CN105177382B - A kind of high-toughness casting magnesium alloy and preparation method thereof - Google Patents
A kind of high-toughness casting magnesium alloy and preparation method thereof Download PDFInfo
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Abstract
The present invention is a kind of high-toughness casting magnesium alloy, and this alloy is Mg Bi Ca Zn alloy, and the mass percent of its component is: Bi 3~8.0wt%;Ca 0.1~1.2wt%;Zn 0.1~2.0wt%, remaining is Mg.The magnesium alloy of the present invention, using Bi element as main alloy element, by simple alloying means, forms substantial amounts of Mg3Bi2Phase, is aided with a small amount of Ca element and the first intensity usually improving alloy of Zn, and Ca unit have and improves Mg simultaneously3Bi2Phase morphology and the effect of distribution, thus improve the plasticity of alloy, and then in Mg Bi alloy series, develop high tough cast magnesium alloy, this cast magnesium alloy has higher intensity, has higher plasticity simultaneously, and after optimizing components, the tensile strength of alloy reaches about 270MPa, yield strength reaches about 145MPa, elongation percentage about 10.0%, had both reached the intensity compared favourably with magnesium-rare earth, had had higher elongation percentage simultaneously concurrently.
Description
Technical field
The invention belongs to class of metal materials and field of metallurgy, relate to a kind of low cost non-rare-earth type high-toughness casting magnesium alloy
And preparation method thereof;This novel magnesium alloy can be as potential heat resistance magnesium alloy and biological medical magnesium alloy material.
Background technology
It is high that magnesium alloy has specific strength, and specific stiffness is high, and good casting property, capability of electromagnetic shielding is good, and machinability is excellent
Good, the plurality of advantages such as it is easily recycled so that it is obtained widely in electronics, Aero-Space and field of track traffic simultaneously
Application, more and more urgent to the demand of loss of weight and environmental protection especially with modern automobile industry, the high-strength light of developing low-cost
Magnesium alloy increasingly obtains the attention of every country.
In the application of existing magnesium alloy, the ratio shared by cast magnesium alloy reaches about 90%, and wherein usage amount is bigger
Commercial cast magnesium alloy include AZ91D, AM60B, AS41 and AE42 etc., these magnesium alloys are mainly used in prepares transmission housing
Body, the general parts such as frame of handwheel and instrumental panel.But the intensity of above commercial cast magnesium alloy is insufficient for load-bearing
The assembly requirement to mechanical property.This is mainly due in process of setting, the hardening constituent of the AZ series magnesium alloy of high Al content,
Mg17Al12Being netted precipitation with the form of divorsed eutectic along crystal boundary, the plasticity causing alloy is relatively low, when stress, opens too early
Split and make alloy strength the highest.Therefore, the exploitation tough cast magnesium alloy of novel high-strength is one of cast magnesium alloy exploitation focus.
Cast magnesium alloy relies primarily on alloyage process and coordinates suitable Technology for Heating Processing to produce intercrystalline strengthening, solution strengthening
With precipitation strength effect, wherein producing precipitation strength by Ageing Treatment is to improve magnesium alloy strength, thus obtains high tough casting
One of important means making magnesium alloy.In prior art, CN102534330A discloses a kind of cast Mg alloy with high strength, this conjunction
The percetage by weight of the component of gold is Gd 8~14wt%, Y 1~5wt%, Al 0.6~2wt%, and remaining is for magnesium and can not keep away
The impurity element exempted from, after solid solution and Ageing Treatment, the tensile strength of this alloy between 300~355MPa, yield strength
Between 210~255MPa, elongation percentage, between 2~8%, has higher intensity.But this alloy needs add substantial amounts of Gd,
The rare earth element costly such as Y, directly increases the cost of alloy, and adds the density of alloy, also results in and is cast as
Shape degradation.CN1752251 discloses a kind of high-strength magnesium alloy and preparation method thereof, the percentage by weight of its constituent
It is respectively as follows: Nd2.5~3.6wt%, Zr 0.35~0.8wt%, Zn content and is not more than 0.4wt%, Ca content no more than
0.5wt%, remaining is magnesium and inevitable impurity.This alloy, after solid solution and Ageing Treatment, has higher mechanical property,
Equally containing more in tensile strength 280~320MPa, yield strength 140~155MPa, elongation percentage 5~12%, and alloy
Noble element (Nd2.5~3.6wt%), indirectly improve the cost of alloy.CN102560211A discloses a kind of containing Gd's
Cast magnesium alloy and preparation method thereof, the percentage by weight of its constituent is respectively as follows: Zn 6wt%, Y 1wt%, Zr
0.6wt%, Gd 0.5~1.0wt%, surplus is magnesium and inevitable impurity.After heat treatment the tensile strength of alloy reaches
285MPa, elongation percentage is 8.7%.But this alloy needs add the rare earth element costly such as substantial amounts of Gd, Y, Zr, directly increase
Add the cost of alloy. limit the further genralrlization application of alloy.
Visible, the tough cast magnesium alloy of the non-rare earth high-strength of developing low-cost, for reducing cost of alloy, finally realize magnesium alloy
Application on the civil areas such as auto parts and components, significant.
Summary of the invention
The problem existed for above-mentioned prior art of the present invention, it is provided that a kind of high-toughness casting magnesium alloy and preparation side thereof
Method.The novel Mg-Bi-Ca-Zn alloy of the present invention, utilizes Ca element to change Mg3Bi2Phase morphology and the effect of distribution so that close
Mg in gold3Bi2Become tiny, dispersion mutually, and by the solution treatment of appropriate temperature and time and Ageing Treatment means, regulate and control
Hardening constituent in alloy, final acquisition high-toughness casting magnesium alloy, its raw material and preparation cost are cheap.
The technical scheme is that
A kind of high-toughness casting magnesium alloy, for Mg-Bi-Ca-Zn alloy, the mass percent of its component is: Bi 3~
8.0wt%;Ca 0.1~1.2wt%;Zn 0.1~2.0wt%, remaining is Mg.
The preparation method of described high-toughness casting magnesium alloy, comprises the following steps:
1) dispensing: with pure Mg ingot, pure Bi block, pure Zn block and Mg-Ca intermediate alloy as raw material, becomes according to described magnesium alloy
Divide and carry out dispensing;
2) melting: put into by pure Mg ingot in the crucible of smelting furnace, setting furnace temperature 700~730 DEG C also keep, treat that it melts
After, join being preheating to the pure Bi block of 200~250 DEG C, pure Zn block and Mg-Ca intermediate alloy in magnesium melt respectively;Then rise
High smelting temperature 10~20 DEG C, and it is incubated 5~15 minutes, then stirring 3~10 minutes, carry out refine degassing processing;
3) cast: furnace temperature is turned down 10~30 DEG C to pouring temperature, after be incubated 2~10 minutes, by magnesium alloy fused mass cast
In corresponding mould, prepare as-cast magnesium alloy;From melting to cast whole during all at CO2/SF6Mixed gas protected
Under carry out;
4) solid solution: the as-cast magnesium alloy obtained is carried out solution treatment, solid solution temperature is 500~530 DEG C, and the time is
4~24 hours, with 40~80 DEG C of warm water quenchings;The heating of solution treatment and insulating process are passed through noble gas (argon) carry out
Protection;
5) Ageing Treatment: carry out the alloy after solid solution being first incubated 0.5~2 hour at 300~350 DEG C, then 150~
The two-stage time effect being incubated 8~24 hours at 200 DEG C processes, and prepares described high-toughness casting magnesium alloy.
Described Mg-Ca intermediate alloy is preferably Mg-20Ca.
Described CO2/SF6Mixed gas composition is preferably volume ratio CO2:SF6=100:1.
The preparation method of above-mentioned superhigh intensity novel magnesium alloy, raw material used and equipment are all obtained by known approach
, operating procedure used is that those skilled in the art can grasp.
The substantive distinguishing features of the present invention is:
The magnesium alloy of the present invention is with Bi as main alloying elements, because the Bi limit solid solubility in Mg when 553 DEG C
For 8.73wt%, and when 200 DEG C, Bi solid solubility in Mg is almost nil, the therefore addition of Bi element, and coordinates suitably
Solid solution and Ageing Treatment, can ensure that alloy has good Precipitation strengthening effect.High-melting-point Mg in alloy3Bi2Phase
(fusing point is 823 DEG C), its high thermal stability can compare favourably with the heat stability of Mg-RE phase, and cheap, Mg3Bi2Phase
Can the movement of effectively pin crystal boundary, hinder dislocation motion, during suppression heat treatment, crystal grain is grown up, and then carries heavy alloyed mechanical property
Energy.Ca element, due to advantages such as its aboundresources, cheap and low-density, is alloy element conventional in magnesium alloy, can
To be used for improving non-oxidizability and the mechanical performance of magnesium alloy, Ca has preferable Grain Refinement Effect in AZ series magnesium alloy,
Also it is one of alloy element conventional in heat resistance magnesium alloy.We experimentally found that interpolation the addition of C a element has improvement and closes
Mg in gold3Bi2Phase morphology and the effect of distribution, such that it is able to improve the plasticity of alloy.Additionally, the adding on a small quantity of Zn element in alloy
Enter, Bi Precipitation effect in the alloy can be strengthened, simultaneously work as certain solution strengthening effect.
Compared with prior art, the marked improvement of the present invention is with advantage:
1) magnesium alloy of the present invention is using Bi element as main alloy element, by simple alloying means, is formed big
Amount Mg3Bi2Phase, is aided with a small amount of Ca element and the first intensity usually improving alloy of Zn, thus in Mg-Bi alloy series
Developing high tough cast magnesium alloy, this cast magnesium alloy has higher intensity, has higher plasticity simultaneously, and composition is excellent
After change, the tensile strength of alloy reaches about 270MPa, and yield strength reaches about 145MPa, elongation percentage about 10.0%, both reaches
To the intensity compared favourably with magnesium-rare earth, have higher elongation percentage concurrently simultaneously.
2) present invention passes through experimentation, finds that Ca element has first and improves Mg in alloy3Bi2Phase morphology and distribution
Effect, such that it is able to improve the plasticity of alloy, this has directive significance widely for the design of Mg-Bi system alloy from now on.
3) preparation method of Mg-Bi-Ca-Zn alloy in the present invention, due to metal Bi (fusing point 271 in the raw material that used
DEG C) and Zn, and relatively low with fusing point all ratios of Mg-Ca intermediate alloy, close with the magnesium alloy containing rare earth and the magnesium containing copper etc.
Metallographic compares, and is easier to make alloy mix homogeneously, thus saves the energy during melting.Due to hardening constituent Mg in alloy3Bi2It is former mutually
Position generates, so it all can be processed by existing magnesium alloy smelting and Equipment for Heating Processing, it is not necessary to additional improvement, to production
The requirement of equipment is low.(equipment is simple, and production efficiency is high)
4) the developed alloy of the present invention has the prospect as heat resistance magnesium alloy.Hardening constituent (Mg in alloy3Bi2Phase) molten
Point higher (fusing point is 823 DEG C), can compare favourably with the heat stability of the hardening constituent in magnesium-rare earth alloy, so when high temperature,
Due to better heat stability, its invigoration effect remains to keep, such that it is able to put forward heavy alloyed heat resistance.
5) magnesium alloy of the present invention is with low cost.Due to without precious metals such as rare earths, steady for in-situ preparation high heat
Mg qualitatively3Bi2The metal Bi of phase is cheap, cost of alloy low (general 1000 to the 5000 yuan of per kilograms of rare earth, and this patent
Metal Bi per kilogram used is only with about 200 yuan);Can be widely applied to cast on automobile the civil use such as parts.
6) the main alloy element Bi element of this alloy does not has toxic action to environment and human body, belongs to environmental friendliness section bar
Material, this alloy also holds promise as bio-medical material application.
7) alloy of present component is when as cast condition and solid solution state, due to Mg3Bi2The pattern of phase and distribution are by Ca element institute
Improve, consequently facilitating plastic working, may be used for the plastic workings such as extruding, the higher material of production performance.
Accompanying drawing explanation
In order to make the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing the present invention done into
The description of one step.
Fig. 1 is the microstructure morphology of the cast alloy obtained in as cast condition Mg-6Bi alloy and embodiment 1,2,3;Wherein,
Fig. 1 a is the as-cast microstructure pattern of Mg-6Bi alloy;Fig. 1 b is the as-cast microstructure of Mg-4Bi-0.3Ca-1.0Zn alloy
Pattern;
Fig. 1 c is the as-cast microstructure pattern of Mg-6.0Bi-0.5Ca-1.0Zn alloy;Fig. 1 d is Mg-7.0Bi-
The as-cast microstructure pattern of 0.7Ca-1.0Zn alloy.
Fig. 2 is for obtain respective alloy in Mg-6Bi alloy and embodiment 1,2,3 after Overheating Treatment after Overheating Treatment
Microstructure morphology;Wherein, Fig. 2 a is Mg-6Bi alloy microstructure morphology after Overheating Treatment;Fig. 2 b is Mg-4Bi-
0.3Ca-1.0Zn alloy microstructure morphology after Overheating Treatment;Fig. 2 c is that Mg-6.0Bi-0.5Ca-1.0Zn alloy passes through
Microstructure morphology after heat treatment;Fig. 2 d is Mg-7.0Bi-0.7Ca-1.0Zn alloy microstructure shape after Overheating Treatment
Looks.
Fig. 3 is embodiment 1, embodiment 2, the embodiment 3 Typical tensile curve of gained alloy after Overheating Treatment.
Detailed description of the invention
Being described further the present invention (technical scheme) by detailed description of the invention below, following example are all at this
Implement under premised on bright technical scheme, give detailed embodiment and concrete operating process, but the guarantor of the present invention
The scope of protecting is not limited to following embodiment.
Choose three kinds of alloying components Mg-4Bi-0.3Ca-1.0Zn (wt%) (alloy 1), Mg-6.0Bi-0.5Ca-1.0Zn
(wt%) (alloy 2), Mg-7.0Bi-0.7Ca-1.0Zn (wt%) (alloy 3) are as exemplary.
According to technical scheme, choose pure Mg (99.8wt%), pure Bi (99wt%), pure Zn (99.9wt%) and
Mg-20Ca (the actually detected content of Ca is 20.01wt%) intermediate alloy is raw material, through dispensing, melting, cast and heat treatment, obtains
Magnesium alloy needed for, and gained alloy microstructure and mechanical property are carried out detection analysis.
Embodiment 1
(1) raw material is weighed by the mass percent of alloy Mg-4Bi-0.3Ca-1.0Zn (wt%): pure Bi, pure Zn, Mg-
20Ca, remaining be Mg (every 1000 grams of subject alloy can by 15 grams of Mg-20Ca, 10g gram of Zn, 40 grams of Bi and 935 grams of Mg preparation and
Become).And carry out raw material surface process (as removed dirt, oxide skin etc.).
(2) first smelting furnace cleaned out and be heated to 450 DEG C, the magnesium ingot being preheating to 200 DEG C is put into smelting furnace
In crucible, setting furnace temperature 720 DEG C, be slowly heated, heating rate is 20~40 DEG C/min, and keeps setting furnace temperature;
(3) after pure magnesium ingot all melts, close being preheated in the middle of the pure Bi of about 200 DEG C, pure Zn and Mg-20Ca respectively
Gold joins in Serum Magnesium, and furnace temperature rises to 730 DEG C, is incubated 5~10 minutes, then mechanical agitation 3~5 minutes, is then charged with
Argon gas carries out refine degasification, and furnace temperature is adjusted to pouring temperature 720 DEG C afterwards, stands 2~10 minutes, is poured in mould system
Obtain cast alloy.From melting to cast whole during all at CO2/SF6Carry out under mixed gas protected, CO2:SF6Volume ratio
For 100:1;The present embodiment alloy casting state microstructure is as shown in Figure 1 b.
(4) solid solution: the alloy obtained carries out solution treatment: be 510 DEG C at solid solution temperature, the time is 4 hours, uses
40~80 DEG C of warm water quenchings.The heating of solution treatment and insulating process are passed through noble gas (argon) protect.
(5) timeliness: carry out the alloy obtained first being incubated 0.5 hour at 300 DEG C, then be incubated 16 hours at 160 DEG C
Two-stage time effect process, prepared wanted magnesium alloy.
After the process of the present embodiment alloy aging, microstructure is as shown in Figure 2 b.The tensile strength of alloy reaches 264MPa, bends
Take intensity and reach 140MPa, elongation percentage 12.5%.
Embodiment 2
(1) raw material is weighed by the mass percent of alloy (Mg-6.0Bi-0.5Ca-1.0Zn): pure Bi, pure Zn, Mg-
20Ca, remaining is Mg;And carry out raw material surface process (as removed dirt, oxide skin etc.).
(2) first smelting furnace cleaned out and be heated to 450 DEG C, the magnesium ingot being preheating to 200 DEG C is put into smelting furnace
In crucible, setting furnace temperature 720 DEG C, being slowly heated heating rate is 20~40 DEG C/min, and keeps setting furnace temperature;
(3) after pure magnesium ingot all melts, will be preheated in the middle of the pure Bi and pure Zn and Mg-20Ca of about 200 DEG C respectively
Alloy joins in Serum Magnesium, and furnace temperature rises to 730 DEG C, is incubated 5~10 minutes, then mechanical agitation 3~5 minutes, then fills
Entering argon gas and carry out refine degasification, furnace temperature is adjusted to pouring temperature 720 DEG C afterwards, stands 2~10 minutes, cast prepares as cast condition
Alloy.From melting to cast whole during all at CO2/SF6Carry out under mixed gas protected, CO2:SF6Volume ratio is 100:
1;The present embodiment alloy casting state microstructure is as illustrated in figure 1 c.
(4) solid solution: the alloy obtained carries out solution treatment: be 510 DEG C at solid solution temperature, the time is 4 hours, uses
40~80 DEG C of warm water quenchings.The heating of solution treatment and insulating process are passed through noble gas (argon) protect.
(5) timeliness: carry out the alloy obtained first being incubated 0.5 hour at 300 DEG C, then be incubated 16 hours at 160 DEG C
Ageing Treatment, prepared wanted magnesium alloy.
After the process of the present embodiment alloy aging, microstructure is as shown in Figure 2 c.The tensile strength of alloy reaches 268MPa, bends
Take intensity and reach 147MPa, elongation percentage 10.4%.
Embodiment 3
(1) raw material is weighed by the mass percent of alloy (Mg-7.0Bi-0.7Ca-1.0Zn): pure Bi, pure Zn, Mg-
20Ca, remaining is Mg;And carry out raw material surface process (as removed dirt, oxide skin etc.).
(2) first smelting furnace cleaned out and be heated to 450 DEG C, the magnesium ingot being preheating to 200 DEG C is put into smelting furnace
In crucible, setting furnace temperature 720 DEG C, being slowly heated heating rate is 20~40 DEG C/min, and keeps setting furnace temperature;
(3) after pure magnesium ingot all melts, will be preheated in the middle of the pure Bi and pure Zn and Mg-20Ca of about 200 DEG C respectively
Alloy joins in Serum Magnesium, and furnace temperature rises to 730 DEG C, is incubated 5~10 minutes, then mechanical agitation 3~5 minutes, then fills
Entering argon gas and carry out refine degasification, furnace temperature is adjusted to pouring temperature 720 DEG C afterwards, stands 2~10 minutes, cast prepares as cast condition
Alloy.From melting to cast whole during all at CO2/SF6Carry out under mixed gas protected, CO2:SF6Volume ratio is 100:
1;The present embodiment alloy casting state microstructure is as shown in Figure 1 d.
(4) solid solution: the alloy obtained carries out solution treatment: be 510 DEG C at solid solution temperature, the time is 4 hours, uses
40~80 DEG C of warm water quenchings.The heating of solution treatment and insulating process are passed through noble gas (argon) protect.
(5) timeliness: carry out the alloy obtained first being incubated 0.5 hour at 300 DEG C, then be incubated 16 hours at 160 DEG C
Ageing Treatment, prepared wanted magnesium alloy.
After the process of the present embodiment alloy aging, microstructure is as shown in Figure 2 d.The tensile strength of alloy reaches 274MPa, bends
Take intensity and reach 149MPa, elongation percentage 9.6%,
Microscopic structure and mechanical property relative analysis:
Fig. 1 a is the as-cast microstructure of the Mg-6Bi alloy obtained under same experimental conditions, it can be seen that as cast condition
Mg in Mg-6Bi3Bi2The thickest, connect into netted at grain boundaries, in solution treatment subsequently, the second thick phase
Can be relatively difficult to dissolve.Fig. 1 b, c, d are embodiment 1 respectively, the as-cast microstructure of 2,3, and the as cast condition of contrast Mg-6Bi alloy shows
Micro-assembly robot (Fig. 1 a), it will be apparent that find the Mg in embodiment 1,2,3 alloy3Bi2The most all become tiny.
Fig. 2 a is in the microscopic structure of Mg-6Bi alloy after solid-solution and aging heat treatment, it can be seen that as cast condition Mg-
6Bi connects webbed thick Mg at grain boundaries3Bi2Remaining in that bigger size mutually, on the one hand this illustrate on solid solution rank
Section, the content of the Bi element that matrix is entered in solid solution is less, and the second phase separated out after on the other hand can be seen that its Ageing Treatment is the biggest
Big minimizing, thus be difficult to obtain strong Precipitation effect.Additionally, the second phase of the large-size still existed will be isolated
Matrix, makes the plasticity of alloy reduce.Fig. 2 b, c, d are micro-group after solid-solution and aging heat treatment of embodiment 1,2,3 respectively
Knit, embodiment 1, the Mg in 2,3 alloys can be found significantly3Bi2Become mellow and full, tiny mutually, have substantial amounts of precipitated phase to go out simultaneously
Existing, this will largely facilitate the raising of alloy strength, and solid solution enters the second of matrix owing to becoming mellow and full, thin the most completely
Little, Dispersed precipitate in the base, also can play certain dispersion-strengthened action, and will not cause substantial amounts of to the plasticity of alloy
Reduce.Visible Ca unit have the Mg in refining alloy3Bi2The effect of phase, is conducive to its heat treatment subsequently.
Fig. 3 is the room temperature tensile curve of embodiment 1, embodiment 2, embodiment 3.It can be seen that the tensile strength of alloy
Reaching about 270MPa, yield strength reaches about 145MPa, elongation percentage about 10.0%, existing higher mechanical property, with
Time have higher elongation percentage concurrently.Illustrate that this alloy is a kind of magnesium alloy with high strength and ductility.On the other hand, along with the rising of Bi content, real
Executing example 1, the intensity of 2,3 gradually rises, and elongation percentage is declined slightly, and this is mainly at Mg3Bi2Quantity is along with the liter of Bi content mutually
High and increase, on the one hand this can put forward heavy alloyed intensity, on the other hand can drop again low-alloyed plasticity.
Unaccomplished matter of the present invention is known technology.
Claims (4)
1. a high-toughness casting magnesium alloy, is characterized by that this alloy is Mg-Bi-Ca-Zn alloy, the mass percent of its component
For: Bi 3 ~ 8.0 wt%;Ca 0.1~1.2 wt%;Zn 0.1 ~ 2.0 wt%, remaining is Mg.
2. the preparation method of high-toughness casting magnesium alloy as claimed in claim 1, is characterized by comprise the following steps:
1) dispensing: with pure Mg ingot, pure Bi block, pure Zn block and Mg-Ca intermediate alloy as raw material, according to described magnesium alloy composition
Carry out dispensing;
2) melting: put into by pure Mg ingot in the crucible of smelting furnace, sets furnace temperature 700 ~ 730 DEG C and keeps, after it melts, point
Do not join being preheating to the pure Bi block of 200 ~ 250 DEG C, pure Zn block and Mg-Ca intermediate alloy in magnesium melt;Then melting is raised
Temperature 10 ~ 20 DEG C, and it is incubated 5~15 minutes, then stirring 3~10 minutes, carry out refine degassing processing;
3) cast: furnace temperature is turned down 10 ~ 30 DEG C to pouring temperature, after being incubated 2 ~ 10 minutes, magnesium alloy fused mass is poured into accordingly
Mould in, prepare as-cast magnesium alloy;From melting to cast whole during all at CO2/SF6Carry out under mixed gas protected;
4) solid solution: the as-cast magnesium alloy obtained is carried out solution treatment, solid solution temperature is 500 ~ 530 DEG C, and the time is 4 ~ 12
Hour, with 40 ~ 80 DEG C of warm water quenchings;The heating of solution treatment and insulating process are passed through argon protect;
5) Ageing Treatment: carry out the alloy after solid solution being first incubated 0.5 ~ 2 hour at 300 ~ 350 DEG C, then at 150 ~ 200 DEG C
The two-stage time effect being incubated 8 ~ 24 hours processes, and prepares described high-toughness casting magnesium alloy.
3. the preparation method of high-toughness casting magnesium alloy as claimed in claim 2, is characterized by described Mg-Ca intermediate alloy
It is preferably Mg-20Ca.
4. the preparation method of high-toughness casting magnesium alloy as claimed in claim 2, is characterized by described CO2/SF6Gaseous mixture
Body composition is preferably volume ratio CO2:SF6=100:1.
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CN109797331A (en) * | 2017-11-17 | 2019-05-24 | 北京有色金属研究总院 | A kind of heat resistance magnesium alloy of low-cost high-strength and preparation method thereof |
CN109280826B (en) * | 2018-10-17 | 2020-08-07 | 合肥诺瓦新材料科技有限公司 | Nano-structure-containing non-rare earth high-strength magnesium alloy material and preparation method thereof |
CN109266928B (en) * | 2018-10-17 | 2020-08-07 | 合肥诺瓦新材料科技有限公司 | Low-cost high-room-temperature plastic deformation magnesium alloy and preparation method thereof |
CN109182857B (en) * | 2018-11-08 | 2024-01-30 | 中信戴卡股份有限公司 | High-strength and high-toughness deformed magnesium alloy and preparation method thereof |
CN109182860A (en) * | 2018-11-08 | 2019-01-11 | 中信戴卡股份有限公司 | A kind of magnesium alloy with high strength and ductility and preparation method |
CN109266930B (en) * | 2018-11-19 | 2019-11-08 | 河北工业大学 | A kind of high tough wrought magnesium alloy and preparation method thereof |
CN109234592B (en) * | 2018-11-19 | 2020-07-14 | 河北工业大学 | Low-temperature rolled high-strength-toughness wrought magnesium alloy and preparation method thereof |
CN110499440B (en) * | 2019-09-20 | 2021-11-30 | 江西理工大学 | Modification method for enhancing coarse magnesium three-bismuth two-phase morphology in magnesium-bismuth alloy |
CN115505858B (en) * | 2022-09-29 | 2023-05-09 | 上海交通大学 | Heat treatment method for large complex magnesium-rare earth alloy component |
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