | 2001-06-04 | 2007-05-30 | Sony Corp | LIGHT RECHARGEABLE SECONDARY BATTERY |
| JP4165586B2 (ja) * | 2006-08-02 | 2008-10-15 | ソニー株式会社 | 電池パック |
| US8268471B2 (en) | 2006-08-15 | 2012-09-18 | Massachusetts Institute Of Technology | High-amperage energy storage device with liquid metal negative electrode and methods |
| US8323816B2 (en) | 2009-07-20 | 2012-12-04 | Massachusetts Institute Of Technology | Alkaline earth metal ion battery |
| WO2014055873A1 (en) | 2012-10-05 | 2014-04-10 | Massachusetts Institute Of Technology | Low-temperature liquid metal batteries for grid-scaled storage |
| EP2731181B1 (en) * | 2012-11-12 | 2019-01-09 | Karlsruher Institut für Technologie | Secondary battery and method for its manufacturing |
| US20140211370A1 (en) * | 2013-01-25 | 2014-07-31 | Ionova Technologies, Inc. | Electrochemical Cell, Related Material, Process for Production, and Use Thereof |
-
2014
- 2014-03-13 US US14/208,218 patent/US10090564B2/en active Active
- 2014-03-14 CN CN201480014953.1A patent/CN105190984A/zh active Pending
- 2014-03-14 JP JP2015562368A patent/JP2016510936A/ja active Pending
- 2014-03-14 KR KR1020157029207A patent/KR20150132402A/ko not_active Withdrawn
- 2014-03-14 WO PCT/IB2014/000617 patent/WO2014140792A2/en not_active Ceased
- 2014-03-14 AU AU2014229643A patent/AU2014229643A1/en not_active Abandoned
- 2014-03-14 EP EP14728275.0A patent/EP2973837B1/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102498589A (zh) * | 2009-07-20 | 2012-06-13 | 麻省理工学院 | 液体电极蓄电池 |
| WO2012040176A1 (en) * | 2010-09-20 | 2012-03-29 | Massachusetts Institute Of Technology | Alkali metal ion battery with bimetallic electrode |
Non-Patent Citations (4)
| Title |
|---|
| DAVID J. BRADWELL ET AL: "Magnesium-Antimony Liquid Metal Battery for StationaryEnergy Storage", 《JOURNAL OF THE AMERICAN CHEMICAL SOCIETY》 * |
| DONALD R. SADOWAY: "Block and graft copolymer electrolytes for high-performance,solid-state, lithium batteries", 《JOURNAL OF POWER SOURCES》 * |
| HOJONG KIM ET AL: "Liquid Metal Batteries Past, Present, and Future", 《CHEMICAL REVIEWS》 * |
| HOJONG KIM ET AL: "Liquid Metal Batteries: Past, Present, and Future", 《CHEMICAL REVIEWS》 * |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10608212B2 (en) | 2012-10-16 | 2020-03-31 | Ambri Inc. | Electrochemical energy storage devices and housings |
| US11721841B2 (en) | 2012-10-18 | 2023-08-08 | Ambri Inc. | Electrochemical energy storage devices |
| US11211641B2 (en) | 2012-10-18 | 2021-12-28 | Ambri Inc. | Electrochemical energy storage devices |
| US11387497B2 (en) | 2012-10-18 | 2022-07-12 | Ambri Inc. | Electrochemical energy storage devices |
| US10541451B2 (en) | 2012-10-18 | 2020-01-21 | Ambri Inc. | Electrochemical energy storage devices |
| US11196091B2 (en) | 2012-10-18 | 2021-12-07 | Ambri Inc. | Electrochemical energy storage devices |
| US11611112B2 (en) | 2012-10-18 | 2023-03-21 | Ambri Inc. | Electrochemical energy storage devices |
| US10270139B1 (en) | 2013-03-14 | 2019-04-23 | Ambri Inc. | Systems and methods for recycling electrochemical energy storage devices |
| US10297870B2 (en) | 2013-05-23 | 2019-05-21 | Ambri Inc. | Voltage-enhanced energy storage devices |
| US12347832B2 (en) | 2013-09-18 | 2025-07-01 | Ambri, LLC | Electrochemical energy storage devices |
| US11909004B2 (en) | 2013-10-16 | 2024-02-20 | Ambri Inc. | Electrochemical energy storage devices |
| US12374684B2 (en) | 2013-10-17 | 2025-07-29 | Ambri, LLC | Battery management systems for energy storage devices |
| US12142735B1 (en) | 2013-11-01 | 2024-11-12 | Ambri, Inc. | Thermal management of liquid metal batteries |
| US10566662B1 (en) | 2015-03-02 | 2020-02-18 | Ambri Inc. | Power conversion systems for energy storage devices |
| US10181800B1 (en) | 2015-03-02 | 2019-01-15 | Ambri Inc. | Power conversion systems for energy storage devices |
| US11289759B2 (en) | 2015-03-05 | 2022-03-29 | Ambri, Inc. | Ceramic materials and seals for high temperature reactive material devices |
| US11840487B2 (en) | 2015-03-05 | 2023-12-12 | Ambri, Inc. | Ceramic materials and seals for high temperature reactive material devices |
| US10637015B2 (en) | 2015-03-05 | 2020-04-28 | Ambri Inc. | Ceramic materials and seals for high temperature reactive material devices |
| US11929466B2 (en) | 2016-09-07 | 2024-03-12 | Ambri Inc. | Electrochemical energy storage devices |
| US11411254B2 (en) | 2017-04-07 | 2022-08-09 | Ambri Inc. | Molten salt battery with solid metal cathode |
| CN107968230A (zh) * | 2017-11-09 | 2018-04-27 | 新奥科技发展有限公司 | 一种液态金属电池 |
| US12224447B2 (en) | 2018-12-17 | 2025-02-11 | Ambri Inc. | High temperature energy storage systems and methods |
| CN109786862B (zh) * | 2018-12-25 | 2021-06-08 | 大连理工大学 | 一种带抑制流体不稳定性栅格装置的方形截面液态金属电池 |
| CN109786862A (zh) * | 2018-12-25 | 2019-05-21 | 大连理工大学 | 一种带抑制流体不稳定性栅格装置的方形截面液态金属电池 |
| CN113193179A (zh) * | 2021-03-29 | 2021-07-30 | 西安交通大学 | 一种液态金属电池及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2973837A2 (en) | 2016-01-20 |
| EP2973837B1 (en) | 2019-01-09 |
| AU2014229643A1 (en) | 2015-09-03 |
| US20140272481A1 (en) | 2014-09-18 |
| WO2014140792A3 (en) | 2014-12-31 |
| US10090564B2 (en) | 2018-10-02 |
| WO2014140792A2 (en) | 2014-09-18 |
| KR20150132402A (ko) | 2015-11-25 |
| JP2016510936A (ja) | 2016-04-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2973837B1 (en) | High amperage batteries with displacement salt electrodes | |
| US10903528B2 (en) | Multi-element liquid metal battery | |
| KR101895087B1 (ko) | 이원금속 전극을 갖는 알칼리 금속 이온 배터리 | |
| US10177405B2 (en) | Low-temperature liquid metal batteries for grid-scaled storage | |
| US9905888B2 (en) | Self-healing liquid/solid state battery | |
| US8268471B2 (en) | High-amperage energy storage device with liquid metal negative electrode and methods |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170717 Address after: Massachusetts Applicant after: Massachusetts Institute of Technology Applicant after: Total new energy company activities in the United States Applicant after: Total S.A. Address before: Massachusetts Applicant before: Massachusetts Institute of Technology Applicant before: Whole marketing service company |
|
| TA01 | Transfer of patent application right | ||
| AD01 | Patent right deemed abandoned |
Effective date of abandoning: 20190326 |
|
| AD01 | Patent right deemed abandoned |