CN105170316B - Device and method for achieving molecule/ion-level separation of homogeneous mixing liquid through magnetizing force - Google Patents

Device and method for achieving molecule/ion-level separation of homogeneous mixing liquid through magnetizing force Download PDF

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CN105170316B
CN105170316B CN201510650545.1A CN201510650545A CN105170316B CN 105170316 B CN105170316 B CN 105170316B CN 201510650545 A CN201510650545 A CN 201510650545A CN 105170316 B CN105170316 B CN 105170316B
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magnetic field
liquid
field space
magnetic
flow
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CN105170316A (en
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吴平
王立
张师平
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University of Science and Technology Beijing USTB
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University of Science and Technology Beijing USTB
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Abstract

The invention provides a device and method for achieving molecule/ion-level separation of homogeneous mixing liquid through magnetizing force. The device comprises a liquid conveying part, a gradient magnetic field separation device and a liquid collection part, wherein the gradient magnetic field separation device can be achieved by permanent magnets or combination of permanent magnets and yokes or electromagnets or superconducting magnets or solenoids or superconducting solenoids and is used for generating a gradient magnetic field in magnetic field space. The liquid conveying part is composed of a liquid storage bottle, a liquid conveying pump and a liquid conveying pipe. Liquid flows in the magnetic field space in a deflection flowing mode, a magnetic screening flowing mode and a magnetic screening and deflection composite flowing mode, and separation or enrichment of paramagnetic and diamagnetic molecules (or ions) in the homogeneous mixing liquid and separation or enrichment of magnetic/paramagnetic particles in the liquid are achieved under the action of the magnetizing force. The device and method have the advantages of being convenient to operate, low in manufacturing cost, low in energy consumption, long in service life, wide in applicability, low in magnetic pollution and the like.

Description

A kind of utilization magnetizing force realizes the molecular/ionic level segregation apparatuss of homogeneous mixing liquid And method
Technical field
The invention belongs to homogeneous mixing liquid separation technology field, it is proposed that a kind of homogeneous mixed using magnetizing force effect realization Close paramagnetism, diamagnetism molecule in liquid(Or ion)The device and method for separating or being enriched with.Which mixes in can be additionally used in liquid Magnetic/paramagnetic particle thing separation or enrichment.
Background technology
The other separation of molecular level between homogeneous mixing liquid different component is enriched in scientific research or commercial Application There is very important meaning.At present, as magnetism separate method has easy to operate, quick, high-efficiency environment friendly, with low cost etc. all Many remarkable advantages, are successfully used to separate the magnetic-particle material with certain intensity of magnetization, i.e. heterogeneous separation.And for Molecule in homogeneous thing system(Or ion)The detached research of rank is also little, realizes dividing in homogeneous liquid in particular with magnetic force The method and apparatus of son/ion isolation still belongs to blank.
The content of the invention
It is an object of the invention to provide a kind of utilization magneticaction is realized the paramagnetism of homogeneous mixing liquid different component, is resisted Magnetic molecule(Or ion)Between segregation apparatuss and method.Which can be realized at normal temperatures and pressures, suitable in homogeneous mixing liquid Magnetic, diamagnetism molecule(Or ion)Separation or enrichment, with simple structure, easy to operate, cheap, energy consumption is low, make With life-span length, the suitability is wide, electromagnetic pollution is little the features such as.
The separation or enrichment of the magnetic that the present invention mixes in can be additionally used in liquid/paramagnetic particle thing.
Technical scheme is as follows:
A kind of utilization magnetizing force realizes the detached device of molecular/ionic level of homogeneous mixing liquid, and the device includes liquid Transport portion(1), gradient magnetic segregation apparatuss(5)And liquid collecting part(12);
Wherein, the gradient magnetic segregation apparatuss(5)Can by permanent magnet or permanent magnet combine yoke or electric magnet or Person's superconducting magnet or solenoid or superconducting solenoid are realized, for producing magnetic field space(6);
The liquid supplying part(1)By liquid containing bottle(2), liquid delivery pump(3)And liquid delivery tube(4)Composition, it is described Liquid supplying part(1)Homogeneous mixing liquid can be transported to magnetic field space(6)In, through gradient magnetic deflecting action with Interception function, the liquid rich in paramagnetic ion/molecule and the liquid rich in diamagnetism ion/molecular are different from two respectively Go out head piece to flow out and by liquid collecting part(12)Collect, described device can be used for paramagnetism, diamagnetism in homogeneous mixing liquid Molecule(Or ion)Separation or enrichment, it may also be used for the separation or enrichment of the magnetic mixed in liquid/paramagnetic particle thing.
Wherein, the magnetic field space is directly constituted by permanent magnet, and its cross sectional shape can be square, triangle, circle, ladder Shape, polygon, the cross sectional shape of the permanent magnet to adopting can also be square, triangle, circle, trapezoidal or polygon.
Wherein, the magnetic field space(6)Can be made up of yoke, its cross sectional shape can be square, triangle, circle Shape, trapezoidal, polygon, the cross sectional shape of the yoke to adopting can also be square, triangle, circle, trapezoidal or polygon.
Wherein, the magnetic field space(6)Can be constituted by solenoid is wound outside enclosed runner, the section shape of runner Shape can be square, triangle, circle, trapezoidal, polygon.
Wherein, the gradient magnetic segregation apparatuss(5)Using the liquid outlet of multilevel hierarchy, i.e. previous stage as rear stage Liquid inlet;Or realized by the way of the parallel connection of many magnetic field spaces, i.e., liquid flows into gradient magnetic segregation apparatuss by entrance (5)Several mutually parallel magnetic field spaces are flowed into afterwards respectively simultaneously can(6)In, flow out from outlet after then collecting.
Wherein, the gradient magnetic segregation apparatuss(5)In magnet adopt stepped construction, you can be made up of multiple magnets Stacked magnet array constitutes similar array structure by yoke, and the spacing of spacing or yoke between two adjacent magnets is magnetic The thickness range in space is 0.1 mm~1000mm, the thickness for constituting the magnet or yoke of array portion be 0.1mm~ 1500mm。
Wherein, the magnetic field space(6)It is straight, forniciform or into spiral form coiling.
Wherein, the gradient magnetic segregation apparatuss(5)In permanent magnet can be replaced using electromagnet.
Wherein, the gradient magnetic segregation apparatuss(5)Using solenoid type by electrified wire(11)And magnetic field space(5)Group Into electrified wire is wrapped in magnetic field space(5)Outer ring, magnetic field space then helically shape coiling, flow through energization when there is electric current Wire(11)When, in magnetic field space by formed one be directly proportional to the current intensity for flowing through, with solenoid coil radius R square Gradient magnetic in inverse ratio, wherein, electrified wire can be made up of normal conductor, it is also possible to be made up of superconductor.
It is a kind of that paramagnetism in homogeneous mixing liquid, diamagnetism molecule are realized using above-mentioned device(Or ion)Separate or rich The method of collection, it is characterised in that the magnetic field space can have deflection flow pattern, magnetic sieve flow pattern and deflection-magnetic Sieve complex flow patterns;
During work, for magnetic field space is deflection flow pattern, then liquid and liquid are installed in the both sides of magnetic field space The encapsulant that lewis' acid or particulate matter in body cannot be passed through is pointing to the gradient inside magnetic field space as flow path wall In the presence of magnetic field, the paramagnetism molecule or ion in homogeneous mixing liquid is subject to the effect of magnetic field force to flow simultaneously to magnetic field center Flowed out from head piece is gone out by deflector, and the then relative flowing on the outside of magnetic field space of diamagnetism molecule or ion, and pass through water conservancy diversion Plate will collect from two the liquid after the separation or enrichment that go out head piece outflow from head piece outflow, fluid collection device is gone out;
For magnetic field space be magnetic sieve flow pattern, then in the both sides of magnetic field space are provided with liquid and liquid from Son or molecule or particulate matter through porous damping material as flow path wall, and can have at the both sides of the edge of magnetic field space High-gradient magnetic field is magnetic sieve, and the flow liquid scale of construction that of mouth is made in the time control that works makes partially liq flow out by damping layer, works as liquid flow Overdamp layer when due to being in gradient magnetic, paramagnetism molecule or ion are subject to the effect of magnetic field force to be intended to stay in magnetic field It is in space and logical final from going out head piece outflow, and diamagnetism molecule or ion are then flowed out from damping layer and from going out head piece outflow, liquid Body collection device will collect from two the liquid after the separation or enrichment that go out head piece outflow;
For magnetic field space be deflection-magnetic sieve complex flow patterns, then the both sides of magnetic field space be provided with liquid and Lewis' acid or particulate matter in liquid can have inside magnetic field space and refer to through porous damping material as flow path wall To the gradient magnetic inside magnetic field space, it is magnetic sieve still to have high-gradient magnetic field in the edge of magnetic field space both sides, during work The flow liquid scale of construction that goes out of control outlet makes partially liq flow out by porous damping layer, when liquid is inside magnetic field space, in magnetic In the presence of field force, the paramagnetism molecule or ion in homogeneous mixing liquid is subject to the effect of magnetic field force to flow simultaneously to magnetic field center Flowed out from head piece is gone out by deflector, and the then relative flowing on the outside of magnetic field space of diamagnetism molecule or ion, and pass through water conservancy diversion From head piece outflow is gone out, when liquid flow overdamp layer, due to being in high-gradient magnetic field, paramagnetism molecule or ion are subject to magnetic to plate The effect of field force and be intended to stay in magnetic field space, it is and logical final from going out head piece outflow, and diamagnetism molecule or ion then from Damping layer flows out and from head piece outflow is gone out, fluid collection device will be collected from the liquid gone out after the separation or enrichment of head piece outflow.
The present invention has advantages below:
1 invention can realize the separation or enrichment of homogeneous mixing liquid at normal temperatures and pressures;
2 using in the case of permanent magnet, it may not be necessary to consumed energy in addition;
The main working parts of 3 systems do not have mechanical movement and wear problem, long service life;
4 can realize continuous separation or enrichment work;
5 simple structures.
Description of the drawings
Fig. 1 is that liquid supplying part constitutes diagram.
Fig. 2 is that permanent magnet type gradient magnetic segregation apparatuss regard longitudinal section diagram.
Fig. 3 is that yoke formula gradient magnetic generator regards longitudinal section diagram.
Fig. 4 is that solenoid type gradient magnetic generator overlooks planing surface figure
Fig. 5 is magnetic field space and flow direction diagram under deflection flow pattern.
Fig. 6 is magnetic field space and flow direction diagram under magnetic sieve flow pattern.
Fig. 7 sieves-deflects magnetic field space and flow direction diagram under complex flow patterns for magnetic.
Magnetic field spaces of the Fig. 8 for helical coil.
Fig. 9 is the experimental provision structural front view of the present invention.
Specific embodiment
For making the object, technical solutions and advantages of the present invention become more apparent, below in conjunction with specific embodiment and coordinate Accompanying drawing, the present invention is described in more detail.
Specific embodiment of Fig. 1 ~ 9 for the present invention.
As shown in figure 1, liquid supplying part 1 is made up of liquid containing bottle 2, liquid delivery pump 3 and liquid delivery tube 4.Liquid is defeated Send pump 3 to pump out and pass through liquid delivery tube 4 liquid in liquid containing bottle 1 and send into gradient magnetic segregation apparatuss 5.
As shown in Fig. 2 permanent magnet type gradient magnetic segregation apparatuss 5 are by permanent magnet 7, yoke 8, cushion block 9 and encapsulant 10 or damping material 11 constitute, and be made up of magnetic field space 6 gap between permanent magnet 7, permanent magnet therein 7 can be by electricity Magnet or superconducting magnet are substituted.
As shown in figure 3, yoke formula gradient magnetic segregation apparatuss 5 are by permanent magnet 7, yoke 8, cushion block 9 and flow path wall 10, flow Road wall 10 can be by encapsulant(Lewis' acid or particulate matter in liquid and liquid cannot be passed through)Composition can also be by Damping material(Lewis' acid or particulate matter in liquid and liquid can be passed through)Composition, and by the gap between yoke 7 Magnetic field space 6 is constituted, permanent magnet therein 7 can be substituted by electromagnet or superconducting magnet.
As shown in figure 4, solenoid type gradient magnetic segregation apparatuss 5 are made up of electrified wire 11 and magnetic field space 5, energization is led Line is wrapped in the outer ring of magnetic field space 5, and magnetic field space is in then shape coiled coil as shown in Figure 8, flows through energization when there is electric current During wire 11, one will be formed in magnetic field space and be directly proportional to the current intensity for flowing through, with solenoid coil radius R square be in The gradient magnetic of inverse ratio.Wherein, electrified wire can be made up of normal conductor, it is also possible to be made up of superconductor.
Fig. 5~7 respectively deflect under magnetic field space under flow pattern, magnetic sieve flow pattern magnetic field space and magnetic sieve-partially Turn magnetic field space under complex flow patterns.And under these flow patterns, the magnetic field space formed by magnet or yoke can also It is helical form, as shown in Figure 8.
Fig. 9 illustrates the magnetic separating device topology view of one of embodiment of the present invention.Single unit system is by liquid delivery section 1, gradient magnetic segregation apparatuss 5 and fluid collection device 12 is divided to constitute.The homogeneous mixing liquid being placed in liquid containing bottle 1 is by liquid Delivery pump 3 is pumped out, and is sent in gradient magnetic segregation apparatuss 5 by liquid delivery tube 4.Into in gradient magnetic segregation apparatuss 5 Homogeneous mixing liquid by liquid delivery tube flow into magnetic field space 6 in.
For magnetic field space 6 is deflection flow pattern(Fig. 4), then liquid and liquid are installed in the both sides of magnetic field space 6 The encapsulant that lewis' acid or particulate matter in body cannot be passed through is being pointed to inside magnetic field space 6 as flow path wall 10 In the presence of gradient magnetic, the paramagnetism molecule or ion in homogeneous mixing liquid is subject to the effect of magnetic field force to magnetic field center stream Move and pass through deflector 13 and flow out from head piece 14 is gone out, and the then relative flowing on the outside of magnetic field space of diamagnetism molecule or ion, and Flowed out from head piece 15 is gone out by deflector 13.Fluid collection device 12 will be collected from after two separation for going out head piece outflow or being enriched with Liquid.
For magnetic field space 6 is that magnetic sieves flow pattern(Fig. 5), then liquid and liquid are installed in the both sides of magnetic field space 6 Lewis' acid or particulate matter in body can be through porous damping material as flow path wall 10, and the two of magnetic field space 6 There is at lateral edges high-gradient magnetic field i.e. magnetic sieve, and the time control that works is made the flow liquid scale of construction that of mouth and partially liq made by damping laminar flow Go out, when liquid flow overdamp layer due to being in gradient magnetic, paramagnetism molecule or ion are subject to the effect of magnetic field force to become To in staying in magnetic field space, and it is logical it is final flow out from going out head piece 14, and diamagnetism molecule or ion are then flowed out simultaneously from damping layer Flow out from head piece 15 is gone out.Fluid collection device 12 will collect from two the liquid after the separation or enrichment that go out head piece outflow.
For magnetic field space 6 is that deflection-magnetic sieves complex flow patterns(Fig. 6), then it is provided with the both sides of magnetic field space 6 Lewis' acid or particulate matter in liquid and liquid can be through porous damping material as flow path wall 10, in magnetic field space It is internal that there is the gradient magnetic pointed to inside magnetic field space 6, in the edge of 6 both sides of magnetic field space with high-gradient magnetic field be still Magnetic is sieved, and the flow liquid scale of construction that of mouth is made in the time control that works makes partially liq flow out by porous damping layer, when liquid is in magnetic field space When internal, under the action of a magnetic force, the paramagnetism molecule or ion in homogeneous mixing liquid is subject to the effect of magnetic field force to magnetic Field center flow is simultaneously flowed out from head piece 14 is gone out by deflector 13, and diamagnetism molecule or ion are then relative on the outside of magnetic field space Flowing, and flowed out from head piece 15 is gone out by deflector 13.It is when liquid flow overdamp layer, due to being in high-gradient magnetic field, suitable Magnetic molecule or ion are subject to the effect of magnetic field force and are intended to stay in magnetic field space, and it is logical it is final flow out from going out head piece 14, And diamagnetism molecule or ion are then flowed out and are flowed out from head piece 15 is gone out from damping layer.Fluid collection device 12 will be collected from going out head piece Liquid after the separation or enrichment of outflow.
The above is only the preferred embodiment for the present invention, it is noted that for the member of ordinary skill of the art comes Say, on the premise of without departing from the technology of the present invention principle, some improvement and modification can also be made, these improve and modification also should This is considered as protection scope of the present invention.

Claims (12)

1. a kind of utilization magnetizing force realizes the detached device of molecular/ionic level of homogeneous mixing liquid, it is characterised in that the device Including liquid supplying part (1), gradient magnetic segregation apparatuss (5) and liquid collecting part (12);
Wherein, gradient magnetic segregation apparatuss (5) combine yoke or electric magnet or superconducting magnetic by permanent magnet or permanent magnet Body is realized, for producing magnetic field space (6);
Liquid supplying part (1) is made up of liquid containing bottle (2), liquid delivery pump (3) and liquid delivery tube (4), the liquid Transport portion (1) is transported to homogeneous mixing liquid in magnetic field space (6), makees with intercepting through the deflecting action of gradient magnetic Different go out head piece from two respectively with, the liquid rich in paramagnetic ion/molecule and the liquid rich in diamagnetism ion/molecular Flow out and collected by liquid collecting part (12), described device is used for paramagnetism, diamagnetism molecular/ionic in homogeneous mixing liquid Separation or enrichment, the separation or enrichment of the magnetic mixed in being additionally operable to liquid/paramagnetic particle thing;
Wherein, described gradient magnetic segregation apparatuss (5) are made up of electrified wire (11) and magnetic field space (6) using solenoid type, Electrified wire is wrapped in the outer ring of magnetic field space (6), and magnetic field space then helically shape coiling flows through electrified wire when there is electric current (11) when, one will be formed in magnetic field space and is directly proportional to the current intensity for flowing through, with solenoid coil radius R square in instead The gradient magnetic of ratio, wherein, electrified wire is made up of normal conductor, or is made up of superconductor.
2. according to the device described in claim 1, it is characterised in that the magnetic field space is directly constituted by permanent magnet, its section Shape is square, triangle, circular or trapezoidal, and the cross sectional shape of the permanent magnet to adopting is square, triangle, circle or ladder Shape.
3. according to the device described in claim 1, it is characterised in that the magnetic field space is directly constituted by permanent magnet, its section Shape is polygon, and the cross sectional shape of the permanent magnet to adopting is polygon.
4. according to the device described in claim 1, it is characterised in that:Magnetic field space (6) is made up of yoke, and its cross sectional shape is Polygon, the cross sectional shape of the yoke to adopting is polygon.
5. according to the device described in claim 1, it is characterised in that:Magnetic field space (6) is made up of yoke, and its cross sectional shape is Square, triangle, circular or trapezoidal, the cross sectional shape of the yoke to adopting is square, triangle, circular or trapezoidal.
6. according to the device described in claim 1, it is characterised in that:Magnetic field space (6) winds spiral shell by outside enclosed runner Spool is constituted, and the cross sectional shape of runner is square, triangle, circular or trapezoidal.
7. according to the device described in claim 1, it is characterised in that:Magnetic field space (6) winds spiral shell by outside enclosed runner Spool is constituted, and the cross sectional shape of runner is polygon.
8. according to the device described in claim 1, it is characterised in that gradient magnetic segregation apparatuss (5) adopt multilevel hierarchy, That is liquid inlet of the liquid outlet of previous stage as rear stage;Or realized by the way of the parallel connection of many magnetic field spaces, i.e. liquid Gradient magnetic segregation apparatuss (5) are flowed into by entrance to flow into simultaneously respectively afterwards in several mutually parallel magnetic field spaces (6), then Flow out from outlet after collecting.
9. according to the device described in claim 1, it is characterised in that the magnet in gradient magnetic segregation apparatuss (5) is adopted Stepped construction, i.e., constitute stacked magnet array by multiple magnets or constitute similar array structure, two adjacent magnetic by yoke It is 0.1mm~1000mm that the spacing of spacing or yoke between body is the thickness range of magnetic field space, constitutes the magnet of array portion Or the thickness of yoke is 0.1mm~1500mm.
10. according to the device described in claim 1, it is characterised in that:Magnetic field space (6) are straight or forniciform.
11. according to the device described in claim 1, it is characterised in that:Magnetic field space (6) are spiral form coilings.
Device described in a kind of one of 12. employing claim 1-11 realize paramagnetism in homogeneous mixing liquid, diamagnetism molecule/ Ion isolation or the method for enrichment, it is characterised in that the magnetic field space have deflection flow pattern, magnetic sieve flow pattern and Deflection-magnetic sieves complex flow patterns;
During work, for magnetic field space is deflection flow pattern, then in the both sides of magnetic field space are provided with liquid and liquid Lewis' acid or the encapsulant that cannot pass through of particulate matter as flow path wall, pointing to the gradient magnetic inside magnetic field space In the presence of, the paramagnetism molecule or ion in homogeneous mixing liquid is subject to the effect of magnetic field force to flow to magnetic field center and pass through Deflector is from going out head piece outflow, and diamagnetism molecule or ion are then relative flows on the outside of magnetic field space, and by deflector from Go out head piece outflow, fluid collection device will collect from two the liquid after the separation or enrichment that go out head piece outflow;
For magnetic field space be magnetic sieve flow pattern, then the ion in the both sides of magnetic field space are provided with liquid and liquid or Molecule or particulate matter through porous damping material as flow path wall, and can have high ladder at the both sides of the edge of magnetic field space Degree magnetic field is magnetic sieve, and the flow liquid scale of construction that of mouth is made in the time control that works makes partially liq flow out by damping layer, when liquid flows through resistance Buddhist nun's layer when due to being in gradient magnetic, paramagnetism molecule or ion are subject to the effect of magnetic field force to be intended to stay in magnetic field space Interior and logical final from head piece outflow, and diamagnetism molecule or ion is gone out then from damping layer outflow and from head piece outflow is gone out, liquid is received Acquisition means will collect from two the liquid after the separation or enrichment that go out head piece outflow;
For magnetic field space is that deflection-magnetic sieves complex flow patterns, then liquid and liquid are installed in the both sides of magnetic field space In lewis' acid or particulate matter can have inside magnetic field space and point to magnetic through porous damping material as flow path wall The gradient magnetic of field interior volume, it is magnetic sieve still to have high-gradient magnetic field in the edge of magnetic field space both sides, is controlled during work The flow liquid scale of construction that goes out of outlet makes partially liq flow out by porous damping layer, when liquid is inside magnetic field space, in magnetic field force In the presence of, the paramagnetism molecule or ion in homogeneous mixing liquid is subject to the effect of magnetic field force to flow to magnetic field center and pass through Deflector is from going out head piece outflow, and diamagnetism molecule or ion are then relative flows on the outside of magnetic field space, and by deflector from Go out head piece outflow, when liquid flow overdamp layer, due to being in high-gradient magnetic field, paramagnetism molecule or ion are subject to magnetic field force Effect and be intended to stay in magnetic field space, it is and logical final from going out head piece outflow, and diamagnetism molecule or ion are then from damping Laminar flow goes out and from head piece outflow is gone out, fluid collection device will be collected from the liquid gone out after the separation or enrichment of head piece outflow.
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