CN105174864B - A kind of weather resistant polymer emulsion cement mortar and preparation method thereof - Google Patents

A kind of weather resistant polymer emulsion cement mortar and preparation method thereof Download PDF

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Publication number
CN105174864B
CN105174864B CN201510520856.6A CN201510520856A CN105174864B CN 105174864 B CN105174864 B CN 105174864B CN 201510520856 A CN201510520856 A CN 201510520856A CN 105174864 B CN105174864 B CN 105174864B
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polymer emulsion
weather resistant
cement mortar
mortar
water
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CN105174864A (en
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荀武举
吴长龙
李林
李杨
辛德胜
王岳华
王跃松
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Dalian Research & Design Institute Of Building Science Stock Co ltd
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Dalian Building Science Research & Design Institute Co Ltd
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Abstract

The invention discloses a kind of weather resistant polymer emulsion cement mortar and preparation method thereof, is related to chemical building material technical field, and weather resistant polymer emulsion cement mortar of the invention is made up of following component by mass percentage:Cement 25%~35%, quartz sand 50%~60%, water-loss reducer 0.04%~0.2%, defoamer 0.055%~0.15%, water reducer 0.05%~0.3%, polymer emulsion 5%~10% and water 6%~10%.The preparation method of the polymer emulsion cement mortar is simple, cost is low, and improve the workability and anti-contracility energy of mortar, improve the adhesion strength and weatherability of mortar, available for building repairing work or directly apply to particular/special requirement architectural engineering (such as subway, reservoir, basement), to extending building service life, construction cost is reduced, reduce environmental pollution etc. is significant.

Description

A kind of weather resistant polymer emulsion cement mortar and preparation method thereof
Technical field
The present invention relates to a kind of mortar for building, more particularly to a kind of weather resistant polymer emulsion cement mortar and its preparation Method.
Background technology
With the sustainable development of concrete technology and the continuous improvement of China's Technological Economy demand, concrete harbour, It is widely applied in the modernization project construction such as dam, bridge, airport, municipal administration, highway and high-speed railway, however, Because the Concrete Structure Design is unreasonable, construction existing defects, and environmental attack, the reason such as improper is safeguarded, China is repaiied early stage Industry and the civil buildings built, which have, is greatly badly in need of reinforcing and maintenance, or even architectural engineering newly-built in recent years also occurs Different degrees of damage.
It is contemplated that within suitable long-term from now on, China's building trade will complete from based on newly-built infrastructure to repairing Mend and renovate the strategic change based on infrastructure.This strategic change, research and application for patching material provide Wide space, even more brings stern challenge.
Existing patching material can be divided into inorganic, organic and organically-modified class, wherein inorganic repairing material by composition There is the problems such as adhesion strength is low, shrinkage factor is big in material, and organic patching material is then poor with cement concrete substrate compatibility, and And cost is too high.Organically-modified class patching material is mostly using redispersable latex powder, polyvinyl acetate emulsion, epoxy emulsion It is modified Deng polymer, the shortcomings of cost is higher, shrinkage factor is big is present.
The content of the invention
In order to overcome drawbacks described above, a kind of technique of present invention offer is simple, cost is low, the polymer emulsion water of excellent performance Cement mortar and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is:A kind of weather resistant polymer emulsion cement mortar, By mass percentage, it is made by following raw materials according:
The polymer emulsion is at least one of styrene-acrylic emulsion and styrene-butadiene emulsion;The styrene-acrylic emulsion is purchased from Bei Jingdong Fang Yongyu high molecular products Co., Ltd.
The present invention is modified using at least one of styrene-acrylic emulsion and styrene-butadiene emulsion as polymer emulsion to mortar, The polymer emulsion cement mortar of preparation has the characteristics of shrinkage factor is small, adhesion strength is high, pressure-proof and snap-resistent intensity is high.
It is preferred that the cement is at least one of 42.5 grades of portland cements and sulphate aluminium cement.
It is preferred that the quartz sand is the quartz sand of 20-140 mesh.
It is preferred that the water-loss reducer is hydroxypropyl methyl cellulose.
The defoamer can be at least one of liquid antifoam agent and solid defoaming agent;The solid defoaming agent is P803;Liquid antifoam agent is at least one of NXZ and F111.
It is preferred that the defoamer is made up of solid defoaming agent and liquid antifoam agent, it is described as further preferred scheme The content of solid defoaming agent is 0.05%~0.1% in weather resistant polymer emulsion cement mortar, the content of liquid antifoam agent 0.005%~0.05%, it can so improve the workability and compression strength of mortar.
It is preferred that the water reducer is at least one of polycarboxylate water-reducer and melamine water reducer.
(the cement of the quality of polymer emulsion × 0.48/ it is preferred that polymer cement ratio in the weather resistant polymer emulsion cement mortar Quality) be 8-16%.It can so obtain that toughness is stronger, and shrinkage factor is lower, the higher mortar of adhesion strength.
The present invention also provides a kind of preparation method of weather resistant polymer emulsion cement mortar:By cement, quartz sand, water conservation Agent, solid defoaming agent, water reducer put into mortar mixer successively, are well mixed, obtain premix powders;By polymer emulsion, liquid Body defoamer, water put into mixer successively, are well mixed, and obtain premixing liquid material;It is slowly added to premix liquid material in premix powders, Stir, obtain weather resistant polymer emulsion cement mortar.
Beneficial effects of the present invention are as follows:
1. the present invention prepares mortar using styrene-acrylic emulsion and styrene-butadiene emulsion, reduce the shrinkage factor of mortar, improve mortar Adhesion strength, rupture strength.
2. defoamer of the present invention is made up of solid defoaming agent and liquid antifoam agent, the association of solid defoaming agent and liquid antifoam agent Same-action makes prepared mortar have more preferable workability and compression strength.
3. polymer cement ratio is 8-16% in polymer emulsion cement mortar.It can so obtain that toughness is stronger, and shrinkage factor is lower, The higher mortar of adhesion strength.
4. the preparation method of the weather resistant polymer emulsion cement mortar is simple, cost is low, and the mortar prepared can be When use.
5. the present invention reduces engineering cost, reduce environmental pollution etc. has to improving construction quality and service life Significance, available for building repairing work or directly apply to particular/special requirement architectural engineering (such as subway, reservoir, underground Room etc.).
Embodiment
Comparative example 1
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g polyvinyl acetate emulsions, 0.5g liquid antifoam agent NXZ, 210g water are put into mixer successively afterwards, agitated machine mixing is equal It is even, obtain premixing liquid material;Finally 2004.9g premix powders are put into mortar mixer, starts to stir, is slowly added to 330.5g Liquid material is premixed, stirs, obtains weather resistant polymer emulsion cement mortar D-1.
Comparative example 2
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g formaldehyde polyvinyl acetals, 0.5g liquid antifoam agent NXZ, 210g water are put into mixer, agitated machine mixing successively afterwards Uniformly, obtain premixing liquid material;Finally 2004.9g premix powders are put into mortar mixer, starts to stir, is slowly added to 330.5g premixes liquid material, stirs, obtains weather resistant polymer emulsion cement mortar D-2.
Embodiment 1
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent NXZ, 210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2004.9g premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 330.5g premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-1.
Embodiment 2
700g portland cements, 1300g quartz sands (20-140 mesh), 1g hydroxypropyl methyl celluloses, 1.5 grams of solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.25g liquid are defoamed afterwards Agent NXZ, 210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2003.9 grams of premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 330.25 grams of premix liquid materials, is stirred, obtain weather resistant Polymer emulsion cement mortar S-2.
Embodiment 3
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5 grams of solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 1.0g liquid are defoamed afterwards Agent NXZ, 210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2004.9 grams of premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 331.0 grams of premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-3.
Embodiment 4
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 2.6 grams of solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.25g liquid are defoamed afterwards Agent NXZ, 210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2006.0 grams of premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 330.25 grams of premix liquid materials, is stirred, obtain weather resistant Polymer emulsion cement mortar S-4.
Embodiment 5
By 665g portland cements, 35 grams of sulphate aluminium cements, 1300g quartz sands (20-140 mesh), 3g hydroxypropyl methyls Cellulose, 2.6 grams of solid defoaming agent P803,1.4g polycarboxylate water-reducers put into mortar mixer successively, and agitated machine mixing is equal It is even, obtain premix powders;Then 120g styrene-acrylic emulsions (are purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.25g liquid antifoam agents NXZ, 220g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material; Finally 2007.0 grams of premix powders are put into mortar mixer, start to stir, are slowly added to 340.25 grams of premix liquid materials, fully Stir, obtain weather resistant polymer emulsion cement mortar S-5.
Embodiment 6
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5 grams of solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-butadiene emulsions (solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are put into mixer, agitated machine successively afterwards It is well mixed, obtain premixing liquid material;Finally 2004.9 grams of premix powders are put into mortar mixer, start to stir, are slowly added Enter 330.5 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion cement mortar S-6.
Embodiment 7
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5 grams of solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 140g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent NXZ, 200g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2004.9 grams of premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 340.5 grams of premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-7.
Embodiment 8
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5 grams of solids are disappeared Infusion P803,7.0g melamine water reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;Then By 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid antifoam agents NXZ, 210g water put into mixer successively, and agitated machine is well mixed, and obtain premixing liquid material;Finally by 2010.5 grams of premix powders It is put into mortar mixer, starts to stir, is slowly added to 330.5 grams of premix liquid materials, stirs, obtain weather resistant polymerization Thing emulsion cement mortar S-8.
Embodiment 9
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5 grams of solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent F111,210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2004.9 grams of premixs Powder is put into mortar mixer, starts to stir, and is slowly added to 330.5 grams of premix liquid materials, is stirred, obtain weather resistant Polymer emulsion cement mortar S-9.
Embodiment 10
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5 grams of solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 140g styrene-butadiene emulsions (solid content 48%), 0.5g liquid antifoam agent NXZ, 210g water are put into mixer, agitated machine successively afterwards It is well mixed, obtain premixing liquid material;Finally 2004.9 grams of premix powders are put into mortar mixer, start to stir, are slowly added Enter 350.5 grams of premix liquid materials, stir, obtain weather resistant polymer emulsion cement mortar S-10.
Embodiment 11
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 225g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent NXZ, 200g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2004.9g premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 425.5g premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-11.
Embodiment 12
By 700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.4g polycarboxylic acids Water reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;Then by the (purchase of 120g styrene-acrylic emulsions From Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 2g liquid antifoam agent NXZ, 210g water puts into stir successively Machine is mixed, agitated machine is well mixed, and obtains premixing liquid material;Finally 2003.4g premix powders are put into mortar mixer, started Stirring, 332g premix liquid materials are slowly added to, stirs, obtains weather resistant polymer emulsion cement mortar S-12.
Embodiment 13
By 700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 2g solid defoamings Agent P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;Then 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 210g water are put into successively Mixer, agitated machine are well mixed, and obtain premixing liquid material;Finally 2005.4g premix powders are put into mortar mixer, opened Begin to stir, be slowly added to 330g premix liquid materials, stir, obtain weather resistant polymer emulsion cement mortar S-13.
Embodiment 14
By 700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.4g polycarboxylic acids Water reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;Then by the (purchase of 120g styrene-acrylic emulsions From Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 1.28g liquid antifoam agent NXZ, 210g water throws successively Enter mixer, agitated machine is well mixed, and obtains premixing liquid material;Finally 2003.4g premix powders are put into mortar mixer, Start to stir, be slowly added to 330.28g premix liquid materials, stir, obtain weather resistant polymer emulsion cement mortar S- 14。
Embodiment 15
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 3.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 210g water are thrown successively afterwards Enter mixer, agitated machine is well mixed, and obtains premixing liquid material;Finally 2006.9g premix powders are put into mortar mixer, Start to stir, be slowly added to 330g premix liquid materials, stir, obtain weather resistant polymer emulsion cement mortar S-15.
Embodiment 16
545g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent NXZ, 210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 1849.9g premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 330.5g premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-16.
Embodiment 17
880g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent NXZ, 210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2184.9g premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 330.5g premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-17.
Embodiment 18
700g portland cements, 1035g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent NXZ, 210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 1739.9g premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 330.5g premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-18.
Embodiment 19
700g portland cements, 1552g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent NXZ, 210g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2256.9g premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 330.5g premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-19.
Embodiment 20
700g portland cements, 1300g quartz sands (20-140 mesh), 2g hydroxypropyl methyl celluloses, 1.5g solids are disappeared Infusion P803,1.4g polycarboxylate water-reducer puts into mortar mixer successively, and agitated machine is well mixed, and obtains premix powders;So 120g styrene-acrylic emulsions (being purchased from Beijing Orient Yong Yu high molecular products Co., Ltd, solid content 48%), 0.5g liquid are defoamed afterwards Agent NXZ, 140g water puts into mixer successively, and agitated machine is well mixed, and obtains premixing liquid material;Finally by 2004.9g premixing flours Material is put into mortar mixer, starts to stir, and is slowly added to 330.5g premix liquid materials, is stirred, obtain weather resistant and gather Compound emulsion cement mortar S-20.
Weather resistant polymer emulsion cement mortar and domestic and international product mortar performance correction data prepared by above example is shown in Table 1.
The mortar performance correction data of table 1
Product takes 2Kg respectively
As can be seen from Table I, weather resistant polymer emulsion cement mortar of the present invention all has excellent workability, bonding Intensity, low-shrinkage and higher compression strength, rupture strength, effect is suitable with external product effect, excellent combination property.

Claims (6)

1. a kind of weather resistant polymer emulsion cement mortar, by mass percentage, is made by following raw materials according:
The polymer emulsion is at least one of styrene-acrylic emulsion and styrene-butadiene emulsion, polymer cement ratio 8-16%, the defoamer It is made up of solid defoaming agent and liquid antifoam agent, the solid defoaming agent is P803;Liquid antifoam agent be NXZ and F111 in extremely Few one kind;Wherein the content of solid defoaming agent is 0.05%~0.1%, and the content of liquid antifoam agent is 0.005%~0.05%.
2. weather resistant polymer emulsion cement mortar according to claim 1, it is characterised in that:The cement is 42.5 grades Portland cement.
3. weather resistant polymer emulsion cement mortar according to claim 1, it is characterised in that:The quartz sand is 20- The quartz sand of 140 mesh.
4. weather resistant polymer emulsion cement mortar according to claim 1, it is characterised in that:The water-loss reducer is hydroxypropyl Ylmethyl cellulose.
5. weather resistant polymer emulsion cement mortar according to claim 1;It is characterized in that:The water reducer is poly- carboxylic At least one of sour water reducer and melamine water reducer.
6. the preparation method of the weather resistant polymer emulsion cement mortar described in claim 1 or 5, it is characterised in that by cement, Quartz sand, water-loss reducer, solid defoaming agent, water reducer put into mortar mixer successively, are well mixed, obtain premix powders;Will be poly- Compound emulsion, liquid antifoam agent, water put into mixer successively, are well mixed, and obtain premixing liquid material;Slowly add in premix powders Enter to premix liquid material, stir, obtain weather resistant polymer emulsion cement mortar.
CN201510520856.6A 2015-08-21 2015-08-21 A kind of weather resistant polymer emulsion cement mortar and preparation method thereof Expired - Fee Related CN105174864B (en)

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