CN105174661B - A kind of acid washing phosphorization waste water treatment process - Google Patents
A kind of acid washing phosphorization waste water treatment process Download PDFInfo
- Publication number
- CN105174661B CN105174661B CN201510721292.2A CN201510721292A CN105174661B CN 105174661 B CN105174661 B CN 105174661B CN 201510721292 A CN201510721292 A CN 201510721292A CN 105174661 B CN105174661 B CN 105174661B
- Authority
- CN
- China
- Prior art keywords
- waste water
- acid washing
- washing phosphorization
- sent
- treatment process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Removal Of Specific Substances (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Activated Sludge Processes (AREA)
Abstract
The present invention provides a kind of acid washing phosphorization waste water treatment process, comprises the following steps：1) acid washing phosphorization waste water is tentatively filtered through grid；2) the acid washing phosphorization waste water after preliminary filtering is sent into homogeneous regulating reservoir；3) the acid washing phosphorization waste water after homogenization is sent into by hybrid reaction clarifier by elevator pump；4) waste water that blended reaction clarifier is isolated delivers to reactor for hydrolysis and acidification through water pump and carries out acidification；5) waste water after acidification is sent into anaerobic pond；6) waste water after anaerobic pond is handled is sent into Aerobic Pond；7) waste water after Aerobic Pond processing enters flotation tank；8) waste water after flotation tank is handled is sent into mechanical filter unit, and clear water storage pool is sent into after removing the suspension in water removal.The technique sets up anaerobic pond and Aerobic Pond, handles the phosphorus containg substances and organic matter in acid washing phosphorization waste water using A/O methods, high treating effect, cost is low, environmentally friendly.
Description
Technical field
The present invention relates to a kind of acid washing phosphorization waste water treatment process.
Background technology
Phosphorating treatment is a kind of chemical reprocessing technique to metal material and its article surface progress.Through parkerized
Metal material and its product surface form dipped type phosphate film layer, and the film layer and metallic matrix have good binding ability, resistance to
Mill property and the adhesive ability to coating, therefore, the industry such as machinery, steel is all using phosphorization treatment technology come production machinery part
Overcoat.Phosphorization treatment process generally comprise alkali cleaning oil removing, hot water rinsing, cold rinse, acid pickling and rust removing, secondary cold rinse and
Several steps such as phosphatization.It is main to produce alkali cleaning emulsifying waste water, poaching wastewater, pickle liquor and etching waste liquor etc. during it
Various wastewater.
In phosphorized waste water in addition to containing substantial amounts of phosphate, zinc ion, acid-base material and organic matter, according to production technology not
Together, it is sometimes also multiple containing the pollutant such as heavy metal and surfactant, compositions such as a certain amount of nickel ion, copper ion or lead ions
Miscellaneous, intractability is larger.Phosphate discharge capacity is big, mainly exists in the form of the inorganic salts such as zinc dihydrogen phosphate, in addition with
The pollutants such as COD, petroleum-type and suspension.
Currently the main flow handling process in engineering practice of phosphorized waste water is：Chemical precipitation/coagulation air-float/sand filtration/work
Property charcoal absorption, complex process, dosage is more, and operating cost is high.
On the other hand, the country is primarily present following patent document at present：
Patent publication No.：CN104671493A, a kind of acid washing phosphorization waste water medicament neutralisation treatment technique is disclosed, is by mixing
Close reaction tank, sedimentation basin, mechanical dehydration or sludge drying bed, detection means composition.The invention has the advantages that hybrid reaction
Pond mixes waste water and nertralizer, is fully reacted.Reacted insoluble matter precipitates in sedimentation basin.Sludge under precipitation enters
Row mechanical dehydration or sludge drying.Device detects whether after reaching discharge standard water after processing after testing, discharges or locates again
Reason.However, the patent processing method is excessively simple, neutralisation treatment, place are carried out to acid washing phosphorization waste water merely by nertralizer
It is not very obvious to manage effect.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of acid washing phosphorization waste water treatment process, institute
State technique and set up anaerobic pond and Aerobic Pond, the phosphorus containg substances and organic matter in acid washing phosphorization waste water, processing effect are handled using A/O methods
Fruit is good, and cost is low, environmentally friendly.
To reach above-mentioned purpose, the technical scheme is that：
A kind of acid washing phosphorization waste water treatment process, comprises the following steps：
1) acid washing phosphorization waste water is tentatively filtered off except useless impurities in water through grid；
2) the acid washing phosphorization waste water after preliminary filtering is sent into homogeneous regulating reservoir, acid washing phosphorization waste water is obtained homogeneous；
3) the acid washing phosphorization waste water after homogenization is sent into by hybrid reaction clarifier by elevator pump, and passes through dosing pump
Coagulant is added into the hybrid reaction clarifier so that the acid washing phosphorization waste water is consolidated in hybrid reaction clarifier
Liquid separates, and adds alkali aluminium, polyacrylamide removal phosphate anion, heavy metal ion and COD；
4) waste water that blended reaction clarifier is isolated delivers to reactor for hydrolysis and acidification through water pump and carries out acidification；
5) waste water after acidification is sent into anaerobic pond, the denitrifying bacterium in anaerobic pond carries out dephosphorization treatment to waste water；
6) waste water after anaerobic pond is handled is sent into Aerobic Pond, in Aerobic Pond in the presence of organic matter degradation bacteria, drop
Solve the organic matter in waste water；
7) waste water after Aerobic Pond processing enters flotation tank, removes the grease in waste water, reduces COD；
8) waste water after flotation tank is handled is sent into mechanical filter unit, and clear water storage is sent into after removing the suspension in water removal
Pond.
Further, residence time of the acid washing phosphorization waste water in homogeneous regulating reservoir is 2 ~ 3h in step 2).
In addition, coagulant described in step 3) is in aluminum sulfate, alchlor, ferrous sulfate, calcium hydroxide and magnesium carbonate
One kind.
Separately have, coagulant described in step 3) is calcium hydroxide.
Again, the residence time in hybrid reaction clarifier of acid washing phosphorization waste water described in step 3) is 0.5 ~ 1h.
Further, pH value is 10 ~ 11 in step 3).
And sanitary sewage residence time in Aerobic Pond is 0.3 ~ 0.5h in step 6).
In addition, DO is 2 ~ 4mg/L in Aerobic Pond described in step 6).
Again, YDT type elastic solid fillers are provided with Aerobic Pond described in step 6), adhered on YDT type elastic solid fillers
By microorganism, one layer of microorganism film layer is formed.
The beneficial effects of the present invention are：
The technique uses A/O method handling process, combine anaerobism, it is aerobic the advantages of, effectively acid washing phosphorization can be given up
Phosphorus and organic matter in water are explained and removed, and the water outlet pH value after the completion of processing is 6 ~ 8, meets discharging standards, goes out
COD in watercrContent≤35mg/L, hence it is evident that less than the 100mg/L in national standard, phosphorus content is 0.4 ~ 0.5mg/L in water outlet, place
Reason effect is good, and cost is low, environmentally friendly.
Embodiment
Following examples are used to illustrate the present invention, but can not be used for limiting the scope of the present invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
A kind of acid washing phosphorization waste water treatment process provided by the present invention, comprises the following steps：
1) acid washing phosphorization waste water is tentatively filtered off except useless impurities in water through grid；
2) the acid washing phosphorization waste water after preliminary filtering is sent into homogeneous regulating reservoir, acid washing phosphorization waste water is obtained homogeneous；
3) the acid washing phosphorization waste water after homogenization is sent into by hybrid reaction clarifier by elevator pump, and passes through dosing pump
Coagulant is added into the hybrid reaction clarifier so that the acid washing phosphorization waste water is consolidated in hybrid reaction clarifier
Liquid separates, and adds alkali aluminium, polyacrylamide removal phosphate anion, heavy metal ion and COD；
4) waste water that blended reaction clarifier is isolated delivers to reactor for hydrolysis and acidification through water pump and carries out acidification；
5) waste water after acidification is sent into anaerobic pond, the denitrifying bacterium in anaerobic pond carries out dephosphorization treatment to waste water；
6) waste water after anaerobic pond is handled is sent into Aerobic Pond, in Aerobic Pond in the presence of organic matter degradation bacteria, drop
Solve the organic matter in waste water；
7) waste water after Aerobic Pond processing enters flotation tank, removes the grease in waste water, reduces COD；
8) waste water after flotation tank is handled is sent into mechanical filter unit, and clear water storage is sent into after removing the suspension in water removal
Pond.
Further, residence time of the acid washing phosphorization waste water in homogeneous regulating reservoir is 2 ~ 3h in step 2).
In addition, coagulant described in step 3) is in aluminum sulfate, alchlor, ferrous sulfate, calcium hydroxide and magnesium carbonate
One kind.
Separately have, coagulant described in step 3) is calcium hydroxide.
Again, the residence time in hybrid reaction clarifier of acid washing phosphorization waste water described in step 3) is 0.5 ~ 1h.
Further, pH value is 10 ~ 11 in step 3).
And sanitary sewage residence time in Aerobic Pond is 0.3 ~ 0.5h in step 6).
In addition, DO is 2 ~ 4mg/L in Aerobic Pond described in step 6).
Again, YDT type elastic solid fillers are provided with Aerobic Pond described in step 6), adhered on YDT type elastic solid fillers
By microorganism, one layer of microorganism film layer is formed.
A kind of acid washing phosphorization waste water treatment process provided by the present invention, using A/O method handling process, combine anaerobism,
The advantages of aerobic, effectively the phosphorus in acid washing phosphorization waste water and organic matter can be explained and removed, going out after the completion of processing
Water pH value is 6 ~ 8, meets discharging standards, COD in water outletcrContent≤35mg/L, hence it is evident that less than in national standard
100mg/L, phosphorus content is 0.4 ~ 0.5mg/L in water outlet, and high treating effect, cost is low, environmentally friendly.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (8)
1. a kind of acid washing phosphorization waste water treatment process, it is characterised in that comprise the following steps：
1) acid washing phosphorization waste water is tentatively filtered off except useless impurities in water through grid；
2) the acid washing phosphorization waste water after preliminary filtering is sent into homogeneous regulating reservoir, acid washing phosphorization waste water is obtained homogeneous；
3) the acid washing phosphorization waste water after homogenization is sent into by hybrid reaction clarifier by elevator pump, and by dosing pump to institute
State in hybrid reaction clarifier and add coagulant so that the acid washing phosphorization waste water carries out solid-liquid point in hybrid reaction clarifier
From, and add alkali aluminium, polyacrylamide removal phosphate anion, heavy metal ion and COD；
4) waste water that blended reaction clarifier is isolated delivers to reactor for hydrolysis and acidification through water pump and carries out acidification；
5) waste water after acidification is sent into anaerobic pond, the denitrifying bacterium in anaerobic pond carries out dephosphorization treatment to waste water；
6) waste water after anaerobic pond is handled is sent into Aerobic Pond, and in Aerobic Pond in the presence of organic matter degradation bacteria, degraded is useless
Organic matter in water；
7) waste water after Aerobic Pond processing enters flotation tank, removes the grease in waste water, reduces COD；
8) waste water after flotation tank is handled is sent into mechanical filter unit, and clear water storage pool is sent into after removing the suspension in water removal；
YDT type elastic solid fillers are provided with Aerobic Pond described in step 6), attachment is by micro- life on YDT type elastic solid fillers
Thing, form one layer of microorganism film layer.
2. according to a kind of acid washing phosphorization waste water treatment process described in claim 1, it is characterised in that pickling phosphorus in step 2)
It is 2 ~ 3h to change residence time of the waste water in homogeneous regulating reservoir.
3. according to a kind of acid washing phosphorization waste water treatment process described in claim 1, it is characterised in that mixed described in step 3)
The solidifying one kind of agent in aluminum sulfate, alchlor, ferrous sulfate, calcium hydroxide and magnesium carbonate.
4. according to a kind of acid washing phosphorization waste water treatment process described in claim 2, it is characterised in that mixed described in step 3)
Solidifying agent is calcium hydroxide.
5. according to a kind of acid washing phosphorization waste water treatment process described in claim 1, it is characterised in that sour described in step 3)
It is 0.5 ~ 1h to wash phosphorized waste water residence time in hybrid reaction clarifier.
6. according to a kind of acid washing phosphorization waste water treatment process described in claim 1, it is characterised in that pH value is in step 3)
10~11。
7. according to a kind of acid washing phosphorization waste water treatment process described in claim 1, it is characterised in that life is dirty in step 6)
Water residence time in Aerobic Pond is 0.3 ~ 0.5h.
8. a kind of acid washing phosphorization waste water treatment process according to claim 1, it is characterised in that aerobic described in step 6)
DO is 2 ~ 4mg/L in pond.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510721292.2A CN105174661B (en) | 2015-10-30 | 2015-10-30 | A kind of acid washing phosphorization waste water treatment process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510721292.2A CN105174661B (en) | 2015-10-30 | 2015-10-30 | A kind of acid washing phosphorization waste water treatment process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105174661A CN105174661A (en) | 2015-12-23 |
| CN105174661B true CN105174661B (en) | 2018-02-02 |
Family
ID=54897200
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510721292.2A Active CN105174661B (en) | 2015-10-30 | 2015-10-30 | A kind of acid washing phosphorization waste water treatment process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105174661B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106116022B (en) * | 2016-07-14 | 2019-02-01 | 胡大苇 | A kind of ammonia nitrogen processing method in acid waste water containing heavy metal |
| CN106186415A (en) * | 2016-07-15 | 2016-12-07 | 舒城联科表面处理有限公司 | A kind of phosphorus removing method of the phosphorus-containing wastewater produced in anodic oxidation surface with chemical polishing technology |
| CN106673304A (en) * | 2016-12-19 | 2017-05-17 | 徐州工程学院 | Device for treating phosphatized wastewater through biological reaction and working method thereof |
| CN109694144A (en) * | 2017-10-23 | 2019-04-30 | 宜兴市联丰化工机械有限公司 | A kind of end socket phosphatized wastewater treatment process |
| CN109694143A (en) * | 2017-10-23 | 2019-04-30 | 宜兴市联丰化工机械有限公司 | A kind of end socket production wastewater treatment process |
| CN110902963B (en) * | 2019-12-10 | 2022-06-24 | 九江天赐高新材料有限公司 | Treatment method of alkali-soluble polymer-containing wastewater |
| CN111153557A (en) * | 2020-01-20 | 2020-05-15 | 上海泓济环保科技股份有限公司 | Integrated treatment device and treatment process for pickling and phosphating production wastewater |
| CN113387511A (en) * | 2021-06-17 | 2021-09-14 | 南京工大膜应用技术研究所有限公司 | Zero discharge device and process flow for phosphating wastewater |
| CN117602774A (en) * | 2023-12-27 | 2024-02-27 | 广东拓致环境科技有限公司 | Pickling phosphating wastewater treatment method and system |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101708923A (en) * | 2009-11-16 | 2010-05-19 | 同济大学 | Denitrifying phosphorus and nitrogen removal method for wastewater with low carbon-phosphorus ratio |
| CN101993167A (en) * | 2009-08-28 | 2011-03-30 | 李雁北 | Industrial waste water treatment method |
| CN102276061A (en) * | 2011-05-18 | 2011-12-14 | 贾立敏 | Hydrolysis and denitrification system and method |
| CN103058467A (en) * | 2013-01-22 | 2013-04-24 | 富民宝地纸业有限公司 | Water paper paper-making wastewater efficient treatment and comprehensive recycling method and device |
| CN103553275A (en) * | 2013-11-14 | 2014-02-05 | 安徽省绿巨人环境技术有限公司 | Treatment process of wave-soldering cleaning wastewater |
| CN104291522A (en) * | 2014-09-16 | 2015-01-21 | 天津千鑫有色金属制品有限公司 | Method for treating industrial wastewater |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130134089A1 (en) * | 2011-11-30 | 2013-05-30 | General Electric Company | Method and system for treating wastewater |
-
2015
- 2015-10-30 CN CN201510721292.2A patent/CN105174661B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993167A (en) * | 2009-08-28 | 2011-03-30 | 李雁北 | Industrial waste water treatment method |
| CN101708923A (en) * | 2009-11-16 | 2010-05-19 | 同济大学 | Denitrifying phosphorus and nitrogen removal method for wastewater with low carbon-phosphorus ratio |
| CN102276061A (en) * | 2011-05-18 | 2011-12-14 | 贾立敏 | Hydrolysis and denitrification system and method |
| CN103058467A (en) * | 2013-01-22 | 2013-04-24 | 富民宝地纸业有限公司 | Water paper paper-making wastewater efficient treatment and comprehensive recycling method and device |
| CN103553275A (en) * | 2013-11-14 | 2014-02-05 | 安徽省绿巨人环境技术有限公司 | Treatment process of wave-soldering cleaning wastewater |
| CN104291522A (en) * | 2014-09-16 | 2015-01-21 | 天津千鑫有色金属制品有限公司 | Method for treating industrial wastewater |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105174661A (en) | 2015-12-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105174661B (en) | A kind of acid washing phosphorization waste water treatment process | |
| CN101456647B (en) | Automobile manufacturer wastewater treatment method | |
| Bourgeois et al. | Treatment of drinking water residuals: comparing sedimentation and dissolved air flotation performance with optimal cation ratios | |
| CN100497193C (en) | High polymer composite coagulant for treatment of oily waste water and making method thereof | |
| CN102765819B (en) | Self-draining water recycling process of water circulating system | |
| CN104843809B (en) | Coking sewage treatment agent and preparing method thereof | |
| CN102126799B (en) | Method for treating fluorine-containing and ammonia nitrogen-containing waste water in electronic industry | |
| KR101278230B1 (en) | The method and Appuratus of removing total nitrogen and phosphate in sewage and wastewater using precipitation-agent of rapidity for coagulation an flocculation | |
| CN101973669A (en) | Electric power storage (EPS) waste water treatment technique | |
| CN107381881A (en) | The method of wastewater treatment and processing unit of desulfurization wastewater zero-emission | |
| CN102336501A (en) | Cold rolled steel coil wastewater treatment method | |
| CN205773743U (en) | A kind of boiler acid washing wastewater processing system | |
| CN204224358U (en) | Stainless-steel cold-rolling acid waste water treatment unit | |
| JP2014210232A (en) | Method for processing alkaline waste water including calcium-eluting particles | |
| CN103288241B (en) | Waste water circulation cooling two-stage clarifying and softening system | |
| CN206680307U (en) | A kind of filtering neutralizing tower of stainless steel production waste water | |
| CN105110579A (en) | Sewage disposal process | |
| CN104926048A (en) | Treatment method for waste water in coal chemical industry | |
| CN104787965B (en) | Treatment method of pharmaceutical industry wastewater | |
| CN101591054A (en) | Compound color-odor removal coagulating agent and production method and be used for the technology that leather sewage is handled | |
| CN204999771U (en) | Refractory wastewater's processing system | |
| CN210193576U (en) | Waste water treatment device in coating process | |
| CN209081509U (en) | Suspension rapid precipitation system for abrasive material mixing jetting de-scaling | |
| CN207227212U (en) | A kind of fermented pharmaceutical waste water Treated sewage reusing device | |
| CN104310650A (en) | Chromium-containing stainless steel cold-rolled wastewater treatment device and method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190325 Address after: 418200 Hongjiang Industrial Park No. 27, Huaihua City, Hunan Province Patentee after: Hongjiang Jinyi Water Treatment Co., Ltd. Address before: Room 618, Building A, Nanjiulong Avenue, North Ring Road, Fuqiao Town, Taicang City, Suzhou City, Jiangsu Province Patentee before: Taicang Dongneng Environmental Protection Equipment Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A treatment process for pickling and Phosphating Wastewater Effective date of registration: 20210331 Granted publication date: 20180202 Pledgee: Bank of China Limited by Share Ltd. Huaihua branch Pledgor: Hongjiang Jinyi Water Treatment Co.,Ltd. Registration number: Y2021980002265 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |