CN105155137A - Straw fiber and jute fiber blended non-woven fabric for warming anti-bacterial, environment-friendly and seamless wall paper and preparation method for non-woven fabric - Google Patents
Straw fiber and jute fiber blended non-woven fabric for warming anti-bacterial, environment-friendly and seamless wall paper and preparation method for non-woven fabric Download PDFInfo
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- CN105155137A CN105155137A CN201510504919.9A CN201510504919A CN105155137A CN 105155137 A CN105155137 A CN 105155137A CN 201510504919 A CN201510504919 A CN 201510504919A CN 105155137 A CN105155137 A CN 105155137A
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Abstract
The invention discloses a straw fiber and jute fiber blended non-woven fabric for a piece of warming anti-bacterial, environment-friendly and seamless wall paper. The non-woven fabric is made from the following raw material according to weight by parts: straw taking up of 200 to 205 parts, original hemp of 100 to 104 parts, proper amount of NaOH, proper amount of water, polyving akohol of 0.8 to 0.85 part, lignin of 0.5 to 0.6 part, methylacrylic acid trifluro-ethyl ester of 0.2 to 0.3 parts, methylacrylic acid Dodecafluoroheptyl of 0.2 to 0.3 part, ethyl acetate of 5 to 6 parts, tea tree essential oil of 0.3 to 0.4 part, activated carbon fibers of 2.5 to 3 parts, nanometer polytetrafluoroethylene of 0.3 to 0.4 part, and peroxidation cumin of 0.05 to 0.1 part. With the use of the tea tree essential oil and the activated carbon fibers, the non-woven fabric has performance of preventing bacteria and absorbing harmful gas; and tenacity, tear-resistance and low temperature-resistance of the non-woven fabric are enhanced due to the use of the polyurethane acrylic resin and the lignin.
Description
Technical field
The present invention relates to nonwoven fabric manufacturing technology field, particularly relate to the seamless wallpaper rice-straw fibre of a kind of antibacterial environment protection and flax fibre hybrid nonwoven cloth and preparation method thereof.
Background technology
There is abundant stalk resource in China, occupies first of the world.Wherein rice straw accounts for 27.5%, and maize straw accounts for 36.7%, and wheat stalk accounts for 15.2%, and can be used as the stalk total amount that the energy is used is 3.761 hundred million t.At present, a large amount of discarded rice straw still faces and burns this unique process approach.Exploitation rice straw novelty teabag, solves rice straw process new problem, both can reduce rice straw as the environmental pollution brought after castoff burning and management cost, and also can turn waste into wealth, and make full use of the value of rice straw resource itself, economize on resources.
By chemical constitution study, in rice straw, make it can be used as providing the resource of native cellulose fibre containing the cellulose reaching 31.51%.There is a large amount of rice straw resources in China, if can be used by weaving, can create good economic worth and environmental value.And utilize the prerequisite of rice straw fiber to be to remove other impurity of rice straw.Found through experiments, extracting at rice straw in the technique of fiber to use certain density NaOH to carry out alkali lye kiering to rice straw, to remove its major impurity such as the hemicellulose contained and lignin, thus obtain comparatively ideal fiber, for following process process.In order to efficiency utilization reclaims rice straw, consider to utilize nonwovens process to be made as nonwoven fabric.But because the mechanical properties such as rice straw brute force itself are poor, can must produce a desired effect with other known traditional fibre are blended.
The function admirable of flax fibre, biocompatibility is good.Along with the continuous progress of technology of nonwoven, application flax fibre is that raw material is produced high performance non-weaving cloth and become heat subject.This test selects flax fibre and rice straw fiber to carry out blended, and its feature is as follows: (1) is more excellent based on flax fibre brute force, and fiber stiffness is comparatively large, can make up the shortcoming of rice straw fiber strength deficiency.(2) because flax fibre contains a large amount of polar hydrophilic group, giant fibril longitudinal splitting and present many cracks and hole, and be communicated with lumen by capillary channel, this kind of structure makes flax fibre have remarkable moisture permeability (official regain is about 15%), and this growth for agricultural plant and preservation have good effect.Meanwhile, good hygroscopicity makes flax fibre have stronger antistatic behaviour.(3) natural chemical substance contained by flax fibre has the function of anti-bacteria.Under normal conditions, in the hole in flax fibre, be full of air, be unfavorable for the breeding of anaerobic bacteria, there is fungi-proofing, mildew-resistant, deodorization, corrosion-resistant function, antibacterial, bacteriostasis is more excellent.(4) as native cellulose fibre, the more cheap easy acquisition of flax fibre, and be all bast fibers with rice straw, composition is similar, when extracting fiber can kiering simultaneously to save operation, reduce costs.
Mixed with flax fibre by rice-straw fibre, with polyvinyl alcohol as adhesive, the nonwoven fabric of making has good hygroscopicity, higher fracture strength.If using the bottom of this nonwoven fabric as seamless wallpaper; can not only cost-saving, protection of the environment, raising straw additional application be worth; and useful to health, but the performances such as the hygroscopicity of this nonwoven fabric, intensity, durability can't meet the demands, and need to improve.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides the seamless wallpaper rice-straw fibre of a kind of antibacterial environment protection and flax fibre hybrid nonwoven cloth and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of seamless wallpaper rice-straw fibre of antibacterial environment protection and flax fibre hybrid nonwoven cloth, be made up of the raw material of following weight portion: straw 200-205, raw ramie 100-104, NaOH are appropriate, water is appropriate, polyvinyl alcohol 0.8-0.85, lignin 0.5-0.6, polyurethane acrylic resin 0.3-0.4, trifluoroethyl methacrylate 0.2-0.3, dodecafluoroheptyl methacrylate 0.2-0.3, ethyl acetate 5-6, tea tree ethereal oil 0.3-0.4, activated carbon fiber 2.5-3, nanometer polytetrafluoroethylcomposite 0.3-0.4, dicumyl peroxide 0.05-0.1.
The preparation method of described antibacterial environment protection is seamless wallpaper rice-straw fibre and flax fibre hybrid nonwoven cloth, comprises the following steps:
(1) straw is cut into the section of 3-5cm, by straw: the weight ratio 1:20-21 of water adds water, by straw: the weight ratio 1:0.6-0.65 of NaOH adds NaOH, stir, be heated to 89-91 DEG C, stirring reaction 1.8-2h under heat-retaining condition, filter, cleaning to pH with water is 7-8, and drying, obtains rice-straw fibre;
(2) raw ramie is cut into the section of 3-5cm, by raw ramie: the weight ratio 1:20-21 of water adds water, by raw ramie grass: the weight ratio 1:0.1-0.12 of NaOH adds NaOH, stir, be heated to 89-91 DEG C, stirring reaction 1.5-1.6h under heat-retaining condition, filter, cleaning to pH with water is 7-8, and drying, obtains flax fibre;
(3) polyvinyl alcohol is added water be mixed with the solution of 8-8.5% concentration, add lignin, stir, obtain adhesive, get rice-straw fibre, each 50 weight portions of flax fibre, mix with activated carbon fiber, be placed in sizing in sizing net, be placed in acupuncture on needing machine again, be pressed into cloth, with described adhesive uniform application, resin added controls at 7-7.5%, to send in drying box dry 1.5-2h at 80-82 DEG C again, obtain nonwoven fabric;
(4) trifluoroethyl methacrylate, dodecafluoroheptyl methacrylate, ethyl acetate are mixed, add tea tree ethereal oil, polyurethane acrylic resin, nanometer polytetrafluoroethylcomposite, be heated to 65-70 DEG C, add dicumyl peroxide, stirring reaction 30-40 minute, obtains mixture, on the nonwoven fabric obtained in (3) step by mixture uniform application, drying, to obtain final product.
A kind of seamless wallpaper, do superficial layer by PVC mantle, flexible polyurethane foams does intermediate layer, and antibacterial environment protection described in claim 1 is seamless wallpaper rice-straw fibre and flax fibre hybrid nonwoven cloth do bottom, carry out laminating make with make-up machine.
Advantage of the present invention is: nonwoven fabric of the present invention uses trifluoroethyl methacrylate, dodecafluoroheptyl methacrylate, nanometer polytetrafluoroethylcomposite to carry out coating modification, reduce regain, prevent from going mouldy, improve toughness, extend service life, and improve intensity; By using tea tree ethereal oil, activated carbon fiber, nonwoven fabric is made to have the performance of antibacterial absorption pernicious gas; By using polyurethane acrylic resin, lignin, improve the toughness of nonwoven fabric, resistance to tearing and lower temperature resistance; The seamless Soft Roll wallpaper environmental protection made of this nonwoven fabric, durable, ventilative.
Detailed description of the invention
A kind of seamless wallpaper rice-straw fibre of antibacterial environment protection and flax fibre hybrid nonwoven cloth, be made up of the raw material of following weight portion (kilogram): straw 200, raw ramie 100, NaOH is appropriate, water is appropriate, polyvinyl alcohol 0.8, lignin 0.5, polyurethane acrylic resin 0.3, trifluoroethyl methacrylate 0.2, dodecafluoroheptyl methacrylate 0.2, ethyl acetate 5, tea tree ethereal oil 0.3, activated carbon fiber 2.5, nanometer polytetrafluoroethylcomposite 0.3, dicumyl peroxide 0.05.
The preparation method of described antibacterial environment protection is seamless wallpaper rice-straw fibre and flax fibre hybrid nonwoven cloth, comprises the following steps:
(1) straw is cut into the section of 3cm, by straw: the weight ratio 1:20 of water adds water, by straw: the weight ratio 1:0.6 of NaOH adds NaOH, stirs, be heated to 89 DEG C, stirring reaction 1.8h under heat-retaining condition, filter, cleaning to pH with water is 7, and drying, obtains rice-straw fibre;
(2) raw ramie is cut into the section of 3cm, by raw ramie: the weight ratio 1:20 of water adds water, by raw ramie grass: the weight ratio 1:0.1 of NaOH adds NaOH, stirs, be heated to 89 DEG C, stirring reaction 1.5h under heat-retaining condition, filter, cleaning to pH with water is 7, and drying, obtains flax fibre;
(3) polyvinyl alcohol is added water be mixed with the solution of 8% concentration, add lignin, stir, obtain adhesive, get rice-straw fibre, each 50 weight portions of flax fibre, mix with activated carbon fiber, be placed in sizing in sizing net, be placed in acupuncture on needing machine again, be pressed into cloth, with described adhesive uniform application, resin added controls 7%, to send in drying box dry 1.5h at 80 DEG C again, obtain nonwoven fabric;
(4) trifluoroethyl methacrylate, dodecafluoroheptyl methacrylate, ethyl acetate are mixed, add tea tree ethereal oil, polyurethane acrylic resin, nanometer polytetrafluoroethylcomposite, be heated to 65 DEG C, add dicumyl peroxide, stirring reaction 30 minutes, obtains mixture, on the nonwoven fabric obtained in (3) step by mixture uniform application, drying, to obtain final product.
A kind of seamless wallpaper, do superficial layer by PVC mantle, flexible polyurethane foams does intermediate layer, and antibacterial environment protection described in claim 1 is seamless wallpaper rice-straw fibre and flax fibre hybrid nonwoven cloth do bottom, carry out laminating make with make-up machine.
Test result is: vertical and horizontal ultimate strength is respectively 92N, 95N, and thickness is 0.141mm, and regain is 1.1%.
Claims (3)
1. the seamless wallpaper rice-straw fibre of antibacterial environment protection and a flax fibre hybrid nonwoven cloth, is characterized in that being made up of the raw material of following weight portion: straw 200-205, raw ramie 100-104, NaOH are appropriate, water is appropriate, polyvinyl alcohol 0.8-0.85, lignin 0.5-0.6, polyurethane acrylic resin 0.3-0.4, trifluoroethyl methacrylate 0.2-0.3, dodecafluoroheptyl methacrylate 0.2-0.3, ethyl acetate 5-6, tea tree ethereal oil 0.3-0.4, activated carbon fiber 2.5-3, nanometer polytetrafluoroethylcomposite 0.3-0.4, dicumyl peroxide 0.05-0.1.
2. the preparation method of the seamless wallpaper rice-straw fibre of antibacterial environment protection according to claim 1 and flax fibre hybrid nonwoven cloth, is characterized in that comprising the following steps:
(1) straw is cut into the section of 3-5cm, by straw: the weight ratio 1:20-21 of water adds water, by straw: the weight ratio 1:0.6-0.65 of NaOH adds NaOH, stir, be heated to 89-91 DEG C, stirring reaction 1.8-2h under heat-retaining condition, filter, cleaning to pH with water is 7-8, and drying, obtains rice-straw fibre;
(2) raw ramie is cut into the section of 3-5cm, by raw ramie: the weight ratio 1:20-21 of water adds water, by raw ramie grass: the weight ratio 1:0.1-0.12 of NaOH adds NaOH, stir, be heated to 89-91 DEG C, stirring reaction 1.5-1.6h under heat-retaining condition, filter, cleaning to pH with water is 7-8, and drying, obtains flax fibre;
(3) polyvinyl alcohol is added water be mixed with the solution of 8-8.5% concentration, add lignin, stir, obtain adhesive, get rice-straw fibre, each 50 weight portions of flax fibre, mix with activated carbon fiber, be placed in sizing in sizing net, be placed in acupuncture on needing machine again, be pressed into cloth, with described adhesive uniform application, resin added controls at 7-7.5%, to send in drying box dry 1.5-2h at 80-82 DEG C again, obtain nonwoven fabric;
(4) trifluoroethyl methacrylate, dodecafluoroheptyl methacrylate, ethyl acetate are mixed, add tea tree ethereal oil, polyurethane acrylic resin, nanometer polytetrafluoroethylcomposite, be heated to 65-70 DEG C, add dicumyl peroxide, stirring reaction 30-40 minute, obtains mixture, on the nonwoven fabric obtained in (3) step by mixture uniform application, drying, to obtain final product.
3. a seamless wallpaper, is characterized in that: do superficial layer by PVC mantle, flexible polyurethane foams does intermediate layer, and antibacterial environment protection described in claim 1 is seamless wallpaper rice-straw fibre and flax fibre hybrid nonwoven cloth do bottom, carry out laminating make with make-up machine.
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CN201510504919.9A CN105155137A (en) | 2015-08-17 | 2015-08-17 | Straw fiber and jute fiber blended non-woven fabric for warming anti-bacterial, environment-friendly and seamless wall paper and preparation method for non-woven fabric |
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Cited By (4)
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CN105908522A (en) * | 2016-04-22 | 2016-08-31 | 滁州市莎朗新材料科技有限公司 | Rice straw fiber and hemp fiber mixed non-woven fabrics for high-strength moistureproof seamless wallpaper and preparation method thereof |
CN105908521A (en) * | 2016-04-22 | 2016-08-31 | 滁州市莎朗新材料科技有限公司 | Rice straw fiber and hemp fiber mixed non-woven fabrics for tear-proof seamless wallpaper and preparation method thereof |
CN108656768A (en) * | 2018-03-16 | 2018-10-16 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of deposit receipt printing method |
CN112481810A (en) * | 2020-11-23 | 2021-03-12 | 舒城娃娃乐儿童用品有限公司 | Preparation method of non-glue soft cotton |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105908522A (en) * | 2016-04-22 | 2016-08-31 | 滁州市莎朗新材料科技有限公司 | Rice straw fiber and hemp fiber mixed non-woven fabrics for high-strength moistureproof seamless wallpaper and preparation method thereof |
CN105908521A (en) * | 2016-04-22 | 2016-08-31 | 滁州市莎朗新材料科技有限公司 | Rice straw fiber and hemp fiber mixed non-woven fabrics for tear-proof seamless wallpaper and preparation method thereof |
CN108656768A (en) * | 2018-03-16 | 2018-10-16 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of deposit receipt printing method |
CN112481810A (en) * | 2020-11-23 | 2021-03-12 | 舒城娃娃乐儿童用品有限公司 | Preparation method of non-glue soft cotton |
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Application publication date: 20151216 |