CN105174864A - Weatherability polymer emulsion cement mortar and preparation method thereof - Google Patents

Weatherability polymer emulsion cement mortar and preparation method thereof Download PDF

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Publication number
CN105174864A
CN105174864A CN201510520856.6A CN201510520856A CN105174864A CN 105174864 A CN105174864 A CN 105174864A CN 201510520856 A CN201510520856 A CN 201510520856A CN 105174864 A CN105174864 A CN 105174864A
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polymer emulsion
sand
weather resistant
cement slurry
resistant polymer
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CN105174864B (en
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荀武举
吴长龙
李林
李杨
辛德胜
王岳华
王跃松
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Dalian Research & Design Institute Of Building Science Stock Co ltd
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Dalian Building Science Research & Design Institute Co Ltd
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Abstract

The invention discloses a weatherability polymer emulsion cement mortar and a preparation method thereof, and relates to the technical field of chemical construction materials. The cement mortar is composed of the following components in percentage by weight: 25 to 35% of cement, 50 to 60% of quartz sand, 0.04 to 0.2% of water retaining agent, 0.055 to 0.15% of antifoaming agent, 0.05 to 0.3% of water reducer, 5 to 10% of polymer emulsion, and 6 to 10% of water. The preparation method of the cement mortar is simple, has a low cost, can improve the construction performance and anti-shrinking performance of mortar, and enhances the binding strength and weatherability of mortar. The cement mortar can be used to repair buildings or directly used to build special buildings such as subway, reservoir, basement, and the like, can prolong the service life of buildings, and reduces the construction cost and environment pollution.

Description

A kind of weather resistant polymer emulsion sand-cement slurry and preparation method thereof
Technical field
The present invention relates to a kind of mortar for building, particularly relate to a kind of weather resistant polymer emulsion sand-cement slurry and preparation method thereof.
Background technology
Along with the sustainable development of concrete technology and improving constantly of China's Technological Economy demand, concrete is widely applied in the modernization project construction such as harbour, dam, bridge, airport, municipal administration, motorway and high-speed railway, but, because the Concrete Structure Design is unreasonable, construction existing defects, and the reason such as environmental attack, maintenance be improper, the industry that China builds in early days and covil construction have to be badly in need of reinforcing and keeping in repair greatly, and damage in various degree has also appearred in construction work newly-built even in recent years.
Can predict, from now on quite over a long time in, China's building trade is main to repair and renovation Infrastructure is main strategic change by completing by newly-built Infrastructure.This strategic change, the investigation and application for patching material provides wide space, brings stern challenge especially.
Existing patching material can be divided into mineral-type, organic and organically-modified class by composition, and wherein mineral-type patching material exists the problems such as cohesive strength is low, shrinking percentage is large, and organic patching material is then poor with cement concrete substrate compatibility, and cost is too high.Organically-modified class patching material uses the polymkeric substance such as redispersable latex powder, aqueous polyvinyl acetate emulsion, epoxy emulsion to carry out modification mostly, there is the shortcomings such as cost is higher, shrinking percentage is large.
Summary of the invention
In order to overcome above-mentioned defect, the invention provides that a kind of technique is simple, cost is low, the polymer emulsion sand-cement slurry of excellent performance and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: a kind of weather resistant polymer emulsion sand-cement slurry, by mass percentage, is obtained by following raw materials according:
Described polymer emulsion is at least one in benzene emulsion and styrene-butadiene emulsion; Described benzene emulsion is purchased from Beijing Orient Yong Yu high molecular products company limited.
The present invention adopts at least one in benzene emulsion and styrene-butadiene emulsion to carry out modification as polymer emulsion to mortar, and the polymer emulsion sand-cement slurry of preparation has the advantages that shrinking percentage is little, cohesive strength is high, pressure-proof and snap-resistent intensity is high.
Preferred described cement is at least one in 42.5 grades of silicate cements and aluminosulfate cement.
Preferred described quartz sand is 20-140 object quartz sand.
Preferred described water-holding agent is Vltra tears.
Described defoamer can be at least one in liquid antifoam agent and solid defoamer; Described solid defoamer is P803; Liquid antifoam agent is at least one in NXZ and F111.
Preferred described defoamer is made up of solid defoamer and liquid antifoam agent, as further preferred version, in described weather resistant polymer emulsion sand-cement slurry, the content of solid defoamer is 0.05% ~ 0.1%, the content 0.005% ~ 0.05% of liquid antifoam agent, can improve workability and the ultimate compression strength of mortar like this.
Preferred described water reducer is at least one in polycarboxylate water-reducer and melamine water reducer.
In preferred described weather resistant polymer emulsion sand-cement slurry, polymer cement ratio (quality of quality × 0.48/ cement of polymer emulsion) is 8-16%.Can obtain toughness so stronger, shrinking percentage is lower, the mortar that cohesive strength is higher.
The present invention also provides a kind of preparation method of weather resistant polymer emulsion sand-cement slurry: cement, quartz sand, water-holding agent, solid defoamer, water reducer are dropped into mortar mixer successively, mixes, obtain premix powders; Polymer emulsion, liquid antifoam agent, water are dropped into stirrer successively, mixes, obtain premix liquid material; In premix powders, slowly add premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry.
Beneficial effect of the present invention is as follows:
1. the present invention uses benzene emulsion and styrene-butadiene emulsion to prepare mortar, reduces the shrinking percentage of mortar, improves cohesive strength, the folding strength of mortar.
2. defoamer of the present invention is made up of solid defoamer and liquid antifoam agent, and the synergy of solid defoamer and liquid antifoam agent makes prepared mortar have better workability and ultimate compression strength.
3. in polymer emulsion sand-cement slurry, polymer cement ratio is 8-16%.Can obtain toughness so stronger, shrinking percentage is lower, the mortar that cohesive strength is higher.
4. the preparation method of this weather resistant polymer emulsion sand-cement slurry is simple, cost is low, and the mortar of preparation can use immediately.
5. the present invention is to raising construction quality and work-ing life, reduce engineering cost, reduce the aspects such as environmental pollution significant, can be used for the repairing work of buildings or directly apply to particular requirement construction work (as subway, reservoir, vault etc.).
Embodiment
Comparative example 1
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g polyvinyl acetate emulsion, 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9g premix powders is put into mortar mixer, start to stir, slowly add 330.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry D-1.
Comparative example 2
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g formaldehyde polyvinyl acetal, 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9g premix powders is put into mortar mixer, start to stir, slowly add 330.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry D-2.
Embodiment 1
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9g premix powders is put into mortar mixer, start to stir, slowly add 330.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-1.
Embodiment 2
700g silicate cement, 1300g quartz sand (20-140 order), 1g Vltra tears, 1.5 grams of solid defoamer P803,1.4g polycarboxylate water-reducers are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.25g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2003.9 grams of premix powders are put into mortar mixer, start to stir, slowly add 330.25 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-2.
Embodiment 3
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5 grams of solid defoamer P803,1.4g polycarboxylate water-reducers are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 1.0g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9 grams of premix powders are put into mortar mixer, start to stir, slowly add 331.0 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-3.
Embodiment 4
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 2.6 grams of solid defoamer P803,1.4g polycarboxylate water-reducers are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.25g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2006.0 grams of premix powders are put into mortar mixer, start to stir, slowly add 330.25 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-4.
Embodiment 5
665g silicate cement, 35 grams of aluminosulfate cements, 1300g quartz sand (20-140 order), 3g Vltra tears, 2.6 grams of solid defoamer P803,1.4g polycarboxylate water-reducers are dropped into mortar mixer successively, mix through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.25g liquid antifoam agent NXZ, 220g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2007.0 grams of premix powders are put into mortar mixer, start to stir, slowly add 340.25 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-5.
Embodiment 6
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5 grams of solid defoamer P803,1.4g polycarboxylate water-reducers are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g styrene-butadiene emulsion (solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9 grams of premix powders are put into mortar mixer, start to stir, slowly add 330.5 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-6.
Embodiment 7
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5 grams of solid defoamer P803,1.4g polycarboxylate water-reducers are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 140g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 200g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9 grams of premix powders are put into mortar mixer, start to stir, slowly add 340.5 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-7.
Embodiment 8
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5 grams of solid defoamer P803,7.0g melamine water reducers are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2010.5 grams of premix powders are put into mortar mixer, start to stir, slowly add 330.5 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-8.
Embodiment 9
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5 grams of solid defoamer P803,1.4g polycarboxylate water-reducers are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent F111,210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9 grams of premix powders are put into mortar mixer, start to stir, slowly add 330.5 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-9.
Embodiment 10
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5 grams of solid defoamer P803,1.4g polycarboxylate water-reducers are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 140g styrene-butadiene emulsion (solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9 grams of premix powders are put into mortar mixer, start to stir, slowly add 350.5 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion sand-cement slurry S-10.
Embodiment 11
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 225g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 200g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9g premix powders is put into mortar mixer, start to stir, slowly add 425.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-11.
Embodiment 12
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 2g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2003.4g premix powders is put into mortar mixer, start to stir, slowly add 332g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-12.
Embodiment 13
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 2g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2005.4g premix powders is put into mortar mixer, start to stir, slowly add 330g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-13.
Embodiment 14
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 1.28g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2003.4g premix powders is put into mortar mixer, start to stir, slowly add 330.28g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-14.
Embodiment 15
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 3.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2006.9g premix powders is put into mortar mixer, start to stir, slowly add 330g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-15.
Embodiment 16
545g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 1849.9g premix powders is put into mortar mixer, start to stir, slowly add 330.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-16.
Embodiment 17
880g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2184.9g premix powders is put into mortar mixer, start to stir, slowly add 330.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-17.
Embodiment 18
700g silicate cement, 1035g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 1739.9g premix powders is put into mortar mixer, start to stir, slowly add 330.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-18.
Embodiment 19
700g silicate cement, 1552g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2256.9g premix powders is put into mortar mixer, start to stir, slowly add 330.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-19.
Embodiment 20
700g silicate cement, 1300g quartz sand (20-140 order), 2g Vltra tears, 1.5g solid defoamer P803,1.4g polycarboxylate water-reducer are dropped into mortar mixer successively, mixes through stirrer, obtain premix powders; Then 120g benzene emulsion (purchased from Beijing Orient Yong Yu high molecular products company limited, solid content 48%), 0.5g liquid antifoam agent NXZ, 140g water are dropped into stirrer successively, mix through stirrer, obtain premix liquid material; Finally 2004.9g premix powders is put into mortar mixer, start to stir, slowly add 330.5g premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry S-20.
Weather resistant polymer emulsion sand-cement slurry prepared by above example and both at home and abroad product mortar performance correlation data are in table 1.
Table 1 mortar performance correlation data
Product gets 2Kg respectively
As can be seen from Table I, weather resistant polymer emulsion sand-cement slurry of the present invention all has excellent workability, cohesive strength, low-shrinkage and higher ultimate compression strength, folding strength, and effect is suitable with external product effect, excellent combination property.

Claims (10)

1. a weather resistant polymer emulsion sand-cement slurry, by mass percentage, is obtained by following raw materials according:
Described polymer emulsion is at least one in benzene emulsion and styrene-butadiene emulsion.
2. weather resistant polymer emulsion sand-cement slurry according to claim 1, is characterized in that: described cement is at least one in 42.5 grades of silicate cements and aluminosulfate cement.
3. weather resistant polymer emulsion sand-cement slurry according to claim 1, is characterized in that: described quartz sand is 20-140 object quartz sand.
4. weather resistant polymer emulsion sand-cement slurry according to claim 1, is characterized in that: described water-holding agent is Vltra tears.
5. weather resistant polymer emulsion sand-cement slurry according to claim 1, is characterized in that: defoamer is at least one in liquid antifoam agent and solid defoamer; Described solid defoamer is P803; Liquid antifoam agent is at least one in NXZ and F111.
6. weather resistant polymer emulsion sand-cement slurry according to claim 5, is characterized in that: described defoamer is made up of solid defoamer and liquid antifoam agent.
7. weather resistant polymer emulsion sand-cement slurry according to claim 6; It is characterized in that: wherein the content of solid defoamer is 0.05% ~ 0.1%, the content of liquid antifoam agent is 0.005% ~ 0.05%.
8. weather resistant polymer emulsion sand-cement slurry according to claim 1; It is characterized in that: described water reducer is at least one in polycarboxylate water-reducer and melamine water reducer.
9. weather resistant polymer emulsion sand-cement slurry according to claim 1, is characterized in that: polymer cement ratio is 8-16%.
10. the preparation method of the weather resistant polymer emulsion sand-cement slurry described in claim 6 or 7, is characterized in that cement, quartz sand, water-holding agent, solid defoamer, water reducer to drop into mortar mixer successively, mixes, obtain premix powders; Polymer emulsion, liquid antifoam agent, water are dropped into stirrer successively, mixes, obtain premix liquid material; In premix powders, slowly add premix liquid material, stir, obtain weather resistant polymer emulsion sand-cement slurry.
CN201510520856.6A 2015-08-21 2015-08-21 A kind of weather resistant polymer emulsion cement mortar and preparation method thereof Expired - Fee Related CN105174864B (en)

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Publication number Priority date Publication date Assignee Title
CN105837133A (en) * 2016-05-19 2016-08-10 李金平 Cement mortar for color pavement
CN106336177A (en) * 2016-08-22 2017-01-18 北京中德新亚建筑技术有限公司 Two-component polymer shield tunneling segment repair agent
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CN108569867A (en) * 2018-06-04 2018-09-25 盐城工学院 Modified cement mortar patching material
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CN110590281A (en) * 2019-09-25 2019-12-20 湖州乌米科技有限公司 Concrete suitable for underground engineering

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