CN101906554A - Mg-containing high-strength deforming zinc-copper alloy and preparation method thereof - Google Patents

Mg-containing high-strength deforming zinc-copper alloy and preparation method thereof Download PDF

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Publication number
CN101906554A
CN101906554A CN 201010245585 CN201010245585A CN101906554A CN 101906554 A CN101906554 A CN 101906554A CN 201010245585 CN201010245585 CN 201010245585 CN 201010245585 A CN201010245585 A CN 201010245585A CN 101906554 A CN101906554 A CN 101906554A
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zinc
alloy
titanium
aluminium
copper
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肖来荣
张喜民
周泽鹏
曾德露
胡加瑞
李威
刘彦
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Central South University
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Central South University
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Abstract

The invention relates to an Mg-containing high-strength deforming zinc-copper alloy. The alloy consists of the following components in percentage by mass: 0.1 to 5.0 percent of copper, 0.05 to 3.0 percent of magnesium and the balance of zinc and less than or equal to 0.05 percent of impurities. The alloy can also comprise the following components in percentage by mass: at least one of aluminum and titanium, wherein the aluminum accounts for 0.1 to 2.5 percent and the titanium accounts for 0.02 to 0.3 percent. The method for preparing the Mg-containing high-strength deforming zinc-copper alloy comprises the following steps of: smelting by adopting covering protection method, and adding alloy elements in forms of pure zinc, pure aluminum and intermediate alloys of Zn-Cu, Cu-Mg and Zn-Ti, wherein the smelting temperature is between 620 and 710 DEG C; casting at the temperature of between 450 and 500 DEG C, homogenizing ingots at the temperature of between 360 and 380 DEG C for 6 to 10 hours, and performing extrusion molding at the temperature of between 240 and 310 DEG C, wherein the extrusion ratio is between 10 and 20; and annealing at the temperature of between 170 and 210 DEG C for 2 to 4 hours. The Mg-containing high-strength deforming zinc-copper alloy has the advantages of high strength and comprehensive performance, good flowing property of alloy liquid and good casting performance, and can be used as a structural material.

Description

A kind of high-strength deforming zinc-copper alloy that contains Mg and preparation method thereof
Technical field
The present invention relates to a kind of platina and preparation method thereof, refer more particularly to high-strength deformation platina of a kind of Mg of containing and preparation method thereof, belong to the manufacturing technology field of metal alloy compositions.
Background technology
Lower intensity is one of main bottleneck of applying as the manufacturing structure parts of restrained deformation zinc alloy.For improving the intensity of zinc alloy, abroad some investigator has carried out certain research to the aspects such as deformation mechanism, alloying and processing condition of zinc alloy.Deformation zinc alloy is after entering the sixties in last century, because the progress of smelting, processing technology, improving zinc alloy physicals and Study on mechanical properties work progress accelerates, especially high strength becomes the grasp of zinc alloy melting technology, complete processing, and having broken zinc alloy can not be as the restriction of structured material use.
At present the high-strength deformation zinc alloy there is certain research abroad, the later stage nineties in last century, Japan has carried out a series of research to cold forging, heat-resisting and cast zinc alloy, on the intensity of material, obtained certain progress, but over-all properties is still waiting to improve, and particularly the research of extruded zinc alloy this respect seldom.And domestic in this respect research is almost blank, and this makes deformation zinc alloy have great limitation on using, particularly as the use of structured material.The present invention realizes from aspects such as alloying constituent and complete processings breaking through, and deformation zinc alloy is used as structured material becomes reality.
Summary of the invention
The purpose of this invention is to provide a kind of deformation zinc alloy and preparation method thereof with high strength and good over-all properties, particularly a kind of be suitable as that structured material uses contain high-strength deformation platina of Mg and preparation method thereof.
The objective of the invention is to realize in the following manner:
A kind of high-strength deforming zinc-copper alloy that contains Mg, form by following component by mass percentage:
Copper 0.1~5.0%;
Magnesium 0.05~3.0%;
All the other are zinc and unavoidable impurities, and total impurities is not more than 0.05%.
As preferably, the mass percent of above-mentioned each component of alloy is:
Copper 0.5~4.5%;
Magnesium 0.1~2.7%;
All the other are zinc and unavoidable impurities, and total impurities is not more than 0.05%.
A kind of high-strength deforming zinc-copper alloy that contains Mg, form by following component by mass percentage:
Copper 0.1~5.0%;
Magnesium 0.05~3.0%;
And at least a in the aluminium, two kinds of elements of titanium, the content of described aluminium, titanium is respectively: aluminium 0.1~2.5%, titanium 0.02~0.3%;
All the other are zinc and unavoidable impurities, and total impurities is not more than 0.05%.
As preferably, the mass percent of above-mentioned each component of alloy is:
Copper 0.5~4.5%;
Magnesium 0.1~2.7%;
And at least a in the aluminium, two kinds of elements of titanium, the content of described aluminium, titanium is respectively: aluminium 0.2~2.2%, titanium 0.05~0.25%;
All the other are zinc and unavoidable impurities, and total impurities is not more than 0.05%.
The preparation method of the high-strength deformation platina of the described Mg of containing is: adopt protective covering method to carry out melting, copper, magnesium, titanium add with Zn-Cu, Cu-Mg, Zn-Ti master alloy form respectively, zinc, aluminium then add with pure zinc, fine aluminium form respectively, smelting temperature is 620~710 ℃, after treating that the alloy liquation mixes, under 450~500 ℃, be cast into ingot casting; Ingot casting is after 360~380 ℃ of homogenizing are handled 6~10h, and at 240~310 ℃ of following extrusion moldings, extrusion ratio is 10~20; The extruding back is at 170~210 ℃ of annealing 2~4h.
The preparation method of above-mentioned Zn-Ti master alloy is: the pure Ti that will account for Zn-Ti master alloy total mass 5~8% adds melting in the Zn liquation, treat that Ti all melts and mixes after, be incubated 25~35 minutes, be cast into ingot casting then.
The preparation method of the high-strength deformation platina of a kind of Mg of containing of the present invention: described melting is to carry out in medium-frequency induction furnace.
The high-strength deformation platina of a kind of Mg of containing of the present invention is to reach the effect of reinforcement by adding alloying elements such as an amount of copper, magnesium, aluminium, titanium, and the action effect that adds element is as follows:
The effect of Cu mainly shows solution strengthening, and the Cu solid solution of trace causes lattice distortion in Zn, to the slippage generation obstruction of dislocation, thus reinforced alloys.The solid solubility of Cu in zinc is little under the normal temperature, and Cu can form intermetallic compound ε phase (CuZn 4), this hard second Mass of meeting is distributed in matrix, and is obvious to the strengthening effect of alloy.But when the copper too high levels, the ε phase (CuZn that the crystal boundary place generates 4) cause alloy plasticity sharply to descend too much.Therefore, through a large amount of evidences, in the time of between copper content (massfraction %) fixes on 0.1~5.0%, alloy has higher intensity, and over-all properties is also better.
Mg can solid solution in matrix, but its solid solubility is little, the solid solubility of magnesium only is 0.005% under the room temperature.Solid solution strengthening effect is played in the adding of magnesium, improves alloy strength and creep-resistant property; When Mg content increased, Mg can generate intermetallic compound Cu with Cu 2Mg, disperse is distributed in matrix, can largely improve the intensity of alloy; And magnesium can also prevent intergranular corrosion; But along with Mg content increases, make the flowability of alloy liquid reduce, be unfavorable for the castability of alloy.Therefore the present invention fixes on Mg content (massfraction %) between 0.05~3.0%.
Al can crystal grain thinning, also plays solution strengthening, and tensile strength of alloys and creep strength are obviously improved, and the corrosion resistance nature that improves alloy is also had certain effect.Alloy is in fusion process, and Al can improve the flowability of zinc liquid largely, thereby improves its castability, aluminium can also form one deck compact oxide at molten surface, and the energy slag making, can prevent the alloy liquid oxidation, the castability that improves alloy there is very big benefit.The add-on of Al in the alloy of the present invention (massfraction %) is: 0.1~2.5%.
Ti can generate intermetallic compound TiZn with the zinc reaction 15, be distributed in the crystal boundary place, the intensity that improves alloy there is good supplementary function; In addition, Ti adds as a kind of alterant, mainly is the basic phase of refinement, and improves frangible compounds that impurity and be mingled with the form and the distribution of grade in an imperial examination two-phase improves the over-all properties of alloy.The addition of Ti of the present invention (massfraction %) is: 0.02~0.3%.
In sum, reasonable component formula of the present invention, prepared zinc alloy is the zinc alloy with higher intensity and good over-all properties, and alloy liquid good flowing properties, have advantages of good casting, can be used as structured material and use, be specially adapted to the manufacturing structure part, as fields such as bathroom hot-water heating, five metals and automobile industry's component, be a kind of material that has very much application prospect.
Embodiment
Below in conjunction with specific embodiment 1-10 and Comparative Examples the present invention is described in further detail.
The technological process of production of high-strength deformation zinc alloy is as follows in embodiment of the invention 1-10 and the Comparative Examples:
Starting material are prepared and batching, and------------finished product is checked in hot extrusion---anneal---to the preparation master alloy in the homogenizing processing in founding.
Specifically can be expressed as follows: adopt protective covering method; in medium-frequency induction furnace, carry out melting; copper, magnesium, titanium add with Zn-Cu, Cu-Mg, Zn-Ti master alloy form respectively; zinc, aluminium then add with pure zinc, fine aluminium form respectively; smelting temperature is 620~710 ℃; after treating that the alloy liquation mixes; under 450~500 ℃, be cast into ingot casting; ingot casting is after 360~380 ℃ of homogenizing are handled 6~10h; under 240~310 ℃, be squeezed into pole; extrusion ratio is 10~20, and finished product is checked at last at 170~210 ℃ of annealing 2~4h in the extruding back.Wherein the preparation method of Zn-Ti master alloy is: in medium-frequency induction furnace, the pure Ti that accounts for Zn-Ti master alloy total mass 5~8% is added melting in the Zn liquation, treat that Ti all melts and mixes after, be incubated 25~35 minutes, be cast into ingot casting then.
Embodiment 1
Alloying constituent (weight percent): copper (Cu) 0.1%, magnesium (Mg) 3.0%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg are melt into Zn-Cu, Cu-Mg master alloy respectively; under the insulating covering agent protective condition, after industrial-purity zinc melted fully, again master alloy is added; 620~650 ℃ of smelting temperatures; after treating that alloying element all melts, stirring is removed slag, and is cast into ingot casting then under 450~480 ℃; ingot casting is after 360 ℃ of homogenizing are handled 6h; be squeezed into pole under 240 ℃, extrusion ratio is 20, and at 170 ℃ of annealing 2h.The room temperature tensile strength of present embodiment alloy, yield strength reach 305Mpa respectively, 258Mpa, unit elongation 19.8%.
Embodiment 2
Alloying constituent (weight percent): copper (Cu) 1.58%, magnesium (Mg) 1.2%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg are melt into Zn-Cu, Cu-Mg master alloy respectively; under the insulating covering agent protective condition, after industrial-purity zinc melted fully, again master alloy is added; 650~680 ℃ of smelting temperatures; after treating that alloying element all melts, stirring is removed slag, and is cast into ingot casting then under 460~480 ℃; ingot casting is after 360 ℃ of homogenizing are handled 9h; be squeezed into pole under 280 ℃, extrusion ratio is 15, and at 180 ℃ of annealing 2h.Present embodiment alloy room temperature tensile strength, yield strength reaches 315Mpa respectively, 263Mpa, unit elongation 19.1%.
Embodiment 3
Alloying constituent (weight percent): copper (Cu) 3.2%, magnesium (Mg) 0.8%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg are melt into Zn-Cu, Cu-Mg master alloy respectively; under the insulating covering agent protective condition, after industrial-purity zinc melted fully, again master alloy is added; 670~700 ℃ of smelting temperatures; after treating that alloying element all melts, stirring is removed slag, and is cast into ingot casting then under 480~500 ℃; ingot casting is after 380 ℃ of homogenizing are handled 8h; be squeezed into pole under 300 ℃, extrusion ratio is 12, and at 200 ℃ of annealing 3h.Present embodiment alloy room temperature tensile strength, yield strength reaches 328Mpa respectively, 276Mpa, unit elongation 16.2%.
Embodiment 4
Alloying constituent (weight percent): copper (Cu) 5.0%, magnesium (Mg) 0.05%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg are melt into Zn-Cu, Cu-Mg master alloy respectively; under the insulating covering agent protective condition, after industrial-purity zinc melted fully, again master alloy is added; 680~710 ℃ of smelting temperatures; after treating that alloying element all melts, stirring is removed slag, and is cast into ingot casting then under 480~500 ℃; ingot casting is after 380 ℃ of homogenizing are handled 10h; be squeezed into pole under 310 ℃, extrusion ratio is 10, and at 210 ℃ of annealing 4h.Present embodiment alloy room temperature tensile strength, yield strength reaches 345Mpa respectively, 296Mpa, unit elongation 14.2%.
Embodiment 5
Alloying constituent (weight percent): copper (Cu) 1.65%, magnesium (Mg) 1.08%, aluminium (Al) 0.1%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg are melt into Zn-Cu, Cu-Mg master alloy respectively, under the insulating covering agent protective condition, after industrial-purity zinc melted fully; again master alloy is added; add fine aluminium again, 650~680 ℃ of smelting temperatures treat that alloying element is all after the fusing; stirring is removed slag; be cast into ingot casting then under 460~480 ℃, ingot casting is squeezed into pole under 260 ℃ after 360 ℃ of homogenizing are handled 8h; extrusion ratio is 15, and at 180 ℃ of annealing 3h.Present embodiment alloy room temperature tensile strength, yield strength reaches 335Mpa respectively, 281Mpa, unit elongation 17.6%.
Embodiment 6
Alloying constituent (weight percent): copper (Cu) 1.28%, magnesium (Mg) 1.18%, aluminium (Al) 2.5%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg are melt into Zn-Cu, Cu-Mg master alloy respectively, under the insulating covering agent protective condition, after industrial-purity zinc melted fully; again master alloy is added; add fine aluminium again, 650~680 ℃ of smelting temperatures treat that alloying element is all after the fusing; stirring is removed slag; be cast into ingot casting then under 460~480 ℃, ingot casting is squeezed into pole under 260 ℃ after 360 ℃ of homogenizing are handled 8h; extrusion ratio is 15, and at 180 ℃ of annealing 3h.Present embodiment alloy room temperature tensile strength, yield strength reaches 330Mpa respectively, 276Mpa, unit elongation 18.6%.
Embodiment 7
Alloying constituent (weight percent): copper (Cu) 1.72%, magnesium (Mg) 1.12%, titanium (Ti) 0.3%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg, Ti are melt into Zn-Cu, Cu-Mg, Zn-Ti master alloy respectively; under the insulating covering agent protective condition, after industrial-purity zinc melted fully, again master alloy is added; 670~690 ℃ of smelting temperatures; after treating that alloying element all melts, stirring is removed slag, and is cast into ingot casting then under 480~500 ℃; ingot casting is after 370 ℃ of homogenizing are handled 8h; be squeezed into pole under 280 ℃, extrusion ratio is 15, and at 180 ℃ of annealing 3h.Present embodiment alloy room temperature tensile strength, yield strength reaches 328Mpa respectively, 276Mpa, unit elongation 18.8%.
Embodiment 8
Alloying constituent (weight percent): copper (Cu) 1.22%, magnesium (Mg) 1.02%, titanium (Ti) 0.02%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg, Ti are melt into Zn-Cu, Cu-Mg, Zn-Ti master alloy respectively; under the insulating covering agent protective condition, after industrial-purity zinc melted fully, again master alloy is added; 650~680 ℃ of smelting temperatures; after treating that alloying element all melts, stirring is removed slag, and is cast into ingot casting then under 450~470 ℃; ingot casting is after 360 ℃ of homogenizing are handled 10h; be squeezed into pole under 260 ℃, extrusion ratio is 18, and at 180 ℃ of annealing 3h.Present embodiment alloy room temperature tensile strength, yield strength reaches 312Mpa respectively, 260Mpa, unit elongation 21.8%.
Embodiment 9
Alloying constituent (weight percent): copper (Cu) 1.35%, magnesium (Mg) 1.15%, aluminium (Al) 2.15%, titanium (Ti) 0.12%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg, Ti are melt into Zn-Cu, Cu-Mg, Zn-Ti master alloy respectively, under the insulating covering agent protective condition, after industrial-purity zinc melted fully; again master alloy is added; add fine aluminium again, 660~680 ℃ of smelting temperatures treat that alloying element is all after the fusing; stirring is removed slag; be cast into ingot casting then under 460~480 ℃, ingot casting is squeezed into pole under 280 ℃ after 370 ℃ of homogenizing are handled 8h; extrusion ratio is 12, and at 180 ℃ of annealing 3h.Present embodiment alloy room temperature tensile strength, yield strength reaches 342Mpa respectively, 293Mpa, unit elongation 16.8%.
Embodiment 10
Alloying constituent (weight percent): copper (Cu) 1.4%, magnesium (Mg) 1.22%, aluminium (Al) 1.12%, titanium (Ti) 0.25%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Mg, Ti are melt into Zn-Cu, Cu-Mg, Zn-Ti master alloy respectively, under the insulating covering agent protective condition, after industrial-purity zinc melted fully; again master alloy is added; add fine aluminium again, 650~680 ℃ of smelting temperatures treat that alloying element is all after the fusing; stirring is removed slag; be cast into ingot casting then under 460~480 ℃, ingot casting is squeezed into pole under 280 ℃ after 380 ℃ of homogenizing are handled 8h; extrusion ratio is 10, and at 180 ℃ of annealing 3h.Present embodiment alloy room temperature tensile strength, yield strength reaches 332Mpa respectively, 281Mpa, unit elongation 17.4%.
Comparative Examples
Alloying constituent (weight percent): copper (Cu) 1.8%, aluminium (Al) 1.22%, titanium (Ti) 0.15%, all the other are that zinc (Zn) and total amount are not more than 0.05% impurity.
At first Cu, Ti are melt into Zn-Cu, Zn-Ti master alloy respectively, under the insulating covering agent protective condition, after industrial-purity zinc melted fully; again master alloy is added; add fine aluminium again, 680~700 ℃ of smelting temperatures treat that alloying element is all after the fusing; stirring is removed slag; be cast into ingot casting then under 480~500 ℃, ingot casting is squeezed into pole under 300 ℃ after 380 ℃ of homogenizing are handled 10h; extrusion ratio is 12, and at 200 ℃ of annealing 3h.Comparative Examples alloy room temperature tensile strength, yield strength reaches 282Mpa respectively, 231Mpa, unit elongation 19.4%.
Relatively embodiment of the invention 1-10 and Comparative Examples alloy property detected result, as can be seen, the present invention contain Mg the high-strength deformation platina have higher intensity and over-all properties.This shows reasonable component formula of the present invention, prepared zinc alloy is the zinc alloy with higher intensity and good over-all properties, can be used as structured material uses, be specially adapted to the manufacturing structure part, as fields such as bathroom hot-water heating, five metals and automobile industry's component, be a kind of material that has very much application prospect.

Claims (7)

1. high-strength deformation platina that contains Mg, form by following component by mass percentage:
Copper 0.1~5.0%;
Magnesium 0.05~3.0%;
All the other are zinc and unavoidable impurities, and total impurities is not more than 0.05%.
2. a kind of high-strength deformation platina that contains Mg according to claim 1, form by following component by mass percentage:
Copper 0.1~5.0%;
Magnesium 0.05~3.0%;
And at least a in the aluminium, two kinds of elements of titanium, the content of described aluminium, titanium is respectively: aluminium 0.1~2.5%, titanium 0.02~0.3%;
All the other are zinc and unavoidable impurities, and total impurities is not more than 0.05%.
3. a kind of high-strength deformation platina that contains Mg according to claim 1, form by following component by mass percentage:
Copper 0.5~4.5%;
Magnesium 0.1~2.7%;
All the other are zinc and unavoidable impurities, and total impurities is not more than 0.05%.
4. a kind of high-strength deformation platina that contains Mg according to claim 2, form by following component by mass percentage:
Copper 0.5~4.5%;
Magnesium 0.1~2.7%;
And at least a in the aluminium, two kinds of elements of titanium, the content of described aluminium, titanium is respectively: aluminium 0.2~2.2%, titanium 0.05~0.25%;
All the other are zinc and unavoidable impurities, and total impurities is not more than 0.05%.
5. prepare the method for the high-strength deformation platina of a kind of Mg of containing as claimed in claim 1 or 2, comprise the steps:
(1) alloy adopts the covering protection method to carry out melting, copper, magnesium, titanium add with Zn-Cu, Cu-Mg, Zn-Ti master alloy form respectively, zinc, aluminium then add with pure zinc, fine aluminium form respectively, smelting temperature is 620~710 ℃, after treating that the alloy liquation mixes, under 450~500 ℃, be cast as the zinc alloy ingot casting;
(2) ingot casting is after 360~380 ℃ of homogenizing are handled 6~10h, and at 240~310 ℃ of extrusion moldings, extrusion ratio is 10~20;
(3) after the extruding, at 170~210 ℃ of annealing 2~4h.
6. a kind of preparation method who contains the high-strength deformation platina of Mg according to claim 5, it is characterized in that: described Zn-Ti master alloy is that the pure Ti that will account for Zn-Ti master alloy total mass 5~8% adds melting in the Zn liquation, after treating that Ti all melts and mixes, be incubated 25~35 minutes, be cast into ingot casting then.
7. according to right 5 or 6 described a kind of preparation methods that contain the high-strength deformation platina of Mg, it is characterized in that: described melting is to carry out in medium-frequency induction furnace.
CN 201010245585 2010-08-05 2010-08-05 Mg-containing high-strength deforming zinc-copper alloy and preparation method thereof Pending CN101906554A (en)

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CN102061409A (en) * 2011-01-26 2011-05-18 长安大学 Novel zinc alloy ingot and preparation method thereof
CN102808116A (en) * 2012-06-08 2012-12-05 常州大学 Method for preparing high-performance die casting zinc alloys
CN103614591A (en) * 2013-10-21 2014-03-05 宁波市鄞州诚裕五金厂 Copper material and preparation method thereof
CN103789574A (en) * 2014-01-25 2014-05-14 宁波博威合金材料股份有限公司 Low-copper alloy, and production method and use thereof
WO2015192279A1 (en) * 2014-06-17 2015-12-23 宁波博威合金材料股份有限公司 High-strength creep-resistant low-copper alloy material and application thereof
CN105950913A (en) * 2016-07-15 2016-09-21 河南科技大学 High-strength high-plasticity Zn-Cu-Ti alloy and preparation method thereof
CN106702212A (en) * 2015-11-16 2017-05-24 上海交通大学 Medical degradable Zn-Cu-X alloy material and preparation method thereof
CN107794409A (en) * 2017-10-09 2018-03-13 广州番禺于金属加工有限公司 A kind of kirsite and preparation method thereof and automobile fuse
CN108950259A (en) * 2018-08-02 2018-12-07 济南大学 A kind of metamorphism treatment method of zinc-copper alloy
CN111778428A (en) * 2020-07-16 2020-10-16 扬州大学 Mg-Zn-Sr nanocrystalline and preparation method thereof
CN114293039A (en) * 2021-12-27 2022-04-08 江苏中矿大正表面工程技术有限公司 Preparation method of Zn-Cu-Ti-Mg alloy for thermal spraying

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102061409A (en) * 2011-01-26 2011-05-18 长安大学 Novel zinc alloy ingot and preparation method thereof
CN102808116A (en) * 2012-06-08 2012-12-05 常州大学 Method for preparing high-performance die casting zinc alloys
CN103614591A (en) * 2013-10-21 2014-03-05 宁波市鄞州诚裕五金厂 Copper material and preparation method thereof
CN103789574A (en) * 2014-01-25 2014-05-14 宁波博威合金材料股份有限公司 Low-copper alloy, and production method and use thereof
WO2015192279A1 (en) * 2014-06-17 2015-12-23 宁波博威合金材料股份有限公司 High-strength creep-resistant low-copper alloy material and application thereof
CN106702212A (en) * 2015-11-16 2017-05-24 上海交通大学 Medical degradable Zn-Cu-X alloy material and preparation method thereof
CN105950913A (en) * 2016-07-15 2016-09-21 河南科技大学 High-strength high-plasticity Zn-Cu-Ti alloy and preparation method thereof
CN107794409A (en) * 2017-10-09 2018-03-13 广州番禺于金属加工有限公司 A kind of kirsite and preparation method thereof and automobile fuse
CN108950259A (en) * 2018-08-02 2018-12-07 济南大学 A kind of metamorphism treatment method of zinc-copper alloy
CN108950259B (en) * 2018-08-02 2020-12-29 济南大学 Modification treatment method of zinc-copper alloy
CN111778428A (en) * 2020-07-16 2020-10-16 扬州大学 Mg-Zn-Sr nanocrystalline and preparation method thereof
CN111778428B (en) * 2020-07-16 2022-01-28 扬州大学 Mg-Zn-Sr nanocrystalline and preparation method thereof
CN114293039A (en) * 2021-12-27 2022-04-08 江苏中矿大正表面工程技术有限公司 Preparation method of Zn-Cu-Ti-Mg alloy for thermal spraying
CN114293039B (en) * 2021-12-27 2022-07-12 江苏中矿大正表面工程技术有限公司 Preparation method of Zn-Cu-Ti-Mg alloy for thermal spraying

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